LEMBAR PERHITUNGAN

A. Analisa Kadar Asam Lemak dalam Bahan Baku Minyak Jarak

(𝑉 𝑥 𝑁)𝑁𝑎𝑂𝐻 𝑥 𝐵𝑀𝑀𝐽
% 𝐾𝑎𝑑𝑎𝑟𝐴𝑠𝑎𝑚 𝐿𝑒𝑚𝑎𝑘 = 𝑥 100%
(𝜌 𝑥 𝑉)𝑀𝐽 𝑥 10
(1,850 𝑥 0,155)𝑁𝑎𝑂𝐻 𝑥 1067
% 𝐾𝑎𝑑𝑎𝑟𝐴𝑠𝑎𝑚 𝐿𝑒𝑚𝑎𝑘 = 𝑥 100% = 3,300%
(0,927 𝑥 10)𝑀𝐽 𝑥 10

% Kadar gliserida = % Kadar Bahan Baku - % Kadar Asam Lemak Bahan Baku
= 100% - 1,458% = 96,699%

B. Perhitungan Asam Lemak Bebas Awal

(𝑉 𝑥 𝑁)𝑁𝑎𝑂𝐻
𝐴𝑠𝑎𝑚 𝑙𝑒𝑚𝑎𝑘 𝑏𝑒𝑏𝑎𝑠 𝑎𝑤𝑎𝑙 = = 𝑚𝑜𝑙 𝐴𝑠 𝑙𝑒𝑚𝑎𝑘/𝑔𝑟 𝑀𝐽
(𝜌 𝑥 𝑉)𝑀𝐽
(1,850 𝑥 0,155)𝑁𝑎𝑂𝐻
𝐴𝑠𝑎𝑚 𝑙𝑒𝑚𝑎𝑘 𝑏𝑒𝑏𝑎𝑠 𝑎𝑤𝑎𝑙 = = 30,993 𝑥 10−3 𝑚𝑜𝑙 𝐴𝑠 𝑙𝑒𝑚𝑎𝑘/𝑔𝑟 𝑀𝐽
(0,927 𝑥 10)𝑀𝐽

% 𝑔𝑙𝑖𝑠𝑒𝑟𝑖𝑑𝑎
𝑔𝑙𝑖𝑠𝑒𝑟𝑖𝑑𝑎 𝑎𝑤𝑎𝑙 = = 𝑚𝑜𝑙 𝐴𝑠 𝑙𝑒𝑚𝑎𝑘/𝑔𝑟 𝑀𝐽
% 𝑎𝑠 𝑙𝑒𝑚𝑎𝑘
96,699%
𝑔𝑙𝑖𝑠𝑒𝑟𝑖𝑑𝑎 𝑎𝑤𝑎𝑙 = = 29,302 𝑚𝑜𝑙 𝐴𝑠 𝑙𝑒𝑚𝑎𝑘/𝑔𝑟 𝑀𝐽
3,300%

C. Perhitungan Asam Lemak Bebas Setelah Hidrolisa

(𝑉 𝑥 𝑁)𝑁𝑎𝑂𝐻
𝐶𝐴 𝑠𝑒𝑡𝑒𝑙𝑎ℎ ℎ𝑖𝑑𝑟𝑜𝑙𝑖𝑠𝑎 =
(𝜌 𝑥 𝑉)𝑀𝐽
(𝑉 𝑥 0,155)𝑁𝑎𝑂𝐻 0,155𝑉
𝐶𝐴 𝑠𝑒𝑡𝑒𝑙𝑎ℎ ℎ𝑖𝑑𝑟𝑜𝑙𝑖𝑠𝑎 = =
(0,927 𝑥 10)𝑀𝐽 9,27

0,155𝑉
𝐶𝐴 𝑦𝑎𝑛𝑔 𝑡𝑒𝑟𝑏𝑒𝑛𝑡𝑢𝑘 = − 𝐶𝐴 𝑎𝑤𝑎𝑙
9,27
D. Menghitung Konversi
𝐶𝐴0 − 𝐶𝐴
𝑋𝐴 =
𝐶𝐴0

E. Perhitungan Nilai Konstanta Laju Reaksi

dCA
  k .CA
dt
CA t
dCA
  k  dt
CA 0
CA 0

CA
 ln  k .t
CA 0
CA(1  XA)
 ln  k .t
CA 0
 ln(1  XA)  k .t
 ln(1  XA)  k .t
y  mx

Hasil perhitungan
Variabel 1 suhu 55 °C

t V NaOH Ca Hidrolisa Ca Terbentuk Xa 1-X -Ln 1-X

0 16.2 0.27087378 0 0 1 0
5 17 0.23549696 0.20395719 0.22551594 0.77448405 0.25555820
10 17.2 0.24601021 0.214470447 0.23714047 0.76285952 0.27068137
15 23 0.24811287 0.216573099 0.23946538 0.76053461 0.27373364

Variabel 2 suhu 65 °C

t V NaOH Ca Hidrolisa Ca Xa 1-X -Ln 1-X

Terbentuk

0 21 0.031539772 0 0 1 0
5 21.5 0.23339431 0.20185453 0.22319103 0.77680896 0.25256082
10 21.8 0.23759961 0.20605984 0.22784084 0.77215915 0.25856459
15 25 0.25021552 0.21867575 0.24179028 0.75820971 0.27679526

Variabel 3 suhu 75°C

t V NaOH Ca Hidrolisa Ca Terbentuk Xa 1-X -Ln 1-X

0 32 0.03153977 0 0 1 0
5 35 0.24601021 0.214470447 0.23714047 0.76285952 0.270681372
10 37.5 0.27124203 0.239702265 0.26503935 0.73496064 0.307938323
15 43.5 0.33642423 0.304884459 0.33711145 0.66288854 0.411148415

F. Menghitung Nilai Konstanta Arah Kesetimbangan

−𝑋𝐴
𝐾=
𝑋𝐴 − 1