CHEMCAD 6.3.

0 Page 1

Simulation: Untitled Date: 11/29/2010 Time: 14:50:00

BATCH DISTILLATION 1 CALCULATION RESULTS

Operation Step 1:

Stream Name Pot Charge Accumulator Pot Residue Distillate

Temp F 0.0000 64.2567 163.1684 155.3837
Pres psia 16.7000 14.7000 16.7000 14.7000
Enth MMBtu 0.00000 -0.094668 -0.0059552 -0.0081428
Vapor mass frac. 0.00000 0.00000 0.00000 0.00000
Total lbmol 1.4000 1.3000 0.0735 0.1000
Total lb 101.0100 92.3931 6.3299 8.6130
Total std L ft3 2.5738 2.3657 0.1529 0.2080
Flowrates in lb
Propane 4.4096 4.4097 0.0000 0.0000
N-Butane 17.4369 17.4369 0.0000 0.0000
N-Pentane 36.0750 36.0724 0.0014 0.0244
N-Hexane 43.0885 34.4741 6.3285 8.5885
CHEMCAD 6.3.0 Page 2

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STREAM PROPERTIES

Name Pot Charge Accumulator Pot Residue Distillate

- - Overall - -
Molar flow lbmol 1.4000 1.3000 0.0735 0.1000
Mass flow lb 101.0100 92.3931 6.3299 8.6130
Temp F 0.0000 64.2567 163.1684 155.3837
Pres psia 16.7000 14.7000 16.7000 14.7000
Vapor mole fraction 0.0000 0.1199 0.0000 0.0000
Enth MMBtu 0.00000 -0.094668 -0.0059552 -0.0081428
Tc F 392.2184 386.5526 453.4548 453.2767
Pc psia 540.9658 546.2212 430.6165 430.9119
Std. sp gr. wtr = 1 0.629 0.626 0.663 0.663
Std. sp gr. air = 1 2.491 2.454 2.975 2.974
Degree API 93.5876 94.6842 81.8298 81.8586
Average mol wt 72.1500 71.0714 86.1732 86.1295
Actual dens lb/ft3 0.0000 1.5408 38.1121 38.3777
Actual vol ft3 -1.#IND 59.9653 0.1661 0.2244
Std liq ft3 2.5738 2.3657 0.1529 0.2080
Std vap 60F ft3 531.2700 493.3237 27.8750 37.9480
- - Vapor only - -
Molar flow lbmol 0.1559
Mass flow lb 9.0677
Average mol wt 58.1544
Actual dens lb/ft3 0.1568
Actual vol ft3 57.8437
Std liq ft3 0.2505
Std vap 60F ft3 59.1697
Cp Btu/lbmol-F 23.1256
Z factor 0.9700
Visc cP 0.007366
Th cond Btu/hr-ft-F 0.0090
- - Liquid only - -
Molar flow lbmol 1.4000 1.1441 0.0735 0.1000
Mass flow lb 101.0100 83.3254 6.3299 8.6130
Average mol wt 72.1500 72.8318 86.1732 86.1295
Actual dens lb/ft3 39.2742 38.1121 38.3777
Actual vol ft3 2.1216 0.1661 0.2244
Std liq ft3 2.5738 2.1153 0.1529 0.2080
Std vap 60F ft3 531.2700 434.1540 27.8750 37.9480
Cp Btu/lbmol-F 38.3435 50.1066 49.5389
Z factor 2.2739 0.0048 0.0057 0.0050
Visc cP 1.000 0.2366 0.2071 0.2125
Th cond Btu/hr-ft-F 0.0669 0.0593 0.0602
Surf. tens. dyne/cm 16.1092 12.8708 13.3084

Operation Step 2:

CHEMCAD 6.3.0 Page 3

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FLOW SUMMARIES:

Stream Name Accumulator Pot Residue Distillate

Temp F 96.6457 375.8179 176.1156
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -7.1433 -3.4711E-022 -7.0486
Vapor mass frac. 0.00000 0.00000 0.00000
Total lbmol 101.5138 0.0000 100.2138
Total lb 7321.0444 0.0000 7228.6519
Total std L ft3 185.9699 0.0000 183.6042
Flowrates in lb
Propane 9.3854 0.0000 4.9757
N-Butane 17.4950 0.0000 0.0581
N-Pentane 7251.0723 0.0000 7215.0000
N-Hexane 43.0918 0.0000 8.6177
CHEMCAD 6.3.0 Page 4

