1.

Average Rate 1
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) [AX2] mol/L 0 2.0 6.0 8.0 10.0 20.0 0.0500 0.0448 0.0300 0.0249 0.0209 0.0088

What is the average rate from 8.0 to 20.0 seconds in mol / L s? Use 3 sig figs. [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3 Student Response Value Correct Answer Equals 0.00134 (100%) Equals 0.0013 (100%) Equals 1.3E-3 (100%) Equals 1.34E-3 (100%) Equals .00134 (100%) Equals .0013 (100%) Equals .001341 (100%)

1. not answered

0%

Score:

0/1

2. Relative Rates of Substances 2

Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [D] is decreasing at 0.25 mol/Ls, how quickly is [F] decreasing? Student Response Value 0% 0.125 Answer: not answered Score: 0/1 Correct Answer

3. Rate Law General 3

What is the reaction order of Br- for a reaction with the following rate law? Rate = k[BrO3-][Br-][H+]2 Student Response Value Correct Answer

1. Fifth 2. Fourth 3. Third 4. First 5. Second Score: 0/1

4. Known Rate Law, Change Conc 49

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is doubled, that of Br- is decreased by a factor of 2 and that of H+ is decreased by a factor of 2? Student Response 1. not answered Score: 0/1 Value 0% Correct Answer Equals 0.25 (100%) Equals 1/4 (100%) Equals .25 (100%)

5. Known Rate Law, Change Conc 31

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is tripled and that of Bris is decreased by a factor of 2? Just put in the number as a whole number or fraction. Student Response 1. not answered Score: 0/1 Value 0% Correct Answer Equals 1.5 (100%) Equals 3/2 (100%)

6. Determine Rate Law 30

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.---- order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc of Initial conc of Initial conc of Initial rate, A, mol/L B, mol/L C, mol/L mol/L.s 1 2 3 0.1 0.2 0.3 0.1 0.3 0.1 0.2 0.2 0.2 2 x 10-3 4 x 10-3 6 x 10-3

0.4 Student Response not answered not answered not answered not answered 0/1

0.3 Value 0% 0% 0% 0%

0.4

1.6 x 10-2

1. 2. 3. 4.

Correct Answer Equals first (25%) Equals zero (25%) Equals first (25%) Equals second (25%)

Score:

7. Determine Rate Law 9

Consider the reaction of A(g) + B(g) + C(g) => D(g) for which the following data were obtained: Experiment Initial [A], Initial [B], Initial [C], Initial rate, mol/L mol/L mol/L mol/L.s 1 2 3 4 0.0500 0.100 0.100 0.0500 0.0500 0.0500 0.100 0.0500 0.0100 0.0100 0.0100 0.0200 6.25 x 10-3 2.50 x 10-2 5.00 x 10-2 1.25 x 10-2

What is the rate law for the reaction? Student Response 1. rate = k[A] [B] [C] 2. rate = k[A][B] 3. rate = k[A][B][C] 4. rate = k[A]2[B][C] 5. rate = k[A]2[B]2 Score: 0/1
2 2

Value Correct Answer

8. Calculate k from Rate Law 3

For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at constant temperature. Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min 1 2 3 4 0.200 0.400 0.200 0.400 0.150 0.150 0.300 0.300 5.00 10.0 20.0 40.0

Determine the value of k for the reaction. Give answer to 3 significant figures. Student Response 1. not answered Value 0% Correct Answer Equals 1110 (100%) Equals 1111 (100%) Equals 1100 (100%) Equals 1.11E3 (100%)

Score:

0/1

9. Units of k 3
Which of the following would be a reasonable unit for the rate constant of a third order reaction? Student Response 1. L /mol .sec 2. mol2/sec.L2 3. mol3/sec.L3 4. L/mol.sec 5. L2/mol2.sec Score: 0/1
3 3

Value Correct Answer

10. IRL 1 t 8
A reaction has a rate constant of 0.00660 sec-1, how long will it take (in minutes) until 0.491 mol/L of the compound is left, if there was 0.859 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 0% 1.412 Answer: not answered Score: 0/1 Correct Answer

11. IRL 1 kt % 4
In a first order decomposition, the constant is 0.00475 sec-1. What percentage of the compound has decomposed after 2.23 minutes? Student Response Value 0% 47.0 Answer: not answered Score: 0/1 Correct Answer

