Professional Documents
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Penalties for Late The score for an assessment item submitted after the
Assignments/ designated time on the due date, without an approved
Assessments extension of time, will be reduced by 5% of the
possible maximum score for that assessment item for
each day or part-day that the assessment item is late.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
CC’s Voice: Hello everyone! Welcome to the exciting world of Chemistry! You are
about to undertake a journey where you will acquire a new
understanding of the world around you—the cloths you wear, the food
you eat, the medicine you take, the flesh you are made of, the means of
transportation you use, even the smallest microchips built into your
computer and other gadgets. Everything in all aspects of life are related
to chemistry. Welcome to this course CHEM 205: General Inorganic
Chemistry 1.
CO Before the actual teaching performance, you are expected to describe the
structure and function of atoms, ions, and elements, molecules and
compounds and chemical bonds. Interpret periodic properties, molecular
structure and chemical equations and relate the different chemical
principles and nature of matter to everyday situation.
Let us begin!
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
BIG PICTURE
WEEK 1-2
Unit Learning Outcomes (ULO): At the end of the unit, you are expected to
METALANGUAGE
In this section, the most essential terms relevant to the study of curriculum and
to demonstrate ULOa will be operationally defined to establish a common frame of
reference as to how the texts work in your chosen field or career. You will encounter
these terms as we go through the study of curriculum. Please refer to these definitions
in case you will encounter difficulty in the in understanding educational concepts.
1. Chemistry. The branch of science that deals with the identification of the
substances of which matter is composed; the investigation of their properties
and the ways in which they interact, combine, and change; and the use of these
processes to form new substances.
a. Pure Chemistry. Is pure research in the field of chemistry. This is the
'how', 'what', and 'why' of science.
b. Applied Chemistry. Uses our existing knowledge about all things
chemistry tries to make it useful.
2. Technology. can be most broadly defined as the entities, both material and
immaterial, created by the application of mental and physical effort in order to
achieve some value.
3. Scientific Method. a method of procedure that has characterized natural
science since the 17th century, consisting in systematic observation,
measurement, and experiment, and the formulation, testing, and modification
of hypotheses.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
4. Variables. A variable is any factor, trait, or condition that can exist in differing
amounts or types. An experiment usually has three kinds of variables:
independent, dependent, and controlled.
a. Controlled Variables: These are parts of the experiment that you try to
keep constant throughout an experiment so that they won't interfere with
your test.
b. Independent Variable: This is the variable you control.
c. Dependent Variable: This is the variable you measure. It is called
the dependent variable because it depends on the independent
variable.
Source: https://www.wikipedia.org/
ESSENTIAL KNOWLEDGE
CHEMISTRY AND OTHER SCIENCES
Science is concerned with studying the world, the universe. Ours is a universe
of matter in various forms; we live in a material world. Thus, chemistry, plays a
fundamental role in all fields of science. Biology is a very good example. The progress
of the study of structures, functions and processes on the extent to which the study is
done at the atomic or molecular level. A better understanding of life and living
organisms was achieved when biologists became able to look beyond the appearance
of an organism and determine the function of its parts. They began examining the
structure and function of organisms at the molecular level. For example, genes have
been known for some time as the units responsible for the inheritance of traits. Our
understanding of heredity grew tremendously when we learned how segments of a
gene therefore codes for a specific sequence of amino acids that make up a protein.
to chemistry. Chemistry is the study of the composition of matter, its properties, and
the changes it undergoes. It is a part of a body of knowledge called science. It is
considered a practical science because it makes us understand our environment and
how it works. Chemistry is called the central science because it plays a role in almost
all profession. It overlaps with many other sciences.
Source: https://ibiologia.com/branches-of-chemistry/
The chart above relating the various branches of chemistry. It is further divided
into five fundamental branches:
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
The number of steps can vary from one description to another (which mainly
happens when data and analysis are separated into separate steps), however, this is
a fairly standard list of the six scientific method steps that you are expected to know
for any science class:
Formal observations are a type of brainstorming that can help you find an idea
and form a hypothesis. Observe your subject and record everything about it. Include
colors, timing, sounds, temperatures, changes, behavior, and anything that strikes you
as interesting or significant.
Variables. When you design an experiment, you are controlling and measuring
variables. There are three types of variables:
9|P a ge
College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Source: https://teachersinstitute.yale.edu/curriculum/units/2009/3/09.03.02/2
https://www.youtube.com/watch?v=yi0hwFDQTSQ
SELF-HELP: You can also refer to the sources below to help you
further understand the lesson.
Babaev, E. (2019). Periodic law in chemistry and other sciences. Pure and Applied
Chemistry.Chimie Pure Et Appliquee, 91(12), 2023-2035.
doi:http://dx.doi.org/10.1515/pac-2019-0821
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
LET’S CHECK
Activity #1. Let us try to check your understanding of the topics. In the space
provided, write the answer being asked in the following statements:
1. What is chemistry?
______________________________________________________________
2. What branch of chemistry would study the amount of mercury present in a soil
sample?Explain.
