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Reaction Kinetics First Order Reaction Question 1.

(a ) (b ) Explain what is meant by activation energy of a reaction The inversion reaction of sucrose C12H22O11 + H2O C6H12O6 + C6H12O6 Follows first-order rate equation with the rate constant of 3.55 10-3 min-1. Calculate the time required for 50% of 1 kg of sucrose to react. The following data was obtained from a gaseous reaction A + B C at temperature of 30oC. Experiment 1 2 3 Initial Concentration/mol dm-3 A B 1.0 2.0 1.0 1.0 2.0 2.0 Initial rate of reaction/mol dm-3min-1 0.15 1.20 0.60

(c )

What is the rate equation of the reaction? Question 2 (a) Explain the meaning of the following terms, as used in relation to rate of reaction i) Rate ii) Rate constant iii) Order (b) The following results were obtained in an investigation on the composition of dinitrogen pentoxide at 45oC. N2O5(g) 2NO2(g) + O2(g) Time/min Concentrati on [N2O5] 10-4 (mol dm-3) 0 176 10 124 20 93 30 71 40 53 50 39 60 29

Determine, graphically or otherwise, i) Rate of reaction at time t=15, 35, 50 minutes ii) Order of reaction iii) Rate constant of reaction

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