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Concrete Technology Questions
Concrete Technology Questions
%-AGE RANGE
AVG. %-AGE
CaO
60.0 67.0
63.0
SiO2
17.0 25.0
20.0
Al2O3
3.0 8.0
6.0
Fe2O3
0.5 - 6.0
3.0
MgO
0.5 - 4.0
1.5
0.3 - 1.2
1.0
2.0 - 3.5
2.0
Alkalis(K20
+Na2O)
SO3
The raw materials containing these oxides are used for the production of Portland
cement. It should however be mentioned that these are just the typical compositions,
these oxide compositions could be very well varied to produce cements of different
properties for specific uses.
2) What are the main compounds present in OPC?
Main compounds present in Ordinary Portland Cement are:
Compound
Oxide composition
Abbreviation
Avg. %age
Tricalcium Silicate
3CaO. SiO2
C3S
54.1
Dicalcium silicate
2CaO. SiO2
C2S
16.6
Tricalcium Aluminate
3CaO. Al2O3
C3A
10.8
Tetracalcium
Aluminoferrite
C4AF
9.10
Portland Slag Cement:- PSC is obtained by mixing Portland cement clinker, gypsum and
granulated blast furnace slag in suitable proportions and grinding the mixture to get a
thorough and intimate mixture between the constituents. The resultant product is a
cement which has physical properties similar to OPC. It has low heat of hydration and is
relatively better resistant to chlorides and hence can be used for marine works.
4) If the elemental composition is available, how we can calculate compound
composition?
By using following equations, suggested by Bogue, we can calculate percentage of main
compounds from the percentage of elemental composition.
C3S = 4.07(CaO) 7.60(SiO2) 6.72(Al2O3) 1.43(Fe2O3)
2.85(SO3)
C2S = 2.87(SiO2) 0.754(C3S)
C3A = 2.65(Al2O3) 1.69(Fe2O3)
5) What is the role of C3A in the hydration process?
The reaction of C3A with water is very quick and violent, and leads to immediate
stiffening of
aluminate hydrate(C3AH6).
C3 A + 6 H
C3AH6
This reaction requires much more water than that required for the
hydration of silicates. This causes shortage of water and there is incomplete hydration of
silicates. To prevent this Gypsum(CaSO4.2H2O)
At 3 days
At 90 days
At 13 years
C3 S
58
104
122
C2 S
12
42
59
C3 A
212
311
324
C4AF
69
98
102
7) Discuss the manufacturing of cement using dry process. Illustrate your answer
with schematic diagrams.
In the dry process of manufacturing of cement the raw materials are crushed and fed
in the correct proportions into a grinding mill, where they are dried and reduced in
size to a fine powder.
The dry powder, called raw meal, is then pumped into a blending silo and final
adjustment is made in the proportions of the material.
Raw meal having moisture content about 2% is passed through a pre-heater, usually
of a suspension type(i.e. the raw meal particles are suspended in the rising
gases).Here the raw meal is heated to about 800C before being fed into the kiln.
In the kiln pulverized coal is blown by an air blast at the lower end where the
temperature reaches about 1400C.The mass (raw meal) then fuses into balls, 3-25
mm in diameter known as clinker.
On exit from the kiln the clinker is cooled and the heat being used to the pre-heat of
the combustion air.
The cool clinker which is characteristically black and hard is interground with gypsum
in order to prevent the flash set of cement. Grinding is done in a ball mill consisting of
several compartments with progressively smaller steal balls.
The cement discharged by the mill is passed through a separator, fine particles being
removed to the storage silo by an air current while the coarser particles are passed
through the mill once again.
Lime Stone,
Shale
Crusher
Ball Mill
Raw Meal Silo
Raw Meal PreHeater
Rotary Kiln
Clinker Cooler
Gypsum
Ball Mill
Quantity of coal required to produce 1 Ton of cement is only about 100 kg in case of
dry process compared to 350 kg for wet process.
9) Discuss ten types of cement indicating their compositions, codal provisions
and usage.