______________________________________________________________
______________________________________________________________
4. What branch of chemistry would develop a new carbon-based fiber for clothing?
Explain.
______________________________________________________________
______________________________________________________________
5. What branch of chemistry would study all other elements except carbon based
materials? Explain.
______________________________________________________________
______________________________________________________________
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Activity #2. Let us try to check your understanding on the topic scientific method:
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
LET’S ANALYZE
Activity #3. In this activity, you are required once again to elaborate your answer
to each of the questions below.
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
What tools or equipment will you need to collect the data from your
experiment?
______________________________________________________________
______________________________________________________________
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
IN A NUTSHELL
Activity #4. Albert Einstein, in a speech at the California Institute of technology
in February 1931, said:
“Concern for man and his fate must always form the chief interest of all
technical endeavors…in order that the creations of our mind shall be a blessing
and not a curse to mankind.”
Activity #5. Contrary to common belief, the scientific method is applicable not only to
scientific studies but also to ordinary life situations.
Choose one problem that you encounter everyday. Using the scientific
method, propose how you will solve that problem.
______________________________________________________________
______________________________________________________________
______________________________________________________________
______________________________________________________________
______________________________________________________________
______________________________________________________________
Q&A LIST
Do you have any questions for clarification?
QUESTIONS ANSWERS
1.
2.
3.
4.
5.
KEYWORDS INDEX
chemistry variables data
technology experiment problem
scientific method hypothesis conclusion
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
METALANGUAGE
For you to demonstrate ULOb, you will need to have an operational
understanding of the following terms below.
Source: https://www.wikipedia.org/
ESSENTIAL KNOWLEDGE
SCIENTIFIC MEASUREMENTS
Source: https://wps.prenhall.com/wps/media/objects/165/169061/CH01_1.4_Main.html
Uncertainties in Measurement
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
The best measurements are those which both precise and accurate. Accuracy
is how close a measurement is to the correct value for that measurement. The
precision of a measurement system is referring to how close the agreement is
between repeated measurements (which are repeated under the same conditions).
Measurements can be both accurate and precise, accurate but not precise, precise
but not accurate, or neither.
The more measurements that are taken, the closer we can get to knowing a
quantity’s true value. With multiple measurements (replicates), we can judge the
precision of the results, and then apply simple statistics to estimate how close the
mean value would be to the true value if there was no systematic error in the system.
The mean deviates from the “true value” less as the number of measurements
increases.
Temperature
There are three temperature scales being used. These are the Celsius (formerly
Centigrade), the Fahrenheit, and the Kelvin scales. Their units are 0C (degrees
Celsius), 0F (degrees Fahrenheit), and K (kelvins), respectively.
Two commonly-fixed points are the temperature at which water freezes and the
temperature at which water boils at standard atmospheric pressure. On the Celsius
scale, the freezing point of water is 0 0C and its boiling point is 100 0C. the interval
between these points is divided into 100 equal parts. On the Fahrenheit scale, the
freezing point of water is 32 0F and the boiling point is 212 0F. The interval between
these points is divided into 180 equal parts. On the Kelvin scale, the freezing point of
water is 273 K and the boiling point is 373 K. notice that on the Kelvin scale, the degree
sign is not used. The degree interval on the kelvin scale is the same as in the Celsius
scale. The zero point on the Kelvin scale is 0 K, is called the absolute zero temperature
and is equal to -273 0C.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Significant Figures
1. All non-zero digits are considered significant. For example, 91 has two significant
figures (9 and 1), while 123.45 has five significant figures (1, 2, 3, 4, and 5).
2. Zeros appearing between two non-zero digits (trapped zeros) are significant.
Example: 101.12 has five significant figures: 1, 0, 1, 1, and 2.
3. Leading zeros (zeros before non-zero numbers) are not significant. For example,
0.00052 has two significant figures: 5 and 2.
4. Trailing zeros (zeros after non-zero numbers) in a number without a decimal are
generally not significant (see below for more details). For example, 400 has only
one significant figure (4). The trailing zeros do not count as significant.
5. Trailing zeros in a number containing a decimal point are significant. For
example, 12.2300 has six significant figures: 1, 2, 2, 3, 0, and 0. The number
0.000122300 still has only six significant figures (the zeros before the 1 are not
significant). In addition, 120.00 has five significant figures since it has three
trailing zeros. This convention clarifies the precision of such numbers. For
example, if a measurement that is precise to four decimal places (0.0001) is
given as 12.23, then the measurement might be understood as having only two
decimal places of precision available. Stating the result as 12.2300 makes it
clear that the measurement is precise to four decimal places (in this case, six
significant figures).
6. The number 0 has one significant figure. Therefore, any zeros after the decimal
point are also significant. Example: 0.00 has three significant figures.
7. Any numbers in scientific notation are considered significant. For example, 4.300
x 10-4 has 4 significant figures.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Scientific Notation
Many numbers used in chemistry are either very large or very small that the
number of zeros becomes difficulty to handle. For accuracy and convenience, these
numbers are written in scientific notation. A number in scientific notation has two parts.
