St. Augustines School Iba, Zambales S.Y.

2009-2010

A Thesis Paper entitled Biogas as an effective substitute of fuel in Iba In Partial Fulfillment for the requirements in Social Studies IV

Presented by: Ma. Stephany Pulga Eva Marie Nicole Ecalnir Reena Jane Dacayo Rose Anne Castillo Anne Charmaine Cabal

Presented to: Mr. Johnny G. Galla

Abstract Biofuel is produced either directly from plants or indirectly from industrial, commercial, domestic, or agricultural wastes. In this thesis entitled, Biogas as an effective substitute of fuel in Iba, will cover its effectivity when its going to use in Iba, Zambales. Through surveys to the drivers, consumers, and sellers of the gas these will help to accept of using Biogas in Iba as a substitute in any fuel for vehicles.

TABLE OF CONTENTS

I. Chapter I: Introduction 1.1 Background of the Study 1.2 Statement of the Problem 5 1.3 Significance of the Study 1.4 Scope and Delimitation 1.5 Theoretical Framework 1.6 Conceptual Paradigm 1.7 Definition of Terms II. Chapter 2: Review of Related Literature 8 III. Chapter 3: Formulation of Hypothesis 18 IV. Chapter 4: Methodology 4.1 Procedure 19
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5 6 6 6 7

4.4 Sampling 4.3 Data Gathering 4.4 Presentation and Analysis of Data 19 V. Chapter 5: Presentation, Analysis and Interpretation of Data

19 19

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VI. Chapter 6: Summary of Findings, Conclusion, and Recommendation 6.1 Summary of Findings 22 6.2 Conclusion 6.3 Recommendation 6.4 Bibliography 22 22 23

Chapter I Introduction
1.1 Background of the Study

Biogas refers to a gas produced by the biological breakdown of organic matter in the absence of oxygen. Nowadays, many people prefer biogas especially for vehicles. It is one of the best discoveries for environmental advocacy and can be a great help to our economy.

1.2 Statement of the Problem

This thesis aims to answer the following questions: 1) Is biogas applicable to any kind of engine? 2) What types of vehicle is compatible with biogas? 3) How can biogas help the people in Iba?

1.3 Significance of the Study

This study aims to: a) To know if biogas is applicable in different types of vehicles here in Iba. b) To determine if biogas can help in the life of people here in Iba.

c) To provide the people the knowledge to become aware and to have an eco-friendly inventions.
1.4 Scope and Delimitation

This thesis focuses mainly on what type of vehicles and engines are compatible with biogas. The researchers will only prove that biogas is an effective substitute for fuel. The researchers conduct the study through questionnaire to distributed only in selected consumers like motorcycle drivers, family drivers, vendors, and students using motorcycles.
1.5 Theoretical Framework

Biogas as an effective substitute of fuel is the researchers chosen topic. This study aims to know what will be the impact for the people of Iba if biogas can be implemented here, if it is applicable for any type of vehicle here and how they manage it. So they come up with this thesis. Through this they will be able to know the impact of biogas as a substitute of fuel here in Iba. This study will widen our knowledge in the status of our economy especially in Iba. This thesis will serve as an inspiration to discover new things for the Filipino people especially, the drivers who will benefit from it.
1.6 Conceptual Paradigm 6

The following are the procedures to be done by the researchers in order for the researchers to accomplish the objectives of the study.
Observe the consumers and sellers who are using vehicle fuels like diesel, unleaded, etc. 1.7 Definition of Terms
The researchers will now analyze their research using questionnaires to be given to the selected people.

The researchers will now analyze and interpret the gathered data.

