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MODEL EXAMINATION PAPER IN CHEMISTRY

CHEMISTRY Class XII 2011 12 Instr* ti!ns t! an+i+ates
i.) ii.) iii.) iv.) v.) vi.) All questions are compulsory. Question nos. 01 t! 08 are very short answer questions and carry 1 mark each. Question nos. 0, t! 18 are short answer questions and carry 2 marks each. Question nos. 1, t! 27 are also short answer questions and carry - marks each. Question nos. 28 t! -0 are long answer questions and carry . marks each. Use log tables if necessary, use of calculators is not allowed.

Prepared by Mr% '&ITH &'C()

Max marks: 70 Time: 180 min

1.) ".) *.) /.) 1.) (.) 7.) 9.) ;.)

hy is the ester hydrolysis slow in the beginning and becomes faster after sometime! hich of the following ions will have the highest magnetic moment value! #$r%&"')()*+, #,e%&"')()"+ and #-n%&"')()"+ .ive equation to represent the mole fraction of a solution containing five components. .ive 0UPA$ name of 2ame the monomers of 3una 2. .ive one use of 3una 4 2 hat are broad5spectrum antibiotics! .ive one e6ample. Arrange the following in increasing order of basic strength8 $(&12&", $(&12%$&*)", %$"&1)"2& and $&*2&" hat are en:ymes! .ive one e6ample. a.) hat is the name of the vacancy defect when both ions are missing from an ionic crystal. b.) 'ut of 2a$l and Ag$l which is most li<ely to show this type of defect and why! c.) hat is the effect of this defect on density of the ionic solid d.) hat is the effect of this defect on the stoichiometry of the ionic compound! An element forms he6agonal close pac<ed structure. hat is the total number of voids in =.1 mol of it! &ow many of these are tetrahedral voids! >tate &enry?s law. &ow &enry?s law can be applied to save scuba divers from a very painful and dangerous condition <nown as bends! rite short notes on fuel cell. @6plain on the basis of valence bond theory that #2i%$2) /)" 4 ion with square planar geometry is diamagnetic and the #2i$l/)" 4 ion with tetrahedral geometry is paramagnetic. Ahe outer electronic configuration of two members of the lanthanoid series is as follows8 /f11d1(s" and /f71d=(s". hat are their atomic numbers! Predict the o6idation states e6hibited by these elements in their compounds. @6plain why8 a.) * 4 bromocyclohe6ene is more reactive than / 4 bromocyclohe6ene in hydrolysis with aq. 2a'&! b.) tert 4 butyl chloride reacts with aq 2a'& by >21 mechanism while n 4 butyl chloride reacts with >2" mechanism! Braw the structure of maCor mono5halo products in each of the following reactions8 3r D heat $( & 11'& + >'$l" a.) b.) ' " 2 $( & / $& "$& * &ow can you differentiate between addition and condensation polymeri:ation!
"

1=.) 11.) 1".) 1*.) 1/.) 11.)

1(.) 17.) 19.)

A 1E solution %by mass) of cane sugar in water has free:ing point of "71F. $alculate the free:ing point of 1E glucose in water if free:ing point of pure water is "7*.11F. 1;.) hat are artificial sweetening agents! .ive two e6amples. //0XII CHY02011 20120M!+el examinati!n 1a1er 02 1

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"=.) "1.) "".) "*.) "/.)

At ";1 F, molar conductivities at infinite dilution of 2& /$l, 2a'& and 2a$l are 1";.9, "17./ and 1=9.; ohm 41 cm" mol 41 respectively. 0f molar conductivity of centi5normal solution of 2& /'& is ;.** ohm 41 cm" mol 41, what is the degree of dissociation of 2& /'& solution! a.) .ive mechanism of en:yme catalysis b.) hat is the source of urease! .ive the en:ymatic reaction cataly:ed by urease a.) rite short note on :one refining. 2ame two elements, which are refined by this method. b.) $opper can be e6tracted by hydrometallurgy but not :inc. @6plain. Biscuss the general characteristics of the *d 4 series of the transition elements with special reference to their8 a.) atomic si:e, b.) enthalpies of atomi:ation c.) tendency for comple6 formation a.) &ow can you differentiate between8 i.) @thanol and propanol ii.) ,ormic acid and acetic acid b.) rite the mechanism of the reaction of &0 with metho6ymethane a.) hat happens when white phosphorus is heated with concentrated 2a'& solution in an inert atmosphere of $'". b.) hy does P$l* fume in moist air! c.) hat happens when P$l1 is heated! $omplete the following reactions8 $( & 1 2& " + $&$l* + alc.F'& a.) $( & 1 2 "$l + & * P' " + & "' b.) $( & 1 2 "$l + $" & 1'& c.) a.) >tate two main differences between globular proteins and fibrous proteins. b.) hat is denaturation of proteins! a.) Ahe time required for 1= E completion of a first order reaction at ";9 F is equal to that required for 1= ; , calculate k at *19 F and Ea. its "1 E completion at *=9 F. 0f the value of A is *.1( b.) Ahe decomposition of 2"'1 at an initial pressure of *9= mm and 1= =$ is 1= E complete in 1( minutes and 71 E complete in 1== minutes. hat is the order of reaction! &ow much of 2 "'1 will decompose in 1== minutes at 1= =$ but at an initial pressure of 1== mm a.) hat is oleum! .ive its structure b.) hat happens when >'" is passed through an aqueous solution of ,e%000) salts! c.) &ow is the presence of >'" detected! d.) Bescribe the structure of >'". &ow can you e6plain the fact that two > 4 ' bonds in >'" are of equal length. e.) .ive two important uses of >'" a.) b.) c.) rite short notes on i.) Folbe?s electrolysis ii.) >tephen reaction Predict the products of the following reaction
$& * $& = $& $&' + & " 2 $' 2& 2& "

"1.)

"(.)

"7.) "9.)

";.)

*=.)

Arrange the following compounds in increasing order of the property as indicated8 i.) Acetaldehyde, acetone, di 4 tert 4 butyl <etone, methyl tert butyl <etone %reactivity towards &$2) ii.) $&*$&"$&%3r)$''&, $&*$&%3r)$&"$''&, %$&*)"$&$''&, $&*$&"$&"$''& %acid strength) iii.) 3en:oic acid, / 4 nitroben:oic acid, *,/ 4 binitroben:oic acid, / 4 metho6yben:oic acid %acid strength) "

//0XII CHY02011 20120M!+el examinati!n 1a1er 02