H

0
298

= i H

298

= i G

fi

ln

ln K=ln k 0 +

X=

k =k [ i ]

( )

k yi=[ yi i ]

y i=

P
n

P
n

ln=
i

( )

1
1

T 298

H 0298
B
+ A ( 298 ) +
( 29 8 2) + C ( 298 3 )
R
2
3
p
n

()

BP
RT

^ = BP
B
RT

ni
n

1
0
^
B=B
+ B

n0i

Si y solo si

298

fi

G
RT

k =[ ni ]

ni=ni 0+ i
ln K=

K H
=
K0
R

H =cte ;

T es pequea
0

H 298 1
1
ln K=ln k 0

R
T 298

B 1=0.134

0.172
T r4.2

B 0=0.083

0.422
T r 1.6

f^i
^
=
yi P
^ =

f^ i
yi P
Pi