T (K)

599
629
647
666
683
700
1/T
0.001669449 0.001589825 0.001545595 0.001501502 0.001464129 0.001428571
k (dm/mol.s)
0.00054
0.0025
0.0052
0.014
0.025
0.064
Ln (k)
-7.523941418 -5.991464547 -5.259096653 -4.268697949 -3.688879454 -2.748872196

Ln k = Ln A - (E/R) . 1 / T
Ln A = 24.94
A (Lt/moL.s) =

1/T (1/K)

0.0014
0
-1
-2

Ln k

-3
-4
-5

-6
-7
-8

0.00145

0.0015

0.00155

0.0016

y = -19471x + 24.94

0.00165

0.0017

67811660440

R (atmLt/molK)
0.082
E/R = 19471
E (atmLt/mol) = 1596.622
E (kcal/mol) = 38.65421862

t (seg)

636

2040

3000

4000

7200

Conversin

CA
Ln CA/CA

10
0.1
0.09
0.105360516

25.7
0.257
0.0743
0.297059234

34
0.34
0.066
0.415515444

41
0.41
0.059
0.527632742

55.2
0.552
0.0448
0.802962047

1.111111111

3.458950202

5.151515152

6.949152542

12.32142857

1/CA - 1/CA

y = 0,0001x + 0,0763
R2 = 0,9857

0.9
0.8
Ln CA/CA

0.7
0.6

0.5
0.4
0.3
0.2
0.1
0
0

500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500
t (min)

k=

0.0001

y = 0.0017x + 0.017
R = 0.9999

14
12

1/CA-1/CA

10
8
6
4
2

0
0

1000

2000

3000

4000
t(seg)

k=

0.0017

5000

6000

0.1

Ca

5500 6000 6500 7000

6000

7000

8000

t (seg)
-

[I ]
CA

230

465

720

1040

1440

1920

2370

0.015

0.026

0.035

0.044

0.052

0.059

0.064

0.085

0.074

0.065

0.056

0.048

0.041

0.036

Ln CA/CA

0.162518929 0.301105093 0.430782916 0.579818495 0.733969175 0.891598119 1.021651248

1/CA - 1/CA

1.764705882 3.513513514 5.384615385 7.857142857 10.83333333

y = 0,0004x + 0,1238
R2 = 0,9856

1.2

Ln CA/CA

1
0.8

0.6
0.4

0.2
0
0

500

1000

1500

2000

2500

1500

2000

2500

1/CA - 1/CA

t (seg)

y = 0,0075x + 0,0354
R2 = 1

20
18
16
14
12
10
8
6
4
2
0
0

500

1000

t (seg)

14.3902439 17.77777778

CA(mol/Lt) = 0.1

t (seg)
P0 (torr)
P0 (atm)

634

393

255

212

R (atmLt/molK) =

0.082

86.5

164

290

360

T (K) =

1030

0.113815789 0.215789474 0.381578947 0.473684211

N=

Ca (mol/Lt) 0.00134757 0.002554931 0.004517866 0.005608385

CA(mol/Lt) 0.000673785 0.001277466 0.002258933 0.002804193
k.t
Ln (t )
Ln P0

742.0763006
391.4
221.3434483 178.3044444
6.452048954 5.973809612 5.541263545 5.356586275
4.460144414 5.099866428 5.669880923 5.886104031
y = 1,3465x - 119,65
R2 = 0,9972

800
700
600
k.t

500
400
300
200
100
0
0

100

200

300

400

500

600

700

Ln P

t (seg)

y = -1,3081x + 12,906
R2 = 0,9997

7
6
5
4
3
2
1
0
0

Ln (t )