LEMBAR PERHITUNGAN

1. Perhitungan Reagen
NaOH 0,25N 300 ml
N =

x valensi
gr =

3 gram

asam asetat =
1.04 gr/ml

etanol =
0.8 gr/ml

H2SO4 =
1.84 gr/ml
H
2
SO
4
0,24 N
N =

x eq x kadar
gr =

3 gram
V
H2SO4
=


= 1,63 ml
Volume total = V
H2SO4
+ V
etanol
+ V
asam asetat

250 = 1,63 + V
etanol
+ V
asam asetat

V
etanol
+ V
asam asetat
= 248,37 ml
Perbandingan mol etanol : Asam asetat = 1,5 : 1

V
etanol
+ V
asam asetat
= 248,37 ml
V
etanol
+ V
etanol
= 248,37 ml
V
etanol
= 150,08 ml
V
asam asetat
= 98,3 ml


Variabel 1(katalis H
2
SO
4
)
Gram asam asetat = v kadar = 1.04

98,3 ml 0,98 = 98,15

gram
C
AO
=

= 6,54 mol/L
Gram etanol = v kadar = 0,8

150,08 ml 0,96 = 115,26 gram

C
BO
=

= 10,0227 mol/L
C
A
=

= 0.05v 0.24
Xa = 1-

T
(menit)
Volume NaOH C
A
= 0.05v 0.24 Xa
0 92 4,36 0,333
14 84 3,96 0,394
28 64 2,96 0,547
42 62 2,86 0,563
56 60 2,76 0,578

CH
3
COOH + C
2
H
5
OH C
2
H
5
COOCH
3
+ H
2
O
A B C D

C
A
= C
AO
(1-X
A
) = C
AO
C
AO
.XA = 6,54 (1-X
A
)
C
B
= C
BO
C
AO
.X
A
= 10,0227 6,54 X
A

C
C
= C
AO
.X
A
= 6,54 X
A
C
D
= C
AO
.X
A
= 6,54X
A
M =

= 1,564
-

= k
1
(

= k
1
(

= k
1
(

= k
1
(

= k
1

= k
1

= k
1

)

Pada saat kesetimbangan
k =

=
(

)(

)

Konstanta Kesetimbangan
K =

= 0,65

= k
1

= k
1

)
Mencari nilai

=

*

Rumus ABC

= (X
A
0,55)(X
A
+ 5,31)
-0,0823

= -0,0823

A + B = 0
-0,87A - 5.33B = 1
A = 0.22
B = -0.22
Sehingga persamaan menjadi
0.37*

+ = k1 . t
0.0814xln *

+ = k1. t y = mx
t (x) X
A
Y XY X
2
0 0.68 -0.113 -0.113 0
5 0.72 -0.131 -0.131 25
10 0.81 -0.204 -2.04 100
15 0.82 -0.219 -3.285 225
20 0.83 -0.237 -4.74 400
25 0.84 -0.260 -6.5 625
30 0.87 - - 900
35 0.87 - - 1225
40 0.87 - - 1600



5100

= 0.004

mol/men
K =

k
2
=

= 1.44.10
-3
mol/men
Variabel 2 (suhu operasi : 50
o
C)
t (menit) Volume NaOH C
A
= 0.02v-0.5
X
A
= 1-

0 103 1.56 0.63
5 96 1.42 0.66
10 81 1.12 0.73
15 68.7 0.874 0.79
20 61.5 0.73 0.82
25 61.5 0.73 0.82
30 61.5 0.73 0.82

Pada saat kesetimbangan
k =

=
(

)(

)

K =

= 1.74
Mencari nilai

Rumus abc
X
A
2
9.23X
A
+ 6.91 = (

0.56

= 0.56
=

- 0.82A+ B

=(A+B)

A + B= 0
-0,82A- 8.4B= 1
A = 0.13
B = -0.13
Sehingga persamaan menjadi
0.56 X 0.13*

+ = K1 . t
0.0728 ln*

+ = k1. t y = mx
t (X) X
A
Y XY X
2
0 0.63 -0.1 0 0
5 0.66 -0.11 -0.55 25
10 0.73 -0.15 -1.5 100
15 0.79 -0.23 -3.45 225
20 0.82 - - 400
25 0.82 - - 625
30 0.82 - - 900

k
1
= m =

= 4.79 . 10
-3
mol/men
K =

k
2
=

= 2.75.10
-3
mol/men
Variabel 2 (suhu operasi : 65
o
C)
t (menit) Volume NaOH C
A
= 0.02v-0.5
X
A
= 1-

0 90 1.3 0.69
5 83.5 1.17 0.72
10 60.5 0.71 0.83
15 60.5 0.71 0.83
20 60.5 0.71 0.83

Pada saat kesetimbangan
k =

=
(

)(

)

K =

= 1.90
Mencari nilai

=

(

=

(

Rumus abc
X
A
2
8.45X
A
+ 6.32 = (

0.51

= 0.51
=

- 0.83A+ B

=(A+B)

A + B= 0
-0,83A- 7.62B= 1
A = 0.15
B = -0.15
Sehingga persamaan menjadi
0.51*

+ = K1 . t
0.077 ln*

+ = k1. t y = mx
t (X) X
A
Y XY X
2
0 0.69 -0.13 0 0
5 0.72 -0.115 -0.75 25
10 0.83 - - 100
15 0.83 - - 225
20 0.83 - - 400

k
1
= m =

= 8.2 . 10
-3
mol/men
K =

k
2
=

=
1

= 4.3.10
-3
mol/men