Noi Dung On Tap Hoa Phan Tich

HNG DN N TP MN HA PHN TCH
Ni dung n tp mn ha phn tch bao gm ton b kin thc c bn, quan trng
ca chng trnh ha hc phn tch. Yu cu v mt kin thc c c th ha trong
cu hi thi. Sau y l nhng hng dn c th:
Phn I
C S L THUYT C BN TRONG HA PHN TCH
1. Nhng khi nim c bn
- S in ly v dung dch cht in ly, s in ly ca nc, ch s pH.
- Tch s tan v iu kin kt ta hay ho tan.
- Cu to phc cht v iu kin to thnh phc cht.
2. Nhng nh lut c bn
- nh lut bo ton khi lng.
- nh lut thnh phn khng i.
- nh lut ng lng.
3. Nng dung dch v cch biu th nng
- Nng phn trm (%)
- Nng phn t (Nng mol/lt)
- Nng ng lng (N)
- Mt s cch biu th nng khc (nng gam/lt, nng ion gam, chun,
nng phn triu (ppm), nng phn t (ppb))
- Mi lin h gia mt s nng dung dch
Phn II
HA PHN TCH NH TNH
1. Nguyn tc chung ca phn tch nh tnh, cc phng php ca ha phn tch nh
tnh xc nh mt ion hoc mt cht cha bit.
2. Cc phn ng ha hc dng trong ha phn tch
- Phn ng trao i ion
- Phn ng to phc
- Phn ng oxy ha kh
3. Phn loi cc nhm phn tch nh tnh.
4. Phn tch nh tnh cation ( cation nhm I, II, III, IV, V, VI )
5. Phn tch nh tnh anion (anion nhm I, II, III)
6. Phn tch nh tnh hn hp cation v anion trong dung dch
PHN III
HA PHN TCH NH LNG
Bi 1. i cng v ha phn tch nh lng.
- Trnh by c khi nim v sai s, cc i lng c trng ca ton thng k.
- ng dng ton thng k x l cc kt qu thu c t thc nghim.
- Trnh by kt qu phn tch m bo c mc chnh xc theo yu cu
Bi 2. Cc sai s trong phn tch nh lng.
- Trnh by c v tr, i tng ca mn hc
- Nu c cc nguyn tc chung ca cc phng php ha hc dng trong phn tch nh
lng.
- Phn loi cc phng php ha hc phn tch nh lng v nu nguyn tc c bn ca
tng phng php .
- Trnh by c yu cu c bn ca phng php phn tch nh lng
Bi 3. Phng php phn tch khi lng
- Trnh by c ni dung v phn loi ca phng php phn tch khi lng.
- M t cc giai on chnh ca phn tch khi lng.
- Tnh c kt qu ca nh lng bng phng php khi lng.
Bi 4. Phng php phn tch th tch
- Trnh by c ni dung ca phng php phn tch th tch. Nu c cch xc nh
im tng ng.
- K tn c bn loi phng php chun chnh v ba k thut chun .
- Trnh by c quy tc chung v cch tnh kt qu nh lng theo nng nh lng.
Bi 5. Phng php chun acid-base
- Nu c cc khi nim v acid base theo cc thuyt Arrhenius, Lewis, Bronsted.
- S dng c cc cng thc tnh pH ca cc dung dch c tnh acid -base.
- Trnh by c ngha ca phng php nh lng acid-base v cch chn ch th mu

