Kurva titrasi 25,0 mL larutan ion kalsium, Ca(II), 0,100 M dengan larutan EDTA 0,100 M dengan titrasi yang

dilakukan pada pH 9,00.

Kurva Titrasi Kompleksometri (Vedta vs pCa)

10
9
8
7

pCa

6
5
pCa

4
3
2
1
0
0.0

10.0

20.0

30.0
Volume EDTA (mL)

40.0

50.0

60.0

Data Kurva :

Ca(II)
V
(mL)
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

M
(
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100

EDTA
V
M
(mL)
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20.0
21.0
22.0
23.0
24.0
24.1
24.2
24.3
24.4
24.5
24.6
24.7
24.8
24.9
25.0
25.1
25.2
25.3
25.4
25.5

0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100

V total
(mL)
25.0
26.0
27.0
28.0
29.0
30.0
31.0
32.0
33.0
34.0
35.0
36.0
37.0
38.0
39.0
40.0
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
49.0
49.1
49.2
49.3
49.4
49.5
49.6
49.7
49.8
49.9
50.0
50.1
50.2
50.3
50.4
50.5

Ph

Kf

9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00

1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09

[Ca2+]
sisa

[CaY2-]

1.00E-01
9.23E-02
8.52E-02
7.86E-02
7.24E-02
6.67E-02
6.13E-02
5.63E-02
5.15E-02
4.71E-02
4.29E-02
3.89E-02
3.51E-02
3.16E-02
2.82E-02
2.50E-02
2.20E-02
1.90E-02
1.63E-02
1.36E-02
1.11E-02
8.70E-03
6.38E-03
4.17E-03
2.04E-03
1.83E-03
1.63E-03
1.42E-03
1.21E-03
1.01E-03
8.06E-04
6.04E-04
4.02E-04
2.00E-04
5.23E-06
1.37E-07
6.88E-08
4.60E-08
3.47E-08
2.78E-08

0.00E+00
3.85E-03
7.41E-03
1.07E-02
1.38E-02
1.67E-02
1.94E-02
2.19E-02
2.42E-02
2.65E-02
2.86E-02
3.06E-02
3.24E-02
3.42E-02
3.59E-02
3.75E-02
3.90E-02
4.05E-02
4.19E-02
4.32E-02
4.44E-02
4.57E-02
4.68E-02
4.79E-02
4.90E-02
4.91E-02
4.92E-02
4.93E-02
4.94E-02
4.95E-02
4.96E-02
4.97E-02
4.98E-02
4.99E-02
5.00E-02
5.01E-02
5.02E-02
5.03E-02
5.04E-02
5.05E-02

[EDTA]
sisa

2.00E-04
3.98E-04
5.96E-04
7.94E-04
9.90E-04

pCa
1
1.034762
1.069636
1.104735
1.140179
1.176091
1.212608
1.249877
1.288065
1.327359
1.367977
1.410174
1.454258
1.500602
1.549672
1.60206
1.658541
1.720159
1.78837
1.865301
1.954243
2.060698
2.194977
2.380211
2.690196
2.736839
2.788875
2.847749
2.915576
2.995635
3.093422
3.219235
3.396199
3.698101
5.281907
6.86311
7.162413
7.336785
7.46001
7.555214

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100

25.6
25.7
25.8
25.9
26.0
27.0
28.0
29.0
30.0
31.0
32.0
33.0
34.0
35.0
36.0
37.0
38.0
39.0
40.0
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
49.0
50.0

0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
1.100
2.100
3.100
4.100
5.100
6.100
7.100
8.100
9.100
10.100
11.100
12.100
13.100
14.100

50.6
50.7
50.8
50.9
51.0
52.0
53.0
54.0
55.0
56.0
57.0
58.0
59.0
60.0
61.0
62.0
63.0
64.0
65.0
66.0
67.0
68.0
69.0
70.0
71.0
72.0
73.0
74.0
75.0

9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00

1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09
1.83E+09

2.33E-08
2.00E-08
1.76E-08
1.57E-08
1.42E-08
7.37E-09
5.10E-09
3.96E-09
3.28E-09
2.82E-09
2.50E-09
2.25E-09
2.06E-09
1.91E-09
1.79E-09
1.68E-09
1.60E-09
1.52E-09
1.46E-09
1.40E-09
1.35E-09
1.30E-09
1.26E-09
1.23E-09
1.20E-09
1.17E-09
1.14E-09
1.11E-09
1.09E-09

5.06E-02
5.07E-02
5.08E-02
5.09E-02
5.10E-02
5.19E-02
5.28E-02
5.37E-02
5.45E-02
5.54E-02
5.61E-02
5.69E-02
5.76E-02
5.83E-02
5.90E-02
6.56E-01
1.27E+00
1.89E+00
2.52E+00
3.17E+00
3.82E+00
4.49E+00
5.17E+00
5.85E+00
6.54E+00
7.25E+00
7.96E+00
8.67E+00
9.40E+00

1.19E-03
1.38E-03
1.57E-03
1.77E-03
1.96E-03
3.85E-03
5.66E-03
7.41E-03
9.09E-03
1.07E-02
1.23E-02
1.38E-02
1.53E-02
1.67E-02
1.80E-02
2.13E-01
4.33E-01
6.78E-01
9.46E-01
1.24E+00
1.55E+00
1.88E+00
2.23E+00
2.60E+00
2.99E+00
3.39E+00
3.81E+00
4.25E+00
4.70E+00

7.632695
7.697949
7.754254
7.803727
7.847811
8.13245
8.292747
8.402446
8.484633
8.549573
8.602732
8.64736
8.685547
8.718716
8.747874
8.773763
8.796944
8.817847
8.836815
8.85412
8.869983
8.884588
8.898085
8.910601
8.922245
8.933109
8.94327
8.952799
8.961754