TRNG THPT PHONG IN

T Ha Sinh CN

THI TH I HC KHI A, B LN 1
MN: HA HC
Nm hc 2013 - 2014
Thi gian lm bi: 90 pht;
(50 cu trc nghim)

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho Na = 23; Ca = 40; Ag = 108; C = 12; O = 16; N = 14; H = 1.
Cu 1. un nng alanin thu c mt s peptit trong c peptit A c phn trm khi lng nit l 18,54%. Khi lng
phn t ca A l :
A. 231.
B. 160.
C. 373.
D. 302.
Cu 2. Pht biu no sau y khng ng
A. Glucoz v fructoz l ng phn ca nhau.
B. Trong phn t amiloz tn ti c lin kt -1,4-glicozit v -1,6-glicozit.
C. Thy phn saccaroz thu c 2 monosaccarit khc nhau.
D. Thy phn hon ton tinh bt v xenluloz cng thu c mt monosaccarit.
Cu 3. Cho cc pht biu sau v cacbohirat:

(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.

(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c
mt loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag .
S pht biu ng l
A. 2.
B. 5.
C. 3.
D. 4.
Cu 4. Khi lng xenluloz v khi lng axit nitric cn ly sn xut ra 445,5 kg xenluloz trinitrat,
bit hiu xut phn ng t 75% l
A. 162 kg xenluloz v 378 kg HNO3.
B. 182,25 kg xenluloz v 212,625 kg HNO3.
C. 324 kg xenluloz v 126 kg HNO3.
D. 324 kg xenluloz v 378 kg HNO3.
Cu 5. Khng nh no sau y l ng?
A. Poli(tetrafloetilen); poli(metyl metacrylat); t nitron u c iu ch bng phn ng trng hp.
B. T poliamit km bn v mt ho hc l do c cha cc nhm peptit d b thu phn.
C. Cao su lu ho; nha rezit(hay nha bakelit); amilopectin ca tinh bt l nhng polime c cu trc mng khng gian.
D. T visco, t nilon-6,6, t enang, t axetat thuc loi t nhn to.
Cu 6. t chy hon ton hn hp gm etanol v phenol c t l mol 3:1, cho ton b sn phm chy

vo bnh ng dung dch nc vi trong th thu c 15 gam kt ta, ly dung dch sau phn ng tc
dng vi dung dch NaOH d th thu c 7,5 gam kt ta na. Khi lng bnh ng dung dch nc
vi s
A. tng 5,4 gam.
B. tng 3,6 gam.
C. tng 13,2 gam.
D. tng 18,6 gam.
Cu 7. Hn hp T gm hai axit cacboxylic no mch h.
- Th nghim 1: t chy hon ton a (mol) hn hp T thu c a (mol) H2O.
- Th nghim 2: a (mol) hn hp T tc dng vi dung dch NaHCO3 d thu c 1,6a (mol) CO2.
Phn trm khi lng ca axit c phn t khi nh hn trong T l

A. 31,76%.
B. 46,67%.
C. 25,41%.
D. 40,00%.
Cu 8. Ha tan 281,4 gam hn hp X gm anilin, phenol, axit axetic v ancol etylic vo hexan ri chia thnh 3 phn bng
nhau.
- Phn 1 cho tc dng vi Na d thu c 13,44 lit kh (ktc).
- Phn 2 cho tc dng vi dung dch nc brom d cho 165,3 gam kt ta trng.
- Phn 3 cho tc dng va vi 160 ml dung dch NaOH 14% (d=1,25 g/ml).
Thnh phn % theo khi lng ca ancol etylic trong hn hp l
A. 30,06%.
B. 19,83%.
C. 24,52%.
D. 25,59%.
Cu 9. Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dd HCl 2M, thu c dung dch X.

Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l
A. 0,50.
B. 0,70.
C. 0,65.
D. 0,55.
Cu 10. Ln men m gam glucoz vi hiu sut 70% ri hp th ton b kh thot ra vo 4 lt dung dch
NaOH 0,5M (d =1,05g/ml) thu c dung dch cha 2 mui c tng nng l 3,211%. Gi tr ca m
l:
A. 270,0.
B. 192,9.
C. 135,0.
D. 384,7.
Cu 11. S polime hoc t b t mch khi phn ng vi NaOH c hoc HCl c l: PVA, Cao su Buna, PVC, T
Clorin, Thy tinh hu c, T 6,6, T Capron, T Lapsan
A. 6
B. 4
C. 3
D. 8
Cu 12. Cho hn hp X gm hai hp cht hu c no, n chc A, B tc dng va vi 100 ml dung

dch KOH 0,40M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng
hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 d th khi lng
bnh tng 5,27 gam. Cng thc ca A, B l
A. HCOOH v HCOOC3H7.
B. HCOOH v HCOOC2H5.
C. CH3COOH v CH3COOCH3.
D. CH3COOH v CH3COOC2H5.
Cu 13. C cc nhn xt sau:
(1) Trong s cac protein fibroin, anbumin, keratin, mizoin co 1 protein co dang tn tai khac vi dang tn tai cua 3
protein con lai.
(2) T nilon - 6,6; t capron; t lapsan u c iu ch bng phn ng trng ngng.
(3) Trong s cac este vinylaxetat, triolein, anlylaxetat, phenylaxetat chi co 1 este c iu ch trc tip bng phan ng
cua axit va ancol tng ng (vi xuc tac H2SO4 c, t0).
(4) Phn t fructoz co nhom chc xeton, glucoz co nhom chc andehit nn co th phn bit c glucoz va fructoz
bng dung dich AgNO3 trong NH3.
(5) un nhe hn hp etylbromua trong dung dich NaOH d, ng thi lc u. Sau o yn, ta thy hn hp phn
thanh 2 lp.
(6) Benzen, naphtalen, axeton u xay ra phan ng th vi dung dich nc brom iu kin thich hp
S cu nhn xt ng l:
A. 2.
B. 3.
C. 5.
D. 4.
Cu 14. Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) anehit khng no (c

mt lin kt i C=C), mch h; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt
lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch
h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. (5), (6), (8), (9).
B. (1), (3), (5), (6), (8). C. (2), (3), (5), (7), (9). D. (3), (4), (6), (7), (10).
Cu 15. Cho cc cht sau: (1) anilin , (2) amoniac, (3) p-metyl-anilin, (4) etylamin, (5) p-nitro-anilin, (6) propyl amin. Dy
gm cac cht sp xp theo chiu tng dn tnh baz l:
A. (3) < (5) < (1) < (2) < (4) < (6)
B. (1) < (5) < (3) < (2) < (4) < (6)
C. (5) < (1) < (3) < (2) < (4) < (6)
D. (5) <(1) < (3) < (2) < (6) < (4)

Cu 16. Xc nh Phn t khi gn ng ca mt Polipeptit cha 0,32% S trong phn t. Gi s trong phn t ch c 2
nguyn t S?
A. 20.000(vC)
B. 10.000(vC).
C. 15.000(vC).
D. 45.000(vC).
Cu 17. Cng thc no sau y ca pentapeptit (A) tha iu kin sau ? Thy phn hon ton 1 mol A th thu c cc amino axit l : 3 mol glyxin, 1 mol alanin, 1 mol valin. Thy phn khng hon ton A, ngoi thu c cc amino axit th
cn thu c 2 ipeptit : Ala-Gly ; Gly-Ala v 1 tripeptit Gly-Gly-Val.
A. Ala-Gly-Gly-Gly-Val. B. Gly- Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly.
Cu 18. Thc hin phn ng este ho gia axit axetic v hn hp gm 8,4 gam 3 ancol l ng ng ca

