BO GrAODUCVA DAO TAO :

DAI HOC HUE

Hq ,-dtn thi sinh: SAnao danh;

KV THI TUYEN SINH SAU DATHQC NAM

2OO8

MOn thi: Co s6 Ij thuyt hoti hgc vd Ciiu no chht (ddnhcho Cao hoc) Thdi gian ldm bdi: 180 phft Cf,u I (1,5dim): Cho I mol H2 vi 1 mol 12viro m6t binh 30 lit dd hirt chAnkh6ne.dun n6Irsln 470"C. 1) Tinh 6p su6ttrong binh. 2) Tinh 6p sudtriOngcua 12vd HI trong h6n ho.pc6n bang. Biet o 4J0oC,phan vngH2(k) + I.(k) : zHI(k) c6 hangsd c A nb d n gK : 5 0 . Chu 2(1,0dim):

c Khi hoatan0,85gamZnClztrong 725gamH2Oth\ dungdich nhin ilucr.c6 nhitd0 tl6ngddcla -0,23'C. Chonguyn tl6ngcta nu6cld K6= 1,86. Tinhd6 di6nly a cia ZnCl2 trongdungdichtrdn.nl6t trings6nghiQm - 6) vdcuaL I = J5.5. tu kholcua ln Ciu 3(l .0 dim): -+ O nhitd6 913K, phin fng dehydro metylamin: ho6 H3C-NHr&) HCNft/ + ZHz&) gtdy-1 c6hing st5 d6 bing 5.1,0'3 ttic . 1) Tinh thdi giannriaphin img 1172. glim 99Vo voi bandiu. so 2) Tinhthoigianphdn huj,cin thi6td6ndngtl6 metylamin CArt40 .5 did: Chophin img: Fe2** AB* : Fe3*+ Ag. diQntlQng cua 1) O ndngdOnhu nhaucriaion Fez*vd Fe3*, ndngd6 ion Ag- phai bAngbao nhi6utlii srirc ? pin dinc6utaotri c6cdincuc Ag./Ag vd Fe3./Fe'?* kh6ng bang ^ -' . : ^ j) . , , drnn. : socan. : xac nang rmgren. Dargo z)-L cuapnan = v Chothi:khuti6uchuin Pf,n-,on 0,'19g , Ql,;.re;.:0,771Y . Cin 5(2,0diiinl: Chophin rmgd th6khi: K(k) + F(k) ------+K. (k) + F (k). k6t HiQu ungnhi6tcriaphanimg ld AH: 19kcal.mol-r, trongdiduki6nc6cion bi ngdn khong hgp tlo cin (EA) cnaF(k1. duocvdi nhau.Biiit l]dngluong ion hoi thri nhAtcnaK(k) lit EI = 4,3 eV. HZy tinh 6i lqc electron cho I ev = 1,602.10-'e r,= 6,022.1023 J, N . Ciu 6(1.5didd: Electroncu6i (electron ning lugng caonh6Lt) cdcnguyn A vi B d trAngthiii co bin tluqc dic cua tu c6 trungbdi cic s6 luo.ng sau: tri
A: n:3 {:l
lT)l: *l mr: -

n:2

!:1,

filt:

*1

ms: -

1 2 1 2

1) Hey du tlorlLn tri t6i tla c6 thii c6 cta c6c nguy6n t6 A vd B. hoe 2) Dirng thuydt MO, hly x5c dinh tu tinh cria phdntu Br. 3) A vir B t?o phentd ABr c6 ciu truc 1amgiricphing. ddu.Lin k6t A-B c6 phiLn cuc kh6ng?PhAn AB, co hr phin cuc kh6ng? T4i sao? Ciu 7(1,5 dint): Cho hai phuc [Co(NH3)6]3'vd [CoF6]r-c6 ndng luong t6ch A" lAn luot liL275 kJhnol vdL 155 kJ/mol. Ndng luo,,ng cin cho sg ghdp d6i electron li 251 kJ/mol. Hdy x6c tlinh ciu trric hinh hoc, c6u hinh electron ve flr tinh cira lrai phric ch6t tr6n. Chi rO phric spin cao, phric spin thdp. ptrIc lai hoi trong, phr?clai ho6 ngodi? Cho dientich h4t nhin (Z) cua c6c nguynt6: H(Z = l), N(Z = 1),F(Z= 9), Co(Z = 27).

Ghi chri: Cdn bo coi thi khonggiai thich gi thm.