PUSAT PENGAJIAN SAINS KIMIA UNIVERSITI SAINS MALAYSIA KTT 212 Inorganic Chemistry II

Tutorial I
1. Give the electronic configuration for the following elements or ions: (i) (ii) (iii) (iv) 2. Fe(0) dan Fe(III) Co(0) dan Co(V) V(0) dan V(IV) Mn(0) dan Mn(VII)

What is the oxidation state for the metal in each of the following complexes? (i) (ii) [Mn(CO)5Br] [Ni(en)3]SO4 (iii) (iv) [Pt(py)(NH3)BrCl] [Cr(NH3)2(H2O)3(OH)](NO3)2

3.

Write the formula for the following compounds. (i) (i) (ii) (iii) Tetraamminedichlororuthenium(III) nitrate Hydridonitrosylbis(triphenylphosphine)nickel(II) Diaquadiiododinitritopalladium(IV) (note: all ligands trans) Aquachlorobis(ethylenediamine)rhodium(III) chloride

4.

Suggest an example for each of the following ligands. (i) (ii) (iii) (iv) Asymmetrical bidentate ligand Tetradentate ligand Bridging ligand with one donor atom Hexadentate ligand

5.

Give the correct names according to the IUPAC system for the following compounds: (i) (ii) (iii) (iv) [Ni(C5H5)NO] cis-[PtCl2(Et3P)2] [Co(NH2)2(NH3)4]OC2H5 [Fe(py)3][Fe(CO)4]

6.

For the octahedral complex having the formula M(ABC)(NH3)(H2O)Br, where ABC = the tridentate ligand H2N-C2H4-PH-C2H4-AsH2; answer the following questions: (i) (ii) How many isomers are possible? How many of these consist of pairs of enantiomers?

Sketch all isomers.