trong tng php nh lng.
- ng dng phng php acid base nh lng cc hot cht trong thuc.
Bi 6. Phng php chun kt ta
Gii thch c biu thc tch s tan, tan v ngha trong phn tch.
Trnh by c hin tng hp ph khi chun theo phng php bc.
Nu c nguyn tc, iu kin tin hnh v ng dng ca 3 phng php: Mohr,
Fajans, Volhard.
Bi tp ng dng
Bi 7. Phng php chun to phc
Trnh by c nh ngha phc cht v phn bit c phc cht cng, phc cht ni,
mui kp.
Gii thch c ngha ca hng s to phc.
Trnh by c nguyn tc v cch chn ch th trong phng php chun bng
Complexon III.
Trnh by c cc k thut chun bng Complexon III.
Bi tp ng dng
Bi 8. Phng php chun oxy ha kh
Trnh by c khi nim v cht oxy ho, cht kh, phn ng oxy - ho kh.
Trnh by cc phng php oxy ho kh hay c s dng trong ngnh Dc.
Bi tp ng dng
MT S V D THAM KHO
Cu 1 :
Cho cc ion sau: Na+, NH4+, Ba2+, Ca2+, Fe3+, Al3+, K+, Mg2+, Cu2+, CO32-, PO43-, Cl-, NO3-, SO42-,
Br-. Trnh by mt phng n la chn ghp tt c cc ion trn thnh 3 dung dch, mi dung dch
u c 3 cation v 2 anion ( nhng ion chn dung dch ny th khng c chn li dung
dch khc).
Cu 2:
Ch dng 1 thuc th, hy nhn bit 4 cc cha 4 dung dch mt nhn gm:
CaCl2 ; Na2CO3 ; AgNO3 ; Mg(NO3)2.
Cu 3:
a) pha ch 10 lt dung dch NH3 0,1 M phi dng bao nhiu ml dung dch NH3 26%
(d = 0,904 g/ml).
b) Sau khi pha ch xong ngi ta kim tra li thy nng dung dch NH3 l 0,11M. Tnh th
tch nc v th tch dung dch NH3 pha ch phi trn vi nhau c c 1 lt dung dch
NH3 c nng mong mun.
Cu 4:
a) Trn m1 gam dung dch NaOH 20% vi m2 gam dung dch NaOH 45 % thu c 400 gam
dung dch NaOH 25 %. Tm m1 v m2.
b) Tnh th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch hn hp gm HNO3 v
HCl c pH = 1 thu c dung dch c pH =2.
Cu 5:
Ha tan 0,114g CaCO3 nguyn cht trong HCl v pha long thnh 250ml. Chun 25ml dung
dch thu c ht 40,25ml dung dch Complexon III. Tnh nng mol ca dung dch
Complexon III.
Cu 6:
Ha tan 42 g mu NaOH c cha 11,13 % Na2CO3 v 6% H2O trong nc n th tch 1 lt. Nu
cho 100 ml dung dch ny phn ng hon ton vi HCl 1,0N th phi dng ht bao nhiu ml HCl
? (Coi nh khi phn ng, Na2CO3 b trung ha hon ton)
Cu 7
a. trung ha 0,5g hn hp Na2CO3v K2CO3 ti CO2 cn 39,5ml dung dch HCl 0,2M. Xc
nh hm lng % Na2CO3 trong hn hp. Bit rng trong hn hp khng cha cc cht khc
na.
b. Trung ha 25 ml dung dch NH3 a M cn dng 50 dung dch HCl 0,1M. Tnh a v khi lng
NH3 trong 25 ml dung dch
Cu 8:
Ha tan 0,65g mt mu hp kim ca nhm. Tch b cc nguyn t gy cn tr, thm nc n
250ml. Ly 20ml dung dch, thm complexonat magie d ri chun dung dch thu c pH
= 9 vi ch th en eriocrom T th ht 7,6ml dung dch Complexon III 0,1M. Tnh hm lng %
ca Al trong hp kim.
Cu 9:
Tnh s gam nc cha trong 100 ml dung dch H2SO4 95% (d=1,834 g/ml). Sau mt thi gian
khng kh khi lng ca dung dch axit ny tng ln 15% do ht m.
a) Tnh nng % ca dung dch axit sau khi ht m (dung dch A)
b) Tnh khi lng SO3 cn thm vo dung dch A thu c dung dch c nng 98%.
Cu 10:
C 4 l mt nhn cha dung dch cc cht sau: AlCl3, ZnCl2, NaCl, MgCl2. Bng phng php
ha hc, hy nhn bit cc dung dch ha cht trn. Vit phng trnh phn ng (nu c).
Cu 11:
C cc l mt nhn cha dung dch cc cht sau: CaCl2 , (NH4)2CO3 , KHCO3 , NH4NO3 , KNO3 .
Ch c dng 1 thuc th, hy nhn bit cc dung dch ha cht trn. Vit phng trnh phn
ng (nu c).
Cu 12:
xc nh hm lng CH3COOH trong mt loi axit axetic c bn trn th trng, ta lm th