Type of
Compositio
cement
Codal Provisions
Usage
Ordinar
10mm
Autoclave test : Expansion 0.8
y
Portlan
d
Cemen
t
C3S, C2S,
percent
Setting
Time:
Vicat test : Initial Setting Time
C3A, C4AF
30 min
Final Setting Time 600
min
Compressive Strength(Min):
33 Grade 43 Grade
Rapid
Contains
Harden
more C3S
-ing
and Less
Portlan
C2S than
OPC
Cemen
t
of construction
where no special
durability
condition is
present
53
Grade
721hr :
16 Mpa
23 MPa
27 MPa
1682hr :
22 Mpa
33 MPa
37 MPa
6724hr :
33 Mpa
43 MPa
53 MPa
Specification given in : IS 8041:1990
Fineness: Blaines air permeability test :
2
i) In prefabricated
concrete
construction.
ii) Where formwork
needs to be
removed to use
elsewhere.
ii)Road repair
min
Compressive Strength(Min):
24hr30minutes : 16 Mpa
721hr :
27 Mpa
concrete where
rapid hardening
reduces chances of
Sulphat
e
Resisti
2C3A+C4AF
ng
should not
Portlan
exceed 25
percent
Cemen
cement
Portlan
Cemen
granulated
slag which
continuous wetting
and drying. In
marine
construction.
ii) Concrete used in
Codal Provisions
n
A mixture Specification given in : IS 455:1989
Fineness: Blaines air permeability test :
of Portland
specific surface 225m2/kg
cement
Soundness: La Chatelier test : Expansion
clinker and
10mm
blast
Autoclave test : Expansion 0.8
furnace
accelerated by
basement
30 min
Compositio
d Slag
t
percent
Setting Time: Vicat test : Initial Setting Time
min
Compressive Strength(Min):
721hr :
1682hr :
6724hr :
Type of
10mm
Autoclave test : Expansion 0.8
frost action
i) Sulphate attack
percent
Setting Time: Vicat test : Initial Setting Time
30 min
Final Setting Time 600
sulphates.
iii) In sewage
treatment work
Usage
Low heat of
hydration so used
in mass
concreteing
is a waste
Supers
ulphate
d
Cemen
t
min
product in Compressive Strength(Min):
721hr :
16 Mpa
making of
1682hr :
22 Mpa
pig iron.
6724hr :
33 Mpa
produced Specification given in : IS 6909:1990
Fineness: Blaines air permeability test :
by
specific surface 400m2/kg
intergrindi
Soundness: La Chatelier test : Expansion
ng a
5mm
mixture of
Autoclave test : Expansion 0.8
80 to 85 %
granulated
blastfurnac
e slag, 10
to 15
percent
calcium
sulphate
percent
Setting Time: Vicat test : Initial Setting Time
30 min
i) In marine
construction.
ii) Concrete used in
basement
construction where
soil is infested with
sulphates
iii) In sewage
15 Mpa
22 Mpa
30 Mpa
and a
small
amount of
Portland
cement
Specification given in : IS 12600:1989
Fineness: Blaines air permeability test :
specific surface 320m2/kg
Soundness: La Chatelier test : Expansion
Low
Lower
Heat
content of
Portlan
rapidly
hydrating
Cemen
compound
Type of
Compositio
cement
10mm
Autoclave test : Expansion 0.8
percent
Setting Time: Vicat test : Initial Setting Time
Mass concreting.
30 min
Final Setting Time 600
min
Compressive Strength(Min):
721hr :
1682hr :
6724hr :
10 Mpa
16 Mpa
35 Mpa
Codal Provisions
Usage
Specification given in :
IS 1489(Part1):1991(fly ash based)
IS 1489(Part2):1991(calcined clay
based)
Fineness: Blaines air permeability test :
Portlan
Pozzolanic
material is
Pozzola
mixed with
na
portland
Cemen
cement
clinker
Hydrop
Grinding
hobic
with water
Cemen
repellant
film
forming
substances
like oleic
i) Economical,
Reduce
permeability, Used
For hydraulic
structure
ii) For marine
structure.
iii) Mass concreting
for Dam etc.
acid,
stearic
30 min
acid etc.
Film get
broken
when
mixing is
15.69 Mpa
21.57 Mpa
30.4 Mpa
done.
Used by the
Oil-well
petroleum industry
cement of
classes A,
B, C, D, E,
F, G and H,
Oil well
Cemen
t
shall be
manufactur
edby
grinding
clinker
consisting
of hydraulic
The total
have to remain
pumpable at this
elevated temp and
press for a
sufficient length of
time and then
rapidly.