ancol etylic. Sau phn ng thu c 16,8 gam 3 este. Ly sn phm ca phn ng este ho trn thc
hin phn ng x phng ho vi dung dch NaOH 4 M th thu c m gam mui. (Gi s hiu sut phn
ng este ho l 100%). Gi tr ca m l
A. 10,0.
B. 20,0.
C. 16,4.
D. 8,0.
Cu 19. un nng hn hp gm etanol v butan-2-ol vi H 2SO4 c th thu c ti a bao nhiu sn
phm hu c? (Khng k sn phm ca phn ng gia ancol vi axit)
A. 7.
B. 6.
C. 5.
D. 8.
Cu 20. T 1,0 tn cht bo cha 89% khi lng tristearin (cn 11% tp cht tr b loi b trong qu
trnh nu x phng) em x phng ha bi NaOH. Tnh khi lng x phng thu c?
A. 1,0 tn.
B. 1,5 tn.
C. 0,9 tn.
D. 1,2 tn.
Cu 21. Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat,
s este c th iu ch trc tip bng phn ng ca axit v ancol tng ng (c H 2SO4 c lm xc tc)
l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 22. Cho hn hp X (gm CH3OH, C2H4(OH)2, C3H5(OH)3) c khi lng m gam. t chy hon
ton m gam hn hp X thu c 5,6 lt kh CO 2 ( ktc). Cng m gam hn hp X trn cho tc dng vi
Na (d) thu c V lt kh H2 (ktc). Gi tr ca V l
A. 3,36 .
B. 2,8.
C. 11,2.
D. 5,6.
Cu 23. Cho CTPT ca hp cht thm X l C 7H8O2. X tc dng vi dung dch NaOH theo t l mol 1:1.
S cht X tha mn l
A. 5.
B. 3.
C. 6.
D. 2.
Cu 24. Aminoaxit Y cha 1 nhm-COOH v 2 nhm - NH 2 cho 1 mol Y tc dng ht vi dung dch HCl v c cn th thu
c 205g mui khan. Tm cng thc phn t ca Y.
A. C5H12N2O2
B. C6H14N2O2
C. C5H10N2O2
D. C4H10N2O2
Cu 25. Thuc th c dng phn bit Ala-Ala-Gly vi Gly-Ala l
A. dung dch NaOH.

B. Cu(OH)2 trong mi trng kim.

C. dung dch NaCl.

D. dung dch HCl.

Cu 26. Cho cc nhn xt sau:

(1) C th to c ti a 2 ipeptit t phn ng trng ngng hn hp alanin v glyxin

(2) Khc vi axit axetic, axt amino axetic c th tham gia phn ng vi axit HCl
(3) Ging vi axit axetic, aminoaxit c th tc dng vi baz to mui v nc
(4) Axit axetic v axit -amino glutaric khng lm i mu qu tm thnh
(5) Thy phn khng hon ton peptit: Gly-Ala-Gly-Ala-Gly c th thu c ti a 2 ipeptit
(6) Cho Cu(OH)2 vo ng nghim cha anbumin thy to dung dch mu xanh thm
S nhn xt khng ng l
A. 4.
B. 3.
C. 1.
D. 2.

Cu 27. C cc nhn nh sau:

(1) Cht bo l trieste ca glixerol vi cc axit monocacboxylic c mch cacbon di khng phn
nhnh.
(2) Lipit gm cht bo, sp, steroit, photpholipit,
(3) Cht bo cha cc gc axit khng no thng l cc cht rn nhit thng.
(4) Phn ng thy phn cht bo trong mi trng kim l phn ng thun nghch.
(5) Cht bo l thnh phn chnh ca du m ng, thc vt.
(6) Khi un cht bo lng vi hiro c xc tc Ni trong ni hp th chng chuyn thnh cht bo rn.
Cc nhn nh ng l:
A. (1), (2), (5), (6).
B. (1), (2), (3).
C. (1), (2), (4), (5).
D. (3), (4), (5).
Cu 28. Thy phn mt lng mantoz, trung ha dung dch sau phn ng v bng phng php thch hp, tch thu c
71,28 gam hn hp X, ri chia thnh hai phn bng nhau. Phn mt phn ng vi H 2 d thu c 29,12 gam sobitol. Phn
hai tc dng vi mt lng d dung dch AgNO3/NH3 thu c m gam Ag. Gi tr ca m l
A. 34,56.
B. 69,12.
C. 38,88.
D. 43,20.
Cu 29. Cho 11,8 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra

hon ton thu c dung dch Y. Lm bay hi dung dch Y c 19,1 gam mui khan. S cng thc cu
to ng vi cng thc phn t ca X l
A. 5.
B. 4.
C. 6.
D. 3.
Cu 30. Mt cht hu c X c CTPT l C 4H11NO2. Cho X tc dng hon ton vi 100ml dung dch
NaOH 2M, sau phn ng thu c dung dch X v 2,24 lt kh Y (ktc). Nu trn lng kh Y ny vi
3,36 lt H2 (ktc) th c hn hp kh c t khi so vi H 2 l 9,6. Khi lng cht rn thu c khi c
cn dung dch X l
A. 8,62 g.
B. 12,3 g .
C. 8,2 g.
D. 12,2 g.
Cu 31. Cho cng thc phn t ca ancol v amin ln lt l: C 4H10O v C4H11N. Tng s ng phn
ancol bc 1 v amin bc 2 l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 32. Cho 100,0 ml hn hp X gm: phenyl axetat 0,2M v etyl axetat 0,4M vo 40,0 ml dung dch NaOH 2,5M, un
nng, sau khi cc phn ng hon ton, c cn dung dch thu c m gam cht rn khan. Gi tr m l
A. 8,04 gam.
B. 7,24 gam.
C. 4,92 gam.
D. 6,52 gam.
Cu 33. Cho cc este: C6H5OCOCH3 (1); CH3COOCH=CH2 (2); CH2=CH-COOCH3 (3); CH3-CH=CH-OCOCH3 (4);
(CH3COO)2CH-CH3 (5). Nhng este no khi thy phn khng to ra ancol?
A. 1 , 2 , 4 , 5
B. 1 , 2 , 4
C. 1 , 2 , 3
D. 1 , 2 , 3 , 4 , 5
Cu 34. Cho cc dd sau: glucoz, axit axetic, glixerol, saccaroz, ancol etylic. S lng dung dch c th

ho tan c Cu(OH)2 l
A. 5.
B. 4.
C. 2.
D. 3.
Cu 35. t chy hon ton 1 lng cao su buna-N vi lng khng kh va , thy to 1 hn hp kh
nhit trn 127oC trong CO2 chim 20,41% v th tch.T l s mt xch butaien v vinyl xianua
trong polime ny l (bit khng kh chim 20% O2 v 80% N2 v th tch)
A. 3:4.
B. 2:3.
C. 2:1.
D. 1:2.
Cu 36. Trong s cc loi t sau: t lapsan, t nitron, t visco, t nilon-6,6, t axetat, t capron, t nilon7. S loi t thuc loi t nhn to l
A. 2.
B. 3.
C. 4.
D. 1.

Cu 37. X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X

v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu
c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l
A. 68,1.
B. 17,025.
C. 19,455.
D. 78,4
Cu 38. Thu phn C2H5COOCH=CH2 trong mi trng axit to thnh nhng sn phm l
A. C2H5COOH ; C2H5OH.
B. C2H5COOH ; HCHO.
C. C2H5COOH ; CH2=CH-OH.
D. C2H5COOH ; CH3CHO.
Cu 39. Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c
(xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh
cht ca xenluloz l:
A. (1), (3), (4) v (6)
B. (3), (4), (5) v (6)
C. (2), (3), (4) v (5)
D. (1,), (2), (3) v (4)
Cu 40. Cho 9,3 gam mt ankylamin tc dng vi dung dch FeCl3 d thu c 10,7 gam kt ta.

