TEST Series Chemistry Test - 1

Test Report Student Details Name Harpriya Test Date: 11Jul2012

Subject

Chemistry

Time Allotted: 30

Class

XI-Science

Max Marks 15 View Solutions

Your Score 5

Your Percentage Score 33.00%

Topper's Score 14

Your Grade F

Q1. If the temperature of a substance on the Celsius scale is 75C, then what would be its temperature on the Fahrenheit scale? A: B: C: D: 30F 75F 167F 348F

The relationship between the temperatures on Celsius scale and Fahrenheit scale is given by

Temperature of the substance on Celsius scale = 75C [Given]

Therefore, temperature of the substance on Fahrenheit scale = = [9 15 + 32]F = [135 + 32]F = 167F The correct answer is C.

Q2. Under standard temperature and pressure conditions, the number of gram-atoms of nitrogen in a sample of 10 cm3 of nitrogen will be A: B: C: D: 2.23 104 4.46 104 2.23 104 4.46 104

At STP, 22 400 cm3of nitrogen = 1 g-atom of nitrogen 10 cm3 of nitrogen

The correct answer is B.

Q3. 45 g of hydrogen and 104 g of oxygen are mixed to produce water. How many grams of water are produced in the given reaction?

A: B: C: D:

117 g 149 g 312 g 405 g

The balanced chemical equation for the given chemical reaction is represented as

It can be concluded from the balanced chemical equation that 2 moles of hydrogen react with 1 mole of oxygen to produce 2 moles of water i.e., to produce water, 4 g of hydrogen reacts with 32 g of oxygen to form 36 g of water.

Therefore, 45 g of hydrogen reacts with

of oxygen i.e., 360 g of oxygen.

However, only 104 g of oxygen is available for the reaction. Therefore, in this case, oxygen is the limiting reagent. Thus, water is formed only with the available amount of oxygen. 32 g of oxygen produces 36 g of water.

Therefore, 104 g of oxygen produces The correct answer is A.

of water i.e., 117 g of water.

Q4. Use the following information to answer the next question. Pure zinc can be produced in the following manner: 2ZnS + 3O2 2ZnO + 2SO2.. (1) ZnO + CO Zn + CO2 .. (2) If 5.12 kg of ZnS yields 3.07 kg of pure zinc, then the percentage yield will be

A: B: C: D: Molar mass of ZnS = (65.39 + 32.07) = 97.46 gmol1 The number of moles of ZnS = (5 120/97.46) = 52.5

50.4 % 62.7 % 77.6 % 89.4 %

Equation (1) can be written as ZnS + On adding equation (2), one gets

O2 ZnO + SO2

ZnS +

O2 ZnO + SO2

ZnO + CO Zn + CO2 ZnS + 3/2O2+ CO SO2 + Zn + CO2 .. (3)

It can be determined from equation (3) that 1 mole of ZnS yields 1 mole of Zn, or 52.5 moles of ZnS yields 52.5 moles of Zn. Therefore, the mass of Zn = (52.5 65.39) = 3432.98 g The actual yield is 3.07 kg. Therefore, percentage yield = (3.07/3.433) = 0.894 = 89.4 % The correct answer is D. 3.433 kg

Q5. Use the following information to answer the next question.

42 gram of iron can be converted into its oxide (Fe3O4) by the action of 18 gram of steam on it. The balanced chemical equation of this reaction is represented as

What volume of hydrogen gas is liberated by 42 g of iron? A: B: C: D: 1 mole of Fe = 56 g 3 moles of Fe = 168 g 4 moles of H2 = = 89.6 L According to the given balanced chemical equation, 168 g of iron will produce 89.6 L of H2. 11.2 L 22.4 L 44.8 L 89.6 L

42 g of iron = = 22.4L of H2 The correct answer is B.

Q6. Use the following information to answer the next question. A chemical compound containing 31.1 per cent iron, 53.3 per cent oxygen, and 15.6 per cent nitrogen is prepared by dissolving iron in cold dilute nitric acid. If the molecular mass of the compound is 180 gmol1, then its molecular formula will be

A: B: C: D:

Fe(NO3)2 FeNO3 Fe2NO3 Fe(NO3)3 Atomic Mass (amu) 56 14 16 Relative number of moles 31.1/56 = 0.555 15.6/14 = 1.114 53.3/16 = 3.33 Simplest ratio of moles 0.555/0.555 = 1 1.114/0.555 2 3.330/0.555 = 6

element

Percentage

Fe N O

31.1 15.6 53.3

Therefore, the empirical formula of the compound will be FeN2O6. Molecular mass of the empirical formula = {56 + (2 14) + (16 6)} = 180 gmol1 Since the molecular formula mass of the compound is equal to its empirical formula mass; therefore, the molecular formula of the compound will be FeN2O6or Fe(NO3)2. The correct answer is A.

Q7. Which one of the following arrangements is the correct order of the number of molecules present in 400 mL each of Cl2, NO2, SO2, and CO at STP? A: B: C: D: SO2> NO2 > Cl2 > CO NO2> SO2 > Cl2 > CO NO2> SO2 > CO > Cl2 NO2= SO2 = CO = Cl2

At STP, 22.4 L of a gas contains 6.023 1023 molecules. 22 400 mL contains 6.023 1023 molecules.

400 mL will contain = = 1.075 1022molecules

400

Thus, irrespective of the compound, at STP, 400 mL of any compound will always contain 1.075 1022 molecules, i.e., the same number of molecules. The correct answer is D.

