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Unit4-MAL 2
Unit4-MAL 2
Introduction:
Chemical reactions play a vital role in manufacturing process. For design of chemical
process equipment, the operating conditions such as pressure, temperature,
composition and flow of the streams should be known. The material balance and energy
balance calculations come to the rescue of the designer and allows him to calculate the
various flow rates and temperature of the streams. Assuming that the kinetic data of the
reaction is available, the overall material balance of the steady state condition will be
discussed here.
Material balances:
The general mathematical statement can be written as
Total mass entering the unit = Total mass of products leaving the unit
It should be noted that in chemical reactions, the total mass of the input remains
constant, but the total moles may or may not remain constant.
Example: Consider the shift reaction
CO +H2O
CO2 +H2
In this, it can be observed that two moles of reactants react with each other and
produce also two moles, thus the number of moles of the reactants entering the reaction
equals the number of the products leaving the reaction. The ammonia synthesis
reaction can be written as
N2 +3H2
2NH3
It can be observed that four moles of reactant only produce two moles of ammonia. The
total mass of the reactant entering and the product leaving the reaction are equal. For
the reaction of first type
1 mole CO
1 mole H2O
1 mol H2
1 mole CO2
3 mole of H2
2 mole of NH3
The above equalities decide the stoichiometric requirements of the components. In the
processes involving chemical reaction, the total mass of various compounds entering a
reaction is equal to the total mass of various components leaving the reaction, but
entering moles of components need not be equal to the moles of components leaving.
While doing material balance calculations in such case, it is very convenient to use
basis of calculations in molar units. Generally calculations should be based on limiting
reactant and quantity of new products formed should be calculated with the help
of chemical reactions and amount of limiting reactants reacted.
For any reactant material the balance of material can be written as
Material entering= material reacted +material un reacted
For products we can write
Material leaving = material produced by the reaction.
If the material is produced by more than one reaction, then the material leaving is sum
of the materials produced by all he reactions.
Definitions:
Stoichiometry:
It is a theory of the proportions in which chemical species combine with one another.
Stoichiometric equations:
Stoichiometric equation of a chemical reaction is a statement indicating relative moles of
reactant and products that take part in the reaction. Any balanced reaction equation is a
stoichiometric equation.
For example consider the stoichiometric equation
CO + 2H2
CH3OH
According to the equation one molecule (mol or kmol) of CO reacts with two molecules
(mol or kmol) of hydrogen to produce one molecule (mol or kmol) of methanol.
Stoichiometric co-efficient:
It is the number that precedes the formula of each component involved in a chemical
reaction.
Thus in the above example, the Stoichiometric co-efficient of CO is one. The
stoichiometric co-efficient of H2 is 2 and stoichiometric co-efficient of methanol is one.
The stoichiometric requirements of components are given as
1kmol of CO 1kmol of CH3OH 2kmol of H2
Stoichiometric ratio:
Two reactants A and B are said to be present in Stoichiometric proportions if the ratio of
moles of A present to the moles of B present is equal to the Stoichiometric ratio
obtained from the balanced equation.
Consider a reaction
CO + 2H2
CH3OH
For the reactants in the above equation to be present in Stoichiometric proportion there
must be 2 moles of H2 for every mole of CO (then nH2/ n CO = 2/1 = 2) present in the
feed to the reactor.
When the reactants are fed to a reactor in Stoichiometric proportion and the reaction
goes to completion all of the reactants will be consumed. In case of above cited
reaction, for example, if 200 kmol of H2 and 100kmol of CO are initially present, the H2
and CO would disappear at the same instant. It follows that if we start with 100ml of CO
and less than 200 mol of H2 (i.e., of H2 is present in less than its Stoichiometric
proportion) H2 disappears before the CO. On the other hand, if there are more than 200
moles of H2 initially present, the CO disappears first.
C2H4O
SO3
And suppose that 100 moles SO2 /hr and 75 moles O2 /h are fed to the reactor. SO2 is
clearly the limiting reactant and to be in stoichiometric proportions, moles of O2 would
have to be 50 kmol / hr. The percent excess of O2 is therefore
= [(75 50) / 50] x 100 = 50
CONVERSION:
Conversion or fractional conversion or degree of completion is defined with respect to
limiting reactant and it gives idea regarding degree of completion of reaction. The
unreacted quantities of raw materials are easily obtained knowing the charged
quantities with the help of conversion then in turn it gives idea in case of unit process
whether recycling is to be done or not for process to be economically feasible.
Consider a chemical reaction
A+B
Moles of A reacted
x 100
Series reaction
A+B
C+B
Parallel reaction
x 100
and A
UNIT PROCESSES:
A Unit Process is a step in manufacturing in which chemical reaction takes place like
oxidation of toluene to benzaldehyde, hydrogenation of oils to vanaspathi.
