Fiitjee Paper Main Sol

AITS-CRT-I PCM(S)-JEE(Main)/14
FIITJEE
JEE(Main)-2014
ANSWERS, HINTS & SOLUTIONS
CRT I
(Main)
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Q. No.
1.
PHYSICS
C
CHEMISTRY
D
MATHEMATICS
A
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
1.
PART I
3 14 106 5
1
15.7 ohm metre.
2r L R

ohm metre.
L
R
r
01 01 01
15 7 2
ohm metre
1
1
5
15.7 02 01 002 ohm metre

15.7 032 m
5024 m
P
3 0 1 2 0 2 3 0 3 4 0 1
P
3 4 9 4 2%
2.
100
3.
A N0 e t0
3Ae 3N0 e t
1
tt
e 0 e 1
e
1
t t0 .
v o sin
,v1 v 0 cos i
g
v 2 v 0k gtj

v 2 v1 v0 k gt j v 0 cos i
4.
At t
5.
f a2 Z b .
(D)
6.
dv k mg x
dx
m
0
x0
k mg
vdv
xdx
m
o
v
0
x0 v0
7.
Imax
Imin
m
k mg
I1 I2
I1 I2
2
2
I1 1
if I1 > I2
I2 1
8.
Ic
10 2
5 2
100
sin 50t
4
5 2
/4
/4
I=Ic+IL
/4
/4
100
IL
sin 50t
4
5 2
I = 20sin(50t)
9.
5 2
2mg sin30 T = 2m(a)

T = ma
mg
a g/3&T
3
Net force =
T
600
T
300
Result of these forces T j T cos600 j T sin 60 i
3 3
T i Tj
2
2
mg
3i 3j
6
As net force in pulley = 0,
mg
force by clamp
3i 3 j
6
10.
The circuit can be simplified as:

00 ,peak current =20 Ampere.
.004F
.1H
1
5
c
100 sin [50t] volts.
12.
When u decreases v increases. For plane mirror u decreases.

the image in plane mirror moves towards the left.
13.
14.
.004F
L5
0I
1 1
. sin 450 sin 450
4
R 2R
I
0I
1
0 2
2R
2R

10
4 volts = 5 volt
44
100 4
10
100 4
V2
100 4
4
100 4
= 4.9 volts V1 V2 0.1 volt
V1
15.
In both cases
applying com,
mv 0 Mv
V
16.
mv0
M
V1
1: 1
V2
In steady state :E
E
VP VQ
R
2R
2
E
E
VQ VS
R
2R
2
VS VR
VP VR E
Q A CE
QB
CE
2
17.
VP V0 10 10 10 10
= - 200 volts.
18.
For the two blocks to move together

F
F
min
m
g
2Mg
As min ,
the two blocks move together.
Velocity of the system (M+m) is
F
v at
t
2M
P Fv F
19.
P
4r 2
t
F
F2
t
t.
2m
2M
Axt mcT
4r 2mcT
PA
20.
A b 2 T .
21.
After collision,
the rod starts rotating about its centre of mass.
Now the torque of mg about the centre of mass = 0, hence is constant.
22.
x 0 elongation in equilibrium
ma cos mgsin kx0
(1)
For x = elongation from equilibrium
net force mgsin macos k x0 x
(i)
kx
N
ma
Mg sin
kx
acc
m
m
T 2
k
23.
K(x0 + x)
Mg cos
4 3
r n n0 g 6rVT .
3
VT
Pg
2r 2 n n0
9
2r
4 3
r .n.g.
3
n n0 g
9
24.
25.
8r n
n n0 g2 55. x 2cm 0.02m
27
kx 100 .02
= 2rad
2T
2T
gh P0
r
2r
T ghr.
P0
26.
M
G
GM
2GM
4
5R
2R
5R
2
27.
The apparent frequency initially decreases & then increases in one time period.
28.
29.
v 2 u2 2gh 02 402 2 10 h
GMem GMem GMem
12R
4R
6R
h 80m
where h is maximum height reached by ball A
v = u gt t = 4 sec,
80
t'
2 sec
uA uB
A(t=4sec)
UA=0
u A (T=t+t)
u B
h =80 m
u' A gt ' 20m / s

u'B 40 2 10 20m / s
B 40m/sec = uB
Thus the speed of each ball gets interchanged (for equal mass & elastic collision)
30.
T1 T2 m2r1
T2
T1
T2 m 2 r1 r2
T2
T1 m 2 2r1 r2
Thus T1 T2
Chemistry
1.
PART II
Mwt C6H5Cl = 112.5

