AMMONIA SYNTHESIS

IDEAL GAS
Data
P, atm 250
T, C 500
Fo, mol/s 100
Kp, atm-2 1.45E-05

Trial
Konvesi N2 0.288534

Fi, umpan Reaksi, Produk,

Komponen yo yi Pi, atm Kp calc del K/ Kp
mol/s mol/s
Ar 0.01 1 0 1 0.0115 2.883
CH4 0.05 5 0 5 0.0577 14.413
N2 0.23 23 6.636284 16.36372 0.1887 47.170 1.450E-05 6.45E-07
H2 0.69 69 19.90885 49.09115 0.5660 141.510
NH3 0.02 2 13.27257 15.27257 0.1761 44.025
TOTAL 1 100 86.72743 1.0000 250.000
Sintesis amonia (Gas Non Ideal)

Data
P, atm 250 R 82.057
T, C 500
Fo, mol/s 100
Kp, atm-2 1.45E-05

Trial
Konvesi N2 0.327142

Kompone Fi, umpan Reaksi, Produk,

yo yi a b c B
n mol/s mol/s
Ar 0.01 1 0 1 0.0118 154.2 119.3 105.1 17.52871
CH4 0.05 5 0 5 0.0589 206.4 159.5 133 16.96093
N2 0.23 23 7.52427 15.47573 0.1822 185.4 141.8 88.7 26.36201
H2 0.69 69 22.57281 46.42719 0.5465 315 289.7 9.47 21.72976
NH3 0.02 2 15.04854 17.04854 0.2007 44.3 23.6 766.6 -19.3103
TOTAL 1 100 84.95146 1.0000
 B1j B2j B3j B4j B5j yjB1j yjB2j yjB3j yjB4j yjB5j

17.52871 17.24248 21.49632 19.51652 -0.89078 0.206338 0.202969 0.253042 0.229737 -0.01049
17.24248 16.96093 21.14531 19.19784 -1.17467 1.014843 0.998272 1.244553 1.12993 -0.06914
21.49632 21.14531 26.36201 23.93408 3.525873 3.916016 3.852072 4.802406 4.360106 0.642313
19.51652 19.19784 23.93408 21.72976 1.209748 10.66606 10.49189 13.08032 11.87563 0.661145
-0.89078 -1.17467 3.525873 -19.3103 -0.17877 -0.23574 0.707592 #VALUE! -3.87529
15.62449 15.30946 20.08791 #VALUE! -2.65146
yi Sum Psi i Pi, atm Kp calc Kpsi K del K/ Kp
yjBij
0.183923 #VALUE! 2.943
0.901071 #VALUE! 14.714
3.659444 #VALUE! 45.543 2.167044E-05 #VALUE! #VALUE! #VALUE!
#VALUE! #VALUE! 136.629
-0.53211 #VALUE! 50.171
#VALUE! 250.000
Primary Reformer

F0, mol/s 200

P, atm 35 Kp1 174.4534
T,C 800 1073.15 Kp2 1.081598

Trial CO,molC/mol C 0.304056 alpha

CO2,mol C/mol C 0.314364 beta

Fi, Umpan atom C atom H atom O atom N F out

KomponenyF mol/s mol/s mol/s mol/s mol/s mol/s yi Pi
N2 0.00029 0.058 0 0 0 0.116 0.058 0.000222 0.007757
CH4 0.24978 49.956 49.95600 199.824 0 0 19.10792 0.073016 2.555543
H2O 0.74933 149.867 0 299.7336 149.87 0 103.3965 0.3951 13.82851
CO 0.00000 0.000 0.00000 0 0.00 0 15.22585 0.058181 2.036344
CO2 0.00060 0.120 0.11980 0 0.2396 0 15.74203 0.060154 2.10538
H2 0.00000 0.000 0 0 0.00 0 108.1665 0.413327 14.46646
1.00000 200.00 50.0758 499.5576 150.1064 0.116 261.6968 1 35
Kp1 Kp2 Del Kp1 Del Kp2

174.4534 1.081598 -2.15716E-11 0

Secondary Reformer

F0 200 Kp1 8624.812

P 35 Kp2 0.594392
T 996 1269.15

Trial CO 0.655783
CO2 0.328084

Fi Atom C atom H O Ar N Fout yi

KomponenyF mol/s mol/s mol/s mol/s mol/s mol/s mol/s
Argon 0.00209 0.4180 0 0 0 0.418 0 0.418 0.001954
O2 0.04396 8.7920 0 0 17.584 0 0 0 0
N2 0.1636 32.7200 0 0 0 0 65.44 32.72 0.152951
Ch4 0.05924 11.8480 11.848 47.392 0 0 0 0.489727 0.002289
H2O 0.31504 63.0080 0 126.016 63.008 0 0 68.75041 0.321376
CO 0.045158 9.0316 9.0316 0 9.0316 0 0 19.90656 0.093054
CO2 0.047379 9.4758 9.4758 0 18.9516 0 0 9.959116 0.046554
H2 0.323537 64.7074 0 129.4148 0 0 0 81.68153 0.381823
Jumlah 1.000004 200.0008 30.3554 302.8228 108.5752 0.418 65.44 213.9253 1
Pi Kp1 Kp2 del Kp1 del Kp2

0.068388 8624.812 0.594392 0 0

0
5.353269
0.080124
11.24815
3.256881
1.629396
13.36379
35
Secondary Reformer

F0 200 Kp1 274.3837

P 35 Kp2 1.008975
Tf 764.3 1037.45

Trial T 819.5927 1092.743

CO 0.394095
CO2 0.415071

dHf Cp Tref Fi Atom C atom H O Ar

KomponenJ/mol yF mol/s mol/s mol/s mol/s mol/s
Argon 0 30.731 25 0.00209 0.4180 0 0 0 0.418
O2 0 43.437 25 0.04396 8.7920 0 0 17.584 0
N2 0 42.994 25 0.1636 32.7200 0 0 0 0
Ch4 -74600 52.745 25 0.05924 11.8480 11.848 47.392 0 0
H2O -241800 49.643 25 0.31504 63.0080 0 126.016 63.008 0
CO -110500 42.994 25 0.045158 9.0316 9.0316 0 9.0316 0
CO2 -395300 54.814 25 0.047379 9.4758 9.4758 0 18.9516 0
H2 0 43 25 0.323537 64.7074 0 129.4148 0 0
Jumlah 1.000004 200.0008 30.3554 302.8228 108.5752 0.418
N Fout yi Pi Kp1 Kp2 del Kp1 del Kp2 dHsF HF, 25C
mol/s mol/s
0 0.418 0.002056 0.071956 274.3837 1.008975 0 0 -9496.72 0
0 0 0 0 -282337.27 0
65.44 32.72 0.160929 5.632525 -1040020.39 0
0 5.792842 0.028491 0.997198 -462005.40 -883861
0 71.41301 0.351236 12.29326 -2312461.01 -1.5E+07
0 11.96292 0.058838 2.059335 -287073.60 -997992
0 12.59964 0.06197 2.168941 -383997.23 -3745784
0 68.41271 0.336479 11.77678 - 2,035,562 0
65.44 203.3191 1 35 -6.8130.E+06 -2.1E+07
HP, 25C dHsP dH

0 -10207
0 0
0 -1117804
-432146 -242783
-1.7E+07 -2816955
-1321903 -408686
-4980636 -548775
0 -2313083
-2.4E+07 -7458292 -17410625