Following are some of the examples of unit processes
Acetaldehyde
C6H6
1/2O2
CH3COOH
oxygen
Acetic acid
1/2O2
C4H2O3
Benzene
2CO2
2H2O
maleic anhydride
4HCl
+ O2
2Cl2
2 H2O
HYDROGENATION:
This unit process specifically refers to the chemical reaction of a substance with
molecular hydrogen in the presence of a catalyst.
CO2
+ 3H2
CH3OH
R CH = CH R' + H2
H2O
NITRATION:
Those reactions where one or more nitro group (- NO2)n are introduced into the reacting
molecule.
CH3
C6H5 CH3 +
HNO3
C6H4
H2O
NO2
Toluene
nitric acid
HYDROLYSIS:
It is applied to the reaction where in water effect a double decomposition with another
compound, hydrogen going to one component hydronyl to other.
C5H10Cl2
Mono chloro pentane
H2O
HCl
hydro chloride
C5H11OH
n pentanol
KCN
H2O
HCN
Pot.cyanide
KOH
hydrogen cyanide
pot.hydroxide
NEUTRALISATION:
The reaction taking place between an acid and alkali resulting in the formation of salt
and water is called neutralization.
CH3COOH
Acetic acid
NaOH
sodium hydroxide
CH3COONa
H2O
sodium acetate
ALKYLATION:
It may be defined as introduction of alkyl radical by substitution or addition into an
organic compound.
CH3Br
Methyl bromide
2Na
sodium
C2H5Br
CH3C2H5
ethyl bromide
propane
2NaBr
sodium bromide
AMINATION:
The amination reaction is one which results in the formation of amines. This may be by
reduction or by ammonolysis
Amination by reduction:
It refers to those reactions which involve the synthesis of amines by reductive
methods.
Amines may be defined as derivatives of ammonia where one or more of the hydrogen
is replaced by alkyl, aryl, hydronyl, aralkyl or heterocyclic groups.
NO2
NH2
Zn
Acid
Nitro benzene
aniline
Amination by ammonolysis:
It is the process of forming amines by the action of ammonia. It also includes the
use of the primary and secondary amines as aminating agents.
H2
RCHO + NH3
R CN (H2O + H2)
RCH2 NH2
SULFONATION:
It may be defined as any chemical processes by which the sulfonic acid group (SO2OH) or the corresponding salt or sulfonyl halide group (- SO2Cl) is introduced into
an organic compound.
R CH2COOH
NH2COOH
+ SO3
R CH (SO2OH) COOH
H2S2O7
NH2SO3H
CO2
EMULSIFICATION:
All chemical reactions resulting in the formation of esters are all under this category.
CH3COOH
Acetic acid
CH3CH2OH
n-propanol
CH3COOC2H5
H2O
ethyl acetate
water
HALOGENATION (Chlorination):
It can be defined as the process where by one or more halogen atom is introduced into
an organic compound.
C6H6
Benzene
C6H5Cl
Cl2
chlorine
Cl2
chlorine
CH2 = CH2
Br2
Ethylene
bromide
C6H5Cl
HCl
dichlorobenzene
CH2Br - CH2Br
ethylene bromide
HCl
Oxidation reactions:
Note:
Air is used as source of oxygen
Air is a mixture of oxygen and nitrogen
Air contains 79% nitrogen and 21% oxygen by mole
Solution Procedure:
Assume a suitable basis
Write the possible reactions
Calculate the oxygen required assuming complete oxidation
Calculate oxygen supplied from the excess
Calculate nitrogen entering along with oxygen
Identify the products of oxidation for the problem
Calculate the quantities of each of the products
Calculate the other required quantities as per problem requirement
1. Ethylene oxide is produced by oxidation of ethylene. 100 kmol of ethylene are fed to
a reactor and the product is found to contain 80 kmol ethylene oxide and 10 kmol CO2.
Calculate
a) the % conversion of ethylene and b) the percent yield to ethylene oxide.
Basis: 100 kmol ethylene fed to the reactor.
Reactions:
C2H4+1/2 O2C2H4O
(1)
C2H4+3O22CO2+2H2O (2)
80 kmol ethylene oxide is produced and this is possible only by reaction 1. As per
Stoichiometry 1kmol ethylene oxide will be produced per kmol of ehylene. Therefore
ethylene reacted for reaction 1 is 80 kmoles.
10 kmol of CO2 is produced and this possible through reaction 2. As per Stoichiometry 2
moles CO2 will be produced per mol ethylene. Therefore kmol ethylene reacted by
reaction 2 is 10/2=5 kmol.
Total ethylene reacted towards equation1and 2 = 80 + 5 = 85 kmol.
