QUMICA INORGNICA II

TALLER - SIMETRA MOLECULAR E INTRODUCCIN A LA QUMICA DE

COORDINACIN
1)

Which of the following does not contain a C3 axis?

POCl3
[NH4]+
[H3O]+
ClF3

2)

Which of the following symmetry elements does contain cisN2F2?

a C2 axis
a h plane
an inversion center
an S2 axis

3)

Which two species belong to the same point group?

XeF2 and OF2
H2O and CO2
H2S and OF2
[NO2]+ and [NO2]

4)

Which of the following belongs to the C3v point group?

SO3
BBr3
NH3
AlCl3

5)

Which molecule does not have Td symmetry?

SiF4

P4
CH4
XeF4

6)

SO2 belongs to which point group?

C2v
C2
Dh
C2h

7)

Which of the following molecules or ions possesses an inversion

center (center of symmetry)?
[PF6]
SiH4
BF3
PF5

8)

Which of the following molecules or ions belongs to the C4v

point group?
SF5Cl
[BH4]
XeF4
trans-WCl2F4

9)

Which statement is true about the change in symmetry on

going from BF3 to [BF4]?
The point group changes from D3h to Td
The point group changes from C3v to Td
The point group changes from D3h to D4h
The point group changes from D3h to C3v

10)

The number of degrees of vibrational freedom possessed by CH 4

is:

10
6
4
9

11)

Enantiomers of [Cr(ox)3]3 are:

stereoisomers.
geometrical isomers.
structural isomers.
related by a rotation axis.

12)

How many isomers are there of octahedral [CrCl2(H2O)4]+ and

octahedral [CoCl2(en)2]+?
2 for [CrCl2(H2O)4]+; 2 for [CoCl2(en)2]+
2 for [CrCl2(H2O)4]+; 3 for [CoCl2(en)2]+
3 for [CrCl2(H2O)4]+; 3 for [CoCl2(en)2]+
3 for [CrCl2(H2O)4]+; 2 for [CoCl2(en)2]+

13) Deduzca la frmula de cada uno de los siguientes compuestos de coordinacin:

(a) Bromuro de hexaaminocromo (III).
(b) Tetracianonicolato(II) de potasio.
(c) Hexacianoferrato(II) de hierro (II)
(d) Cloruro de tetraacuodiclorocromo(III) dihidratado
14) Nombre sistemticamente cada uno de los siguientes compuestos de coordinacin:
(a) [Co(NH3)5(OH2)]Br3
(b) (NH4)2[Cu(Cl)4]
(c) [Co(SCN)2(OH4)](NCS).3H2O
(d) [Cu(NH3)4] (ClO4)2
15) Dibuje los tres ismeros del [Fe(acac)2(OH2)2]Cl octadrico y para cada uno
mencione qu tipo de isomera experimenta.