nghim sau:
Cn vo cc cn c np 4,00 g axit , ha tan vo bnh nh mc 250 ml bng nc ct. Dng
pipet ly mi ln 50 ml em chun bng dung dch NaOH 0,5M. Kt qu trung bnh sau ba ln
chun l 20 ml NaOH.
a. Hy cho bit k thut chun dng trong phng php xc nh hm lng CH3COOH trn
b. Tnh hm lng % theo khi lng ca CH3COOH (M = 60,052) c trong axit th trng.
Cu 1 3:
xc nh nng ca mt hn hp dung dch gm c Na2CO3 v NaOH ngi ta tin hnh
nh sau:
Ly chnh xc 10,00ml hn hp dung dch NaOH v Na2CO3 cn xc nh nng cho vo mt
bnh nn, thm 7-8 git phenolphtalein lm ch th, dung dch c mu hng, chun bng dung
dch HCl 0,1000M n khi dung dch mt mu hng th th tch HCl 0,1000M c c trn
buret l 15ml. Thm tip vo bnh nn 1-2 git methyl da cam dung dch chuyn sang mu vng,
chun tip n khi dung dch chuyn t vng sang da cam th th tch HCl c c trn buret
l 25ml.
a) Hy vit phn ng xy ra (theo th t khi chun t t hn hp bng HCl).
b) Bit rng
- Khi phenolphtalein chuyn t mu hng sang khng mu l ton b lng NaOH phn ng
ht vi HCl v Na2CO3 chuyn ht thnh NaHCO3.
- Khi methyl da cam chuyn t mu vng sang da cam th NaHCO3 phn ng va ht vi HCl.
Hy xc nh nng mol/lt ca NaOH v Na2CO3 trong hn hp
Cu 14:
a) Tnh s gam Na2HPO4.12H2O cn pha ch c 1 lt dung dch Na2HPO4 10%. Nu khi
lng ring ca dung dch ny l 1,09 g/ml.
b) Tnh th tch nc cn pha ch c dung dch trn 20oC , bit rng khi lng ring ca
nc nhit ny l 0,998 g/ml
Cu 15:
Mt hn hp X ch cha NaCl v KCl. Ha tan 0,1225 gam X vo nc ri chun bng
AgNO3 theo phng php Mohr ht 15,62 ml AgNO3 0,1170 M. Tnh % khi lng ca mi
mui trong hn hp.
Cu 16: un si 1,000g mt mu mui amoni th vi lng d NaOH. Ton b kh NH3 bay ra
c hp th ht trong 50,00ml HCl 0,2500M. Chun axit cn tha ht 16,00 ml NaOH
0,0500M. Tnh hm lng % ca NH3 c trong mui amoni.
Cu 17:
chun Fe3+ v Al3+ trong cng mt hn hp ngi ta lm nh sau: Ly 50,00 ml dung dch
hn hp, iu chnh pH=2 ri chun Fe3+ bng dung dch chun Complexon III 0,0402M th
ht 29,60 ml. Tip theo thm vo dung dch y 50,00 ml dung dch Complexon III na, un nng,
iu chnh pH ca dung dch n 5 ri chun lng Complexon III d bng dung dch chun
Fe3+ 0,0323 M th ht 19,50 ml. Tnh nng mol ca mi ion c trong dung dch ban u.
Cu 18
Cu 19:
C 4 dung dch trong sut, mi dung dch cha mt loi ion dng v mt loi ion m trong cc
ion sau: Ba2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-.
a) Xc nh cng thc ca mui c trong mi dung dch.
b) Trnh by phng php ha hc nhn bit 4 dung dch ring bit trn.
Cu 20:
xc nh nng ca mt hn hp dung dch gm c Na2CO3 v NaOH ngi ta tin hnh
nh sau:
Ly chnh xc 10,00ml hn hp dung dch NaOH v Na2CO3 cn xc nh nng cho vo mt
bnh nn, thm 7-8 git phenolphtalein lm ch th, dung dch c mu hng, chun bng dung
dch HCl 0,1000M n khi dung dch mt mu hng th th tch HCl 0,1000M c c trn
buret l 10 ml. Thm tip vo bnh nn 1-2 git methyl da cam dung dch chuyn sang mu vng,
chun tip n khi dung dch chuyn t vng sang da cam th th tch HCl c c trn buret
l 15ml.
a) Hy vit phn ng xy ra (theo th t khi chun t t hn hp bng HCl).
b) Bit rng
- Khi phenolphtalein chuyn t mu hng sang khng mu l ton b lng NaOH phn ng
ht vi HCl v Na2CO3 chuyn ht thnh NaHCO3.
- Khi methyl da cam chuyn t mu vng sang da cam th NaHCO3 phn ng va ht vi HCl.
Hy xc nh nng mol/lt ca NaOH v Na2CO3 trong hn hp

