LAMPIRAN

Tabel 1. Hasil Pegamatan Penentuan Ketetapan Kalorimeter

n
X (t)
Y (T)
X2
XY
1
1
317 K
1
317
2
2
317 K
4
632
3
3
316 K
9
945
4
4
315 K
16
1258
5
5
314,5 K
25
1570
6
6
314 K
36
1881
7
7
313 K
49
2191
8
8
312 K
64
2496
9
9
312 K
81
2808
10
10
311 K
100
3110

45
3455 K
385
17208

Tp = 89oC = 362 K
Td = 20oC =293 K
Tc = 44oC =317 K

( y . x 2) ( x . xy )
a=
n ( x 2 ) ( x)2

b=

( 3455 x 385 )( 45 x 17208)

=
10 (385 )( 45)2
=

555815
1825

= 304,55
Yn = a + bXn
Y1 = (304,55) + (9,09 x 1) = 313,64
Y2 = (304,55) + (9,09 x 2) = 322,73
Y3 = (304,55) + (9,09 x 3) = 331,82
Y4 = (304,55) + (9,09 x 4) = 340,91
Y5 = (304,55) + (9,09 x 5) = 350
Y6 = (304,55) + (9,09 x 6) = 359,09
Y7 = (304,55) + (9,09 x 7) = 368,18
Y8 = (304,55) + (9,09 x 8) = 377,27
Y9 = (304,55) + (9,09 x 9) = 386,36
Y10 = (304,55) + (9,09 x 10) = 395,45
Q1 = m . c . t
= 20 x 4,2 x (317 293)
= 2016 j
Q2 = m . c . t
= 73,5 j/k

n ( xy ) ( x . y )
n ( x 2 )( x) 2

10 ( 17208 ) ( 45 x 3455)
=
10 ( 385 )(45)2
=

16605
1825

= 9,09
= 20 x 4,2 x (362 317)
= 3780 j
Q3 = Q2 Q1
= 3780 2016
= 1764 j

TcTd

K =
Q3

317293

=
1764

Grafik 1. Hasil Pengamatan Penentuan Ketetapan Kalorimeter

450
400
350
300
Tcampuran

250

nilai y

200
150
100
50
0
0

Tabel 2. Hasil Pengamatan Penentuan Kalor CuSO4

n
X (t)
Y (T)
X2
1
0,5
323
0,25
2
1
324
1
3
1.5
325
2,25
4
2
325
4

5
1297
7,5

10

+ Zn
XY
161,5
324
487,5
650
1623

12

Tc = 39 oC = 312 K
Td = 20,5 oC = 293,5 K
t1j = Tc Td

= 312 293,5 = 18,5

( y . x 2) ( x . xy )
a=
n ( x 2 ) ( x)2

n ( xy ) ( x . y )
n ( x 2 )( x) 2

b=

( 1297 x 7,5 )(5 x 1623)

4 ( 7,5 )(5)2

4(1623)(5 x 1297)
4 (7,5)(5) 2

1612,5
5

7
5

= 322,5

= 1,4

Yn = a + bXn
Y1 = (322,5) + (1,4 x 0,5) = 323,2
Y2 = (322,5) + (1,4 x 1) = 323,9
Y3 = (322,5) + (1,4 x 1,5) = 324,6
Y4 = (322,5) + (1,4 x 2) = 325,3

= 1359,75 j
Q2 = Mcamp . Pcamp . Ccamp . t1j
= 22 x 1,4 x 3,52 x 18,5
= 1633,2 j

Q4 = k . t1j
= 73,5 x 18,5

Q6 = Q4 + Q5
= 1359,75 + 1633,2

= 2992,95 j

H=

2
Mol Zn = 65,4

2992,95
0,03

= 99,765

= 0,03

Grafik 2. Hasil Pengamatan Penetuan Kalor CuSO4 + Zn

325.5
325
324.5
324

Tcampuran
nilai y

323.5
323
322.5
322
321.5
0.4

0.6

0.8

1.2

1.4

1.6

Tabel 3. Hasil Pengamatan Penentuan Kalor Etano dan Air

n
X (t)
Y (T)
X2
1
0,5
304
0,25
2
1
304,5
1
3
1,5
304,5
2,25
4
2
304
4
5
2,5
304
6,25
6
3
304
79
7
3,5
304
12,25
8
4
304
16
18
2433
51

