Energy balance

Asad Raza 2015-CH-724

For Cp Calculation:
Propylene: Propane: Isobutene:
C1=114140 C1=62.983 C1=182050
C2=-343.72 C2=113630 C2=-1611
C3=1.0905 C3=633.21 C3=11.963
C4=0 C4=-873.4 C4=-0.037454
C5=0 C5=0 C5=0.00004502

Isopropyl Ether: Isopropyl Acetate: Water:

C1=251890 C1=76330 C1=276370
C2=-468.32 C2=400.1 C2=-2090.1
C3=1.2209 C3=0 C3=8.125
C4=0 C4=0 C4=-0.014116
C5=0 C5=0 C5=0.00000937
Acetic Acid:
C1=139640
C2=-320.8
C3=0.8985
C4=0
C5=0
Formula

For Heat capacity (J/kmole)

For latent Heat (J/kmole)

 Assumption:
C-101 Pressure drop=0.2 atm

Bubble Temperature=61.5 °C

Gas Liquid
T=295 °C T=60 °C
P=25.2 atm P=25 atm
m=2350.0657 (kg/hr) m=2350.0657 (kg/hr)

Heat duty=(-388.7241 kw)

 Assumption:
H-101 Pressure drop=0.2 atm
Bubble Temperature=272 °C

Liquid Liquid
T=57 °C T=78.18 °C
P=25.2 atm P=25 atm
m=3583.6939 (kg/hr) m=3583.6939 (kg/hr)

Heat duty=(47.3839) kw
 Assumption:
M-101 No Pressure drop
Bubble Temperature=61.5 °C
Liquid
T=60 °C
P=25 atm
m=2350.0657 (kg/hr)

Bubble Temperature=272 °C Bubble Temperature=104

Liquid Liquid
T=78.18 °C T=70 °C
P=25 atm P=25 atm
m=3583.694 (kg/hr) m=5933.882 (kg/hr)
 Assumption:
R-101 Pressure drop=0.5 atm
ΔHr1=(-291.8579103 kw)
ΔHr2=(-.057356272 kw)

Bubble Temperature=104 Bubble Temperature=170

Liquid Liquid
T=70 °C T=70 °C
P=25 atm P=24.5 atm
m=5933.8 (kg/hr) m=5933.8 (kg/hr)
Qin=(179.1310077 kw) Qout=(158.451 kw)

Heat to be removed=(Qin+ΔHr) –Qout=(-312.596 kw)

 Assumption:
C-102 Pressure drop=0.5 atm

Bubble Temperature=170 °C

Liquid Liquid
T=70 °C T=60 °C
P=24.5 atm P=24 atm
m=5933.8 (kg/hr) m=5933.8 (kg/hr)

Heat duty=(-35.71031947) kw
 Assumption:
C-103 No Pressure drop

Bubble Temperature=86 °C

Vapours Liquid
T=89.5 °C T=89.3 °C
P=1 atm P=1 atm
m=9997.8909 (kg/hr) m=9997.8909 (kg/hr)

Heat duty=(-959.52 kw)

H-103

Heat duty of reboiler =Qb = Qc+Hd+Hw-Hf

Heat of feed =Hf =103.5027 (kW)

Heat of bottom product =Hw =62.89 (kW)
Heat of top product =Hd =152.9869 (kW)
Heat duty of condensor =Qc =959.52 (kW)
Heat duty of reboiler =Qb = 1071.895 (Kw)