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The Principles of Bond Strength Part-1
The Principles of Bond Strength Part-1
THE PRINCIPLES
OF BOND
STRENGTH Part-1
A Background Overview
03/23/15
Electrostati
c Approach
CHEMICA
L
BONDING
Covalent
Approach
Ionic Bond
Covalent Bond
Metalic Bond
Hydrogen Bond
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Normal Covalent
Bond
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CH4
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CH4 :
- bonding
Axial
Overlaping
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C2H4 :
- bonding
Lateral
Overlaping
- bonding
Axial Overlaping
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Orbital pz
NH3
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NH3 :
Non Bonding Electrons
Lone Pair Electrons
Free Electrons
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H2O
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H2O :
Non Bonding Electrons
Lone Pair Electrons
Free Electrons
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Atomic Charge
NH3
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Atomic Charge
+
H2O
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Formal Charge
Definition :
Formal charge may be regarded as the
electrical charge that an atom in a molecule
would have if all of the atoms had the same
electronegativity (all chemical bonds involved,
are assumed to have 0 % ionic character) .
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Oxidation Number
Definition :
Oxidation number may be regarded as the
electrical charge that an atom in a molecule
would have if all chemical bonds involved, are
assumed to have 100 % ionic character.
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WARNING ! ! !
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The Principles :
Covalent bonds between small atoms
tend to be stronger than covalent
bonds between larger atoms
Covalent bonds between atoms tend
to be weaker, the greater the
difference in principal quantum
number of the valence shell of the
two elements
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Pentadiene
C5H8 :
Delocalized Bonding
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Pentadiene
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C5H8 :
Localized
Bonding
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