4.2.

2 Entropy as a function of temperature and pressure

In the same way, if the entropy is expressed as a function of
temperature and pressure, mathematically formulated as follows,
S = S(T, P)
4.3
0

dS S dT S dP
P T
= T P

To complete the equation (4.30) can be performed using the energy

relationship and enthalpy, H = U + PV, the total differential form 4.31
as
follows
4.32
dH = dU + PdV + VdP
4.3
1
V
dH
VdP
dS =
= dQ
3
dHrev
+dP
4.3
T
T
4
H
dH C P dT
dP

4.3
P T
5

C
1 H
dS

dT

T P

V dP

S
&

CP
T

2S
1 C P

PT
T P

H
By using equations

CP
P

obtained equation

4.3
6
4.3
7

2S
1 2H

PT T PT

4.3
8

Meanwhile if Equation (4:36) downgraded to temperature, it will obtain Equation (4:39).

1 H

T P

V
V

(4.39)

2 S 1 2 H V 1

2
TP T TP T P T

V
P T

(4.40)

2S
2S

TP
PT

The substitution of Equation (4:38) and Equation (4:39) into Equation (4:40) obtained
1 2 H V
1 H

T TP T P T P
1 H

T P

V
V

1 2H
V
T PT

(4.41)
P

By comparing Equation (4:36) and (4:41) obtained the following relationship

S
V

V
P T
T P
CP
dS =
dT V dP
T

(4.42)

(4.43)