Chem 6A Slide Set #14

Overview

CHAPTER 6

Ionic Bonding Ionic Compounds Electron Configuration of Ions

2013-10-30

Ions With Noble Gas Configuration

Know the charges of these ions.

Ions With Noble Gas Configuration

Know the charges of these ions.

Ions of transition elements

Electrons with the highest n value are removed first. E.g.: V: [Ar] 4s2 3d3 V2+: [Ar] 3d3 So the electrons that were first-in (4s ! are first-out when the ion is formed.
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Electron pairing and magnetic properties Paramagnetic: unpaired electron(s!" attracted #$ a magnetic field Diamagnetic: all electrons paired" ver$ slightl$ repelled #$ magnetic field

%aramagnetic &nS'4() ' is drawn #etween the poles of a magnet

18-Electron

ule

!"seudo-Noble Gas Configuration#

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Sb5+ Bi5+
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Know the charges of these ions.

$he Inert "air Effect

&etals in *roups +,- +4- . +/ ma$ show the inert-pair effect: outer s electrons are especiall$ sta#lenot necessarily lost when a cation forms.

Pseudo-noble-gas configuration

%Inert "air& Ions

Know the charges of these ions.

'etals With 1( )( or * Common Ion Charges

Know these common ions and their charges.

"roblem
0hat is the formula of gallium selenide1 2! *aSe B! *a Se C! *aSe, 3! *a,Se E! *a Se, 4! *a,Se *! *a,Se4
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"roblem
0hat is the formula of vanadium(5! o6ide1 2! 5'/ B! 5 ', C! 5 '/ 3! 5,' E! 5/' 4! 5/' *! 5/',
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+O'EWO ,

7ead: Chapter 8- Sections 8-8 and 8-9 :e6t#oo; pro#lems from the end of Chapter 8: 8- - 8-4- 8-8- 8-+<- 8-+4- 8-+8- 8- 4- 8- 8- 8-,<

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