Q8. Which of the following factors influences the actual atomic weight of an element? A: B: C: D: The mass number of isotopes and the relative abundance of isotones The mass number of isotopes and the relative abundance of these isotopes The mass number of isotones and the relative abundance of these isotones The mass number of isotones and the relative abundance of isotopes

The actual atomic weight of an element depends on (i) the mass number of isotopes, and (ii) relative abundance of these isotopes The correct answer is B.

Q9. Use the following information to answer the next question.

The molality of a solution of KCl (molar mass = 74.5 g mol1) in water is 3 m.

What is the mass percent of KCl in the solution? A: B: C: D: 1 mole of KCl = 74.5 g of KCl In 3 m solution of KCl in water, 1000 g of water contains 3 moles of KCl. i.e., 1000 g of water contains 3 74.5 g of KCl i.e., 223.5 g of KCl. 18.27% 22.35% 77.65% 81.73%

Therefore, mass percent of KCl =

The correct answer is A.

Q10. Which of the following units is the SI unit of pressure? A: B: C: D: Atmosphere Pascal Bar Torr

In order to answer this question correctly, the student must know that the S.I. unit of pressure is Pascal and is equivalent to the force of 1 N per unit area

. The correct answer is B. Why alternative A is wrong: Atmosphere is not an S.I. unit of pressure. One atm or 101325 Pascal calculates the mean atmosphere pressure at sea level. Thus, this alternative is incorrect. Why alternative C is wrong: Bar is not the S.I unit and its value is equal to 100 000 Pascals. Thus, this alternative is incorrect. Why alternative D is wrong: The unit mm/hg is known as Torr and is equal to 133.3224 Pascals. Thus, this alternative is incorrect.

Q11. The multiplication of the significant figures of numbers 3.05 and 5.20 gives A: B: C: D: The given numbers can be multiplied as 3.050 5.20 = 15.860 Here, number 5.20 has three significant figures. Therefore, the result should also have only three significant figures. Moreover, if the second digit after the decimal is greater than 5, then the preceding number is increased by 1. Hence, the result will be 15.9. The correct answer is B. 15.8 15.9 15.86 15.860

Q12. Use the following information to answer the next question. Sodium hydroxide (NaOH) reacts with hydrochloric acid (HCl) to produce sodium chloride (NaCl) and water (H2O). The balanced chemical equation of this reaction is represented as

How many grams of NaCl are produced from 50 mL of 0.5 M NaOH? A: B: C: D: 1.46 g 2.92 g 4.38 g 5.84 g

In 0.5 M NaOH solution, 1000 mL solution contains 0.5 mole of NaOH.

Therefore, 50 mL solution contains In the given reaction, 1 mole of NaOH gives 1 mole of NaCl.

mole of NaOH i.e., 0.025 mole of NaOH.

Therefore, 0.025 mole of NaOH will give 0.025 mole of NaCl. Molar mass of NaCl = 58.5 g mol1 i.e., 1 mole of NaCl = 58.5 g of NaCl Therefore, 0.025 mole of NaCl = (58.5 0.025) g of NaCl = 1.46 g (approx.) Thus, 1.46 g of NaCl is produced from 50 mL of 0.5 M NaOH solution. The correct answer is A.

Q13. Molar mass of a substance when divided by Avogadro number, gives the

A: B: C: D:

absolute mass of a single atom molecularmass of a single atom absolute masses of all atoms present in it molecular masses of all atoms present in it

This question requires the student to know Avogadros number. Molar mass of a substance when divided by Avogadro number, gives the absolute mass of a single atom. The correct answer is A.

Q14. Use the following information to answer the next question. In an experiment, Maria dissolved 19 g of sugar (C12H22O11) in water, making a 300 mL solution. What is the concentration of the solution prepared by Maria? A: B: C: D: 0.555 molL1 0.183 molL1 3.66 104molL1 1.83 104molL1

The molar mass of sugar (C12H22O11) = {(12 12) + (22 1) + (11 16)}= 342 gmol1 the number of moles in 19 g of sugar = (19/342) = 0.055 The concentration of sugar in 300 mL of the solution = {0.055 (1000/300)} = 0.183 molL1 The correct answer is B.

Q15.

Use the following information to answer the next question.

During an investigation, the police deduced that the victim was given a glass of water which contained chloroform, a carcinogen with a contamination level of 83 ppm by mass. The percent by mass of the solution and molality of the chloroform in water samples were calculated by forensic experts. The percent by mass was calculated as____I____ % and molality of chloroform in the water sample was calculated as____II____ m.

Which of the following ralternative completes the above statement correctly? A: I II

0.001 9 0.000 542

B:

II

0.008 3 0.000 695

C:

II

0.000 542 0.001 9

D:

II

0.000 695 0.008 3 In order to answer this question correctly, the student must know how to calculate the molality and percentage using the mass of a compound. Since the level of contamination is 83 ppm, Mass of solution = 106g Mass of solute (WB) = 83 g

Percentage by mass = Where WA+ WB= mass of solvent + mass of solute = 106g

 Percentage by mass = Mass of solvent (WA) = 106 83 = 999 917 g Molar mass of chloroform (CHCl3) = (12 1) + (1 1) + (35.5 3) = 119.5 g

Molality (m) of chloroform = 6.95 104m = 0.000 695 m The correct answer is B.