Professional Documents
Culture Documents
Prepared By
Revision 0
Elizabeth J. Smith
January 5, 1983
Revision 1.0
Bryan Louque
August 21, 2000
Contents
082100 TC-1
Contents (Continued)
9.0 Summary..........................................................................................................9-1
Tables
082100 TC-2
1.0 Introduction
The Electric Power Research Institute (EPRI) has estimated the cost assigned to
corrosion in the electric power industry to be 0.24 percent of the gross national product
(GNP). This is equivalent to more than 17 billion dollars annually expressed in 1998
dollars. Of these costs, EPRI estimates that 15 percent, or 2.5 billion dollars, could have
been avoided by application of available technology such as equipment design, material
selection, protective coatings and linings, inhibitors and cathodic protection. Experience
has demonstrated that installation and maintenance of effective cathodic protection
systems can mitigate corrosion, increase remaining useful life and significantly reduce
these costs for all underground, on-grade and submerged metallic structures subject to
corrosion.
This discussion provides a brief introduction into the methods for control of
corrosion as recommended by Black & Veatch for installations at generating stations with
emphasis on corrosion control by cathodic protection. In-depth design recommendations
will not be provided, since there are numerous conditions which may cause corrosion and
the method of control appropriate for each situation must be considered on an individual
basis.
082100 1-1
2.0 How Corrosion Occurs
C
O R T
R E E
R S M
O I P
S S E
I T p R
O I H A
N V T
I U
R T R
A Y E
T
E
082100 2-1
Although seldom used in buried or submerged service, amphoteric materials such as lead
and aluminum may not react according to the relationships illustrated in the above figure.
Another common form of corrosion is stray current corrosion, frequently refered
to as man made corrosion. Stray current corrosion may occur at generating stations using
impressed current cathodic protection systems and on underground metallic structures
which are buried in areas where stray direct currents flow through the earth. Stray
current corrosion occurs when stray direct currents are picked up from the electrolyte by
a metallic structure which is so located that it is a preferential path for the stray current
but has no metallic connection to provide a path back to the source of the stray current.
The stray current will protect the metallic conducting structure to which it has strayed at
its pickup locations, but unless appropriate protective measures are taken, corrosion will
occur at the locations where it leaves that structure and reenters the electrolyte to return
to its source.
Stray current can also be generated by improper welding operations in a
generating station. Welding machines grounded to a structure allow the welding current
to return to the welding machine through the structure. Welding current discharge from
the structure, into an electrolyte will cause severe corrosion of the structure at the current
discharge point.
082100 2-2
3.0 Typical Corrosion Cells
The practical galvanic series indicates the relationship of the natural potential
(voltage) of several common metals installed in neutral soils and water. This table
indicates which material will experience metal loss (anode) and which will receive
protection (cathode) when any two dissimilar metals are coupled in such a manner that a
corrosion cell is formed. A practical galvanic series is shown below in Table 3-1.
082100 3-1
Table 3-1
Practical Galvanic Series
Metal Volts*
Commercially pure magnesium -1.75 Anodic (most active)
Zinc -1.1
Aluminum alloy (5 percent zinc) -1.05
Carbon steel -0.2 to -0.8
Cast iron -0.5
Stainless Steel
Carbon steel in concrete -0.2
Copper, brass, bronze -0.2
Mill scale on steel -0.2
Titanium +0.3 Cathodic (least active)
*Typical potential normally observed in neutral soils and water, measured with respect
to a copper sulfate reference electrode.
082100 3-2
The following figure illustrates the galvanic series of some commercial metals and alloys
in seawater:
Magnesium
Aluminum
Steel
Cast Iron
Chromium Stainless Steel 13% Cr (Active)
Ni-Resist (High Ni cast iron)
18-8 Stainless Steel (Active)
18-8 Mo Stainless Steel (Active)
Tin ACTIVE OR ANODIC
Copper PASSIVE OR CATHODIC
CuproNickels (60-90Cu-40-10Ni)
Monel (70Ni-30Cu)
Inconel (80Ni-18Cr-18Mo) (Passive)
Chromium Stainless Steel 11-30% Cr (Passive)
18-8 Stainless Steel (Passive)
18-8 Mo Stainless Steel (Passive)
Hastelloy C (62Ni-13Cr-7Fe)
Titanium
Platinum
082100 3-3
concrete. Therefore, the pipe surrounded with soil will corrode, with the most severe
corrosion occurring at the soil-concrete interface where the current flow between the
anode and the cathode will be greatest.
082100 3-4
4.0 Cathodic Protection--How It Works
082100 4-1
• Check electrical continuity to determine if the structure being protected
contains any deleterious electrical discontinuities.
082100 4-2
5.0 Designing the Cathodic Protection System
The stages of development for design of a cathodic protection system include the
following:
• Analysis of the requirements.
• Selection of the optimum system.
• Selection and arrangement of the specific components.
• Preparation of the drawings and specifications.
082100 5-1
5.2.2 Desirable Features
The following features, while not essential, are extremely desirable if they can be
achieved without compromising the performance of a cathodic protection system:
• Maintainability.
• Cost-effectiveness.
• Simplicity.
082100 5-2
Providing more current to a structure than is required for its protection is a
problem primarily associated with impressed current cathodic protection systems. The
effects of overprotection, as it is commonly called, include the following:
• Disbonding or failure of protective coatings and linings.