1) Absorption the uptake of liquid into the fibers of a substance 2) Adsorption the adhesion of a thin layer of molecules of some

substances to the surface of a solid or liquid

3) Biofuel - any solid, liquid, or gaseous fuel produced from organic

(once-living) matter.
4) Biogas a type of biofuel made up of organic materials. 5) Butane a colorless, highly flammable gas that has two different

molecular structure isomers

6) Efficient well organized 7) Esters an organic, often fragrant compound formed in a reaction

between an acid and alcohol with the elimination of water

8) Ethane colorless, odorless gas that is highly flammable

9) Fermentation chemical changes in organic substances produced

by the action of enzymes

10)

Isomers each of two or more molecules have the same

number of atoms but have different chemical structures and therefore different properties
11)

Natural Gas - a flammable gaseous mixture consisting mostly

of hydrocarbons
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Propane a flammable colorless hydrocarbon gas

Chapter II Review of Related Literature 2.1 Natural Gas Natural Gas is a flammable gaseous mixture consisting mostly of hydrocarbons (chemical compounds that contain carbon and hydrogen). Along with coal and petroleum, natural gas is a fossil fuel. Natural gas may contain as much as 85 percent methane (CH4) and about 10 percent ethane (C2H6), and also contains smaller amounts of propane (C3H8), butane (C4H10), pentane (C5H12), and other alkanes. Natural gas, which is usually found together with petroleum deposits in Earths crust, is extracted and refined into fuels that provide approximately 25 percent of the world energy supply. It is used both as a fuel and as a raw material in the manufacture of chemicals. As a residential fuel, it is burned in furnaces, water heaters, cooking stoves, and clothes dryers. As an industrial fuel, it is burned in kilns (special furnaces) used to bake bricks and ceramic tiles and to produce cement. Natural gas is also used for generating steam in water boilers and as a source of heat in glass making and food processing. Natural gas serves as a raw material for creating petrochemicals, which are chemicals that are specifically derived from natural gas or petroleum. In turn, petrochemicals are used as a base product for making fertilizers, detergents, pharmaceuticals, plastics, and numerous other goods.
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Once natural gas has been extracted from the ground, it is usually transported by pipeline to a refinery, where it is processed. Natural gas is processed in an extraction unit to remove the nonhydrocarbon compounds, especially hydrogen sulfide and carbon dioxide. Two processes used for this purpose are absorption and adsorption. Absorption uses a liquid that absorbs the natural gas and impurities and disperses them throughout its volume. In a process known as chemisorption, the impurities react with the absorbing liquid. The natural gas can then be stripped from the absorbent, while the impurities remain in the liquid. Common absorbing liquids are water, aqueous amine solutions, and sodium carbonate. Adsorption is a process that concentrates the natural gas on the surface of a solid or a liquid in order to remove impurities. A substance commonly used for this purpose is carbon, which has a large surface area per unit mass. For example, sulfur compounds in natural gas collect on a carbon adsorbing surface. The sulfur compounds are then combined with hydrogen and oxygen to form sulfuric acid (H2SO4), which can be removed. After the impurities have been removed in the extraction unit, the natural gas is transported to a processing plant, where compounds such as ethane, propane, butane, and other substances are separated and removed for different uses. For example, ethane, propane, and butane are used extensively in the petrochemical industry.
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2.2 Biofuel Any solid, liquid, or gaseous fuel produced from organic (once-living) matter. Biofuel is produced either directly from plants or indirectly from industrial, commercial, domestic, or agricultural wastes. There are three main methods for the development of biofuels: the burning of dry organic wastes (such as household refuse, industrial and agricultural wastes, straw, wood, and peat); the fermentation of wet wastes (such as animal dung) in the absence of oxygen to produce biogas (containing up to 60 percent methane), or the fermentation of sugarcane or corn to produce alcohol and esters; and energy forestry (producing fast-growing wood for fuel). Fermentation produces two main types of biofuels: alcohols and esters. These could theoretically be used in place of fossil fuels but, because major alterations to engines would be required, biofuels are usually mixed with fossil fuels. The European Union will require 5.75 percent ethanol, derived from wheat, beet, potatoes, or corn, to be added to fossil fuels by 2010 and 20 percent by 2020. About a quarter of Brazil's transportation fuel in 2002 was ethanol.