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STREAM PROPERTIES

Name Accumulator Pot Residue Distillate

- - Overall - -
Molar flow lbmol 101.5138 0.0000 100.2138
Mass flow lb 7321.0444 0.0000 7228.6514
Temp F 96.6457 0.0000 176.1156
Pres psia 14.7000 0.0000 14.7000
Vapor mole fraction 0.3008 0.0000 0.0000
Enth MMBtu -7.1433 0.00000 -7.0486
Tc F 385.6788 0.0000 385.6676
Pc psia 489.7903 0.0000 489.0733
Std. sp gr. wtr = 1 0.631 0.000 0.631
Std. sp gr. air = 1 2.490 0.000 2.491
Degree API 92.8906 0.0000 92.8677
Average mol wt 72.1187 0.0000 72.1323
Actual dens lb/ft3 0.6074 0.0000 35.0136
Actual vol ft3 12052.9453 0.0000 206.4526
Std liq ft3 185.9699 0.0000 183.6042
Std vap 60F ft3 38522.3320 0.0000 38029.0078
- - Vapor only - -
Molar flow lbmol 30.5327
Mass flow lb 2196.1938
Average mol wt 71.9291
Actual dens lb/ft3 0.1843
Actual vol ft3 11918.4443
Std liq ft3 55.8397
Std vap 60F ft3 11586.5254
Cp Btu/lbmol-F 29.7199
Z factor 0.9613
Visc cP 0.007353
Th cond Btu/hr-ft-F 0.0092
- - Liquid only - -
Molar flow lbmol 70.9811 100.2138
Mass flow lb 5124.8506 7228.6519
Average mol wt 72.2002 72.1323
Actual dens lb/ft3 38.1027 35.0136
Actual vol ft3 134.5011 206.4526
Std liq ft3 130.1302 183.6042
Std vap 60F ft3 26935.8047 38029.0078
Cp Btu/lbmol-F 39.9086 45.2940
Z factor 0.0045 0.0043
Visc cP 0.2093 0.1593
Th cond Btu/hr-ft-F 0.0627 0.0538
Surf. tens. dyne/cm 14.2943 9.6846

Operation Step 3:

CHEMCAD 6.3.0 Page 5

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FLOW SUMMARIES:

Stream Name Pot Add Accumulator Pot Residue Distillate

Temp F 83.1109 0.0000 0.0000 0.0000
Pres psia 16.7000 0.0000 0.0000 0.0000
Enth MMBtu -1.5243 0.00000 0.00000 0.00000
Vapor mass frac. 0.00000 0.00000 0.00000 0.00000
Total lbmol 20.0000 0.0000 0.0000 0.0000
Total lb 1499.1080 0.0000 0.0000 0.0000
Total std L ft3 37.7190 0.0000 0.0000 0.0000
Flowrates in lb
Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 464.9840 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0000 0.0000 0.0000
N-Hexane 1034.1240 0.0000 0.0000 0.0000
CHEMCAD 6.3.0 Page 6

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STREAM PROPERTIES

Name Pot Add Accumulator Pot Residue Distillate

- - Overall - -
Molar flow lbmol 20.0000 0.0000 0.0000 0.0000
Mass flow lb 1499.1079 0.0000 0.0000 0.0000
Temp F 83.1109 0.0000 0.0000 0.0000
Pres psia 16.7000 0.0000 0.0000 0.0000
Vapor mole fraction 0.0000 0.0000 0.0000 0.0000
Enth MMBtu -1.5243 0.00000 0.00000 0.00000
Tc F 407.0823 0.0000 0.0000 0.0000
Pc psia 529.3731 0.0000 0.0000 0.0000
Std. sp gr. wtr = 1 0.637 0.000 0.000 0.000
Std. sp gr. air = 1 2.588 0.000 0.000 0.000
Degree API 90.7608 0.0000 0.0000 0.0000
Average mol wt 74.9554 0.0000 0.0000 0.0000
Actual dens lb/ft3 38.9860 0.0000 0.0000 0.0000
Actual vol ft3 38.4525 0.0000 0.0000 0.0000
Std liq ft3 37.7190 0.0000 0.0000 0.0000
Std vap 60F ft3 7589.5723 0.0000 0.0000 0.0000
- - Liquid only - -
Molar flow lbmol 20.0000
Mass flow lb 1499.1080
Average mol wt 74.9554
Actual dens lb/ft3 38.9860
Actual vol ft3 38.4525
Std liq ft3 37.7190
Std vap 60F ft3 7589.5723
Cp Btu/lbmol-F 40.2783
Z factor 0.0054
Visc cP 0.2248
Th cond Btu/hr-ft-F 0.0653
Surf. tens. dyne/cm 15.2938