The first part is a number between 1 and 10 (N). The second part is a power of 10
(10y) as show below
N x 10y
The exponent y can be a positive or a negative integer.
To write numbers in scientific notation, move the decimal point such that you
have a number between 1 and 10. Determine the correct exponent by counting the
number of times the decimal point is moved. When the decimal point is moved to the
right, the exponent is written as a negative number. When decimal point is moved to
the left, the exponent is written as a positive number.
Examples:
0.00567 5.67 x 10-3 ; 456,000 4.56 x 105
0.0145 1.45 x 10-2 ; 3,890,000 3.89 x 106
https://www.youtube.com/watch?v=oAtDAoqdExw
SELF-HELP: You can also refer to the sources below to help you
further understand the lesson.
Vaghela, H. (2017). A proposed technique for automatic sample placing for scientific
measurements. Piscataway: The Institute of Electrical and Electronics
Engineers, Inc. (IEEE). Retrieved from
https://search.proquest.com/docview/2029211446?accountid=31259
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
LET’S CHECK
Activity #6. Based on your understanding on the lesson about measurements,
answer the following:
f. 52,400 _________________________________
g. 1,005,000 _________________________________
h. 0.000,543 _________________________________
i. 0.000,000,870 _________________________________
j. 3.5 _________________________________
C. Mark has a high fever with a body temperature of 104 0F. What is his
temperature in;
k. Celsius scale _________________________________
l. Kelvin scale _________________________________
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
LET’S ANALYZE
Activity #8. Many times when a series of contractors are working on plans, the
units of measurement are sometimes lost and they need to decipher the
pattern that the other builders used.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
IN A NUTSHELL
Activity #9. Look around your house at all of the items with listed measurements
on packages. Notice that most usually have both the English
measurements and the metric measurements. For this activity you will
practice recording and paying attention to the metric measurements of
common household items.
You are not taking the measurements; you are simply reading the
measurements that are labeled on the package. However, if you have
instruments to measure with using the metric system, you can include those
also.
Below is an example of what how you should construct your data table:
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Q&A LIST
Do you have any questions for clarification?
QUESTIONS ANSWERS
1.
2.
3.
4.
5.
KEYWORDS INDEX
METALANGUAGE
Below are the essential terms that you are going to encounter in the pursuit of
ULOc. You will encounter these terms as we go through the study of curriculum.
Please refer to these definitions in case you will encounter difficulty in the in
understanding educational concepts.
1. Matter. Matter is anything that has mass and takes up space. At a minimum,
matter requires at least one subatomic particle, although most matter
consists of atoms.
2. Phases of matter. One of the distinct forms in which matter can exist. Four
states of matter are observable in everyday life: solid, liquid, gas,
and plasma.
3. Element. A substance whose atoms all have the same number of protons:
another way of saying this is that all of a particular element's atoms have
the same atomic number. Elements are chemically the simplest substances
and hence cannot be broken down using chemical reactions.
4. Atom. Smallest unit into which matter can be divided without the release of
electrically charged particles. It also is the smallest unit of matter that has
the characteristic properties of a chemical element. As such, the atom is the
basic building block of chemistry.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Source: https://www.wikipedia.org/
ESSENTIAL KNOWLEDGE
WAYS OF CLASSIFYING MATTER
From your everyday experience, you know that matter exists in different states
or phases. Matter is the "stuff" that makes up the universe — everything that takes up
space and has mass is matter. All matter is made up of atoms, which are in turn made
up of subatomic particles namely; protons (positively charge), neutrons (zero charge)
and electrons (negatively charge). There are four natural states of matter: Solids,
liquids, gases and plasma.
particles in a solid have very low kinetic energy. Solids have a definite shape,
as well as mass and volume, and do not conform to the shape of the container
in which they are placed. Solids also have a high density, meaning that the
particles are tightly packed together.
Liquids. In a liquid, the particles are more loosely packed than in a solid
and are able to flow around each other, giving the liquid an indefinite shape.
Therefore, the liquid will conform to the shape of its container. Much like solids,
liquids (most of which have a lower density than solids) are incredibly difficult
to compress.
Gases. In a gas, the particles have a great deal of space between them
and have high kinetic energy. A gas has no definite shape or volume. If
unconfined, the particles of a gas will spread out indefinitely; if confined, the
gas will expand to fill its container. When a gas is put under pressure by
reducing the volume of the container, the space between particles is reduced
and the gas is compressed.
Source: https://www.britannica.com/science/phase-state-of-matter
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Changes of Phase
There are four states of matter in the universe: plasma, gas, liquid and solid.
But, matter on Earth exists mostly in three distinct phases: gas, liquid and solid. A
phase is a distinctive form of a substance, and matter can change among the
phases. It may take extreme temperature, pressure or energy, but all matter can be
changed.
There are six distinct changes of phase which happens to different substances at
different temperatures. The six changes are:
Source: https://www.123rf.com/photo_48796158_stock-vector-phase-change-of-water.html
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
elements are found in different proportions, and some elements common to living
organisms are relatively rare on the earth as a whole. All elements and the chemical
reactions between them obey the same chemical and physical laws, regardless of
whether they are a part of the living or nonliving world.