Mwt C6H5CH3 = 92
Given:
xC6H5Cl 0.5
So mass% composition reaction of C6H5Cl is
112.5
% C6H5Cl =
100 = 55%
204.5
2.
As density increases, volume of gas decreases so intermolecular forces increase and diffisubility
decreases.
3.
For 432
n = 4, l = 3, m = 2
Angular momentum =
h
12h
3h
1
2
2
Angular node = = 3
3h
So total node =
3 =
3h 3
4.
O
250o C
2H3PO 4
H4P2O7 H2O
HO
O
O
OH
Pyrophosphoric acid
OH
+
5.
O
H
OH
H
O
P
B
B
+
+
O H
H O P
+
O H
3 pp back bonding between B and O and
3 pd back bonding between P and O is possible.
7.
K 2 Cr2 O7 2H2SO 4 2CrO3 2KHSO4 H2 O

Chromic anhydride
Re d Crystal
9.
NH2 behaves as a base and E2 elimination takes place.
10.
OH
OH
OH
CCl 3
CHO
NaOH
CCl
3
11.
Na2S 2O3 AgNO3 Ag2S2 O3 Ag2 S
black ppt
white
8a
1
so Tc ; and b = 4 NA V b r
27Rb
b
12.
Tc
13.
AB type structure in which Zn+2 is tetrahedrally surrounded by S ion, S2 is present in half of

tetradedral acid.
14.
It is an extensive property.
15.
16.
d B
K1
K1t
A 0
K 2 eK 2 t
K1e
dt
K 2 K1
ksp
Fe H2 O OH
H3 O
Fe H2O
6
17.
H K a C1 Ka C 2.5
1
2 2

18.
G0 (net) = G10 G02

Total e exchanged = (a + b)
G0 nFE0
, Ksp should be high.
a b FE03 aFE10 bFE02
E03
19.
aE10 bE20
a b
K 2Cr2 O7
K 2CrO4 Cr2 O3 O2
20.
H3C
C 6H 5
21.
PPh 3
H3C
C6H5
POPh3 (Wittig reaction)
Nitrogen is less electronegative than oxygen and on 3rd reactive site it is sp3 hybridised.
22.
O
(1) NaOI
CO2
COOH
CH3
O
23.
As metallic character increases down the group so acidic nature of oxide decreases.
26.
-2
Cl
Cl
Cl
Ni
Cl
4-
NH3
Cl
Ni
and
NH3
-2
NH3
Cl
Cis
Cl
4-
NH3
Cl
Trans
27.
As2 O3 5H2O 2AsO43 10H 4e
29.
2BeO 2C
Be2 C 2CO
30.
Only lithium nitride with formula LiN3 in first group and Mg with Mg3N.
Mathematics
2.
PART III
Since the equations are consistent

D=0
(a 1)3 (a 2)3 (a 3)3
(a 1) (a 2) (a 3) 0
1
1
1
Put u = (a + 1), v = a + 2, w = a + 3
u v = 1, v wz 1, w u = 2
u + v + w = 3a + 6
u3 v 3 w 3
u
1
w 0
(u v) (v w) (w u) (u + v + w) = 0
(1) (1) (2) (3a + 6) = 0
i.e. a = 2.
3.
567
1011
1234 = 3n + 1, so 1234 = 3m + 1,89 = 3k 1, so 89

Hence 1234567 + 891011 = 3n 1234 is even,
So 1234567 = 4q. 89 = 4r + 1, so 891011 = 4t + 1.
Hence 1234567 + 891011 = 4l + 1. So it is 9x + 1.
= 3p 1.
4.
c2
and tan A . tan B = 1
ab
tan A . tan B = 1 tan A = cot B A = 900 B A + B = 900 C = 900
a
b
sin A = , sin B =
c
c
Here, tan A + tan B =
sin2 A + sin2 B + sin2 C =