Operation Step 4:

Stream Name Accumulator Pot Residue Distillate

Temp F 0.0000 0.0000 0.0000
Pres psia 0.0000 0.0000 0.0000
Enth MMBtu 0.00000 0.00000 0.00000
Vapor mass frac. 0.00000 0.00000 0.00000
Total lbmol 0.0000 0.0000 0.0000
Total lb 0.0000 0.0000 0.0000
Total std L ft3 0.0000 0.0000 0.0000
Flowrates in lb
Propane 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0000 0.0000
CHEMCAD 6.3.0 Page 7

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FLOW SUMMARIES:

N-Hexane 0.0000 0.0000 0.0000

CHEMCAD 6.3.0 Page 8

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STREAM PROPERTIES
 Name Accumulator Pot Residue Distillate
- - Overall - -
Molar flow lbmol 0.0000 0.0000 0.0000
Mass flow lb 0.0000 0.0000 0.0000
Temp F 0.0000 0.0000 0.0000
Pres psia 0.0000 0.0000 0.0000
Vapor mole fraction 0.0000 0.0000 0.0000
Enth MMBtu 0.00000 0.00000 0.00000
Tc F 0.0000 0.0000 0.0000
Pc psia 0.0000 0.0000 0.0000
Std. sp gr. wtr = 1 0.000 0.000 0.000
Std. sp gr. air = 1 0.000 0.000 0.000
Degree API 0.0000 0.0000 0.0000
Average mol wt 0.0000 0.0000 0.0000
Actual dens lb/ft3 0.0000 0.0000 0.0000
Actual vol ft3 0.0000 0.0000 0.0000
Std liq ft3 0.0000 0.0000 0.0000
Std vap 60F ft3 0.0000 0.0000 0.0000

Operation Step 5:

Stream Name Accumulator Pot Residue Distillate

Temp F 0.0000 0.0000 0.0000
Pres psia 0.0000 0.0000 0.0000
Enth MMBtu 0.00000 0.00000 0.00000
Vapor mass frac. 0.00000 0.00000 0.00000
Total lbmol 0.0000 0.0000 0.0000
Total lb 0.0000 0.0000 0.0000
Total std L ft3 0.0000 0.0000 0.0000
Flowrates in lb
Propane 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0000 0.0000
N-Hexane 0.0000 0.0000 0.0000
CHEMCAD 6.3.0 Page 9

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STREAM PROPERTIES

Name Accumulator Pot Residue Distillate

- - Overall - -
Molar flow lbmol 0.0000 0.0000 0.0000
Mass flow lb 0.0000 0.0000 0.0000
Temp F 0.0000 0.0000 0.0000
Pres psia 0.0000 0.0000 0.0000
Vapor mole fraction 0.0000 0.0000 0.0000
Enth MMBtu 0.00000 0.00000 0.00000
Tc F 0.0000 0.0000 0.0000
Pc psia 0.0000 0.0000 0.0000
Std. sp gr. wtr = 1 0.000 0.000 0.000
Std. sp gr. air = 1 0.000 0.000 0.000
Degree API 0.0000 0.0000 0.0000
Average mol wt 0.0000 0.0000 0.0000
Actual dens lb/ft3 0.0000 0.0000 0.0000
Actual vol ft3 0.0000 0.0000 0.0000
Std liq ft3 0.0000 0.0000 0.0000
Std vap 60F ft3 0.0000 0.0000 0.0000