Total kmol of ethylene taken = 100 kmol
Therefore % conversion = (ethylene reacted / ethylene taken) x100
= (85/100) x100= 85%
% yield of ethylene oxide= (moles ethylene reacted to ethylene oxide /Total moles of
ethylene reacted) x100
= (80/85)100=94.12%
2. In the production of chlorine gas by oxidation of hydrochloric acid gas, air is used
30% in excess of that theoretically required. Based on 4 kmol HCl, Calculate a) the
weight ratio of air to hydrochloric aid gas in feed. b) if the oxidation is 80% complete,
find the composition of the product stream on mole basis.
Basis: 4 kmol HCl
4HCl+ O2 2Cl2 + 2 H2O
O2 required = 1 kmol
O2 supplied= 1x1.30 = 1.3 kmol because 30% excess air is used
N2 supplied along with O2= 1.3 x 79/21=4.89
Air supplied= O2 supplied + N2 supplied= 1.3+4.89=6.19 kmol
Weight of air supplied= 6.19x29=179.51 kg
HCl taken= 4 kmol= 4x36.5= 146 kg
Weight ratio of air to hydrochloric acid in feed = 179.51/ 146=1.23
If oxidation is 80% complete composition of the gases in mole%
Gases leaving:
Cl2, H2O, HCl,O2, N2
HCl reacted= 4x0.8=3.2 kmol
HCl leaving unreacted= 4 - 3.2=0.8 kmol
Components
Kmoles
Mole%
Cl2
1.60
17.04
H2O
1.60
17.04
HCl
0.80
8.52
O2
0.50
5.32
N2
4.89
52.08
Total
9.39
100.00
3. Calculate the composition of gases obtained by the burning of pure FeS2 with 60%
excess air. The oxidation proceeds according to the reaction
4FeS2 +11O2 2Fe2O3 + 8 SO2 .
Assume complete conversion of the reaction
Basis: 4 kmol of FeS2
O2 required= 11 kmol
O2 supplied =11x1.6= 17.6 kmol
N2 supplied= 17.6x79/21=66.21 kmol
Gases leaving: SO2,O2,N2
SO2 leaving = SO2 produced= 8 kmol
Component
moles
Mole%
SO
8.00
9.90
6.60
8.17
66.21
81.93
Total
80.81
100.00
4. Iron pyrites FeS2 is burnt with air 100 % in excess of that required to oxidize all iron
to Fe2O3 and all sulphur to sulphur dioxide. Calculate the composition of the exit gases
in mole% and weight %, if 80% of sulphur is oxidized to sulphur dioxide and the rest to
sulphur trioxide. All iron is oxidized to Fe2O3.
Basis: 4 moles of FeS2
4FeS2 +11O2 2Fe2O3 + 8 SO2
SO2 +1/2O2 SO3
O2 required= 11 moles
O2 supplied =11x2= 22 moles
N2 supplied= 22x79/21=82.76 moles
Gases leaving: SO2, SO3,O2,N2
SO2 leaving= SO2 produced- SO2 converted to SO3
= 8 8 x(1-0.8) = 8 -1.6 = 6.4 moles
SO3 leaving = SO3 produced= 1.6 moles
O2 leaving = O2 supplied O2 consumed
= 22 - 11- (1.6 x1/2 ) = 22-11- 0.8 =10.2
Moles
Mole%
Mol.wt
weight
Weight%
SO
6.40
6.34
64
409.46
12.87
1.60
1.58
80
128.00
4.02
10.20
10.10
32
326.40
10.26
82.76
81.97
28
2317.28
72.84
Total
100.96
99.99
3181.14
99.99
SO
O
6. In the oxidation of SO2 to SO3, the conversion is 75% by using 70% excess air.
Calculate a) composition of gases leaving the reactor in mole basis b) kg mole air fed
per kg mole SO2.
Basis: 1mol SO2
SO2+1/2O2 SO3
Mol O2 required= 0.5 mol
O2 supplied= 0.5x1.7= 0.85
N2 supplied=0.85x79/21=3.20
Air supplied= O2 supplied +N2 supplied= 0.85+3.2=4.05
Gases leaving the reactor
SO2,SO3,O2,N2
Moles SO2 reacted=1x0.75= 0.75 kmol
Moes SO2 leaving = SO2 unreacted= 1x(1-0.75)=0.25
Moles SO3 leaving = mol SO3 produced= 0.75x1/1=0.75
Mol O2 leaving= mol O2 supplied-O2 consumed = 0.85-0.75x1/2= 0.85-0.375=0.475
Mol N2 leaving= mol N2 supplied= 3.20
Composition of gases leaving
Component
Mol
Mol%
SO2
0.250
5.35
SO3
0.750
16.04
O2
0.475
10.16
N2
3.200
68.45
Total
4.675
100.00
7. In production of sulphur trioxide (SO3) 100 k mol of SO2 and 200 k mol of O2 are fed
to the reactor. The product stream is found to contain 80 k mol of SO3. Find the percent
conversion of SO2.