An atom is the smallest unit of matter that retains all of the chemical properties
of an element. For example, a gold coin is simply a very large number of gold atoms
molded into the shape of a coin, with small amounts of other, contaminating elements.
Gold atoms cannot be broken down into anything smaller while still retaining the
properties of gold. A gold atom gets its properties from the tiny subatomic particles it's
made up of.
An atom consists of two regions. The first is the tiny atomic nucleus, which is
in the center of the atom and contains positively charged particles called protons and
neutral, uncharged, particles called neutrons. The second, much larger, region of the
atom is a “cloud” of electrons, negatively charged particles that orbit around the
nucleus. The attraction between the positively charged protons and negatively
charged electrons holds the atom together. Most atoms contain all three of these types
of subatomic particles—protons, electrons, and neutrons. Hydrogen (H) is an
exception because it typically has one proton and one electron, but no neutrons. The
number of protons in the nucleus determines which element an atom is, while the
number of electrons surrounding the nucleus determines which kind of reactions the
atom will undergo. The three types of subatomic particles are illustrated below for an
atom of helium—which, by definition, contains two protons.
Source: https://pngio.com/images/png-a1355972.html
Structure of an atom. The protons (positive charge) and neutrons (neutral charge) are
found together in the tiny nucleus at the center of the atom. The electrons (negative
charge) occupy a large, spherical cloud surrounding the nucleus.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Properties of Matter
All matter has physical and chemical properties. Physical properties are
characteristics that scientists can measure without changing the composition of the
sample under study, such as mass, color, and volume (the amount of space occupied
by a sample). Chemical properties describe the characteristic ability of a substance
to react to form new substances; they include its flammability and susceptibility to
corrosion. All samples of a pure substance have the same chemical and physical
properties. For example, pure copper is always a reddish-brown solid (a physical
property) and always dissolves in dilute nitric acid to produce a blue solution and a
brown gas (a chemical property).
Changes in Matter
Classification of Matter
Matter classified into two types, the Pure Substance and Mixture.
1. Pure Substance. Same types of atoms or molecules comprise pure matters.
They have some distinguishing properties. There are two pure matters,
elements and compounds. Iron, alcohol, salt are examples of pure matters.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
2. Mixture. Different two or more than two types of matter (element, molecule,
compound) are mixed to get mixture. All matters forming mixture keep their
original properties. They are not pure matters. We can explain mixtures under
two titles, homogeneous mixtures and heterogeneous mixtures.
a. Homogeneous Mixtures: All parts of mixture show same properties
in homogeneous mixtures. We can call homogeneous mixtures as
solutions. Salt water, sugar water, air are examples of homogeneous
mixtures.
b) Heterogeneous Mixtures: Mixtures do not show same uniformity in
all parts of it. In this types of mixtures, you can see different phases of
matters. Water+Sand, milk, blood, soil are some common examples of
heterogeneous mixtures.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Source: http://selfstudy.co/sp/jee/chemistry/basic-concepts-of-chemistry/mole-concept
https://www.youtube.com/watch?v=NUskg2qWLPQ
Self-Help: You can also refer to the sources below to help you further
understand the lesson.
LET’S CHECK
Activity #10. Using your knowledge about matter, answer the following:
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
___________________21. You leave your bicycle out in the rain and it rusts.
___________________22. A sugar cube dissolves.
___________________23. Scientist break-up water into oxygen and hydrogen gas.
___________________24. Burning coal for a barbecue.
___________________25. Trimming a bush because it has grown too tall.
LET’S ANALYZE
Activity #11. Classify each of the following substances as an element, a
compound, a homogenousmixture, or a heterogeneous
mixture.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
IN A NUTSHELL
Activity #13. In this activity, you are required once again to elaborate your
answer to each of the questions below.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Compound: ______________________________________________
Mixture: _________________________________________________
Pure Substance: __________________________________________
Element: ________________________________________________
Matter: _________________________________________________
Q&A LIST
Do you have any questions for clarification?
QUESTIONS ANSWERS
1.
2.
3.
4.
5.
KEYWORDS INDEX
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
WEEK 4-5
Unit Learning Outcomes (ULO): At the end of the unit, you are expected to
METALANGUAGE
The most essential terms below are operationally defined for you to have a
better understanding of this section in the course.
1. Atoms. Smallest unit into which matter can be divided without the release of
electrically charged particles. It also is the smallest unit of matter that has the
characteristic properties of a chemical element. As such, the atom is the basic
building block of chemistry.
2. Subatomic particles. It also called elementary particle, any of various self-
contained units of matter or energy that are the fundamental constituents of all
matter. Subatomic particles include electrons, the negatively charged, almost
massless particles that nevertheless account for most of the size of the atom,
and they include the heavier building blocks of the small but very dense nucleus
of the atom, the positively charged protons and the electrically
neutral neutrons.
3. Isotopes. Each of two or more forms of the same element that contain equal
numbers of protons but different numbers of neutrons in their nuclei, and hence
differ in relative atomic mass but not in chemical properties; in particular, a
radioactive form of an element.