Cu 21:
a) Tnh th tch dung dch H2SO4 95,7% (d=1,84 g/ml) phi thm vo 1 lt dung dch H2SO4 40%
(d=1,304 g/ml) thu c dung dch H2SO4 50%.
b) Tnh s ml H2O cn thm vo 250 ml dung dch NaOH 1,25M to thnh dung dch NaOH
0,5M. Gi s s ha tan khng lm thay i ng k th tch dung dch.
Cu 22:
Cho NaCl d vo 25,00 ml AgNO3. Lc kt ta, lm kh, cn c 0,4306g. Mt khc, nu
chun 50,00 ml AgNO3 trn th ht 32,58 ml NH4SCN. Tnh nng mol ca AgNO3 v
NH4SCN.
Cu 23:
La chn mt ha cht thch hp phn bit cc dung dch mui sau: NH4Cl, (NH4)2SO4,
NaNO3, MgCl2, FeCl2, FeCl3, Al(NO3)3.
Cu 24:
Ha tan 0,2940 gam K2Cr2O7 trong nc v chuyn vo bnh nh mc 200,00ml. Thm nc
n vch. Ly 25,00ml dung dch thu c axit ha bng H2SO4 thm KI d. Chun I2 gii
phng ra ht 10,00ml Na2S2O3. Tnh nng mol ca dung dch Na2S2O3.
Cu 25:
a) Tnh khi lng CuSO4.5H2O v khi lng nc cn ly pha thnh 200 gam dung dch
CuSO4 8%.
b) Tnh khi lng FeSO4.7H2O cn ly pha thnh 250 ml dung dch X, bit kt ta ht ion
Fe2+ trong 50 ml dung dch X cn 15 gam dung dch NaOH 40 %.
Cu 26:
Trn dung dch A cha NaOH v dung dch B cha Ba(OH)2 theo th tch bng nhau c dung
dch C. Trung ha 100 ml dung dch C cn ht 35 ml dung dch H2SO4 2M v thu c 9,32 g kt
ta. Tnh nng mol/lt ca cc dung dch A v B.
Cu 27:
Xem H2SO4 v Ba(OH)2 in li hon ton theo 2 nc. Hy so snh pH ca cc dung dch sau c
cng nng v iu kin . Gii thch.
a) Cc dung dch : HCl ; H2SO4 ; CH3COOH .
b) Cc dung dch : NaOH ; Ba(OH)2 ; NH 3 .