BASIS: 100 k mol of SO2 entering the reactor
100 k mol of SO2
200 k mol O2
product
REACTOR
Reaction
SO2 + 1/2O2
1 k mol of SO2
SO3
1 k mol of SO3
1 k mol of SO2
?
100
8.10 kg of PbS and 3 kgs of O2 react to yield 6 kgs of Pb and 1 kg of PbO2 according to
the reaction
PbS + O2
Pb+ SO2
PbS+2O2
PbO2+SO2
Calculate a. the amount of PbS that does not react b. %excess O2 based on the amount
of PbS that actually reacts c. amounts of SO2 formed d. % conversion of PbS to Pb.
Basis: 10 kg PbS and 3 kg O2 taken
PbS + O2
Pb+ SO2
( 1)
PbS+2O2
PbO2+SO2 (2)
The atomic weight values are Pb-207.2, S-32, O-16. Therefore weights of PbS = 239.2,
PbO2= 239.2 SO2=64, O2=32
, 2O2=64
CH3CHO + H2O
The conversion is 30% and excess air used is 10%. Calculate the composition of
product stream if 100 kg of C2H5OH per hour is fed to the reactor.
BASIS: 1 hr operation
100 kg/hr of C2H5OH is fed which is equal to = 100/46 = 2.1739 k mole
O2 required for 2.1739 k mole of C2H5OH = 2.1739x1/2 =1.087
O2 supplied = 1.087 x 1.1 = 1.1957 k mole
N2 accompanying = 1.1957 x (79/21) = 4.4981 k mole
Quantity of aldehyde formed = 2.1739 x 0.3 = 0.6522 (the conversion is 30%)
Alcohol (C2H5OH) remaining unconverted = supplied consumed
= 2.1739 (2.1739 x 0.3) = 1.5217 k mole
Water formed during the reaction = 0.6522 k mole
Oxygen leaving= oxygen supplied- oxygen utilized
=1.1957-2.1739x0.3x0.5=1.1957-0.3261=0.8696 kmol
Nitrogen leaving= 4.4981 kmol
Component
Moles
Mole%
Alcohol
1.5217
18.57
Formaldehyde
0.6522
7.96
Water
0.6522
7.96
Oxygen
0.8696
10.61
Nitrogen
4.4981
54.90
8.1938
100.00
10. Ethylene and oxygen are fed to a tubular reactor filled with silver catalyst at 250C.
The product ethylene oxide is recovered from gaseous effluent by absorption in water in
presence of acid at 60C. The reaction taking place is as follows
C2H4 + 1/2O2
C2H4O
C2H4O + H2O
- (1)
CH2OH
- (2)
CH2OH
Conversion for reaction (1) is 90% which for reaction (2) it is 65%. If 100 kg of ethylene
glycol (CH2OH - CH2OH) is formed, Calculate the quantity of ethylene supplied to the
tubular reactor.
BASIS: 100 kg of CH2OH - CH2OH formed
Ethylene glycol formed= 100/62 = 1.6129 k mol
As per reaction (2) the conversion is 65%
Quantity of C2H4O required for 1.6129 k mole of (CH2OH) 2 will be
= 1.6129 x1/1x (100/65)= 2.4814 k mol
As per reaction (1) conversion is 90%
Quantity of C2H4 required for the formation of 2.4814 k mole of C2H4O will be
= 2.4814 x (100/90) = 2.757 kmol
Mass of C2H4 required = 2.757 x 28 = 77.196 kg
Mass of C2H4 required for 100 kg of ethylene glycol formed is 77.196 kg.
11. Ethylene oxide is produced by oxidation of ethylene .100 k mole of ethylene and 100
k mole of oxygen is charged to the reactor. The conversion of ethylene is 85% and
percent yield of C2H4O is 94.12.Calculate the composition of product leaving the
reactor.
BASIS: 100 k mol each of C2H4 and O2 charged
100 k mole of C2H4
100 k mole of O2
REACTOR
Product
C2H4, C2H4O, CO2, H2O
C2H4 + 1/2O2
C2H4O
C2H4 + 3O2
2CO2 + 2H2O
Percent conversion = 85
Moles of C2H4 totally reacted = 0.85 x 100 = 85 k mol
Percent yield of C2H4O = 94.12
Moles of C2H4 reacted to C2H4O by reaction (1)
= 0.9412 x85 = 80 kmol
Moles of C2H4 reacted by reaction (2) = 85 80 = 5 k mole
1 kmol C2H4
2 kmol of CO2
Quantity, kmol
C2H4
15
9.38
C2H4O
85
50.00
O2
45
28.12
CO2
10
6.25
H2O
10
6.25
Total
160
Mole%
100.00
C2H4O
If air is used 20%b in excess of that theoretically required. Calculate the quantity of air
supplied based on 100 k mol of ethylene fed to the reactor.
BASIS: 100 kmol of ethylene fed to the reactor.