1.8

XY
152
304,5
456,75
608
760
912
1064
1216
5473,25

2.2

Tair = 26 oC = 299 K
Tetanol = 26 oC = 299 K
t2j = Ta -Tm

= 304,1 299
= 5,1 K

( y . x 2) ( x . xy )
a=
n ( x 2 ) ( x)2

n ( xy ) ( x . y )
n ( x 2 )( x) 2

b=

( 2433 x 51 )(18 x 5473,25)

8 ( 51 )(18)2

8 ( 5473,25 ) (18 x 2433)

8 ( 51 )(18)2

25564,5
84

8
84

= 304,33
Yn = a + bXn
Y1 = (304,33) + (-0,095 x 0,5) = 304,28
Y2 = (304,33) + (-0,095 x 1) = 304,23
Y3 = (304,33) + (-0,095 x 1,5) = 304,18
Y4 = (304,33) + (-0,095 x 2) = 304,14
Y5 = (304,33) + (-0,095 x 2,5) = 304,09
Y6 = (304,33) + (-0,095 x 3) = 304,04
Y7 = (304,33) + (-0,095 x 3,5) = 303,99
Y8 = (304,33) + (-0,095 x 4) = 303,95
Q7 = Maquadest . Caquadest . t2j
= 18 x 4,2 x 5,1
= 385,56 j
Q8 = Metanol . Cetanol . t2j
= 1,01761 x 1,92 x 5,1
= 9,96 j
Q9 = k . t2j
= 73,5 x 5,1
= 374,85 j

= - 0,095
Q10 = Q7 + Q8 + Q9
= 770,37 j
TA =
=

y 1+ y 8
2
304,28+ 303,95
2

= 304,1

TE =
=

Ta +Te
2
299+ 299
2

= 299 K

Grafik 3. Hasil Pengamatan Penentuan Kalor Etanol da Air

304.6
304.5
304.4
304.3
304.2

Tcampuran

304.1

nilai y

304
303.9
303.8
303.7
303.6
0

0.5

1.5

2.5

3.5

4.5

Tabel 4. Hasil Pengamatan Penentuan Kalor Penetralan HCl + NaOH

n
1
2
3
4
5
6
7
8
9
10

X (t)
0,5
1
1,5
2
2,5
3
3,5
4
4,5
5
27,5

Y (T)
303
308
308
308
308
308
307
307
307
307
3071

X2
0,25
1
2,25
4
6,25
9
12,25
16
20,25
25
96,25

THCl = 27 = 300 K
TNaOH = 25 = 298 K

XY
151,5
308
462
616
770
924
1074,5
1228
1381,5
1535
7350,5

MNaCl =

g 1000
x
mr
p

9
1000
x
2M = 58,5
40

= 4,68 gam
t3j = Ta Tm
= 307,25 299
= 8,25 K

( y . x 2) ( x . xy )
a=
n ( x 2 ) ( x)2
=

( 3071 x 96,25 )( 27,5 x 7350,5)

10 ( 96,25 )( 27,5)2

b=

n ( xy ) ( x . y )
n ( x 2 )( x) 2

10 ( 7350,5 )(27,5 x 3071)

10 ( 96,25 )(27,5) 2

93445
206,25

= 453
Yn = a + bXn
Y1 = (453) + (-53 x 0,5) = 426,5
Y2 = (453) + (-53 x 1) = 400
Y3 = (453) + (-53 x 1,5) = 373,5
Y4 = (453) + (-53 x 2) = 347
Y5 = (453) + (-53 x 2,5) = 320,5
Y6 = (453) + (-53 x 3) = 294
Y7 = (453) + (-53 x 3,5) = 267,5
Y8 = (453) + (-53 x 4) = 241
Y9 = (453) + (-53 x 4,5) = 214,5
Y10 = (453) + (-53 x 5) = 188
Q11 = Mcamp . Pcamp . t3j
= 4,68 x 3,96 x 8,25
= 152,89 j
Q12 = K . t3j
= 73,5 x 8,25
= 606,375 j
Q13 = Q11 + Q12
= 759,265 j

10947,5
206,25

= -53
TA =
=

y 1+ y 10
2
426,5+188
2

= 307,25
TE =
=

Ta +Te
2
300+ 298
2

= 299 K
Mol NaCl =

4,68
58,5

= 0,08 mol

H=

759,265
0,08

= 9490,8125 j/mol

Grafik 4 . Hasil pengamatan Penentuan Kalor Penetralan HCl dan NaOH

450
400
350
300

Tcampuran

250

nilai y

200
150
100
50
0
0