4. Atomic Number. the number of protons in the nucleus of an atom, which
determines the chemical properties of an element and its place in the periodic
table.
5. Atomic Mass. the mass of an atom of a chemical element expressed in atomic
mass units. It is approximately equivalent to the number of protons and
neutrons in the atom (the mass number) or to the average number allowing for
the relative abundances of different isotopes.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
Source: https://www.wikipedia.org/
ESSENTIAL KNOWLEDGE
Everything in this world is made up of matter which in turn is made up of atoms.
These atoms, held closely together to form molecules.
The concept of the atom was revisited and elaborated upon by many scientists
and philosophers, including Galileo, Newton, Boyle, and Lavoisier. In 1661, Boyle
presented a discussion of atoms in his The Sceptical Chymist. However, the English
chemist and meteorologist John Dalton is credited with the first modern atomic theory,
as explained in his A New System of Chemical Philosophy.
Dalton also outlined a law of multiple proportions, which described how reactants
will combine in set ratios. Like the early philosophers, Dalton’s theories were not
popularly accepted for much of the 19 th century, but his ideas have since been
accepted, with amendments addressing subatomic particles and the interconversion
of energy and mass.
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College of Arts and Sciences Education
2nd Floor, DPT Building, Matina Campus, Davao City
Phone No.: (082)300-5456/305-0647 Local 134
One of the first atomic theorists was Democritus, a Greek philosopher who lived
in the fifth century BC. Democritus knew that if a stone was divided in half, the two
halves would have essentially the same properties as the whole. Therefore, he
reasoned that if the stone were to be continually cut into smaller and smaller pieces
then; at some point, there would be a piece which would be so small as to be
indivisible. He called these small pieces of matter "atomos," the Greek word for
indivisible. Democritus, theorized that atoms were specific to the material which they
composed. In addition, Democritus believed that the atoms differed in size and shape,
were in constant motion in a void, collided with each other; and during these collisions,
could rebound or stick together. Therefore, changes in matter were a result of
dissociations or combinations of the atoms as they moved throughout the void.
Although Democritus' theory was remarkable, it was rejected by Aristotle, one of the
most influential philosophers of Ancient Greece; and the atomic theory was ignored
for nearly 2,000 years.
Although the idea of the atom was first suggested by Democritus in the fourth
century BC, his suppositions were not useful in explaining chemical phenomena,
because there was no experimental evidence to support them. It was not until the late
1700's that early chemists began to explain chemical behavior in terms of the atom.
Joseph Priestly, Antoine Lavoisier, and others set the stage for the foundation of
chemistry. They demonstrated that substances could combine to form new materials.
It was the English chemist, John Dalton, who put the pieces of the puzzle together and
developed an atomic theory in 1803.
Dalton’s Law
The law of multiple proportions, also known as Dalton’s law, was proposed by
the English chemist and meteorologist John Dalton in his 1804 work, A New System of
Chemical Philosophy. It is a rule of stoichiometry. The law, which was based on
Dalton’s observations of the reactions of atmospheric gases, states that when
elements form compounds, the proportions of the elements in those chemical
compounds can be expressed in small whole number ratios.
For example, the reaction of the elements carbon and oxygen can yield both
carbon monoxide (CO) and carbon dioxide (CO 2). In CO2, the ratio of the amount of
oxygen compared to the amount of carbon is a fixed ratio of 1:2, a ratio of simple whole
numbers. In CO, the ratio is 1:1.
In his theory of atomic structure and composition, Dalton presented the concept
that all matter was composed of different combinations of atoms, which are the
indivisible building blocks of matter. Dalton’s law of multiple proportions is part of the
basis for modern atomic theory, along with Joseph Proust’s law of definite composition
(which states that compounds are formed by defined mass ratios of reacting elements)
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and the law of conservation of mass that was proposed by Antoine Lavoisier. These
laws paved the way for our current understanding of atomic structure and composition,
including concepts like molecular or chemical formulas.
Although the concept of the atom dates back to the ideas of Democritus, the
English meteorologist and chemist John Dalton formulated the first modern description
of it as the fundamental building block of chemical structures. Dalton developed the
law of multiple proportions (first presented in 1803) by studying and expanding upon
the works of Antoine Lavoisier and Joseph Proust.
Proust had studied tin oxides and found that their masses were either 88.1%
tin and 11.9% oxygen or 78.7% tin and 21.3% oxygen (these were tin(II) oxide and tin
dioxide respectively). Dalton noted from these percentages that 100g of tin will
combine either with 13.5g or 27g of oxygen; 13.5 and 27 form a ratio of 1:2. Dalton
found an atomic theory of matter could elegantly explain this common pattern in
chemistry – in the case of Proust’s tin oxides, one tin atom will combine with either
one or two oxygen atoms.
Dalton also believed atomic theory could explain why water absorbed different
gases in different proportions: for example, he found that water absorbed carbon
dioxide far better than it absorbed nitrogen. Dalton hypothesized this was due to the
differences in the mass and complexity of the gases’ respective particles. Indeed,
carbon dioxide molecules (CO2) are heavier and larger than nitrogen molecules (N 2).
