[CET – 07]

The number of antibonding electron pairs in

O22 – ion on the basis of molecular orbital
theory is: (At. No. of O-atom is 8)

1) 5 2) 4

3) 3 4) 2
[CET – 07]
For a stable molecule, the value of bond
order must be:

1) zero

2) positive

3) negative

4) there is no relation between stability and bond order

 [AIEEE – 06]
Which of the following is diamagnetic?

1) O2 2) O2 2 –

3) B2 4) N2+
 [CET – 06]
Which of the following is diamagnetic?

1) H2+ 2) O2

3) Li2 4) He2+
 [CET – 06]
Which of the following has the highest bond
order?

1) N2 2) O2

3) He2 4) He2+
 [COMEDK – 06]
Which of the following species has unpaired
electrons?

1) N2 2) N22+

3) N22– 4) O22–
 [AIEEE – 05]
Which of the following species is diamagnetic
in nature?

1) He2+ 2) H2

3) H2+ 4) H2 –
 [CET – 08]

A ligand can also be regarded as:

1)Lewis base 2) Bronsted acid

3) Lewis acid 4) Bronsted base

 [CET – 08]
A complex compound in which the oxidation
number of the metal is zero

1)[Ni(CO)4] 2) [Pt(NH3)4]Cl2

3) K4[Fe(CN)6] 4) K3[Fe(CN)6]
 [CET – 07]
Which complex cannot ionize in water?

1) [CoCl3(NH3)3] 2) K4[Fe(CN)6]

3) K2[PtF6] 4) [Pt(NH3)6]Cl4
 [CET – 07]
The oxidation state of iron in K4[Fe(CN)6] is

1) 1 2) 4

3) 3 4) 2
 [CET – 07]
IUPAC name of Na3[Co(NO2)6] is

1) sodium hexanitritocobaltate (II)

2) sodium hexanitrocobalt (II)

3) sodium hexanitrocobaltate (III)

4) sodium cobaltinitrite
 [CET – 07]
The number of unidentate ligands in the
complex ion is called:

1) oxidation number 2) primary valency

3) coordination number 4) EAN

 [COMED-K – 06]
Octahedral structure is shown by

1) nickel carbonyl

2) cuprammonium ion

3) ferrocyanide ion

4) argentocyanide ion
 AIEEE 2009
Using MO theory predict which of the
following species has the shortest bond
length ?

1) O22+ 2) O2+

3) O22– 4) O2–
AIEEE 2009
IIT 2010
 [CET – 06]
In which of the following complex ion, the
central metal ion is in a state of sp 3 d2 –
hybridization

1) [CoF6]3– 2) [Co(NH2)6]3+

3) [Fe(CN)6] 3– 4) [Cr(NH2)6]3+
 [CET – 06]
Which of the following can participate in
linkage isomerism?

1)H2NCH2CH2NH2 2) NO2 –

3) NH3 4) H2O
CET 2009
CET 2009
CET 2009
 [AIEEE – 05]
Which of the following compound shows lowest
value of paramagnetic character?

1) [Co(CN6)]3 – 2) [Fe(CN)6]3–

3) [Mn(CN)6] 3– 4) [Cr(CN)6]3–