Cu 28:
C hai dung dch H2SO4 l A v B.
a) Nu hai dung dch A v B c trn ln theo t l khi lng 7:3 th thu c dung dch
C c nng 29%. Tnh nng % ca dung dch A v dung dch B. Bit nng dung
dch B bng 2,5 ln nng dung dch A.
b) Ly 50 ml dung dch C (D = 1,27 g/ml) cho phn ng vi 200 ml dung dch BaCl2 1M.
Tnh khi lng kt ta v nng mol/lt ca dung dch E cn li sau khi tch ht kt
ta. Gi s th tch dung dch thay i khng ng k.
Cu 29:
Trn dung dch A cha NaOH v dung dch B cha Ba(OH)2 theo th tch bng nhau c dung
dch C. Trung ha 100 ml dung dch C cn ht 35 ml dung dch H2SO4 2M v thu c 9,32 g kt
ta. Tnh nng mol/lt ca cc dung dch A v B.
Cu 30:
Thm t t 4,0 gam dung dch H2SO4 49% vo nc v iu chnh lng nc thu c ng
2 lt dung dch A . Coi H2SO4 phn li hon ton 2 nc.
a) Tnh nng mol ca ion H+ trong dung dch A .
b) Tnh th tch dung dch NaOH 1,8M cn thm vo 0,5 lt dung dch A thu c
* dung dch c pH = 2 ;
* dung dch c pH = 12.
Cu 31:
X l dung dch H2SO4 0,02M, Y l dung dch NaOH 0,035M . Khi trn ln dung dch X vi dung
dch Y ta thu c dung dch Z c th tch bng tng th tch hai dung dch mang trn v c pH =
2. Coi H2SO4 phn li hon ton 2 nc. Hy tnh t l th tch gia dung dch X v dung dch Y .
Cu 32:
A l dung dch H2SO4, B l dung dch NaOH. Tin hnh cc th nghim sau :
- Trn 0,2 lt A v 0,3 lt B thu c 0,5 lt dung dch C . trung ho 20 ml dung dch C
cn 40 ml dung dch HCl 0,5M.
- Trn 0,3 lt A vi 0,2 lt B thu c 0,5 lt dung dch D. trung ho 20 ml dung dch D
cn 80 ml dung dch NaOH 0,1M.
Tnh nng mol ca H2SO4 v NaOH trong dung dch A, B. Coi H2SO4 phn li hon
ton 2 nc.
Cu 33:
Trn dung dch Ba(OH)2 0,5 M vi dung dch KOH 0,5 M ( theo t l th tch 1:1 ) c 200 ml
dung dch A. Tnh th tch dung dch HNO3 10% (D = 1,1g/ml) cn trung ho 1/5 dung dch
A.
Cu 34:
Dung dch H2SO4 98% c khi lng ring D = 1,84 gam/ml. Hy xc nh nng mol/lt, nng
ng lng gam/lt ca dung dch H2SO4 98%.
c) T dung dch H2SO4 98% mun thu c dung dch H2SO4 20% th phi pha long bao
nhiu ln? Cho bit dung dch H2SO4 20% c khi lng ring 1,14 gam/ml.
Cu 35:
Trn 250 ml dung dch hn hp HCl 0,08 mol/l v H2SO4 0,01 mol/l vi 250 ml
dung dch Ba(OH)2 c nng x mol/l thu c m gam kt ta v 500 ml dung dch c pH = 12.
Hy tnh m v x. Coi H2SO4, Ba(OH)2 in li hon ton c hai nc.
Cu 36:
Cho bit gi tr tch s ha tan ca AgCl l 1,6.10-10. Kt ta AgCl c to thnh khng trong hai
trng hp sau:
a) Trn 100 ml dung dch AgNO3 0,1 M vi 100 ml dung dch KCl 0,04 M.
b) Trn 20 ml dung dch AgNO3 10-4 M vi 30 ml dung dch NaCl 10-6 M.
Cu 37:
Cho dung dch HNO3 2M
a) Cn ly bao nhiu ml dung dch NaOH 1,8 M thm vo 100 ml dung dch axit trn
thu c dung dch c pH =1.
b) Cn ly bao nhiu lt dung dch NaOH 1,8 M thm vo 1 lt dung dch axit trn thu
c dung dch c pH =13.
Cu 38:
Ha tan 7,1 gam Na2SO4 ; 7,45 gam KCl ; 2,925 gam NaCl vo nc c 1 lt
dung dch A.
a) Tnh nng mol/lt ca mi ion trong dung dch A.
b) Cn dng bao nhiu mol NaCl v bao nhiu mol K2SO4 pha thnh 400 ml dung dch
mui c nng ion nh trong dung dch A.
c) C th dng 2 mui KCl v Na2SO4 pha thnh 400 ml dung dch mui c nng ion
nh dung dch A c khng? V sao ?
Cu 39:
Ha tan hn hp 2 cht rn NaOH v NaHCO3 vo trong H2O c dung dch A. Trnh by cch
nhn bit tng ion c mt trong dung dch A.
Cu 40:
Trnh by phng php ha hc nhn bit tng cp cht sau (ch dng mt thuc th)
a) AlCl3 v ZnCl2
b) CO2 v SO2
Cu 41:
Cho 3 l ha cht ring bit ng cc dung dch hn hp gm:
- L 1: Na2CO3 v K2SO4
- L 2: NaHCO3 v K2CO3
- L 3: NaHCO3 v Na2SO4
Hy dng dung dch HCl v dung dch BaCl2 phn bit 3 l ha cht trn.
Cu 42:
Dung dch A cha cc ion: NH4+, SO42-, SO32-, CO32-, NO3-. Bng nhng phn ng ha hc no
c th nhn bit tng loi anion c trong dung dch.
Cu 43:
Khng dng thm thuc th no khc, hy trnh by cch phn bit 2 dung dch ring bit mt
nhn sau: HCl ; Na2CO3.
Cu 44:
Ch dng HCl v H2O, hy nhn bit cc cht rn sau y ng ring trong cc l mt nhn: Al,
Ba , MgO, CuCl2, Al2O3, FeO, Fe2O3 v CaCO3.
Cu 45:
Cho dung dch A cha cc ion: Na +, NH4+, HCO3-, CO32- v SO42- (khng k ion H+ v OH- ca
H2O). Ch dng qu tm v cc dung dch HCl, Ba(OH)2 c th nhn bit c cc ion no trong
dung dch A. Vit phng trnh phn ng, nu c.
Cu 46: Cho Na d vo dung dch Al2(SO4)3 n khi cc phn ng xy ra hon ton. Nu hin
tng quan st c. Vit cc phng trnh phn ng minh ha.
Cu 47:
La chn mt ha cht thch hp phn bit cc dung dch mui sau: NH4Cl,
(NH4)2SO4, NaNO3, MgCl2, FeCl2, FeCl3, Al(NO3)3. Vit y d phng trnh phn ng xy ra.
Cu 48:
Ch dng qu tm, hy trnh by phng php nhn bit cc dung dch sau:
BaCl2; NH4Cl; (NH4)SO4; NaOH; Na2CO3.