CHEMCAD 6.3.0 Page 10

Simulation: Untitled Date: 11/29/2010 Time: 14:50:00

BATCH COLUMN HISTORY

OPERATION STEP 1:

Initial Conditions:
Stream Name Accumulator Pot Residue Distillate
Temp F -43.8610 71.2989 -43.8610
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -7.4497E-008 -0.10175 -7.4497E-008
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 0.0001 98.8066 0.0001
Flowrates in lb
Propane 0.0001 2.6301 0.0001
N-Butane 0.0000 17.1615 0.0000
N-Pentane 0.0000 35.9612 0.0000
N-Hexane 0.0000 43.0537 0.0000

ELAPSED TIME = 0.05 Hr Reflux ratio = 5.000

Condenser duty = -0.10634 MMBtu/h Reboiler duty = 0.11876 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
Temp F -35.7394 87.9099 -35.7339
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.0057346 -0.095553 -0.0057345
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 4.7008 94.0449 4.7007
Flowrates in lb
Propane 3.4951 0.6874 3.4950
N-Butane 1.2045 14.5458 1.2045
N-Pentane 0.0012 35.7896 0.0012
N-Hexane 0.0000 43.0222 0.0000

ELAPSED TIME = 0.20 Hr Reflux ratio = 5.000

Condenser duty = -0.12844 MMBtu/h Reboiler duty = 0.1327 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
Temp F 1.8717 122.3374 41.9205
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.025357 -0.075201 -0.0067915
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 22.3155 76.4079 6.2492
Flowrates in lb
Propane 4.4064 0.0029 0.0228
N-Butane 15.5037 1.7001 3.9431
N-Pentane 2.4034 31.8547 2.2814
N-Hexane 0.0020 42.8501 0.0020

ELAPSED TIME = 0.35 Hr Reflux ratio = 5.000

Condenser duty = -0.1364 MMBtu/h Reboiler duty = 0.13733 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
CHEMCAD 6.3.0 Page 11
Simulation: Untitled Date: 11/29/2010 Time: 14:50:00
FLOW SUMMARIES:

Temp F 25.3928 141.3367 94.3431

Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.047263 -0.053186 -0.0073676
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 43.5185 55.2078 7.1982
Flowrates in lb
Propane 4.4097 0.0000 0.0000
N-Butane 17.4021 0.0312 0.1157
N-Pentane 21.5946 12.8465 7.0148
N-Hexane 0.1121 42.3301 0.0676

ELAPSED TIME = 0.50 Hr Reflux ratio = 5.000

Condenser duty = -0.15291 MMBtu/h Reboiler duty = 0.15245 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
Temp F 44.7596 160.9575 133.8566
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.070294 -0.030207 -0.0079734
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 66.6854 32.0352 8.2395
Flowrates in lb
Propane 4.4097 0.0000 0.0000
N-Butane 17.4368 0.0001 0.0008
N-Pentane 35.3242 0.6503 1.9435
N-Hexane 9.5147 31.3847 6.2951

ELAPSED TIME = 0.65 Hr Reflux ratio = 5.000

Condenser duty = -0.15167 MMBtu/h Reboiler duty = 0.1509 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
Temp F 64.2567 163.1684 155.3837
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.094668 -0.0059552 -0.0081428
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 92.3931 6.3299 8.6130
Flowrates in lb
Propane 4.4097 0.0000 0.0000
N-Butane 17.4369 0.0000 0.0000
N-Pentane 36.0724 0.0014 0.0244
N-Hexane 34.4741 6.3285 8.5885

OPERATION STEP 2:

Initial Conditions:
Stream Name Accumulator Pot Residue Distillate
Temp F 64.2567 163.1684 155.3837
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -0.094668 -0.0059552 -0.0081428
Vapor mass frac. 0.00000 0.00000 0.00000
CHEMCAD 6.3.0 Page 12

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FLOW SUMMARIES:
Total lb 92.3931 6.3299 8.6130
Flowrates in lb
Propane 4.4097 0.0000 0.0000
N-Butane 17.4369 0.0000 0.0000
N-Pentane 36.0724 0.0014 0.0244
N-Hexane 34.4741 6.3285 8.5885

