PROBLEMA 9.

CRANK NICHLSON
DAB = 0.05568
Delta t = 300

Se tiene n-octano lquido a 20 C y 1 atm. que se evapora

difunde a travs de N2. El nivel del n-octano se mantiene
constante. La concentracin de en la interfase lquido
xA0 = PAvap/P, siendo la presin de vapor a 20 C 10.4
Hg.

cm2/seg
seg

Delta Z = 10

cm

Asumir que la solubilidad de N2 en n-octano es desprec

que la temperatura y presin son constantes y que los g
comportan idealmente.

Beta = 0.08352
CONDICIONES
LIMITE
X( z, 0 ) = 0

Graficar el perfil de concentracin.

X( 0, t ) = 0.01375
X( L, t ) = 0
0

TIEMPO
seg

1.16704
-0.08352
0
0

DISTANCIA cm
0

10

20

30

0.01375

300

0.01375

0.001978

600

0.01375

900

40
0

50
0

0.000142

0.000010 0.000001

0.003425

0.000493

0.000053 0.000005

0.01375

0.004515

0.000934

0.000142 0.000018

1200

0.01375

0.005358

0.001403

0.000273 0.000042

1500

0.01375

0.006026

0.001867

0.000437 0.000081

1800

0.01375

0.006568

0.002310

0.000626 0.000134

2100

0.01375

0.007016

0.002725

0.000831 0.000200

2400

0.01375

0.007393

0.003111

0.001045 0.000277

2700

0.01375

0.007716

0.003467

0.001262 0.000363

10

3000

0.01375

0.007995

0.003795

0.001479 0.000455

11

3300

0.01375

0.008239

0.004097

0.001693 0.000552

12

3600

0.01375

0.008455

0.004376

0.001901 0.000651

13

3900

0.01375

0.008647

0.004634

0.002102 0.000751

I=0
I=1
I=2
I=3
I=4
I=5
T(0,J+1)
T(5,J+1)

j=0
T(i,j)
0.01375
0
0
0
0
0
0.01375
0

MATRIZ A
-0.08352
1.16704
-0.08352
0

C
0.0022968
0
0
0

0.016
0.014
0.012
0.01
0.008
XA

i
j

0.006
0.004
0.002
0
-0.002

20

20 C y 1 atm. que se evapora y

octano se mantiene
n de en la interfase lquido-gas es
presin de vapor a 20 C 10.45 mm

-octano es despreciable,
n son constantes y que los gases se

MATRIZ A
0
-0.08352
1.16704
-0.08352
J=1
T(i,j)
0.01375
0.00197824
0.00014231
1.0237E-05
7.326E-07
0
0.01375
0

0
0
-0.08352
1.16704

C
0.0039565
0.0002846
2.047E-05
1.465E-06

0.861302773
0.061958674
0.004456941
0.000318964

INVERSA DE A
0.06195867 0.0044569 0.000319
0.86575971 0.0622776 0.0044569
0.06227764 0.8657597 0.0619587
0.00445694 0.0619587 0.8613028

J=2
J =3
T(i,j)
C
T(i,j)
0.01375
0.01375
0.0034255 0.005191227 0.00451504
0.0004928 0.00070104 0.00093396
5.317E-05 8.5876E-05 0.00014168
5.061E-06 8.65673E-06 1.7557E-05
0
0
0.01375
0.01375
0
0

300 seg
600 seg
900 seg
1200 seg
1500 seg
2100 seg
2400 seg
2700 seg
3000
3300 seg

20

40

60

3600 seg
3900 seg

Z (cm)

4200 seg

C
0.0061357
0.0011669
0.0001975
2.646E-05

J=4
T(i,j)
0.01375
0.0053578
0.0014028
0.0002726
4.218E-05
0
0.01375
0

C
0.00687683
0.00163874
0.00034778
5.7906E-05

Z (cm)

4200 seg

J=5
T(i,j)
0.01375
0.006026135
0.001866754
0.000437385
8.09193E-05
0
0.01375
0

C
0.00747224
0.00209476
0.00052699
0.00010393

J=6
T(i,j)
0.01375
0.006568033
0.002309816
0.00062645
0.000133889
0
0.01375
0

C
0.00796062
0.00252487
0.00072591
0.00016385

J=7
T(i,j)
0.01375
0.007016233
0.002725096
0.000831335
0.000199889
0
0.01375
0

C
0.00836864
0.00292533
0.00093676
0.00023593

J=8
T(i,j)
0.01375
0.007393434
0.003110529
0.001045111
0.000276957
0
0.01375
0

C
0.00871503
0.00329573
0.00115346
0.00031798

J=9
T(i,j)
0.01375
0.00771572
0.00346654
0.00126241
0.00036281
0
0.01375
0

C
0.00901321
0.00363734
0.00137137
0.00040765

J=10
T(i,j)
0.01375
0.00799471
0.00379473
0.00147923
0.00045516
0
0.01375
0

C
0.00927301
0.00395212
0.00158709
0.00050268

J=11
T(i,j)
0.01375
0.00823897
0.00409721
0.00169264
0.00055186
0
0.01375
0

C
0.00950173
0.0042423
0.00179819
0.00060105

J=12
T(i,j)
0.01375
0.00845492
0.00437619
0.00190059
0.00065104
0
0.01375
0

C
0.00970491
0.00451009
0.00200299
0.00070103

J=13
T(i,j)
0.01375
0.008647457
0.004633822
0.002101676
0.000751094
0
0.01375
0