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Methane Heat Capacity Data and Analysis

This document contains heat capacity (Cp) data for methane at different temperatures (T) ranging from 298K to 1500K. A polynomial regression was performed to fit the Cp vs T data, resulting in an equation of the form Cp = a0 + a1T + a2T^2, with coefficients a0 = 13.4365, a1 = 0.079778, and a2 = -2.1223E-5. The regression achieved an R^2 value of 0.99498, indicating an excellent fit to the experimental data points.

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0% found this document useful (0 votes)
101 views2 pages

Methane Heat Capacity Data and Analysis

This document contains heat capacity (Cp) data for methane at different temperatures (T) ranging from 298K to 1500K. A polynomial regression was performed to fit the Cp vs T data, resulting in an equation of the form Cp = a0 + a1T + a2T^2, with coefficients a0 = 13.4365, a1 = 0.079778, and a2 = -2.1223E-5. The regression achieved an R^2 value of 0.99498, indicating an excellent fit to the experimental data points.

Uploaded by

YTK96
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

#

1
2
3
4
5

Heat capacity of Methane


T, K
Cp, J/(mol-K)
298
35
600
55
900
66
1200
80
1500
85
1
1
1
1
1

X=

298
600
900
1200
1500
1
298
88804

XT =

1
600
360000

88804
360000
810000
1440000
2250000
1
900
810000

1
1200
1440000

1
1500
2250000

90
80

5
4498
4948804

XTX =

XTY =

4498
4948804
4948804
6074463592
6074463592 7.92969E+012

70

Cp / J60mol-1 K
50
40

321
326330
382818140

30
20
10

beta =

#
1
2
3
4
5

a0 =
a1 =
a2 =

T, K
298
600
900
1200
1500
Avg
R^2 =

13.43651107
0.079778447
-2.1223E-005

Cp, J/(mol-K)
35
55
66
80
85
64.2

0
200

Cp*
35.3
53.7
68.0
78.6
85.4

f(
R

Cp - Cp av Cp
852.6
84.6
3.2
249.6
432.6
Sum 1622.8

- Cp*
0.1
1.8
4.2
1.9
0.1
8.1

0.994984823 = 1 - sum(Cp - Cp*)^2 / sum(Cp - Cp av)^2

Cp, J/(mol-K)
90
80
70

f(x) = - 2.12225032727392E-005x^2 + 0.0797784468x + 13.4365110719


R = 0.994984823

Cp / J60mol-1 K-1
50

Cp, J/(mol-K)

40

Polynomial (Cp, J/(mol-K))

30
20
10
0
200

400

600

800

1000
T/K

1200

1400

1600

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