ENERGY BALANCE

Assume reference temperature of 255C

All temperatures in degree celcius
Table : coefficient for determining specific heat
component
a103
b105
formaldehyde
34.28
4.268
methanol
42.93
8.301
water
33.46
0.6880
hydrogen
28.84
0.00765
oxygen
28.10
1.158
nitrogen
29.00
0.2199

c108

d1012
-8.694
-8.03
-3.593
-0.8698
1.311
-2.871

0.00
-1.87
0.7604
0.3288
-0.6076
0.5723

COOLER (E-803)

T9

: 2005C

T9

: 1005C

F9

: 16640.9 kg/h

F9

: 16640.9 kg/h

mform

: 3751.025 kg/h

mform

: 3751.025 kg/h

mmethanol : 1882.419 kg/h

mmethanol : 1882.419 kg/h

moxygen

: 8.986 kg/h

moxygen

: 8.986 kg/h

mwater

: 3999.307 kg/h

mwater

: 3999.307 kg/h

mhydrogen : 99.346 kg/h

mhydrogen : 99.346 kg/h

mnitrogen : 6899.816 kg/h

mnitrogen : 6899.816 kg/h

Tref : 1005C
200 8.69410-12)T3
Cpform : 0.03428(4.26810-5)T(
=
(8.694 10^-12)T^4
(4.268 10^-5)T^2

100

= 7.706 0.03428T

2
4

- 3.641
= 4.065 kJ/kg.C

200

100

200 (0.760410-8)T2(3.59310-12)T3
Cpwater : 0.03346(0.688010-5)T
=
10^-8)T^3 (3.593 10^-12)T^4 200
(0.6880 10^-5)T^2 (0.7604
100
0
.
03346
T

2
3
4
100

= 6.8483.383
= 3.465 kJ/kg.C
Cpmethanol : 0.04293(8.30110-5)T(- 200 1.8710-8)T2(8.0310-12)T3
=
10^-8)T^3 (8.03 10^-12)T^4
(8.301 10^-5)T^2 (-1.87

100
0
.
04293
T

2
3
4

200

100

10.193 - 4.702
= 5.491 kJ/kg.C
200 0.607610-8)T2(1.31110-12)T3
Cpoxygen : 0.0291(1.15810-5)T(=
10^-8)T^3 (1.31110^-12)T^4 200
(1.158 10^-5)T^2 (-0.6076

100

=
0.0291T

2
3
4

100
6.036 - 2.966
= 3.07 kJ/kg.C

Cphydrogen : 0.02884(0.0076510-5)T

0.02884T

200

(0.328810-8)T2(-0.869810-12)T3

10^-8)T^3 (-0.8698 10^-12)T^4

(0.00765 10^-5)T^2 (0.3288
100

2
3
4

200

100

=
= 5.778 - 2.885
= 2.893 kJ/kg.C
200 (0.572310-8)T2(-2.87110-12)T3
Cpnitrogen : 0.029(0.219910-5)T
=
100 10^-8)T^3 (-2.87110^-12)T^4 200
(0.2199 10^-5)T^2 (0.5723

=
0.029T

2
3
4
100

5.858 - 2.913
= 2.945 kJ/kg.C

m (kg/h)
Cp (kJ/kgC)
5
T (5C)

formaldehyd
e
3751.025

methanol

oxygen

water

hydrogen

nitrogen

882.419

8.986

3999.307

99.346

6899.816

4.065

5.491

3.07

3.465

2.893

2.945

100

100

100

100

100

100

Q = miCpiT
=(3751.025kg/h4.065kJ/kg.5C(200-

100)5C)form+ (1882.419 kg/h5.491

kJ/kg.5C(200-100)C)
5 methanol + (8.986 kg/h3.07 kJ/kg.5C(200-100)5C)oxygen+
(3999.307kg/h3.465kJ/kg.5C(200-100)5C)water+(99.346kg/h2.893kJ/kg.5C
(200-100)5C)hydrogen+(6899.816 kg/h2.945 kJ/kg.5C(200-100)5C)nitrogen
= 6007683 kJ/h = 1668.8kW

COMPRESSOR (C-801)

T1

: 40.75C

T5

: 40.85C

F1

: 226.818 kg/h

F5

: 226.8184 kg/h

P5

: 300kPa

mform

: 0 kg/h

P1

: 101.3kPa

mform

: 0 kg/h

mmethanol : 0.94185 kg/h

mmethanol :0.94185 kg/h

moxygen

: 0 kg/h

moxygen

: 0 kg/h

mwater

: 0.05815 kg/h

mwater

: 0.05815kg/h

Mhydrogen : 0 kg/h

mhydrogen : 0 kg/h

mnitrogen :0 kg/h

mnitrogen : 0 kg/h

Cpmethanol : 0.04293(8.30110-5)T(-

40.8

1.8710-8)T2(8.0310-12)T3

40.7

=
=

(8.301 10^-5)T^2 (-1.87 10^-8)T^3 (8.03 10^-12)T^4

0.04293T

2
3
4

40.8

40.7

1.82016-1.81562
= 0.00454 kJ/kg.C

Cpwater : 0.03346(0.688010-5)T

40.8

(0.760410-8)T2(3.59310-12)T3

=
40.7 10^-8)T^3
(0.6880 10^-5)T^2 (0.7604
(3.593 10^-12)T^4
0
.
03346
T

=
2
3
4
1.3711-1.3677
= 0.0034 kJ/kg.C

Q = miCpiT

= (0.94185 kg/h0.00454 kJ/kg.5C(40.8kJ/kg.5C(40.8-40.7)5C)

= 4.47370910-4kJ/h=0.001243kW

40.7)5C)+(0.05815 kg/h 0.0034

40.8

40.7