Methane= 0.

93 mol
N2= 0.07 mol
Excess air= 30%
T1= 25 C
P= 1 atm

Basis
1 mol of fuel gas

Feed
0.93 mol Methane butuh 2 mol Oksigenuntuk 1 mol metahne
0.07
0.35 Excess air

Menghitung O2 yang dibutuhkan

2.511 mol O2

Menghitung N2 yang dibutuhkan

9.446143 mol N2

Mol of Co2 formed= 0.651 moles

mol pf CO formed= 0.279 moles

so, total aount of heat releases during th ereaction is as follows :

∆H= ∆H Co2 + ∆HCO
-667.461 Kj/mo;

moles of water formed= 1.86 mol

moles of O2 consumed= 1.7205 mol
Water Heater T= 200 C

CO2= 70%
CO= 30%

34 kg/s
Jawab :
a. Step 1 - Step 2 (isotermhal) d. Step 4-step 5(Adiabatic)
p2= 0.552 Mpa Q= 0
p1= 2.758 Mpa ∆S= 0
T1= 700 k
T2= 700 k
∆H= 0
∆U= 0

Q=-W=-RT ln (p2/p1)
9362.388 kj/kmol

∆S=nR-Ln(p2/p1)
-14.1792

b. Step 2-step 3 (Isokoris)

T3= 473.5 K

Cp 29.3 kj/Kmol.K
Cv 20.986 kj/Kmol.K
∆H= -6636.45 Kj/kmol
∆U= -4753.329 Kj/kmol

Q=∆U -4753.329 Kj/kmol

W 0
∆U

c. Step 3-step 4 (isobaris)

T4= 350 k
∆U= -2591.771 Kj/kmol
∆H= -3618.55 Kj/kmol

Q=∆H= -3618.55
W=-R(T4-T3) 1026.779
ep 5(Adiabatic)
One kmol of carbon monoxide considered to be an ideal gas with a heat capacity of 29.3
kJ/kmol-K (Isobaric) is subjected to a following process:
The carbon monoxide is heated from 700 K (state 1 )and 2.758 Mpa, it is expanded isothermally to
0.552 Mpa. It is (state 2) is cooled constant volume to 473.5 K (state 3) is cooled constant pressure to 350 k(state 4
is compressed adiabatically to 2,758 Mpa (state 5) and heated at constant pressure to 700 K.
Compute the heat transfer, the work done, the change in the internal energy and the change
in the enthalpy and entrophy for each step

Diketahui
Cp: 29.3 kJ/kmol-K R: 8.314
T1: 700 k Cv: 20.986
P1: 2.758 Mpa
P2: 0.552 Mpa
T3: 473.5 K
T4: 350 K
P5: 2.758 Mpa

a. Step 1 - Step 2 (isothermal) b. Step 2- step 3 (Isokoris)

T2:T1 700 K (isothermal) ∆H: -6636.45 kJ
∆U: -4753.33 kJ
∆H: 0 kJ Q=∆U: -4753.33 kJ
∆U: 0 kJ W: 0 kJ
Q: 9362.388 kJ ∆S: -8.20402 kJ/k
W: -9362.39 kJ P3: 0.373389 Mpa
∆S: 13.37484 kJ/k

d. Step 4-step 5 (adiabatic) e. Step 5-step 1 (isobaris)

karena adaibatic maka Q=0 ∆U: 1735.739 kJ
y: 1.396169 Q=∆H: 2423.385 kJ
T5: 617.2906 K W: -687.646 kJ
W: 5609.361 kJ ∆S: 129.3693 kJ/k
∆H: 7831.615 kJ
∆U: 5609.361 kJ
jika Q =0 maka entrophy
∆S: 0 kJ/k
rmally to
nt pressure to 350 k(state 4)
K.
e

c. Step 3-step 4 (isobaris)

∆H: -3618.55 kJ
∆U: -2591.771 kJ
Q=∆H: -3618.55 kJ
W: 1026.779 kJ
∆S: -8.8550096136 kJ/k
P3:P4= 0.37338857143 Mpa (tekanan konstan)

∆H (kJ) ∆U (kJ) W (kJ) Q (kJ)

Step1-step2 0 0 -9362.387988 9362.387988
Step2-step3 -6636.45 -4753.329 0 -4753.329
Step3-step4 -3618.55 -2591.771 1026.779 -3618.55
Step4-step5 7831.61531675 5609.3610593 5609.3610593 0
Step5-step1 2423.38468325 1735.7389407 -687.6457425 2423.384683
∆S(kJ)
13.374839982
-8.2040238728
-8.8550096136
0
129.36925559