12. IRL 1 kt % 2
In a first order decomposition, the constant is 0.00509 sec-1. What percentage of the compound has decomposed after 70.9 seconds? Student Response Value 0% 30 Answer: not answered Score: 0/1 Correct Answer

1. Average Rate 4
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) [AX2] mol/L 0 2.0 6.0 8.0 10.0 20.0 0.0500 0.0448 0.0300 0.0249 0.0209 0.0088

What is the average rate from 2.0 to 6.0 seconds in mol / L s? Use 3 significant figures. [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3 Student Response 1. 1.34E-3 Value 0% Correct Answer Equals 0.0037 (0%) Equals 3.7E-3 (100%) Contains .0037 (100%) Equals 3.70E-3 (100%)

Score:

0/1

2.

Relative Rates of Substances 11

Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [F] is decreasing at 0.28 mol/Ls, how quickly is [G] increasing? Student Response Value 0% 0.560 Answer: 0.14 Score: 0/1 Correct Answer

3. Rate Law General 2

What is the reaction order of BrO3- for a reaction with the following rate law? Rate = k[BrO3-][Br-][H+]2 Student Response 1. Fifth 2. First 3. Fourth 4. Second 5. Third Score: 1/1 Value Correct Answer 100%

4. Known Rate Law, Change Conc 21

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of H+ is tripled? Just put in the number as a whole number or fraction. Student Response 1. 9 Value Correct Answer 100% Equals 9 (100%)

Equals 9/1 (100%) Score: 1/1

5. Known Rate Law, Change Conc 44

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is doubled, that of Br- is doubled and that of H+ is decreased by a factor of 2? Student Response 1. 1 Score: 1/1 Value 100% Correct Answer Equals 1 (100%) Equals 1/1 (100%)

6. Determine Rate Law 22

For the reaction, 2 A(g) + 2 B(g) => C(g) + 3 D(g), the following data were obtained at constant temperature. Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min 1 2 3 4 0.11 0.11 0.22 0.22 0.15 0.30 0.45 0.60 2.0 x 10-5 2.0 x 10-5 4.0 x 10-5 4.0 x 10-5

Which of the following is the correct rate law for the reaction? Student Response 1. Rate = k[A][B] 2. Rate = k[A]2[B]2 3. Rate = k[A][B] 4. Rate = k[A]2[B]
2

Value Correct Answer

0%

5. Rate = k[A] Score: 0/1

7. Determine Rate Law 36

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.----order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate, mol/L mol/L mol/L mol/L.s 1 2 3 4 0.1 0.2 0.3 0.4 Student Response 1. 2. 3. 4. 0 1 1 2 0/1 0.2 0.2 0.4 0.6 Value 0% 0% 0% 0% 0.4 0.4 0.4 0.2 2 x 10-3 4 x 10-3 2.4 x 10-2 3.6 x 10-2

Correct Answer Equals first (25%) Equals second (25%) Equals first (25%) Equals fourth (25%)

Score:

8. Calculate k from Rate Law 1

For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at constant temperature. Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min 1 2 3 0.200 0.400 0.200 0.150 0.150 0.300 5.00 20.0 10.0

0.400

0.300

40.0

Calculate the value of k to 3 significant figures. Student Response 1. not answered Score: 0/1 Value 0% Correct Answer Equals 833 (100%) Equals 8.33E2 (100%)

9. Units of k 1
Which of the following would be a reasonable unit for the rate constant of a first order reaction? Student Response 1. mol/L.sec 2. mol2/sec.L2 3. 1/sec 4. L/mol.sec 5. L2/mol2.sec Score: 0/1 Value Correct Answer 0%

10. IRL 1 c 5
A reaction has a rate constant of 0.00822 sec-1, how much of the compound (in mol/L) is left after 54.6 sec, if there was 0.868 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 0% 0.554 Answer: -3.17 Score: 0/1 Correct Answer

11. IRL 1 c 3
A reaction has a rate constant of 0.0324 sec-1, how much of the compound (in mol/L) is left after 0.607 min, if there was 0.595 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 0% 0.183 Answer: -2.24 Score: 0/1 Correct Answer

12. IRL 1 k 2
When 0.866 mol/L of a compound X decomposes via a first order reaction, there are 0.333 mol/L left after 9.74 seconds. Calculate the rate constant, k, in sec-1. Student Response Value 0% 0.098 Answer: 0.0103 Score: 0/1 Correct Answer