Cemen
of such cement
silicates.
cement
pressures. Slurries
harden fairly
Compositio
Alumin
temperatures and
calcium
Type of
High
min
alumina
content
(Al2O3)
shall not be
less than
32 percent
by mass.
Codal Provisions
Usage
30 min
10) How do you measure consistency, setting time, fineness and soundness of
cement? Answer in brief.
Consistency test(P)
300 gm of cement is mixed with 25% water. The paste is filled in the mould(40 mm
height) of Vicats apparatus. And the surface of the filled paste is smoothened and
levelled. A square needle(10mm*10 mm) attached to the plunger is then lowered gently
over the cement paste surface and is released quickly. The plunger pierces the cement
paste. The reading on the attached scale is recorded. When the reading is 5-7 mm from
the bottom of the mould, the amount of water added is the correct percentage of water
for normal consistency.
Setting Time
After preparing the cement paste by adding 0.85 times then water required to give a
paste of standard consistency the mould is filled completely with the paste and placed
into the vicat apparatus. The test is conducted at room temperature of 272C. Initial
setting time is the time required for the needle of the apparatus to reach the level of
5mm measured from the bottom of the mould.
The cement is considered to be finally set when upon applying the needle gently to the
surface of test block, the needle makes an impression, but the attachment fails to do so.
Fineness
Degree of fineness of cement is the measure of mean size of grains in it.3 methods are
generally used for testing fineness: Sieve Method, Blains Air Permeability Method,
Wagner Turbidimeter Method. The last two methods measure the surface area of per
gram of cement whereas the first one measures percent residue by weight.
Soundness
Soundness of cement may be tested by Le-Chatelier Method or by Autoclave Method. In
Le-Chatelier Method, a mould is prepared by mixing 100 gram of cement with o.78 times
the water required to give a paste of standard consistency. Mould is covered with a glass
sheet and submerged in water at temperature of 27-32C.After 24 hours ,mould is taken
out and the distance separating the indicator point is measured. After that mould is
submerged in the boiled water for 3 hours. After removing the mould from water it is
cooled and the distance between the indicator points is measured again. The difference
between the two measurements represents the unsoundness of the cement. In autoclave
test at first Neat cement specimen of 25mm x 25mm x 250mm placed inside autoclave.
Temp of autoclave shall be raised at such a rate as will bring the gauge pressure of the
steam to 2.1 MPa in 1 to 1 h from the time the heat is turned on and maintained for 3
hours. After that pressure is reduced slowly and specimen is removed and cooled.
Change in length of the specimen is measured.
11) How the fineness of cement affects the properties of concrete?
1. The rate of hydration depends directly on the fineness of the cement as finer cements
offer greater surface area for hydration to take place, and for rapid development of
strength, high fineness is necessary. But higher rate of hydration means higher rate of
early heat evolution.
2. Increasing the fineness of cement reduces the amount of bleeding in concrete by
increasing the water requirement of concrete.
3. The workability of non-air-entrained concrete is increased by increasing the cement
fineness.
4. The 28-day compressive strength & modulus of elasticity of concrete, with or without
entrained air, increases with an increase in cement fineness. The difference in
16) What is the difference between segregation and bleeding? How can we control
segregation, bleeding using additives/admixtures/plasticizers?
Segregation:Segregation is defined as the separation of the constituent materials of concrete. There
is a considerable difference in the sizes and specific gravities of the constituent
ingredients of concrete, so there is a natural tendency of the materials to fall apart.
Segregation may be of three types:
The coarse aggregate separating out or settling down from the rest of the mix.
The paste or matrix separating out from the rest of the material.
The water, being of lowest specific gravity, separating out from the rest of the
material.
Bleeding:- Bleeding is a particular form of segregation, in which some of the water in
the mix tends to
rise to the surface of the freshly mixed concrete. This is caused by the inability of the
solid
constituents of the mix to hold all of the mixing water when they settle
downwards, water having the lowest specific gravity of all the mix constituents.
Additives such as fly ash increase the effective surface area of particles thereby reducing
the pores of concrete. Thus chance of bleeding gets reduced. Also available water gets
reduced due to increase of surface area.
17) What is the difference between self-compacting concrete and conventional
concrete?
