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1. # of electrons needed : 2 + 2 + 8 + 8 = 20 e 2. # of electrons we have: 2 + 6 + 4 = 12 e 3. (20-12) 2 = 4, Therefore 4 bonds make sure all atoms get an octet. 4. Draw a symmetrical molecule and add the bonds Rearrange extra e- around the periphery (surrounding) atoms.
Non-Octet Compounds Some compounds will contain central atoms that do not follow the octet rule. The four possibilities for non-octet compounds are: 1. Where more than 4 atoms are bonded to the central atom such as PCl5. 2. A noble gas is participating in bonding such as XeF4. 3. Where the central atom has less than 8 valence electrons such as BH3. 4. Where molecules contain an odd number of nonbonding electrons such as NO.
Ionic Compounds
Use arrows to represent the transfer of electrons. The final structure will contain ions.
VSEPR Geometries
Electron pairs Geometry 2 , AX2
Linear , 1800 3, AX3 Trigonal planar, 1200 4, AX4 Tetrahedral, 109.50 5, AX5 trigonal bipyramidal, 1200 and 900 6, AX6 Octahedral, 900