Cu 49:
Ch dng CO2 v H2O, hy trnh by phng php ha hc nhn bit cc cht rn sau: NaCl,
Na2CO3, CaCO3, BaSO4. Vit phng trnh phn ng (nu c).
Cu 50:
Hy nu phng php ha hc nhn bit cc dung dch b mt nhn sau y: AlCl3, NaCl,
MgCl2, H2SO4. Cho bit c th dng mt trong cc thuc th sau: qu tm, Cu, Zn, dung dch
NH3, HCl, NaOH, BaCl2, AgNO3, Pb(NO3)2.
Cu 51:
Ch c dng kim loi, hy nhn bit cc dung dch sau y: HCl, HNO3 c, AgNO3, KCl,
KOH. Nu ch dng mt kim loi, c th nhn bit c cc dung dch trn hay khng? V sao ?
Cu 52:C 6 l mt nhn ng ring bit tng dung dch sau: K2CO3, (NH4)2SO4, MgSO4,
Al2(SO4)3, FeSO4 v Fe2(SO4)3. Hy dng xt, trnh by c th phng php nhn bit cc
dung dch trn.
Cu 53:
nh lng natri clorid trong mt dung dch ta thc hin nh sau:
Trc ht ta cho chnh xc 10,00 ml AgNO3 0,1M d vo ta ha ton ion clorid trong dung
dch. Sau chun AgNO3 0,1M cn tha th cn dng 6,5 ml dung dch chun KSCN 0,1M
a) Vit phng trnh phn ng xy ra trong php chun trn
b) Hy cho bit k thut chun dng nh lng Natri clorid.
c) Tnh khi lng Natri clorid trong dung dch trn.
Cu 54
C 10,00 ml dung dch Natri clorid cha bit nng . nh lng natri clorid trong
mt dung dch trn ta thc hin nh sau
Trc ht ta cho chnh xc 10,00 ml AgNO3 0,1M d vo 10,00 ml dung dch Natri clorid
ta ha ton ion clorid trong dung dch. Sau chun AgNO3 0,1M cn tha th
cn dng 6,50 ml dung dch chun KSCN 0,1M
a. Vit phng trnh phn ng xy ra trong php chun trn.
b. Hy cho bit k thut chun dng nh lng Natri clorid.
c. Tnh nng mol/l ca dung dch Natri clorid trn.
Cu 55
Thm 25,00ml dung dch AgNO3 0,1248M vo 20,00ml dung dch NaCl, chun
AgNO3 d ht 11,54ml dung dch KSCN 0,0875M.
a. Hy cho bit k thut chun dng nh lng Natri clorid ni trn.
b. Vit phng trnh phn ng xy ra
c. Tnh nng phn trm (kl/tt) ca dung dch Natri clorid trn
Cu 56
Ha tan 0,294g K2Cr2O7 trong nc v pha long thnh 200,0ml. Ly 20,00ml dung dch
trn, acid ha bng dung dch H2SO4 2M, thm KI d, chun I2 gii phng ra ht
10,68ml Na 2S2O3.
a. Vit phng trnh phn ng xy ra
b. Tnh nng mol/lt ca dung dch Na 2S2O3.
Cu 57
C 10,00 ml dung dch Natri clorid cha bit nng . nh lng natri clorid trong mt dung
dch trn ta thc hin nh sau:
Trc ht ta cho chnh xc 10,00 ml AgNO3 0,1M d vo 10,00 ml dung dch Natri clorid ta
ha ton ion clorid trong dung dch. Sau chun AgNO3 0,1M cn tha th cn dng 6,50 ml
dung dch chun KSCN 0,1M
a. Vit phng trnh phn ng xy ra trong php chun trn
b. Hy cho bit k thut chun dng nh lng Natri clorid.
c. Tnh nng phn trm (kl/tt) ca dung dch Natri clorid trn.
Cu 58
xc nh hm lng CH3COOH trong mt loi axit axetic c bn trn th trng, ta
lm th nghim sau:
Cn vo cc cn c np 4,00 g axit , ha tan vo bnh nh mc 250 ml bng nc ct.
Dng pipet ly mi ln 50 ml em chun bng dung dch NaOH 0,5M. Kt qu trung
bnh sau ba ln chun l 18 ml NaOH.
a. Hy cho bit k thut chun dng trong phng php xc nh hm lng
CH3COOH trn.
b. Tnh hm lng % theo khi lng ca CH3COOH (M = 60,052) c trong axit th
trng.
Cu 59
xc nh hm lng CH3COOH trong mt loi axit axetic c bn trn th trng, ta
lm th nghim sau:
Cn vo cc cn c np 5,00 g axit , ha tan vo bnh nh mc 250 ml bng nc ct.
Dng pipet ly mi ln 50 ml em chun bng dung dch NaOH 0,5M. Kt qu trung
bnh sau ba ln chun l 30 ml NaOH.
a) Hy cho bit k thut chun dng trong phng php xc nh hm lng
CH3COOH trn
b) Tnh hm lng % theo khi lng ca CH3COOH (M = 60,052) c trong axit th
trng.
Cu 60
Cu 61
NH4SCN.
Cu 62
mui trong hn hp.
Cu 63
Complexon III.
Cu 64
Cu 65
= 9 vi ch th en eriocrom T th ht 35,5ml dung dch Complexon III 0,25M. Tnh hm lng
% ca Al trong hp kim.
Cu 66
Xc nh hm lng aspirin dc dng ngi ta lm nh sau:
Cho vo bnh nn 0,500g aspirin v 10ml cn 96o, lc cho tan ri cho vo vi git
phenolphtalein lm ch th. Lm lnh bnh nn trong nc xung 8 oC-10oC. Chun
dung dch ny bng NaOH 0,1N th th tch NaOH c c trn buret l 20 ml.
a) Hy cho bit k thut chun dng trong phng php nh lng aspirin trn
b) Tnh hm lng aspirin (M = 180) trong aspirin dc dng trn bit aspirin phn
ng vi NaOH theo t l 1:1 v s mol (trong iu kin phn ng).
Cu 67
Complexon III.
Cu 68
phenolphtalein lm ch th. Lm lnh bnh nn trong nc xung 8oC-10oC. Chun dung
dch ny bng NaOH 0,4M th th tch NaOH c c trn buret l 5,1 ml.
a. Hy cho bit k thut chun dng trong phng php nh lng aspirin trn
b. Hy cho bit du hiu nhn bit im kt thc khi chun bng phng php trn.
c. Tnh hm lng aspirin (M = 180) trong aspirin (M = 180) dc dng trn bit aspirin
phn ng vi NaOH theo t l 1:1 v s mol (trong iu kin phn ng)
Cu 69: chun Fe3+ v Al3+ trong cng mt hn hp ngi ta lm nh sau: Ly 10,00 ml