1. Self-compacting concrete is able to flow and consolidate under its own weight and
completely fills the formwork, even in the presence of dense reinforcement, without the
need of any vibration, whilst maintaining homogeneity. Conventional concrete is one
which needs vibration for consolidation under reinforcements.
2. SCC has lower coarse aggregate contents to reduce the friction between them and
therefore enhances the overall concrete fluidity
3. SCC has higher amounts of sand & cementitious materials including Portland cement
to further increase fluidity as well as enhances its cohesiveness and resistance to
segregation and viscosity.
18) What are the different tests and criterions for self-compacting concrete?
Property measured
Flowability / Filling
ability
Passing ability
Segregation
potential
Test method
Material
Slump flow
Concrete
T50
Concrete
V funnel
Concrete /
mortar
Orimet
Mortar
U box
Concrete
L box
Concrete
J - ring
Concrete
Settlement
column test
Sieve stability
test
Penetration test
Recommended values
(acceptance criterion)
650 800 mm
Average flow diameter
2 5 sec
Time to flow 500 mm
6 12 sec
Time for emptying of funnel
0 5 sec
Time for emptying of apparatus
0 30 mm
Difference in heights in two limbs
0.8 1.0
Ratio of heights at beginning and end of
flow
0 10 mm
Difference in heights at the beginning
and end of flow
Concrete
Concrete
Concrete
The manufacture of Fly-ash concrete is less energy intensive, and the raw material
used is cheaper. Thus reducing the overall cost.
In fly-ash concrete more gel is formed so the ultimate strength is higher than that
of a conventional concrete.
The small particles of fly-ash help better packing, which reduces the permeability
and increases durability.
Fly-ash concrete generates less heat of hydration, as compared to conventional
concrete, so the chances of development of cracks get reduced.
Water requirement of fly-ash concrete is much lesser than that of conventional
concrete.
Fly-ash concrete puts a waste material to good use, and causes fewer global
warming problems.
21) What is fiber concrete and advantages of it over conventional concrete?
Fiber-reinforced concrete (FRC) is concrete containing fibrous material which increases
its structural integrity. It contains short discrete fibers that are uniformly distributed and
randomly oriented. Fibers include steel fibers, glass fibers, synthetic fibers and natural
fibers each of which lend varying properties to the concrete.
Their main purpose is to increase the energy absorption capacity and
toughness of the material, but it also increases the tensile and flexural strength of
concrete. There is considerable improvement in the post-cracking behavior of concretes
containing fibers. Although the ultimate tensile strengths do not increase appreciably,
the tensile strains at rupture do. Compared to plain concrete, fiber-reinforced
concrete is much tougher and more resistant to impact.
The benefits provided by FRC are listed below:-
22) Discuss post cracking behaviour of steel FRC. Illustrate with graph.
The fiber-reinforced concrete composite will carry increasing loads after the first cracking
of the matrix if the pull-out resistance of the fibers at the first crack is greater than the
load at first cracking. At the cracked section, the matrix does not resist any tension and
the fibers carry the entire load taken by the composite. With an increasing load on the
composite, the fibers will tend to transfer the additional stress to the matrix through
bond stresses. This process of multiple cracking will continue until either fibers fail or the
accumulated local debonding will lead to fiber pull-out.
23) What is geo-polymer concrete? Is it different from fly ash concrete?
Geopolymer is essentially a cement free concrete.
source material
that is rich in silica and alumina with alkaline liquid. Unlike ordinary
The role
Reducing aggregate/cement ratio and keeping w/c ratio workability can be increased as
surface as solids(aggregate and cement) decreases so that same amount of water
increases workability.
25) Discuss in brief regarding properties of FA and CA. Mention IS code provisions
and brief detail of the tests.
The properties of aggregates are
i) Size: aggregates having size more than 4.75 mm are called coarse aggregates and
aggregates whose size is less than 4.75 mm are known as fine aggregates.
ii) Shape: shape of aggregate is an important property. It affects workability of concrete.
