BI TP TINH TH

1. St alpha kt tinh theo mng lp phng tm khi.

Xc nh bn knh ca nguyn t Fe trong st alpha bit t trng ca n bng 7,86.
Cho Fe = 55,8 g/mol.
2. Bn knh ca nguyn t Na bng 0,190 nm.
Tnh t trng ca Na kim loi (mng lp phng tm khi).
Cho Na = 23,0 g/mol.
3. Cu kim loi kt tinh theo mng lp phng tm din.
T trng ca n bng 8,96. Tnh bn knh nguyn t ca Cu.
Cu = 63,5.
4. Cho thng s mng tinh th ca 2 dng th hnh ca Fe:
- Fe alpha: lp phng tm khi; a = 0,286 nm.
- Fe gamma: lp phng tm din; a = 0,356 nm.
Tnh bn knh nguyn t v t trng ca Fe trong mi trng hp.
Fe = 55,8 g/mol.
5. Mg kt tinh theo mng lc phng cht kht. Bit a = b = 0,320 nm.
Tnh c.
T kt qu thu c hy tnh t khi ca Mg.
Mg = 24,3 g/mol.
6. Ti kt tinh theo mng lc phng cht kht.
a) M t t bo n v ca Ti.
b) Tnh bn knh nguyn t ca Ti, bit khi lng ring ca Ti bng 4,51 g/cm3
Ti = 47,90 g/mol.
7. T trng ca NaCl bng 2,165.
Tnh tng bn knh ca 2 ion Na+ v ClMNaCl = 58,44 g/mol.
8. Trong tinh th CaF2 cc ion Ca2+ nm trn mt mng lp phng tm din,
cn cc ion F- chim tt c cc l trng t din.
Bn knh ca cc ion Ca2+ v F- tng tng bng 0,099 v 0,133 nm.
Tnh:
- Thng s mng a.
- c kht p.
- T trng ca CaF2
MCaF2 = 78 g/mol.
9. Trong kiu cu trc blend ca ZnS cc ion S2- nm trn mt mng lp phng tm din,
cn cc ion Zn2+ chim mt na s l trng t din theo 4 gc cho nhau ca t bo n v.
Tnh t s nh nht ca r+/r10. Bn knh nguyn t ca C r = 0,077 nm.
Tnh t trng v c kht ca kim cng. C = 12,01 g/mol.
11. FeO c cu trc kiu NaCl vi a = 0,430 nm.
Gi tr ny c ph hp vi cc bn knh ion: r(Fe2+) = 0,075 nm; r(O2-) = 0,140 nm?
12. Cu2O kt tinh theo mng lp phng
trong cc ion O2- to thnh mt mng lp phng tm khi,
cn cc ion Cu2+ nm im gia ca 4/8 na ng cho ca hnh lp phng.

Xc nh:
- Kiu phi tr v s phi tr ca cc ion.
- S phn t Cu2O trong 1 t bo.
- Thng s a ca t bo nu khi lng ring l 6,00 g/cm3
13. Dng th hnh cristobalit ca SiO2 c cu trc nh sau:
Cc nguyn t Si sp xp cc v tr ging nh cc nguyn t C trong kim cng
v gia 2 nguyn t Si l mt nguyn t O.
- V cu trc ca cristobalit.
- Xc nh s phi tr ca Si v O.
- Xc nh thng s a bit khi lng ring l 2,32 g/cm3
MSiO2 = 60,1 g/mol.
14. Xc nh nng lng mng li tinh th ca NaCl, bit (kJ/mol):
delta H (NaCl) = -411,2;
delta Ho (th Na) = 107,3;
delta Ho (pl Cl2) = 240;
delta Ho (ionh Na) = 496;
delta Ho (al Cl) = -349.
15. Mt mu oxit st (II) FexO iu ch trong phng th nghim c t khi 5,71 g/cm3.
Bit rng oxit st (II) c cu trc kiu NaCl.
Gc teta ca phn x bc nht t h mt 200 bng 9,56o khi dng bc x Kalpha ca Mo vi lamda l 71,07
pm.
Xc nh:
- thng s ca mng tinh th
- Gi tr ca x trong FexO
- T l Fe2+ v Fe3+ trong oxit
- Cng thc ha hc ch r ha tr ca st trong hp cht
16. Mt nguyn t c bn knh l l 1,44A0, khi lng ring thc tinh th l 19,36 g/cm3. Nguyn t ny
chim 74% th tch tinh th, phn cn li l khe rng. Hy tm khi lng ring trung bnh ca ton nguyn
t ri suy ra khi lng mol ca nguyn t.
17. Nguyn t Ag c khi lng mol v khi lng ring trung bnh ln lt l 107,87 g/mol v 10,5 g/cm3.
Bit nguyn t ny ch chim 74% th tch tinh th. Xc nh bn knh ngun t Ag.
18. Nguyn t Zn c bn knh v khi lng mol l: 1,38A0 , 65g/mol.
a. Xc nh khi lng ring trunh bnh ca Zn
b. Xc nh khi lng ring thc ca Zn, bit nguyn t Zn ch chim 72,5% th tch tinh th.