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Chem 1B Chapter 18 Exercises With Answers
Chem 1B Chapter 18 Exercises With Answers
Chapter 18 Exercises
Exercises #1:
Redox Reactions
1. Determine the oxidation number (o.n.) of each atom in the followin formula (compounds or
pol!atomic ions):
"nswer:
(a) #$%&': # ( )1* % ( )+* & ( ,$* (b) -aBr&.: -a ( )1* Br ( )/* & ( ,$*
(c) -a$%$&.: -a ( )1* % ( )$* & ( ,$* (d) Ca(&Cl)$: Ca ( )$* Cl ( )1* & ( ,$*
(e) 0n&'
,
: 0n ( )1* & ( ,$* (f) Cr$&1
$,
: Cr ( )+* & ( ,$
$. Balance the followin e2uations and then write balanced net ionic e2uation for each reaction.
3n each reaction4 identif! the oxidi5in aent and the reducin aent. "lso indicate the element that is
oxidi5ed and the element reduced in the reaction.
(a) Cu(s) ) $ "-&.(aq) Cu(-&.).(aq) ) $ "(s)
(b) $ "l(s) ) . Cu%&'(aq) "l$(%&').(aq) ) . Cu(s)
.. Balance the followin redox reactions in acidic solution usin half,reaction method.
3n each case4 identif! the oxidi5in aent4 the reducin aent4 the element that is oxidi5ed and the
element that is reduced.
(a) Ca(&Cl)$(aq) ) $ Cl
,
(aq) ) ' #
)
(a2) $ Cl$(a2) ) Ca
$)
(a2) ) $ #$&
(b) Br&.
,
(aq) ) / Br
,
(aq) ) + #
)
(a2) . Br$(a2) ) . #$&
(c) $ Cu
$)
(a2) ) ' 3
,
(a2) $ Cu3(s) ) 3$(a2)
'. Balanced the followin redox reactions in basic solution. 3n each case4 identif! the oxidi5in aent4 the
reducin aent4 the element bein oxidi5ed4 and the element bein reduced.
(a) $ Cr(&#)'
,
(aq) ) . #$&$(aq) ) $ &#
,
(a2) $ Cr&'
$,
(aq) ) 8 #$&(l)
(b) . Br$(aq) ) + &#
,
(aq) Br&.
,
(aq) ) / Br
,
(aq) ) . #$&(l)
Exercises #$:
Electrochemical Cells and Batteries
1. 6hat are the differences and7or similarities between an electrochemical cell and an electrolytic cell8
6here do oxidation and reduction reactions occur in each t!pe of cell8
("nswer: 3n electrochemical cells4 chemical ener! is con9erted to electrical ener! (to produce
electricit!)* in electrol!tic cell4 electrical ener! is used to cause nonspontaneous processes to occur.
3n both t!pes of cells4 oxidation occurs at anode and reduction occurs at cathode.)
1
Chem 1B
Chapter 18 Exercises
$. :i9en the followin reduction potentials:
#alf,;eaction E
o
(<) ==
3$ ) $e
,
$3
,
* >./'
?e
.)
) e
,
?e
$)
* >.11
Br$ ) $e
,
$Br
,
* 1.>@
0n&'
,
) 8#
)
) /e
,
0n
$)
) '#$&* 1./1