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  • Experiment: Infrared Absorption Spectrum of Polyatomic Molecules

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    Kim Young Min
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    This document summarizes an experiment on infrared absorption spectra of polyatomic molecules. It analyzes the IR spectrum of HCl and fits it to a quadratic equation. It determines values for the vibration wavenumber, vibration constant, and centrifugal distortion constant by comparing to the theoretical equation. It also calculates the maximum J level population at 25°C, moment of inertia, and equilibrium bond distance for HCl. Finally, it indicates the experiment also analyzed the IR spectrum of NH3.

    Original Description:

    Xử lý số liệu bài IR thực tập hóa lý ĐH KHTN

    Original Title

    tt hoas lys IR

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    This document summarizes an experiment on infrared absorption spectra of polyatomic molecules. It analyzes the IR spectrum of HCl and fits it to a quadratic equation. It determines values for the vibration wavenumber, vibration constant, and centrifugal distortion constant by comparing to the theoretical equation. It also calculates the maximum J level population at 25°C, moment of inertia, and equilibrium bond distance for HCl. Finally, it indicates the experiment also analyzed the IR spectrum of NH3.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    5 views3 pages

    Experiment: Infrared Absorption Spectrum of Polyatomic Molecules

    Uploaded by

    Kim Young Min
    This document summarizes an experiment on infrared absorption spectra of polyatomic molecules. It analyzes the IR spectrum of HCl and fits it to a quadratic equation. It determines values for the vibration wavenumber, vibration constant, and centrifugal distortion constant by comparing to the theoretical equation. It also calculates the maximum J level population at 25°C, moment of inertia, and equilibrium bond distance for HCl. Finally, it indicates the experiment also analyzed the IR spectrum of NH3.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    of 3

    Full name: Nguyen Thi Minh Nguyet

    Class: K57T
    Group : 5 ( morning shift)
    Date of experiment : October 11th, 2015
    EXPERIMENT: INFRARED ABSORPTION SPECTRUM OF POLYATOMIC
    MOLECULES
    IV. experimental result
    IR of HCl
    m
    9
    8
    7
    6
    5
    4
    3
    2
    1
    -1
    -2
    -3
    -4
    -5
    -6
    -7
    -8
    -9

    wavenumbers
    3044.09
    3028.66
    3013.23
    2996.84
    2979.48
    2962.13
    2943.8
    2924.52
    2905.24
    2863.77
    2842.56
    2820.38
    2798.21
    2775.06
    2750.96
    2726.85
    2701.78
    2676.71

    wavenumbers
    3100
    f(x) = - 0x^3 - 0.3x^2 + 3000
    20.52x + 2884.83
    R = 1
    2900
    2800
    2700
    2600
    2500

    -10

    -8

    -6

    2400
    -2
    0

    -4

    10

    The resulted graph is a graph of a quadratic function y=-0.0014x^4


    -0.3031 x2 + 20.447x + 2884.8

    Compare with equation 17,v= v01 + (2Be 2

    )m -

    m2- 4 De m^4 , we

    deduced that:
    v01 =2884.8
    -

    =-0.3031 =>

    2Be 2

    =20.447

    =0.3031

    => Be=10.5266

    -4De = -0.0014 => De=0.0014

    Calculate the J level maximum population at 25

    Jmax=

    kT
    2 Bhc

    1
    2

    for HCl

    480298
    210.52666.6261034310 8

    1.85*10^14

    Calculate the moment of inertia

    h
    From B= 8 2 cI

    => I=

    h
    8 B 2 c =2.66*10^-45

    Calculate the equilibrium bond distance:

    1
    2

    Re=
    With

    =1.61551027 (kg)

    Re=1.3*10^-9
    IR of NH3

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