All matter consists of tiny particles called atoms. Dalton and others
imagined the atoms that composed all matter as tiny, solid spheres in various
stages of motion.
Atoms are indestructible and unchangeable. Atoms of an element
cannot be created, destroyed, divided into smaller pieces, or transformed into
atoms of another element. Dalton based this hypothesis on the law of
conservation of mass as stated by Antoine Lavoisier and others around 1785.
Elements are characterized by the weight of their atoms. Dalton
suggested that all atoms of the same element have identical weights.
Therefore, every single atom of an element such as oxygen is identical to
every other oxygen atom. However, atoms of different elements, such as
oxygen and mercury, are different from each other.
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John Dalton's atomic theory was generally accepted because it explained the
laws of conservation of mass, definite proportions, multiple proportions, and other
observations. Although exceptions to Dalton's theory are now known, his theory has
endured reasonably well, with modifications, throughout the years.
Approximately fifty years after John Dalton's proposal of the atom, evidence
began to accumulate which suggested that the atom might not be the solid sphere
that Dalton had envisioned. This evidence came in the form of the discovery of
electrically charged particles and radioactive materials. Based on these new
discoveries, Dalton's proposal of a solid, indestructible atom became unacceptable.
Listed below, are a few of the significant discoveries that were clues that led to the
development of the modern theory of the atom.
In the 1830's, Michael Faraday, a British physicist, made one of the most
significant discoveries that led to the idea that atoms had an electrical component.
Faraday placed two opposite electrodes in a solution of water containing a dissolved
compound. He observed that one of the elements of the dissolved compound
accumulated on one electrode, and the other element was deposited on the opposite
electrode. It was clear to Faraday that electrical forces were responsible for the joining
of atoms in compounds.
In 1879, Sir William Crookes studied the effects of sending an electric current
through a gas in a sealed tube. The tube had electrodes at either end and a flow of
electrically charged particles moved from one of electrodes. This electrode was called
the cathode, and the particles were known as cathode rays. The particles were first
believed to be negatively charged atoms or molecules. However, subsequent
experiments showed that these particles could penetrate thin sheets of material which
would not be possible if the particles were as large as atoms or molecules.
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Atomic Models
Further experiments by other scientists showed that when the beam from a
radioactive ore was passed through a strong magnetic field, there were three kinds of
radiation emitted. These rays were named alpha, beta, and gamma by Ernest
Rutherford. Alpha radiation is a stream of positive particles composed of two protons
and two neutrons (helium nuclei), beta radiation is a stream of particles with negative
charges now known as electrons, and gamma radiation is part of the electromagnetic
spectrum.
Based on the evidence of experiments in the latter part of the 19th century, it
became apparent that the atom was not a solid sphere, and was far more complex
than originally thought by the early Greek philosophers and John Dalton. A
new model of the atom would have to be developed to incorporate these new findings.
nucleus. This model is patterned on the solar system and is known as the planetary
model. The Bohr model can be summarized by the following four principles:
Electrons occupy only certain orbits around the nucleus. Those orbits are stable
and are called "stationary" orbits.
Each orbit has an energy associated with it. The orbit nearest the nucleus has
an energy of E1, the next orbit E2, etc.
Energy is absorbed when an electron jumps from a lower orbit to a higher one
and energy is emitted when an electron falls from a higher orbit to a lower orbit.
The energy and frequency of light emitted or absorbed can be calculated by
using the difference between the two orbital energies.
In 1926 Erwin Schrödinger, an Austrian physicist, took the Bohr atom model one
step further. Schrödinger used mathematical equations to describe the likelihood of
finding an electron in a certain position. This atomic model is known as the quantum
mechanical model of the atom. Unlike the Bohr model, the quantum mechanical model
does not define the exact path of an electron, but rather, predicts the odds of the
location of the electron. This model can be portrayed as a nucleus surrounded by an
electron cloud. Where the cloud is densest, the probability of finding the electron is
greatest, and conversely, the electron is less likely to be in a less dense area of the
cloud. Thus, this model introduced the concept of sub-energy levels.
Until 1932, the atom was believed to be composed of a positively charged nucleus
surrounded by negatively charged electrons. In 1932, James Chadwick bombarded
beryllium atoms with alpha particles. An unknown radiation was produced. Chadwick
interpreted this radiation as being composed of particles with a neutral electrical
charge and the approximate mass of a proton. This particle became known as
the neutron. With the discovery of the neutron, an adequate model of the atom became
available to chemists.
Subatomic Particles
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Atomic Number
Each atom of an element has a specific number of
protons that is equal to every other atom of that
element. The number of protons in the nucleus of
an atom is represented by the atomic number of
that element. For example, carbon has an atomic
number of six, therefore each carbon atom
contains six protons in its nucleus.
Mass Number
The sum of the nuclides in an atom (protons and
neutrons) is called the mass number. If an atom
has six protons and eight neutrons, then the atom
is said to have a mass number of fourteen.
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Location of Electrons
Electrons are found around the nucleus in regions of space called orbitals.
