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    Leidy Honorio Urbina
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    This document contains calculations to determine the diffusion coefficient (DAB) of acetone at different temperatures using vapor pressure data and the Wilke-Lee method. It provides vapor pressure values for acetone at 25°C, 35°C, and 45°C and uses these to calculate partial vapor pressures and other parameters needed to determine DAB values. Solving the relevant equations gives DAB values of 0.036 m2/s at 25°C, 0.0415 m2/s at 35°C, and 0.0684 m2/s at 45°C.

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    This document contains calculations to determine the diffusion coefficient (DAB) of acetone at different temperatures using vapor pressure data and the Wilke-Lee method. It provides vapor pressure values for acetone at 25°C, 35°C, and 45°C and uses these to calculate partial vapor pressures and other parameters needed to determine DAB values. Solving the relevant equations gives DAB values of 0.036 m2/s at 25°C, 0.0415 m2/s at 35°C, and 0.0684 m2/s at 45°C.

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    5 views2 pages

    CÁLCULOS

    Uploaded by

    Leidy Honorio Urbina
    This document contains calculations to determine the diffusion coefficient (DAB) of acetone at different temperatures using vapor pressure data and the Wilke-Lee method. It provides vapor pressure values for acetone at 25°C, 35°C, and 45°C and uses these to calculate partial vapor pressures and other parameters needed to determine DAB values. Solving the relevant equations gives DAB values of 0.036 m2/s at 25°C, 0.0415 m2/s at 35°C, and 0.0684 m2/s at 45°C.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOCX, PDF, TXT or read online from Scribd
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    of 2

    CLCULOS:

    Para la acetona:
    3
    AL = 2.0 g /cm
    T = 25C, 35C, 45C
    Pv1 (25C) = 231.06 mmHg = 0.3040atm.
    Pv2 (35C) =344.804mmHg =0.454atm.
    Pv3 (45C) =50.614mmHg =0.666atm.
    PM= 58.08g/mol
    DATOS:
    PBG=1atm.
    PT=1atm
    R= 82.05 Latm/kmolk
    b1= 140.77 (25C)
    b2 = 143.92 (35C)
    b3= 119.96 (45C)
    Si:
    PBS=PT-PV=PAS
    PBMl = PBG - PBS / Ln (PBG/PBS)
    PV1=0.3040atm
    PBS1=1atm-0.3040atm
    PBS1=0.696atm
    P BMl1 = 0.838atm
    PV2=0.454atm
    PBS2=0.546atm
    P BMl2 = 0.75atm
    PV3=0.666atm
    PBS3=0.334atm
    P BMl3 = 0.61atm

    REEMPLAZANDO EN b:
    a

    RTp BMl Al Zo
    DAB PM A ( p AS 0)

    RTp BMl Al
    2D AB PM A ( p AS 0)

    TENEMOS:
    25C:
    140.77=82.05*298*0.838*2/2DAB*58.08* (0.696-0)
    DAB1 = 3.6cm2/s = 0.036m2/s
    35C:
    143.92 = 82.05*308*0.75*2/2DAB*58.08* (0.546-0)
    DAB2 = 4.15cm2/s =0.0415m2/s
    45C:
    119.96 = 82.05*318*0.61*2/2DAB*58.08* (0.334-0)
    DAB3 = 6.84cm2/s = 0.0684 m2/s
    Mtodo de Wilke Lee:
    IBLIOGRAFIA:
    http://www.quimica.unam.mx/IMG/pdf/4acetona.pdf-pag.1

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