Exercise 1 from Property Relations

PR.1: Consider as a function of and .

Show that
dp
T
v
T dT c TdS
p
p
|
.
|

\
|
c
c
=
s
T
p
Variable definitions
: s Specific entropy
: T
Temperature
: p
Pressure
:
p
c
Specific volume : v
Specific heat capacity at constant pressure
Tools and tricks used
Fundamental relations




Maxwells relation:


Canonical variables: and

vdP sdT dG
pdv sdT dA
vdp Tds dH
pdv Tds dU
+ =
=
+ =
=
p
T
T
v
p
s
vdp sdT dG
|
.
|

\
|
c
c
=
|
|
.
|

\
|
c
c
+ =
) , ( T s ) , ( v p
p
T
T
v
p
s
|
.
|

\
|
c
c
=
|
|
.
|

\
|
c
c

Solution (I)
The question gives us a clue to begin

By elementary calculus,


The second term on the RHS has the canonical
variables :


) , ( p T s
dp
p
s
dT
T
s
ds
T
p
|
|
.
|

\
|
c
c
+
|
.
|

\
|
c
c
=
) , ( T s
p
T
T
v
p
s
|
.
|

\
|
c
c
=
|
|
.
|

\
|
c
c

(1)
Solution (II)
From (1),




Note that the first term does not have the
canonical pair or
dp
p
s
dT
T
s
ds
T
p
|
|
.
|

\
|
c
c
+
|
.
|

\
|
c
c
=
dp
T
v
dT
T
s
ds
p p
|
.
|

\
|
c
c

|
.
|

\
|
c
c
=
) , ( T s
) , ( v p
We seek help from fundamental relations
(2)
Solution (III)
Fundamental relations:



We need to express the final answer in terms of
vdP sdT dG
pdv sdT dA
vdp Tds dH
pdv Tds dU
+ =
=
+ =
=
p
c
p
p
T
H
c
|
.
|

\
|
c
c
=
Therefore look at the fundamental relationship for dH
p
p p
c
T
s
T
T
H
=
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
vdp Tds dH + = (3)
Solution(IV)
From (2) and (3),



Or,
which is what we set out to prove
dp
T
v
dT
T
s
ds
p p
|
.
|

\
|
c
c

|
.
|

\
|
c
c
=
dp
T
v
dT
T
c
ds
p
p
|
.
|

\
|
c
c
=
dp
T
v
T dT c Tds
p
p
|
.
|

\
|
c
c
=
becomes
(4)