Reaction:
C2H4 + 1/2 O2
C2H4O
0.5 kmol of O2
0.5 kmol of O2
Oxygen
acetaldehyde-14.81%
Oxygen-25.93
CH3CHO + 1/2O2
Reaction:
CH3COOH
REACTOR
REACTOR
Product SO3, SO2, O2
Reaction
SO2 + 1/2O2
SO3
k mol
mole%
SO2
20
12.5
SO3
80
50.0
O2
60
37.5
Total
160
100.0
15. In manufacture of SO3,the feed to the reactor consists of 50 k moles of SO2 and 150
k moles of air. Calculate % excess of air used.
BASIS: 50 k moles of SO2 fed to the reactor.
Reaction:
SO2 + 1/2 O2
SO3
0.5 kmol of O2
The dry air is supplied at 100% excess so as to maintain the high yield of
benzaldehyde. The side reaction taking place is
C6H5CH3 (g) + 9O2 (g)
At the above mentioned conditions the overall conversion is 13% based on toluene.
Approximately 0.5 of the toluene charged burns to CO2 and H2O. calculate the
composition of gas stream leaving the converter.
BASIS: 100 kmol of toluene charged
C6H5CH3 (g) + O2 (g)
kmol
mole%
C6H5CH3
87.0
8.18
C6H5CHO
72.5
1.18
N2
752.4
70.79
O2
193.0
18.16
CO2
3.5
0.33
H2O
14.5
1.36
1062.9
100.00
Hydrogenation
17.A mixture of pure carbon dioxide and hydrogen is passed over a nickel catalyst. The
temperature of the catalyst bed is 588K and the reactor pressure is 2.02 mPag. The gas
mixture leaving the reactor is analyzed to contain 57.1% CO2, 41.1% H2, 1.68% CH4
and 0.12% CO by volume on dry basis. The reactions taking place in the reactor are
CO2+4H2 CH4+2H2O
CO2+H2CO+H2O
Find a) the conversion of CO2 per pass b) the yield of CH4 in terms of CO2 reacted and
c) the composition of feed.
Basis: 100 kmol of dry gases leaving the reactor
CO+4H2 CH4+2H2O (1)
CO2+H2CO+H2O (2)
Mol
Mol%
H2
47.94
44.87
CO2
58.90
55.13
Total
106.84
100.00
18.Gaseous benzene C6H6 reacts with hydrogen in presence of Ni catalyst as per the
reaction
C6H6 +
Benzene
3H2
C6H12
cyclohexane
30% excess hydrogen is used above that required by the above reaction. Conversion is
50% and yield is 90%. Calculate the requirement of benzene and hydrogen gas for 100
moles of cyclohexane.
Basis: 1 mol benzene
H2 required= 3 mol
Hydrogen supplied= 3x1.3= 3.9 mol
Cyclohexane produced for a 50% conversion and 100 % yield= (1/1) x 1 x 0.5 = 0.5 mol
Since yield is 90 %, cyclohexane produced = 0.5 x 0.9 = 0.45 mol
(1)
CO+3H2CH4+H2O
.(2)
mol
Mol%
Mol
weight
Weight%
weight
CO
28
30.43
28
784
75.97
H2
59.5
64.68
119
11.53
CH3OH
3.5
3.81
32
112
10.85
H2O
0.5
0.54
18
0.87
CH4
0.5
0.54
16
0.78
Total
92
100.00
1032
100.00
21. The carbon monoxide is reacted with hydrogen to produce methanol. Calculate from
the reaction, the stoichiometric ratio of H2 to CO. k mol of CH3OH produced per k mol
CO reacted. The weight ratios of CO to H2 if both are fed to the reactor in stoichiometric
proportions. The quantity of CO required to produce 1000 kg of CH3OH.
reaction
CO + 2H2
CH3OH
Stoichiometric co-efficient of CO = a =1
Stoichiometric co-efficient of H2 = b = 2
Stoichiometric ratio of H2 to CO = b/a = 2/1 = 2
From the reaction 1 k mol of CO
1 k mol of CH3OH
32 kg CH3OH
H2
2NH3
Calculate the molal flow rate of hydrogen corresponding to nitrogen feed rate of 25
k mol/hr if they are at the stochiometric proportions. The kg of ammonia produced per
hour if percent conversion is 25 and nitrogen feed rate is 25 k mol/hr.
BASIS: 25 kmol / hr of N2 fed to the reactor.
Reaction:
N2 +
H2
2NH3
3 k mol of H2
Amount of NH3 produced = 12.5x molecular weight of NH3 = 12.5x 17 = 212.5 kg/hr.
23.Gaseous benzene (C6H6) reacts with hydrogen in presence of Ni catalyst as per the
reaction
C6H6 (g) + 3H2 (g)
C6H12 (g)
30% excess hydrogen is used above that required by the above reaction. Conversion is
50% and yield is 90%. Calculate the requirement of benzene and hydrogen gas for 100
kmol of cyclo hexane.