dung dch hn hp, iu chnh pH=2 ri chun Fe 3+ bng dung dch chun Complexon III
0,0204M th ht 15,75 ml. Tip theo thm vo dung dch y 50,00 ml dung dch Complexon III
na, un nng, iu chnh pH ca dung dch n 5 ri chun lng Complexon III d bng
dung dch chun Fe3+ 0,0135 M th ht 25,85 ml. Tnh nng mol ca mi ion c trong dung
dch ban u.
Cu 70
phenolphtalein lm ch th. Lm lnh bnh nn trong nc xung 8 oC-10 oC. chun dung
dch ny bng NaOH 0,4 M th th tch NaOH c c trn buret l 8,2 ml.
a. Hy cho bit k thut chun dng trong phng php nh lng aspirin trn.
b. Hy cho bit du hiu nhn bit im kt thc khi chun bng phng php trn.
c. Tnh hm lng aspirin (M = 180) trong aspirin (M = 180) dc dng trn bit aspirin phn
ng vi NaOH theo t l 1:1 v s mol (trong iu kin phn ng)
Cu 71
= 9 vi ch th en eriocrom T th ht 25,45ml dung dch Complexon III 0,25M. Tnh hm lng
% ca Al trong hp kim.
Cu 72
xc nh hm lng Bari trong mt mu BaCl2.2H2O ngi ta cn 0,6531g mu, ha tan
thnh 250 ml dung dch. Ly ra 50ml dung dch cho phn ng vi acid sulfuric th thu c
0,1241g kt ta. Tnh hm lng Bari trong mu.
Cu 73
mui trong hn hp.
Cu 74
xc nh hm lng CaCO3 trong vi ngi ta cn 0,5120g mu ha tan thnh 100 ml
dung dch. Kt ta ion Ca2+ trong 50 ml dung dch di dng CaC2O4. Sau khi lc, ra v
nung ta n khi lng khng i thu c 0,1g CaO.
a. Hy cho bit dng ta v dng cn trong php phn tch trn
b. Tnh hm lng CaCO3 trong mu.
Cu 75
NH4SCN.
Cu 76: Ht chnh xc 10 ml mt dung dch HCl cha bit nng pha thnh 100ml
dung dch trong bnh nh mc. Ly 5 ml dung dch va pha long ny em chun
bng dung dch chun NaOH c nng 0,5 M ht 4,3 ml.
Vit phng trnh phn ng xy ra