Coarse aggregates are classified as
a) Rounded
b) Irregular or partly rounded
c) Angular
d) Flaky
iii) Texture: The relative degree to which surface of admixture are polished or dull,
smooth or rough is called texture. Surface texture are classified as
a) Glassy
b) Smooth
c) Granular
d) Crystalline
e) Honeycomb & porous
iv)
Strength: it depends on the strength of parent rock to some extent. It is measured
by aggregate crushing value. Strength of aggregate refer to the load it can take
v)
vi)
vii)
Abrasion test.
Absorption & Moisture content: some aggregates are porous and absorptive which
will therefore effect the w/c ratio & hence the workability of concrete. The free
moisture content of fine aggregate result in bulking of aggregate. Due to bulking
fine aggregate shows more volume which if not taken proper care can result in a
concrete mix which is under-sanded and harsh.
Testing of aggregates
i)
ii)
iii)
iv)
26) What is the objective of concrete mix design? What should be the right
approach to design a concrete mix?
The selection of mix proportion is simply the process of choosing suitable ingredient of
concrete and determining their relative quantities with the object of producing as
economically as possible concrete of certain minimum properties notable strength,
durability and required consistency. Also workability of the mix should be upto the mark
to meet the requirement of placing the concrete at the site.
To design a concrete mix of appropriate strength and durability and of required
workability one need study the property of concrete in detail with special emphasis on
the rheological behavior of concrete. The properties of admixture should be taken into
account to ascertain workability. Also w/c ratio should be controlled effectively to get the
maximum compressive strength for a fixed aggregate/cement ratio. Now- a-days
porosity of concrete is controlled in an effective manner to control strength and
compactness of concrete. Also computer modeling of the properties of constituents of
concrete should be made to controlled; and measure the properties of all the materials
to produce more appropriate mixes.
27) What are the different methods of concrete mix design generally used? What
are the advantages and disadvantages of these methods? Provide your
opinion regarding applicability of these methods in different situations.
The commonly used methods of mix design are
a) Thw ACI committee 211 method
b) The DOE method
c) The Indian Standard recommended method (as per IS 10262-82)
d) Mix desih=gn of pumpable concrete
The ACI committee 211 method
The advantages of this method arei) It takes into account the amount of water content in agg.
ii) The effects of angularilities of coarse aggregate is reflected in the void content,
thus angular coarse aggregate require more mortar than rounded aggregate.
iii)It takes into account the fact that a definite percentage of air remains
concrete.
The Indian Standard recommended method (as per IS 10262-82)
The advantages of this method are:1. Based on statistical variation, the target strength is fixed on a conservative
side.
2. Water absorption of fine and coarse aggregate is taken into consideration.
3. It incorporates the strength of cement to effect the economy in mix design.
The disadvantage of this method are:1. Now a days high strength cement is available so the 28 days strength
categories should be reviewed.
2. Graph connecting strength of cement and w/c ratio needs to be reestablished.
3. The graph connecting 28 days strength of cement and w/c ratio is to be
extended upto 80 MPa for high strength concrete.
4. As per revised edition of IS 456-2000 the mix design procedure should be
based on degree of workability expressed in terms of slump instead of
compacting factor. This results in the change of values in estimating
28) What is the difference between a low modulus fiber and a high modulus fiber
used to produce FRC?
Fibre reinforced concrete is defined as a composite material consisting of mixture of
cement, mortar of concrete and discontinuous, discrete, and uniformly dispersed
suitable fibre. Its properties largely on the type of fibre, fibre geometry, fibre content,
orientation & distribution of fibre, mixing and compaction techniques and size shape of
the aggregates.
The modulus of elasticity of the matrix must be much lower than that of fibre for efficient
stress transfer. Low modulus fibre such as nylon and polypropylene are therefore unlikely
to give strength improvement but they helps in the absorption of large energy and
therefore impart greater degree of toughness and resistance to impact. High modulus
fibre such as steel, grass and carbon impart strength and stiffness to te composite.
29) Discuss the change in behaviour of concrete exposed to different levels of
temperature up to 1000c.
Up to about 300 C, the concrete undergoes normal thermal expansion.
Above that temperature, shrinkage occurs due to water loss; however, the aggregate
continues expanding, which causes internal stresses.
At 450-550 C the cement hydrate decomposes, yielding calcium oxide.
Up to about 500 C, the major structural changes are carbonatation and coarsening of
pores.
At 573 C, quartz undergoes rapid expansion due to phase transition.
Calcium carbonate decomposes at about 600 C.