BASIS: 100 kmol of cyclo hexane
Reaction:
C6H12 (g)
100 x 100
Kmol of benzene totally reacted
111.11
x 100
Nitration
24.Benzene reacts with nitric acid to produce nitrobenzene and water
C6H6+HNO3 C6H5NO2 +H2O
Nitrobenzene undergo further nitration to form dinitrobenzene
C6H5NO2 +HNO3C6H4 (NO2)2+H2O
The percent conversion of benzene is 90 and acid used is 65% excess over theoretical
required by reaction 1. If the mole ratio of benzene to dinitrobenzene in product stream
is 17:1, calculate the quantities of benzene and nitric acid required for production of
2000 kg/h of nitrobenzene.
Basis: 1kmol / h benzene fed to the reactor
C6H6+HNO3 C6H5NO2 +H2O
C6H5NO2 +HNO3C6H4 (NO2)2+H2O
Benzene converted= 0.9 kmol because conversion is 90%
Kmol nitrobenzene produced = 0.9 x 17/18= 0.85
Kmol dinitrobenzene produced= 0.9 x 1/18= 0.05
(Ratio of nitrobenzene to dinitrobenzene in product is 17:1)
Nitric acid required for the reaction= 1kmol
Nitric acid fed = 1 x 1.65 = 1.65 kmol
Weight of Nitric acid fed = 1.65 x 63 = 103.95 kg/h
Weight of benzene fed to the reactor = 1x78= 78 kg/h
Nitrobenzene produce /h = 0.85 x 123 = 104.55 kg/h
Benzene required for the production of 2000 kg/h of nitrobenzene
= (78/104.55) x 2000 = 1492.11kg/h
Nitric acid required for the production of 2000 kg/h of nitrobenzene
= (103.95/104.55) x 2000 = 1988.52 kg/h
25. Benzene reacts with nitric acid to produce nitrobenzene and water. Some of the
nitrobenzene may further undergo nitration to form dinitrobenzene. If the product
streams contain 10 mol nitrobenzene,2 mol dinitrobenzene and 4mol benzene, calculate
the percent conversion of benzene, yield of nitrobenzene and selectivity to
nitrobenzene.
= (1/1) x 2 = 2 mol
189
229
54
Mol weight of phenol= 94 , mol weight of nitric acid=63 ,molecular weight of picric
acid=229, molecular weight of water=18.
Weight of HNO3 required to react with 100 kg phenol= (189 /94)100= 201.06 kg
HNO3 used = 250 kg. Since HNO3 used is more than the required, it is an excess
reactant. Therefore phenol is the limiting reactant.
200 kg of picric acid is produced.
Therefore weight of phenol reacted to give 200 kg picric acid as per stoichometry
= (94/229) x 200 = 82.1 kg.
Conversion of the reaction= (limiting reactant reacted / limiting reactant taken) x100
= (82.1/100)100= 82.1 %
Components leaving the reactor: Picric acid, phenol, nitric acid, water
Picric acid leaving = picric acid produced = 200 kg
Water leaving = water produced = (54/229)x200 = 47.16 kg
Phenol leaving = phenol unreacted = phenol taken phenol reacted= 100- 82.1= 17.9 kg
Nitric acid leaving = nitric acid unreacted = nitric acid taken - nitric acid reacted
= 250 - (189/94) x 82.1= 250-165.07= 84.93 kg
Composition of the product stream:
Component
Weight
Weight %
Mol weight
mol
Mol%
Picric acid
200.00
57.14
229
0.873
17.70
Phenol
17.90
5.11
94
0.190
3.85
Water
47.16
13.47
18
2.620
53.13
Nitric acid
84.93
24.27
63
1.248
25.31
Total
349.99
99.99
4.931
99.99
27. Toluene reacts with nitric acid to form ortho nitro toluene and water. After carrying
out the nitration operation which can be represented by the equation
C6H5CH3 +HNO3 C6H4CH3NO2+H2O
The product mixture was analyzed and found to contain 75% ortho nitro toluene 10%
water, 15% nitric acid by weight. Comment about the conversion of the reaction. What is
the % excess of the reactant used? What is the quantity of toluene used for the
reaction?
Basis: 100 kg of products
The product does not contain toluene and therefore the conversion is 100% and also
toluene is the limiting reactant.
Amount of ortho nitro toluene produced= 75 kg
HNO3 reacted to produce 75 kg o nitro toluene= (63/137) x 75 = 34.49 kg
HNO3 unreacted= 15 kg
HNO3 fed= HNO3 reacted+HNO3 unreacted= 34.49+15= 49.49 kg
% excess HNO3= (15/ 34.49) x100= 43.49%
Toluene fed for the reaction= (92/ 137) x75= 50.36 kg.
28.Benzoic acid is nitrated to obtain nitro benzoic acid according to the reaction
C6H5COOH+HNO3 C6H4 (COOH) NO2 + H2O.