101
5.
I1 =
101
dx
100
b2
c2
1 2
101
5 2x 2x 1 e
2I1 =
c2
dx
2
100
a2
5 2x 2x 2
2 4x
dx
5 2 1 x 2 1 x 1 e
2
2 4 1 x
100
= I2
I1
1
= .
I2
2
6.
Since f(x) and g(x) are one-one and onto and are also the mirror images of each other with
respect to the line y = 2. It clearly indicates that h(x) = f(x) + g(x) will be a constant function and
will always be equal to 4.
7.
Equation of the curve passing through the points A, B, C, D is

(3x + 4y 24)(4x + 3y 24) xy = 0
If it represents a parabola then the quadratic terms must form a perfect square.
= 1 or 49.
8.
Locus is a hyperbola with eccentricity =
9.
In an equilateral triangle r =
Also exradius r1 = 4R sin
r1 r2
2
r1 r2
R
2
A
B
C
1 3 3 3
cos
cos
= 4R .
.
R
2
2
2
2 2 2
2
r, R, r1 are in A.P.
x2 / 2
10.
lim
t2
x 1 t
2
x /2
lim
11.
t2
1 t
2
x2
form
dt =
dt
x4
x
4
1
x5
= lim 4 x
= lim 5
= .
x
x 2x 8
2x
2
2
(3m + 1)(3n 1) = 3n 1, so if p divides 3n 1, then it also divides 3n 1

and hence also (3n2 1) n(3n 1) = n 1, and hence also (3n 1) 3(n 1) = 2.
So 3n 1 = 0, 1 or 2.
But n must be an integer, so 0, 1, 2 do not work. 1 gives n = 0 and hence m = 0, which is a
solution. 2 gives n = 1 and hence m = 0, which is a solution.
10
12.
13.
15.
Two lines can meet in a point

6C2 = 15
6
4
line and circle meet in two points = ( C1 C1) 2 = 48.
4
Two circles meet in 2 points = C2 2 = 12
total number of points = 48 + 15 + 12 = 75.

7
1 + cos3x+ 1 cos 2x
= 0
6
2
3x
2
2cos2
1 cos 2x
0
2
3
3x
2cos2
2 sin2 x 0
2
3
3x
cos
0 , sin x 0
2
3
2 7
x = , and x = ,
,
, ..
3
3 3 3
x=
is the common value which satisfies both
3
x = 2n +
= (6n + 1)
3
3
(x
=
(x 2 1)
4
(t
x 2 1)co t 1 x
x
dt
dx =
1 2
x
dx
1
2 1
1
x
1
co
t
x
x
x2
1)cot 1 t
1
1
Put x t 1 2 dx dt
x
x
du
=
u
Let cot1 t = u
1

dt du = ln|u| + c
(1 t 2 )
= ln cot 1 x c
x
16.
70 70 70
3 9 27 23 7 2 32

11
17.
Let be the period of sinx + cosax then

sin( + x) + cosa( + x) = sinx + cosax for all x
In this identity, putting x = 0 and x = , we het
sin + cosa = 1 and 1 = sin + cos
solving these equation, we get
sin = 0 and cosa = 1
hence = n and a = 2m. Where m, n are nonzero integers
a 2m
hence
n
2m
or a =
(since 0)
n
18.
A2 = 0, A3 = A4 = = An = 0
then A(I A)n = A(I + nA)
2
= A nA = A.
19.
= sin2A + sin2(135 A) = 1 + sin2A sin2(45 A)

1
= 1+ sin45 sin(2A 45) = 1 +
.sin 2A 450
2
=<
2 1
and >
1
2
2
0 < A < 135
0 < 2A < 270
45 < 2A 45 < 225
1
sin 2A 450 1
2
1
1 2
sin2 A sin2 B
.
2
2
20.
The curve xy = c and the circle x 2 + y2 = 1 touches each other so

c2
x 2 + 2 1 = 0 x 4 x 2 + c2 = 0
x
will have equal roots so ( 1)2 4c2 = 0 4c2 = 1
1
1
c2 =
c=
.
4
2
1
1
Roots of the equations x 4 x 2 0 are x =
4
2
1
y=
.
2
Clearly distance between the points of contact = 2 units
21.
Sum of 7 digits = a multiple of 9