TABLE I

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Table I shows the chemical properties of biogas and other kinds of biofuel. TABLE II

Table II shows the physical properties of biogas that differ it from natural gas. 2.3 Local Study Economics of using Biogas A. COST COMPONENTS OF BIOGAS SYSTEM
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Biogas technology is a complete system in itself with its set objectives (cost effective production of energy and soil nutrients), factors such as microbes, plant design, construction materials, climate, chemical and microbial characteristics of inputs, and the inter-relationships among these factors. Brief discussions on each of these factors or subsystems are presented in this section. Economic. An ideal plant should be as low-cost as possible (in terms of the production cost per unit volume of biogas) both to the user as well as to the society. At present, with subsidy, the cost of a plant to the society is higher than to an individual user. Simple design. The design should be simple not only for construction but also for operation and maintenance. This is an important consideration especially in areas where the rate of literacy is low and the availability of skilled human resource is scarce. Utilization of local materials. Use of easily available local materials should be emphasized in the construction of a biogas plant. This is an important consideration, particularly in areas where transportation system is not yet adequately developed. Durability. Construction of a biogas plant requires certain degree of specialized skill which may not be easily available. A plant of short life could also be cost effective but such a plant may not be reconstructed once its useful life ends. Especially in situation where people are yet to be motivated
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for the adoption of this technology and the necessary skill and materials are not readily available, it is necessary to construct plants that are more durable although this may require a higher initial investment. Suitable for the type of inputs. The design should be compatible with the type of inputs that would be used. If plant materials such as rice straw, maize straw or similar agricultural wastes are to be used, then the batch feeding design or discontinuous system should reused -instead of a design for continuous or semi-continuous feeding. Frequency of Using Inputs and Outputs. . Selection of a particular design and size of its various components also depend on how frequently the user can feed the system and utilize the gas. Inputs and their Characteristics Any biodegradable organic material can be used as inputs for processing inside the biodigester. However, for economic and technical reasons, some materials are more preferred as inputs than others. If the inputs are costly or have to be purchased, then the economic benefits of outputs such as gas and slurry will become low. Also, if easily available biodegradable wastes are used as inputs, then the benefits could be of two folds: (a) economic value of biogas and its slurry; and (b) environmental cost avoided in dealing with the biodegradable waste in some other ways such as disposal in landfill.

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B. BENEFITS FROM BIOGAS SYSTEM There are two (2) kinds of benefits that can be derived from using the biogas system. First are the tangible benefits in which we can put money value on it. These include the savings in energy, feed materials and fertilizer. These benefits are in the form of savings because the amount that was allocated for the purpose was not spent because of available biogas. The other type of benefits are the intangible benefits which we cannot put money value on it. These include the promotion of the conservation of natural resources by not cutting trees for firewood, and controlling pollution by proper waste disposal. These benefits are more rewarding because you have given man the right to live in a fresh, clean and beautiful environment.

Energy Value of Biogas FOR SMALL SCALE: 10 CU.M. BIOGAS PLANT a) Fresh manure production : 54.75 cu.m./ year b) Volume of slurry @ 1:1 ratio : 109.5 cu.m./year c) Biogas production : 3.6 cu.m./day d) Equivalent in conventional energy:
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Firewood : Peso equivalent : LPG : Peso equivalent :

4,559.58 kg/ year Php 13,678.74 657 kg/year Php 29,860.65

The value of recovered sludge as feed materials and organic fertilizer follows the same format of substitution and extent of use. As much as 5% of the feed requirement can be substituted by sludge and that sufficient organic fertilizer (40%) can be recovered from the digested sludge. e) Feed material recoverable from sludge Total feed consumption of hog : 25,000 kgs./year