122
63
167
18
Calculate the weight of 90% HNO3 required for reacting with 250 kg benzoic acid. If
50% excess acid is used and if the conversion is 85% find the composition of the
products leaving the reactor.
Basis: 250 kg benzoic acid
90% HNO3 required to react with 250 kg benzoic acid = (63/122) x250 x 100/90 =143.44
Acid used = 143.44 x 1.5 = 215.16 kg
100% acid = 215.16 x 0.9 = 193.64 kg
Water entering with acid = 215.16 x 0.1= 21.52kg
Conversion is 85%
Benzoic acid reacted = 250 x 0.85 = 212.5 kg
Benzoic acid unreacted = 250 x 0.15 = 37.5 kg
HNO3 reacted
Component
Weight
Weight%
Benzoic acid
37.50
5.87
Nitric acid
83.91
13.12
465.06
72.74
Water
52.87
8.27
Total
639.34
100.00
29. Chlorobenzene is nitrated using a mixture of nitric acid and sulphuric acid. During
the pilot plant studies, a charge of 100 kg chlorobenzene 106.5 kg 65.5% (by weight)
nitric acid and 108.0 kg 93.6% (by weight) sulphuric acid. After two hours of operation,
the final mixture was analysed.It was found that the final product contained 2%
unreacted chlorobenzene. Also the product distribution was found to be 66% p nitro
chloro benzene and 34% O nitro chloro benzene. Calculate a) The analysis of charge
b)The % conversion of chloro benzene and c)The composition of product mixture.
BASIS: 100 kg Chloro benzene
The charge consists of chloro benzene and mixed acid
HNO3 charged = 106.5 x 0.655 = 69.758 kg
H2SO4 charged = 108.8x 0.936 = 101.088 kg
Water in the charge = 106.5 x 0.345 + 108.0 x 0.064 = 43.655 kg
The analysis of the reactant can be tabulated as shown
Component
Chloro benzene
mol weight
Qty Charged
Weight.%
112.5
100.00
31.80
Nitric acid
63.0
69.76
22.18
Sulphuric acid
98.0
101.09
32.14
Water
18.0
43.66
13.88
314.51
100 .00
NO2
+
H2O
+ HNO3
Chloro benzene nitric acid
water
Cl
Cl
+
H2O
+ HNO3
NO2
water
As given in the problem, the yield of P NCB is 66%. Since the total charge (weight)
remains constant.
Unreacted C.B in the product = 314.5 x 0.02 = 6.29 kg.
Amount of C.B that has reacted = 100 6.29 = 93.71 kg.
Conversion of C.B = 93.71 x 100 = 93.71%
100
Sulphuric acid remains unreacted
From reaction I it is clear that 1 kmol of C.B
1 kg mol HNO3
1 kg mol NCB
1 kg mol H2O
112.5 kg of CB 63 kg of HNO3
Thus 63 kg of HNO3 will be consumed for converting 112.5 kg C.B into NCB
Total HNO3 consumed = (63/112.5) x 93.71
=52.478 kg
Unreacted HNO3 = 69.758-52.478 =17.28 kg
Mol wt of NCB=157.5
Total NCB produced = (157.5/112.5) x 93.71=131.194 kg
p-NCB = 0.66x131.194=86.588 KG
o-NCB = 0.34x131.194 =44.606 kg
Water produced = (15/112.5)x 93.71 =14.994 kg
Total water produced =43.665+14.994=58.649 kg
Weight
Weight%
CB
6.27
2.00
P NCB
86.59
27.33
O NCB
44.61
14.18
HNO3
17.28
5.49
H2SO4
101.09
32.15
H2O
58.65
18.65
TOTAL
314.48
100.00
Sucrose
(Monosaccharide)
(d-Glucose) (d-Fructose)
Alcohol
Calculate the theoretical production of rectified spirit of density (0.785 kg/l) in liters per
ton of molasses.
Basis: 1000 kg of molasses.
Sucrose
(d-Glucose)
(d-Fructose)
32.100 kmol of ethyl acetate is charged and hydrolyzed to produce ethyl alcohol and
acetic acid. The product stream is fond to contain 45 kmol ethyl alcohol. What is the
conversion? What will be the amount of acetic acid produced?
Basis: 100 kmol ethyl acetate
CH3COOC2H5 + H2O C2H5OH +CH3COOH
88
18
46
60
40
58.5
18
weight
Weight %
Mol wt
mol
Mol%
NaCl
160.27
64.11
58.5
2.74
42.22
NaOH
40.41
16.16
40
1.01
15.56
H2O
49.32
19.73
18
2.74
42.22
Total
250
100.00
6.49
100.00
35. Ammonium hydroxide is used for neutralizing acetic acid according to the reaction.
CH3COOH +NH4OH CH3COONH4 +H2O
If 120 kg of acetic acid is to be neutralized what will be the quantity of ammonium
hydroxide required? If 25% excess NH4OH is used and if the reaction is 90% complete,
what will be the composition of the product streams?