The orbitals in an atom form a series of energy levels in which
electrons may be found. Each electron in an atom has its own distinct
amount of energy that corresponds to the energy level that it
occupies. Electrons can gain or loss distinct amounts of energy that
cause the electrons to move to different energy levels. As an electron
gains energy it is promoted to a higher energy level.
Ground State Configuration
When the electrons of an atom occupy the lowest available orbitals, the
atom is said to be in the ground state. The electrons in a ground state
atom have filled the available spaces from the lowest energy level to
higher energy levels until all the electrons are accounted for.
When electrons are subjected to stimuli such as heat, light, or
electricity, an electron may absorb energy and temporarily move to a
higher energy level. This unstable condition where lower energy levels
are left unoccupied is called an excited state.
https://www.youtube.com/watch?v=thnDxFdkzZs
Self-Help: You can also refer to the sources below to help you further
understand the lesson.
Shaw, A. (2016, Apr). History of the atomic theory. Skipping Stones, 28, 12.
Retrieved from
https://search.proquest.com/docview/1781773372?accountid=31259
Wessel, W. (1995). The atomic model of matter. Accelerator, 21(2), 12-13. Retrieved
from https://search.proquest.com/docview/204159052?accountid=31259
LET’S CHECK
Activity #14. Use your understanding from the Atomic Structure program to
answer the following questions.
1. The atomic number tells the number of positively charged ________ in the nucleus
of an atom. The atom is __________ because this is also the number of
__________ charged __________ in the atom.
2. The mass number tells the total number of________ and _________ in the nucleus
of an atom. These particles collectively are called ___________ since both are
located in the nucleus.
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3. Isotopes are atoms of the same element with different numbers of _________ which
results in different _______ numbers.
3. Are electrons, protons, or neutrons the smallest particles? If not, what are?
______________________________________________________________
______________________________________________________________
______________________________________________________________
LET’S ANALYZE
Activity #16. This worksheet provides extra practice for writing electron
configurations.
b) Phosphorus
c) Magnesium
d) Calcium
e) Chlorine
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2. Write the ground state electron configuration for neutral atom Iodine and the
Iodine anion.
3. Write the ground state electron configuration for neutral Hydrogen and then
write the electron configuration for an excited state of Hydrogen.
4. Write the ground state electron configuration for neutral Titanium and then
write the electron configuration for an excited state of Titanium.
5. State in your own words the Pauli exclusion principle and Hund’s rule.
Activity #17. Complete the table below without using your periodic table.
Boron 5 11
Copper 29 33
Iron 56 26
Sulfur 16 16
Tin 50 69
Nitrogen 14 7
Neon 10 20
Mercury 201 80
Potassium 39 19
Bromine 35 80
Aluminum 13 27
Gold 79 118
Calcium 20 40
Lead 207 125
Silver 108 61
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IN A NUTSHELL
Activity #18. Based on the topic above, answer the following questions:
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6. Subatomic Particles
A. What is an atom?
________________________________________________________
______________________________________________________________
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
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Q&A LIST
Do you have any questions for clarification?
QUESTIONS ANSWERS
1.
2.
3.
4.
5.
KEYWORDS INDEX
METALANGUAGE
The most essential terms below are operationally defined for you to have a
better understanding of this section in the course.
1. Quantum Mechanics.
2. Electron Configuration. It also called electronic structure, the arrangement of
electrons in energy levels around an atomic nucleus.
3. Valence electron. It is an electron that is the most likely to be involved in a
chemical reaction. They are typically the electrons with the highest energy level.
4. Energy level. It also called electron shells; are fixed distances from the nucleus
of an atom where electrons may be found. Electrons are tiny, negatively
charged particles in an atom that move around the positive nucleus at the
center.
5. Orbitals. It describes where an electron is likely to be found in an atom.
Source: https://www.wikipedia.org/
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ESSENTIAL KNOWLEDGE
THE QUANTUM MECHANICAL MODEL
The principal quantum number n describes the average distance of the orbital
from the nucleus — and the energy of the electron in an atom. It can have positive
integer (whole number) values: 1, 2, 3, 4, and so on. The larger the value of n, the
higher the energy and the larger the orbital. Chemists sometimes call the
orbitals electron shells.
The angular momentum quantum number l describes the shape of the orbital,
and the shape is limited by the principal quantum number n: The angular momentum
quantum number l can have positive integer values from 0 to n–1. For example, if the
n value is 3, three values are allowed for l: 0, 1, and 2.
Orbitals that have the same value of n but different values of l are
called subshells. These subshells are given different letters to help chemists
distinguish them from each other. The following table shows the letters corresponding
to the different values of l.
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0 s
1 p
2 d
3 f
4 g
When chemists describe one particular subshell in an atom, they can use both
the n value and the subshell letter — 2p, 3d, and so on. Normally, a subshell value of
4 is the largest needed to describe a particular subshell. If chemists ever need a larger
value, they can create subshell numbers and letters.