Concrete exposed to up to 100 C is normally considered as healthy. The parts of a
concrete structure that is exposed to temperatures above approximately 300 C
(dependent of water/cement ratio) will most likely get a pink color. Over approximately
600 C the concrete will turn light grey, and over approximately 1000 C it turns yellowbrown. Usually, pink colored concrete is considered as a damaged one that should be
removed.
30) What is the basic requirement of Refractory concrete or high temperature
resistant concrete?
Refractory concrete made with high alumina cement has a good resistance to acid
attack, the chemical attack is increased by firing at 900-1000C. The concrete can be
brought up to service temperature as soon as it is hardened i.e. it does have to be prefired. Refractory high-alumina cement can withstand a considerable thermal shock.
31) What is creep in concrete?
Creep is defined as a time-dependent deformation under a constant load. The
creep develops in a concrete rapidly at the beginning and gradually decreases with time.
Approximately 75% of the ultimate creep in concrete occurs during the first year. The
total deformation of a reinforced concrete specimen consists of the instantaneous
deformation, shrinkage deformation, and creep.
32) Discuss few salient features of creep in concrete. Illustrate your answer with
graphs.
1) Under normal conditions of loading, the instantaneous strain recorded depends on the
speed of
some creep.
application of the load and thus includes not only the elastic strain but also
2) It is difficult to differentiate accurately between the immediate elastic strain and early
creep, but this is
33) What is shrinkage of concrete? How can you control shrinkage of concrete?
Shrinkage of concrete is the time-dependent strain measured in an unloaded and
unrestrained specimen at constant temperature. It can be classified as(a) Plastic Shrinkage
Shrinkage of this type manifests itself soon after the concrete is placed in the forms
while the concrete is still in the plastic state. Loss of water by evaporation from the
surface of concrete or by the absorption by aggregate or subgrade, is believed to be
the reasons of plastic shrinkage. The loss of water results in the reduction of volume.
The aggregate particles or the reinforcement comes in the way of subsidence due to
which cracks may appear at the surface or internally around the aggregate or
reinforcement.
(b) Drying Shrinkage
Under drying conditions, the gel water is lost progressively over a long time, as long
as the concrete is kept in drying conditions. Cement paste shrinks more than mortar
and mortar shrinks more than concrete.
(c) Autogeneous Shrinkage
Autogeneous shrinkage is the consequence of withdrawl of water from the capillary
pores by the anhydrous cement particles. Most of
Both the inter-particle pores (between the individual particles) and the intra-
particle pores (within the particle itself) can be characterized using this technique.
A force balance equation known as Washburn's equation for the above material
having cylindrical pores is given as:
= pressure of liquid
= pressure of gas
= surface tension of liquid
= contact angle of intrusion liquid
= pore diameter
38) Discuss XRD/EDX Method to understand the composition.
X-ray defraction (XRD) or Energy-dispersive X-ray spectroscopy (EDX) is an
analytical technique used for the elemental analysis or chemical characterization of a
sample. It relies on the investigation of an interaction of some source of X-ray excitation
and a sample. Its characterization capabilities are due in large part to the fundamental
principle that each element has a unique atomic structure allowing unique set of peaks
on its X-ray spectrum. To stimulate the emission of characteristic X-rays from a
specimen, a high-energy beam of charged particles such as electrons or protons, or a
beam of X-rays, is focused into the sample being studied. At rest, an atom within the
sample contains ground state (or unexcited) electrons in discrete energy levels or
electron shells bound to the nucleus. The incident beam may excite an electron in an
inner shell, ejecting it from the shell while creating an electron hole where the electron
was. An electron from an outer, higher-energy shell then fills the hole, and the difference
in energy between the higher-energy shell and the lower energy shell may be released in
the form of an X-ray. The number and energy of the X-rays emitted from a specimen can
be measured by an energy-dispersive spectrometer. As the energy of the X-rays are
characteristic of the difference in energy between the two shells, and of the atomic
structure of the element from which they were emitted, this allows the elemental
composition of the specimen to be measured.
39) Discuss Alkali-aggregate Reaction. How can you control Alkali-aggregate
Reaction?