Sum of number 1, 2, 3, 4, 5, 6, 7, 8, 9 = 45 so two left should also have sum of 9.
The pair of left numbers is (1, 8), (2, 7), (3, 6), (4, 5).
with each pair left number of 7 digit number = 7!
So with all 4 pairs = 4 7! .
12
22.
Equation of Ist line is y 0 = 1(x 1)

y=x1
and equation of IInd line is x + y = 1.
Clearly point of intersection is (1, 0).
23.
The centre c of the circle = (5, 7) and the radius

=
52 72 51 = 5 5
PC = 122 52 = 13
q = PA = 13 5 5 and p = PB = 13 + 5 3
G.M of p and q =
=
24.
pq
169 125 2 11 .
A
c
a a
1 0
c c
1 5
a
=cos B =
c
2
cos B =
y = tan x =
5 1
2
cos A = sin B =
25.
(B is acute)
1 cos2 B =
5 1
2
x
From graph it is clear that it will have two
real roots,
/2
26.
13 5 5 13 5 5
a, b, c are in G.P b2 = ac
2
2
2
and c = a + b
2
2
c = a + ac
C (5, 7)
P (7, 2)
3/2 2
The given equation is px3 + qx2 rx r = 0. Its roots are given , , so we have
q
r
r
++=
; + + = ; = .
p
p
p
1 1 1

D = 1 =
= 0.
27.
For local maxima at x R+ and minima at certain x R the roots of f (x) = 0 are of opposite sign
f (0) < 0 b < 0.
13
28.
Drawing the curves y = loge |x|

and y = 2 x2
So, number of solutions = 2
(1, 0)
( 2 , 0)
29.
(1, 0) ( 2 , 0)
Putting cx = c2 + z
a c
ac
f(cx)dx f(c
1 c
z)dz
a c
So, the required value = c
dx c(a 1)
1 c
30.
| z1 z2 |2 | z2 z3 |2 | z3 z1 |2
= 2(|z1|2 + |z2|2 + |z3|2) (z1z2 z1z2 z2 z3 z2 z3 z3 z1 z3 z1 )
= 6 (z1z2 z1z2 z2 z3 z2 z3 z3 z1 z3 z1 )
(1)
2
Now |z1 + z2 + z3| 0
|z1|2 + |z2|2 + |z3|2 + z1z2 z1z2 z2 z3 z2 z3 z3 z1 z3 z1 0
(z1z2 z1z2 z2 z3 z2 z3 z3 z1 z3 z1 ) 3
(2)
from (1) and (2)
maximum value = 6 + 3 = 9

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AITS-CRT-I PCM(S)-JEE(Main)/14

ALL INDIA TEST SERIES

15.7 02 01 002 ohm metre

2mg sin30 T = 2m(a)

Result of these forces T j T cos600 j T sin 60 i

The circuit can be simplified as:

100 sin [50t] volts.

When u decreases v increases. For plane mirror u decreases.

For the two blocks to move together

GMem GMem GMem

u' A gt ' 20m / s

Mwt C6H5Cl = 112.5

K 2 Cr2 O7 2H2SO 4 2CrO3 2KHSO4 H2 O

NH2 behaves as a base and E2 elimination takes place.

Na2S 2O3 AgNO3 Ag2S2 O3 Ag2 S

AB type structure in which Zn+2 is tetrahedrally surrounded by S ion, S2 is present in half of

G0 (net) = G10 G02

, Ksp should be high.

a b FE03 aFE10 bFE02

POPh3 (Wittig reaction)

As2 O3 5H2O 2AsO43 10H 4e

Since the equations are consistent

1234 = 3n + 1, so 1234 = 3m + 1,89 = 3k 1, so 89

Here, tan A + tan B =

sin2 A + sin2 B + sin2 C =

Equation of the curve passing through the points A, B, C, D is

Locus is a hyperbola with eccentricity =

(3m + 1)(3n 1) = 3n 1, so if p divides 3n 1, then it also divides 3n 1

Two lines can meet in a point

Let be the period of sinx + cosax then

= sin2A + sin2(135 A) = 1 + sin2A sin2(45 A)

The curve xy = c and the circle x 2 + y2 = 1 touches each other so

Sum of 7 digits = a multiple of 9

Equation of Ist line is y 0 = 1(x 1)

The centre c of the circle = (5, 7) and the radius

Drawing the curves y = loge |x|

So, the required value = c

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