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Lecture 5c
Balances in terms of molar flow rates
Block 1: Mole Balances
Balance Equation on Every Species
Block 2: Rate Laws
Relative Rates
Transport Laws
Block 3: Stoichiometry
Block 4: Combine
Review Lecture 1
Differential
Algebraic
Integral
NA
dN A
t=
rV
N A0 A
Batch
NA
CSTR
PFR
FA
dFA
= rA
dV
V
PBR
3
W=
FA
FA 0
dFA
rA
FA
Review Lecture 2
Differential
Algebraic
Integral
X
Batch
N A0
dX
= r AV
dt
t
FA 0 X
V=
rA
CSTR
dX
V = FA0
rA
0
PFR
X
PBR
4
dX
FA 0
= rA
dW
Membrane Reactors
Membrane reactors can be used to achieve
conversions greater than the original equilibrium
value. These higher conversions are the result of
Le Chateliers principle; you can remove the
reaction products and drive the reaction to the right.
To accomplish this,
Membrane Reactors
Dehydrogenation Reaction:
Thermodynamically Limited:
exothermic
Xe
Xe
X
T
Membrane Reactors
Membrane Reactors
Membrane Reactors
sweep
FA0
B
A,B,C
B
CBS
CB
A,C stay behind since they are
too big
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Membrane Reactors
Mole Balance on Species A:
dFA
= rA
dV
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Membrane Reactors
Mole Balance on Species B:
Species B:
FB V FB V + V RB V + rB V = 0
12
Membrane Reactors
molar flow rate through membrane mol
'
WB = kC (CB CBS ) =
m 2 s
surface area of membrane
RB = WB a = kC' a[C B C BS ]
kC = kC' a
RB = kC [C B C BS ]
13
mol
m3 s
Membrane Reactors
Mole Balances:
(1 )
(2 )
dF A
= rA
dV
dFB
= rB RB
dV
Rate Law:
14
Membrane Reactors
Relative Rates:
Net Rates:
Transport Law:
Stoichiometry:
(5)
(6)
(7 )
(8)
(10)
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Parameters:
rA = rB , rA = rC
RB = kC C B
F
C A = CT 0 A
FT
F
C B = CT 0 B
FT
(isothermal, isobaric)
FT = FA + FB + FC
Membrane Reactors
Example: The following reaction is to be carried out
isothermally in a membrane reactor with no
pressure drop. The membrane is permeable to
product C, but impermeable to all other species.
H2 (C)
C6H12 (A)
C6H6 (B)
For membrane reactors, we cannot use conversion. We
have to work in terms of the molar flow rates FA, FB, FC.
16
Membrane Reactors
Mole Balances
dFA
= rA
dW
dFB
= rB
dW
dFC
= rC kC CC
dW
17
C6H6 (B)
Membrane Reactors
Relative Rates:
Net Rates:
18
rA rB rC
=
=
1 1
3
Membrane Reactors
Stoichiometry:
Isothermal, no Pressure Drop
P0
CT 0 =
RT0
FA
C A = CT 0
FT
FB
CB = CT 0
FT
FT = FA + FB + FC
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Membrane Reactors
Combine: - Use Polymath
mol
FA0 = 10
s
Parameters:
dm 3
k A = 10
kg cat s
mol 2
K C = 200
dm 6
20
Membrane Reactors
C6H12 (A)
C6H6 (B)
Ci
H2 (C)
21
End of Lecture 5c
22