Ankylamin l
A. CH3NH2.
B. C3H7NH2.
C. C4H9NH2.
D. C2H5NH2.
Cu 41. nh hng ca nhm amino n gc phenyl trong phn t anilin c th hin qua phn ng
gia anilin vi
A. dung dch Br2 v dung dch HCl
B. dung dch HCl
C. dung dch Br2
D. dung dch NaOH
Cu 42. Cho cc nhn xt sau, c bao nhiu nhn xt ng?
(1) C th to c ti a 2 ipeptit t phn ng trng ngng hn hp Alanin v Glyxin.
(2) Axt axetic v axt -amino glutaric c th lm i mu qu tm thnh .
(3) Thy phn khng hon ton peptit: Gly-Phe-Tyr-Gly-Lys-Gly-Phe-Tyr c th thu c 6 tripeptit c cha Gly.
(4) Cho HNO3 c vo ng nghim cha anbumin thy to dung dch mu tm.
A. 1
B. 3
C. 4
D. 2
Cu 43. X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h,

c mt nhm -COOH v mt nhm -NH 2. t chy hon ton 0,1 mol Y thu c sn phm gm CO 2,
H2O, N2, trong tng khi lng ca CO 2 v H2O l 47,8 gam. S mol oxi cn dng t chy hon
ton 0,3 mol X l
A. 3,375 mol.
B. 1,875 mol.
C. 2,025 mol.
D. 2,8 mol.
Cu 44. t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O 2, thu
c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH
1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b
mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3.
B. 4 : 3.
C. 3 : 2.
D. 3 : 5.
Cu 45. Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch
nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi
lng dung dch nc vi trong ban u. Gi tr ca m l
A. 30,0.
B. 13,5.
C. 15,0.
D. 12,15.
Cu 46. X l este ca glyxin. Cho m gam X tc dng vi dung dch NaOH d, hi ancol bay ra i qua
ng ng CuO un nng. Cho sn phm thc hin phn ng trng gng thy c 8,64 gam Ag. Bit
phn t khi ca X l 89. Gi tr ca m l
A. 3,56.
B. 2,67.
C. 1,78.
D. 2,225.
Cu 47. t chy hon ton 2,01 gam hn hp gm: axit metacrylic, vinyl fomat, etyl acrylat. Ton b sn phm chy cho
qua dung dch Ca(OH)2 d, sau phn ng thu c 9,0 gam kt ta v dung dch X. Vy khi lng dung dch X thay
i so vi dung dch Ca(OH)2 ban u l

A. tng 5,13 gam.

B. gim 3,87 gam.
Cu 48. Cho cc pht biu sau:

C. gim 3,42 gam.

D. tng 5,58 gam.

(1) Thu phn hon ton este no, n chc mch h trong dung dch kim thu c mui v ancol.
(2) Phn ng este ho gia axit cacboxylic vi ancol (xc tc H2SO4 c) l phn ng thun nghch.
(3) Trong phn ng este ho gia axit axetic v etanol (xc tc H 2SO4 c), nguyn t O ca phn t
H2O c ngun gc t axit.
(4) t chy hon ton este no mch h lun thu c CO2 v H2O c s mol bng nhau.
(5) Cc axit bo l cc axit cacboxylic n chc v c s nguyn t cacbon chn.
S pht biu ng l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 49. Cho cc nhn xt sau:
(1) Hp cht H2N-CH2CH2CONH-CH2CONH-CH2COOH cha 2 lin kt peptitt ;
(2) Phn t khi ca mt amino axit cha 1 nhm NH2 v 1 nhm COOH trong phn t lun l s l ;
(3) Cc peptit u tc dng vi Cu(OH)2 trong mi trng kim to ra hp cht mu tm ;
(4) Tripeptit l hp cht m phn t cha 3 lin kt peptit ;
(5) dung dch ca anilin khng lm xanh qu tm. S nhn xt ng l:
A. 2
B. 3
C. 4 D. 5
Cu 50. Khi thy phn mt octanpetit X c cng thc cu to l Gly-Phe-Tyr-Lys-Gly-Phe-Tyr-Gly th

thu c bao nhiu tripeptit c cha Gly?

A. 5.
B. 3.

C. 4.

----------- HT ----------

D. 6.