• Hydrogen embrittlement of pre-tensioned or alloyed steel. This
phenomena is most often observed in the catastrophic failure of pre-
stressed concrete cylinder pipe (PCCP) and duplex stainless steel
structural members.
• Hydriding of titanium components in condenser or heat exchanger tubes
and tubesheets.
• Excessive scaling in scale sensitive applications such as condenser water
boxes.
As discussed previously, stray currents can result in electrolytic corrosion of
underground metallic structures. Whether the stray current originates with an impressed
current cathodic protection system designed by Black & Veatch or from some source
with which we are not involved, the effects must be controlled. Control consists of
providing a path back to the source of the stray current such that the current does not
reenter the earth directly from the surface of the structure which is involuntarily receiving
the stray current. The stray current return path may be a metallic bond between the
structures or it may be one or more sacrificial anodes installed as part of the affected
structure for drainage of the stray current.
Black & Veatch encourages the Owners, for whom we design impressed current
cathodic protection systems, to cooperate with the Owners of foreign structures in the
vicinity so that damage to the foreign structures will not occur as a result of stray current
from the Black & Veatch designed systems.
082100 5-3
6.0 Preferred Methods of Corrosion Control
As stated in the Introduction, the design criteria which affect cathodic protection
are numerous, and frequently there are several effective solutions to each problem.
Identification of the best solution requires knowledge, experience, and good judgment.
The following sections describe the principal features of the corrosion control methods
usually recommended by Black & Veatch for several frequently encountered corrosion
problems.
082100 6-1
6.3 Underground Prestressed Concrete Cylinder Pipe (PCCP)
Bond wires should be installed across all joints and the pipe should be encased in
a polyethylene sleeve wherever the pipe is in an area where stray currents may be present.
082100 6-2
installed at each tank grounding pad. The sacrificial anode will provide neutralizing
current to the ground rod-to-tank bottom corrosion cell that will develop. The anode
attached to the copper ground rod will sacrifice itself to both the steel tank base plate and
the copper ground rod to prevent corrosion of the tank bottom.
On-grade tanks installed on concrete pads or asphalt bases shall not be
cathodically protected, as the concrete or asphalt material will effectively shield the steel
surface from the protective effect of the cathodic protection system. Tanks requiring
cathodic protection, such as fuel oil tanks, should not utilize asphalt, concrete, oiled sand
or oil impregnated materials in the foundation.
START
Impressed
Galvanic
Current
CP System
CP System
082100 6-3
Black & Veatch recommends the interior surfaces of the water box wall be cleaned and
coated with a good quality coating. Refer to Black & Veatch Technical Guide, Coating
System Data Sheets, for information on selection and application of condenser waterbox
coating systems.
Some tube/tubesheet materials are sensitive to hydrogen embrittlement or
hydriding in the presence of excessive levels of cathodic protection. These materials
have a history of acceptable performance under impressed current cathodic protection so
long as the cathodic protection system is properly designed, installed and operated.
Special care must be taken when certain combinations of tube and tubesheet materials are
involved (e.g., hydrogen embrittlement of duplex stainless steel materials or hydriding of
titanium tube/tubesheet material is reportedly possible).
082100 6-4
7.0 Maintenance of the Cathodic Protection Systems
Owners are often unfamiliar with the benefits of proper maintenance of cathodic
protection systems. An arrangement for direct communication between a knowledgeable
representative of the Owner and the Black & Veatch materials application section should
be made, on each project where cathodic protection will be provided, to discuss
maintenance procedures.
The Owner should be made aware of the capabilities and limitations of each
cathodic protection system and should be provided with basic information on how to
recognize problems as they occur.
082100 7-1
8.0 Basic Design Philosophy Recommendations
082100 8-1
8.3 Multiple Bond Wires at Pipe Joints
Should one or two bond wires be installed across each pipe joint for electrical
continuity?
If electrical continuity is to be achieved along a section of slip-fitted pipe, a wire
is exothermally welded across the joint. If the exothermal weld at either end is
improperly made, continuity will be interrupted resulting in loss of protection for a
portion of pipe. The possibility of a single inferior weld will increase with the length of
pipe and the subsequent number of welds. Black & Veatch recommends the installation
of two parallel bond wires across each such joint. If the Owner's decision is to use one
bond wire instead of two, the contractor must maintain strict quality control during the
exothermal welding process and backfilling of the pipe trench.
082100 8-2
8.5.2 Impressed Current Anode Application
• Design and install an impresseed current system using mixed metal oxide
or platinized titanium probe-type anodes and an automatic potential
control rectifier.
• Install permanent reference electrodes to measure the degree of protection
achieved.
• Adjust the rectifier so that the protective current will be sufficient to
control corrosion but not in excess to cause hydrogen embrittlement or
hydriding of tube/tubesheet.
• Monitor and adjust the system on a routine basis.
082100 8-3
9.0 Summary
082100 9-1
Appendix A
Process Map of
Design, Construction, and Testing Activities
082100 A-1
Appendix A
Process Map of
Design, Construction, and Testing Activities
082100 A-2
Appendix B
Typical Cathodic Protection Details
082100 B-1
Appendix B
Typical Cathodic Protection Details
082100 B-2