Xc nh nng phn trm (kl/tt) ca dung dch HCl m c ban u.
Cu 77:
Cu 78:
Ht chnh xc 10 ml mt dung dch HCl m c pha thnh 250ml dung dch trong bnh nh
mc. Ly 10 ml dung dch va pha long ny em chun bng dung dch chun NaOH c
nng 0,5 M ht 7,3 ml. Xc nh nng phn trm (kl/tt) ca dung dch HCl m c ban
u.
Cu 79
Complexon III.
Cu 80
nh lng NaHCO3 trong mt ch phm thuc trn th trng ngi ta lm nh sau:
Ha tan 15,0000 g ch phm trong bnh nh mc 500 ml. Chun 50ml dung dch ny bng
dung dch HCl 1M v dng dung dch methyl da cam lm ch th
a.
Hy cho bit du hiu nhn bit im kt thc chun .
b. Vit phng trnh phn ng xy ra.
c. Nu ti thi im kt thc chun th tch HCl 1M tiu tn l 9,5ml th hm lng phn
trm NaHCO3 trong ch phm l bao nhiu.

Noi Dung On Tap Hoa Phan Tich

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Noi Dung On Tap Hoa Phan Tich

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HNG DN N TP MN HA PHN TCH

- Trnh by c ngha ca phng php nh lng acid-base v cch chn ch th mu

Hy xc nh nng mol/lt ca NaOH v Na2CO3 trong hn hp

b) Cc dung dch : NaOH ; Ba(OH)2 ; NH 3 .

BaCl2; NH4Cl; (NH4)SO4; NaOH; Na2CO3.

Cu 69: chun Fe3+ v Al3+ trong cng mt hn hp ngi ta lm nh sau: Ly 10,00 ml

Vit phng trnh phn ng xy ra

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