Basis: 120 kg acetic acid fed
CH3COOH + NH4OH CH3COONH4 +H2O
60
35
77
18
Weight
Weight %
Ammonium acetate
138.6
66.80
Water
32.4
15.61
Ammonium hydroxide
24.5
11.81
Acetic Acid
12.0
5.78
Total
207.5
100.00
Esterifcation
36.Ethyl acetate ester is produced by the reaction between acetic acid and ethanol
using catalyst. The reaction goes to completion. The acetic acid used contained 10%
water. Calculate the quantity of ethyl acetate produced for 200 kg ethanol and complete
analysis of products.
Basis: 200 kg ethanol
CH3COOH+ C2H5OH CH3COOC2H5 +H2O
60
46
88
18
Weight
Weight%
Ethyl acetate
382.61
78.11
Water
107.25
21.89
Total
489.86
100.00
with ethanol in
presence of catalyst. The feed mixture is taken in a batch reactor along with catalyst
and at the end of reaction the products were analyzed and found to contain 35% ethyl
benzoate, 35% water, 10% ether and 20% benzoic acid. What is the % conversion of
the reaction? Which is the excess reactant and what is the % excess?
Basis: 100 kmol reaction products
C6H5 COOH+ C2H5OH C6H5COOC2H5+ H2O
Benzoic acid
ethanol
ethyl benzoate
Neutralization
38.100 kg hydrochloric acid is neutralized by 150 kg of sodium hydroxide. What is the
quantity of sodium chloride that will be produced? Find the composition of neutralized
mixture by eight and mol.
Basis: 100 kg HCl and 150 kg NaOH
HCl+ NaOH NaCl + H2O
36.5
40
58.5
18
weight
Weight %
Mol wt
mol
Mol%
NaCl
160.27
64.11
58.5
2.74
42.22
NaOH
40.41
16.16
40
1.01
15.56
H2O
49.32
19.73
18
2.74
42.22
Total
250
100.00
6.49
100.00
39. Ammonium hydroxide is used for neutralizing acetic acid according to the reaction.
CH3COOH +NH4OH CH3COONH4 +H2O
If 120 kg of acetic acid is to be neutralized what will be the quantity of ammonium
hydroxide required? If 25% excess NH4OH is used and if the reaction is 90% complete,
what will be the composition of the product streams?
35
77
18
Weight
Weight %
Ammonium acetate
138.6
66.80
Water
32.4
15.61
Ammonium hydroxide
24.5
11.81
Acetic Acid
12.0
5.78
Total
207.5
100.00
Esterifcation
40.Ethyl acetate ester is produced by the reaction between acetic acid and ethanol
using catalyst. The reaction goes to completion. The acetic acid used contained 10%
water. Calculate the quantity of ethyl acetate produced for 200 kg ethanol and complete
analysis of products.
Basis: 200 kg ethanol
CH3COOH+ C2H5OH CH3COOC2H5 +H2O
60
46
88
18
Weight
Weight%
Ethyl acetate
382.61
78.11
Water
107.25
21.89
Total
489.86
100.00
with ethanol in
presence of catalyst. The feed mixture is taken in a batch reactor along with catalyst
and at the end of reaction the products were analyzed and found to contain 35% ethyl
benzoate, 35% water, 10% ether and 20% benzoic acid. What is the % conversion of
the reaction? Which is the excess reactant and what is the % excess?
Basis: 100 kmol reaction products
C6H5 COOH+ C2H5OHC6H5COOC2H5+ H2O
Benzoic acid
ClC2H5
C6H5C2H5 +
ethyl chloride
HCl
ethyl benzene
Ethyl chloride is used 15% in excess of theoretically required. The reaction is 95%
complete. During alkylation the liberated HCl is scrubbed with water in order to obtain
20%HCl solution by weight. Calculate the raw materials required for 3000 kg of ethyl
benzene produced and the amount of 20% HCl produced.
Basis: 1 kmol benzene
C6H6 + C2H5Cl C6H5C2H5 + HCl
78
64.5
106
36.5
50.5
92
36.5
Weight
Weight %
Benzene
200
57.14
Chloromethane
150
42.86
Total
350
100.00
feed to the reactor contains only acetone and ammonia. Calculate the fractional
conversion of the limiting reactant and the % by which the other reactant is in excess.
Basis: 100 kmol of products formed
CH3COCH3+ NH3 CH3-CH-NH2-CH3+H2O
Acetone
Amino propane
Benzmide
Mol
mol %
Benzamide
0.9
34.62
Hydrochloric acid
0.9
34.62
Benzyl chloride
0.1
3.85
Ammonia
0.7
26.92
Total
2.6
100.01