Amount of feed materials which can be substituted with sludge: 15% Savings in feed materials : Peso equivalent : 37,500.00 f) Organic fertilizer from sludge 1) Volume of digested sludge : 109.5 cu.m./year 2) Organic fertilizer recovered (20%): 21,900 kgs./year 3,750 kgs. Php

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Peso equivalent (less 35% processing cost) : Php 42,705.00 3) Equivalent in commercial fertilizer: 14-14-14 : 2 bags Urea (60-0-0) : 5 bags Muriate of Potash: 3.33 bags g) Cost of the system : 1) Labor (case to case basis) : 2) Repair and maintenance (3% IC) : 3) Interest on investment (21% IC) : 4) Depreciation : 5) Total Operating Cost : Php 55,000.00 Php 15,600.00 Php 1,650.00 Php 11,550.00 Php 2,200.00 Php 31,000.00

h) Total savings : savings in feeds + fertilizer + energy : Php 93,883.74 i) Net savings: total savings total operating cost : Php 62,883.74

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j) Return of Investment : Net Savings / IC : 114.33 % k) Payback Period : 0.87 year C. Cost and Return Analysis 1) Initial Investment. This refers to the capital used in the construction and installation of biogas. 2) Operating Expenses. These refer to the amount used in operating the biogas system which includes labor, repair and maintenance, interest on investment and depreciation.

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Chapter III Formulation of Hypothesis Null hypothesis: This study will not be effective if there will be no cooperation coming from the respondents.

Alternative hypothesis: This study will be effective through the cooperation of the people.

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Chapter IV Methodology 4.1 Procedure a) Distributed the survey sheets to drivers, students and other

consumers. b) c) Tally the results and put it into a pie chart. Compare the physical and chemical properties of biogas and

natural gas. 4.2 Sampling There were 24 randomly selected respondents who live in Iba, Zambales. They will be the one who will take the survey and insights of using Biogas. 4.3 Data Gathering The researchers will now gather questions with the limit of using biogas as an effective substitute on other vehicle fuels and will distribute to the selected respondents. Once theyre done on answering the survey, the researchers will analyze the data and graph it. 4.4 Presentation and Analysis of Data

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The gathered data were graphed depending on the answers of the respondents using a pie graph. And the people who agreed on using biogas were also graphed. Chapter V Presentation, Analysis and Interpretation of Data Questions:

1. Do you think that biogas can be an effective substitute for fuel?

25 20 15 10 5 0 yes no 1 0 m aybe answ er 23

2. Do you think it(biogas) will be a help in our economy?

30 25 20 15 10 5 0 yes 0 no 0 m aybe answer 24

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3. Would you prefer biogas rather than commercial gas?

20 15 10 6 5 0 yes no 0 ma ybe ans wer 18

4. Do you agree if biogas will be used here in Iba?

18 16 14 12 10 8 6 4 2 0 17

a wer ns 5 2

y es

no

m ybe a

5. If biogas will be used here, would you change your engine compatible with it?
20 15 10 5 0 yes n o m e ayb 4 1 an swer 19

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Chapter VI: Summary of Findings, Conclusion and Recommendation 6.1 Summary of Findings Based from the survey done by the researchers, most of the respondents agreed that biogas can be a good substitute for fuel. 6.2 Conclusion The researchers therefore conclude that biogas can be an effective substitute for natural gas. It is simply because its sources come from wastes. But it can also cost a lot of money because it needs an engine of its own. Biogas can be a help to our economy if it will be used properly and it can also help to lessen the pollution because of its components that consist of wastes. 6.3 Recommendation The researchers recommend the following: Try to do an interview to those people who already made biogas Try to do a research if the engine compatible to biogas can also be made from recycled materials If you can, try to make biogas and compare it to natural gas by testing if it would work

6.4 Bibliography
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http://www.biogas-renewable-energy.info/biogas_composition.html http://en.wikipedia.org/wiki/Biogas Encarta Encyclopedia

http://www.pcierd.dost.gov.ph/index.php http://www.biogas.co.uk/

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