The mixing water turns to be a strongly caustic solution due to solubility of
alkalies from the cement. The caustic solution attacks reactive silica of aggregate to
form alkali-silica gel of unlimited swelling type. Continuous growth of silica gel exerts
strong osmotic pressure to cause pattern cracking particularly in thin section like
pavement. This phenomenon results in loss of strength and elasticity.
Alkali aggregate reaction can be controlled by:
a)Selection of non-reactive aggregates.
b)By use of low alkali cement,
c)By the use of corrective admixture such as pozzolanas.
d)By controlling void space in concrete
e)By controlling moisture condition and temperature.
40) What do you mean by rheological properties of concrete? What is a
rheometer?
41) What do you mean by durability of concrete? Discuss with examples of acid
attack, carbonate attack.
Durability of concrete is defined as its ability to resist weathering action, chemical
attack, abrasion, or any other process of deterioration to maintain its original form,
quality, and serviceability when exposed to its intended service environment.
Acid attack:
Most acid solutions will slowly or rapidly disintegrate portland cement concrete
depending upon the type and concentration of acid. Most vulnerable part of cement
hydrate is Ca(OH)2 but C-S-H gel can also be attacked. Concrete can be attacked by
water of pH value less than 6.5, but attack is severe when pH value is less than 5.5. As
the attack proceeds, all cementitious materials leached away together with any
carbonate aggregate. If acids are able to reach the reinforcing steel through cracks,
corrosion can occur.
Carbonate attack:
Carbonation of concrete is a process by which CO 2 from the air penetrates into
concrete and reacts with calcium hydroxide to form calcium carbonates. Rate of
carbonation depends upon several factors like relative humidity, grade of concrete,
permeability of concrete etc. The highest rate of carbonation occurs at a relative
humidity of between 50 to 70 percent.
42) What is leaching of concrete? Discuss with an example providing emphasis on
chemistry.
When water flows through cracks present in concrete, water may dissolve various
minerals present in the hardened cement paste or in the aggregates, if the solution is
unsaturated with respect to them. Dissolved ions, such as calcium (Ca2+), are leached
out and transported in solution some distance. If the physico-chemical conditions
prevailing in the seeping water evolve with distance along the water path and water
becomes supersaturated with respect to certain minerals, they can further precipitate,
making deposits or efflorescences inside the cracks, or at the concrete outer surface.
This process can cause the self-healing of fractures in particular conditions.
43) What is the effect of water vapour pressure inside the pores of concrete for
concrete subjected to high temperature?
There is always some amount of moisture entrapped within the voids of concrete.
Generally these interstitial voids of concrete are interconnected. In concretes subjected
to high temperature, this water gets evaporated, which causes an increase in volume
and also the vapour pressure. Through the interconnected voids this vapour pressure
moves to different portions of concrete and gets dissipated. This is known as moisture
movement.
But if we use finer additives like fly ash and silica fume in the concrete, the voids
decrease to a very low amount and are no longer interconnected. This prevents the
moisture movement, and results in the increase in tremendous vapour pressure at a
single point. This pressure gets dissipated suddenly causing a big explosion.
44) How to assess durability of concrete by fracture energy approach?
45) How can you relate fracture energy concrete with ductility of concrete
46) Discuss beam test relating assessment of fracturing energy.
47) What do you mean by porosity and sorptivity of concrete?
Sorptivity is a measure of how quickly concrete will draw water in by capillary
action with no pressure head. This is a sensitive measurement method. Sorptivity can
sometimes be estimated from absorption or volume of permeable voids but other
parameters may negate this.
48) What do you mean by gel-space ratio?
The gel-space ratio is the ratio of the volume of solid products of hydration to the space
available for these hydration products.
Let, C=weight of cement in gm.
V=Specific volume of cement in ml/gm. =0.319
w=water cement ratio
Assuming 1ml of cement on hydration produces 2.06ml of gel,
Volume of gel=C x .319 x 2.06 =0.657C
Space available=0.319C+w.C
Gel-space ratio after complete hydration=0.657/ (0.319+w)
A higher gel-space ratio reduces the porosity and therefore increases the strength of
concrete. A higher water-cement ratio decreases the gel-space ratio increasing the
porosity thereby decreasing the strength of concrete.
Power and Brown yard established relationship between gel-space ratio and strength.
S=240r3
Where, S=Strength of concrete and r=gel-space ratio