Source: https://www.dummies.com/education/science/chemistry/atomic-structure-the-quantum-mechanical-model/
As shown in the top row of the figure (a), there are two s orbitals — one for
energy level 1 (1s) and the other for energy level 2 (2s). The s orbitals are spherical
with the nucleus at the center. Notice that the 2s orbital is larger in diameter than the
1s orbital. In large atoms, the 1s orbital is nestled inside the 2s, just like the 2p is
nestled inside the 3p. The second row of the figure (b) shows the shapes of the p
orbitals, and the last two rows (c) show the shapes of the d orbitals. Notice that the
shapes get progressively more complex.
The magnetic quantum number is designated as: ml. This number describes
how the various orbitals are oriented in space. The value of this number depends on
the value of l. The values allowed are integers from –l to 0 to +l. For example, if the
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value of l = 1 (p orbital), you can write three values for this number: –1, 0, and +1. This
means that there are three different p subshells for a particular orbital. The subshells
have the same energy but different orientations in space.
The second row (b) of the figure shows how the p orbitals are oriented in space.
Notice that the three p orbitals correspond to magnetic quantum number values of –1,
0, and +1, oriented along the x, y, and z axes.
The spin quantum number
The fourth and final quantum number is the spin quantum number, designated
as: ms. This number describes the direction the electron is spinning in a magnetic field
— either clockwise or counterclockwise. Only two values are allowed: +1/2 or –1/2.
For each subshell, there can be only two electrons, one with a spin of +1/2 and another
with a spin of –1/2.
Electron Configurations Provide Insight on the Energy Level of the Orbital, the
Type of Orbital, and the Total Number of Electrons in the Orbital. However, the
standard notation often yields lengthy electron configurations (especially for
elements having a relatively large atomic number). In such cases, an abbreviated or
condensed notation may be used instead of the standard notation. In the abbreviated
notation, the sequence of completely filled subshells that correspond to the
electronic configuration of a noble gas is replaced with the symbol of that noble
gas in square brackets. Therefore, the abbreviated electron configuration of sodium
is [Ne]3s1 (the electron configuration of neon is 1s22s22p6, which can be abbreviated
to [He]2s22p6).
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Source: https://byjus.com/chemistry/electron-configuration/
Aufbau Principle
This principle is named after the German word ‘Aufbeen’ which means ‘build
up’.
The Aufbau principle dictates that electrons will occupy the orbitals having
lower energies before occupying higher energy orbitals.
The energy of an orbital is calculated by the sum of the principal and the
azimuthal quantum numbers.
According to this principle, electrons are filled in the following order: 1s, 2s, 2p,
3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The order in which electrons are filled in atomic orbitals as per the Aufbau principle
is illustrated below.
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Source: https://byjus.com/chemistry/aufbau-principle/
It is important to note that there exist many exceptions to the Aufbau principle
such as chromium and copper. These exceptions can sometimes be explained by the
stability provided by half-filled or completely filled subshells.
The Pauli exclusion principle states that a maximum of two electrons, each
having opposite spins, can fit in an orbital.
This principle can also be stated as “no two electrons in the same atom have
the same values for all four quantum numbers”.
Therefore, if the principal, azimuthal, and magnetic numbers are the same for
two electrons, they must have opposite spins.
Hund’s Rule
This rule describes the order in which electrons are filled in all the orbitals
belonging to a subshell.
It states that every orbital in a given subshell are singly occupied by electrons
before a second electron is filled in an orbital.
In order to maximize the total spin, the electrons in the orbitals that only contain
one electron all have the same spin (or the same values of the spin quantum
number).
Examples
The electron configurations of a few elements are provided with illustrations in this
subsection.
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K shell – 2 electrons
L shell – 6 electrons
https://www.youtube.com/watch?v=hSkJzE2Vz_w
Self-Help: You can also refer to the sources below to help you further
understand the lesson.
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LET’S CHECK
Activity #20. For the following elements list the electron configuration.
1. oxygen = ______________________________________________
2. cesium = ______________________________________________
3. krypton = ______________________________________________
4. titanium = ______________________________________________
5. scandium = ______________________________________________
6. nitrogen = ______________________________________________
7. chlorine = ______________________________________________
8. fluorine = ______________________________________________
9. arsenic = ______________________________________________
10. francium = ______________________________________________
Activity #21. Identify the element that has the following electron configuration
LET’S ANALYZE
Activity #22. Provide both STANDARD and SHORT HAND Electron
configuration for the following
1. Copper
Standard: _____________________________________________________
Shorthand: ____________________________________________________
2. Iodine
Standard: _____________________________________________________
Shorthand: ____________________________________________________
3. Barium
Standard: _____________________________________________________
Shorthand: ____________________________________________________
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4. Chlorine
Standard: _____________________________________________________
Shorthand: ____________________________________________________
5. Cesium
Standard: _____________________________________________________
Shorthand: ____________________________________________________
IN A NUTSHELL
Activity #23. Look for an element in a periodic table which starts with the same
letter as your last name.
Q&A LIST
Do you have any questions for clarification?
QUESTIONS ANSWERS
1.
2.
3.
4.
5.
KEYWORDS INDEX
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