ELAPSED TIME = 0.70 Hr Reflux ratio = 0.999

Condenser duty = -159.34 MMBtu/h Reboiler duty = 0.1191 MMBtu/h
Stream Name Accumulator Pot Residue Distillate
Temp F 96.6457 375.8179 176.1156
Pres psia 14.7000 16.7000 14.7000
Enth MMBtu -7.1433 -3.4711E-022 -7.0486
Vapor mass frac. 0.00000 0.00000 0.00000
Total lb 7321.0444 0.0000 7228.6519
Flowrates in lb
Propane 9.3854 0.0000 4.9757
N-Butane 17.4950 0.0000 0.0581
N-Pentane 7251.0723 0.0000 7215.0000
N-Hexane 43.0918 0.0000 8.6177

CHEMCAD 6.3.0 Page 13

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BATCH COLUMN HOLDUPS

Batch Distillation 1, Stage Holdup

<<< Batch Distillation 1, Stage Holdup at the End of Step 1 >>>

Stage 1 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0000 0.0000 0.0000
N-Hexane 0.0000 0.0000 0.0000 0.0000
Total 0.0000 0.0000

Stage 2 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0014 0.0004 0.0011
N-Hexane 0.0044 0.9986 0.3807 0.9989
Total 0.0044 0.3811

Stage 3 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0007 0.0002 0.0006
N-Hexane 0.0044 0.9993 0.3809 0.9994
Total 0.0044 0.3811

Stage 4 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0004 0.0001 0.0003
N-Hexane 0.0044 0.9996 0.3810 0.9997
 Total 0.0044 0.3811

Stage 5 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0003 0.0001 0.0003
N-Hexane 0.0044 0.9997 0.3810 0.9997
Total 0.0044 0.3811

Stage 6 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0003 0.0001 0.0002
N-Hexane 0.0044 0.9997 0.3810 0.9998
Total 0.0044 0.3811

Stage 7 lbmol Mole frac lb Mass frac

CHEMCAD 6.3.0 Page 14

Simulation: Untitled Date: 11/29/2010 Time: 14:50:00

BATCH COLUMN HOLDUPS

Propane 0.0000 0.0000 0.0000 0.0000

N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0003 0.0001 0.0002
N-Hexane 0.0044 0.9997 0.3810 0.9998
Total 0.0044 0.3811

<<< Batch Distillation 1, Stage Holdup at the End of Step 2 >>>

Stage 1 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0000 0.0000 0.0000 0.0000
N-Hexane 0.0000 0.0000 0.0000 0.0000
Total 0.0000 0.0000

Stage 2 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0049 0.9805 0.3553 0.9768
N-Hexane 0.0001 0.0195 0.0084 0.0232
Total 0.0050 0.3638

Stage 3 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0041 0.0009 0.0025
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0050 0.9958 0.3621 0.9974
N-Hexane 0.0000 0.0000 0.0000 0.0000
Total 0.0050 0.3630

Stage 4 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0002 0.0000 0.0001
N-Butane 0.0005 0.0909 0.0269 0.0745
N-Pentane 0.0046 0.9089 0.3336 0.9253
N-Hexane 0.0000 0.0000 0.0000 0.0000
 Total 0.0051 0.3605

Stage 5 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0000 0.0000 0.0000 0.0000
N-Pentane 0.0050 1.0000 0.3634 1.0000
N-Hexane 0.0000 0.0000 0.0000 0.0000
Total 0.0050 0.3635

Stage 6 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0017 0.3333 0.0971 0.2685
N-Pentane 0.0017 0.3333 0.1206 0.3333
CHEMCAD 6.3.0 Page 15

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BATCH COLUMN HOLDUPS

N-Hexane 0.0017 0.3333 0.1440 0.3981

Total 0.0050 0.3617

Stage 7 lbmol Mole frac lb Mass frac

Propane 0.0000 0.0000 0.0000 0.0000
N-Butane 0.0011 0.2835 0.0666 0.2106
N-Pentane 0.0000 0.0000 0.0000 0.0000
N-Hexane 0.0029 0.7165 0.2498 0.7894
Total 0.0040 0.3164

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