1. Average Rate 1
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) [AX2] mol/L 0 2.0 6.0 8.0 0.0500 0.0448 0.0300 0.0249

10.0 20.0

0.0209 0.0088

What is the average rate from 8.0 to 20.0 seconds in mol / L s? Use 3 sig figs. [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3 Student Response Value Correct Answer Equals 0.00134 (100%) Equals 0.0013 (100%) Equals 1.3E-3 (100%) Equals 1.34E-3 (100%) Equals .00134 (100%) Equals .0013 (100%) Equals .001341 (100%)

1. 0.00134

100%

Score:

1/1

2. Relative Rates of Substances 14

Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [G] is increasing at 0.87 mol/Ls, how quickly is [E] decreasing? Student Response Value 0% 1.305 Answer: -0.29 Score: 0/1 Correct Answer

3. Rate Law General 5

What is the overall reaction order for a reaction with the following rate law? Rate = k[Cl2][H+]2[CO]2 Student Response Value Correct Answer

1. Fifth 2. First 3. Second 4. Third 5. Fourth Score: 1/1

100%

4. Known Rate Law, Change Conc 15

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of Br- is decreased by a factor of 3? Just put in the number as a whole number or fraction. Student Response 1. 1/3 Score: 1/1 Value 100% Correct Answer Equals 1/3 (100%) Equals 0.333 (100%) Equals .333 (100%)

5. Known Rate Law, Change Conc 45

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is doubled, that of Br- is decreased by a factor of 2 and that of H+ is doubled ? Student Response 1. 4 Score: 1/1 Value 100% Correct Answer Equals 4 (100%) Equals 4/1 (100%)

6. Determine Rate Law 22

For the reaction, 2 A(g) + 2 B(g) => C(g) + 3 D(g), the following data were obtained at constant temperature. Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min 1 2 3 4 0.11 0.11 0.22 0.22 0.15 0.30 0.45 0.60 2.0 x 10-5 2.0 x 10-5 4.0 x 10-5 4.0 x 10-5

Which of the following is the correct rate law for the reaction? Student Response 1. Rate = k[A] [B] 2. Rate = k[A]2[B] 3. Rate = k[A][B] 4. Rate = k[A] 5. Rate = k[A][B]2 Score: 1/1
2 2

Value Correct Answer

100%

7. Determine Rate Law 28

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.----order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate, mol/L mol/L mol/L mol/L.s 1 2 3 4 0.1 0.2 0.3 0.4 0.1 0.3 0.1 0.3 0.2 0.2 0.2 0.4 2 x 10-3 2 x 10-3 2 x 10-3 4 x 10-3

Student Response 1. 2. 3. 4. 1 1 1 3 0/1

Value 0% 0% 0% 0%

Correct Answer Equals zero (25%) Equals zero (25%) Equals first (25%) Equals first (25%)

Score:

8. Calculate k from Rate Law 37

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate, mol/L mol/L mol/L mol/L.s 1 2 3 4 0.1 0.2 0.3 0.4 0.2 0.2 0.4 0.6 0.4 0.4 0.4 0.2 2 x 10-3 4 x 10-3 2.4 x 10-2 7.2 x 10-2

Calculate the value of k to 3 significant figures. Do NOT use scientific notation! Student Response 1. not answered Score: 0/1 Value 0% Correct Answer Equals 0.500 (100%) Equals .500 (100%) Equals 5.00E-1 (100%)

9. Units of k 3
Which of the following would be a reasonable unit for the rate constant of a third order reaction? Student Response Value Correct Answer

1. L3/mol3.sec 2. mol2/sec.L2 3. mol3/sec.L3 4. L/mol.sec 5. L2/mol2.sec Score: 1/1

100%

10. IRL 1 t 7
A reaction has a rate constant of 0.145 sec-1, how long will it take (in seconds) until 0.245 mol/L of the compound is left, if there was 0.854 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 100% 8.612 Answer: 8.54 Score: 1/1 Correct Answer

11. IRL 1 t 8
A reaction has a rate constant of 0.00657 sec-1, how long will it take (in minutes) until 0.288 mol/L of the compound is left, if there was 0.546 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 100% 1.623 Answer: 1.62 Score: 1/1 Correct Answer

12. IRL 1 c 4

A reaction has a rate constant of 0.00553 sec-1, how much of the compound (in mol/L) is left after 8.16 sec, if there was 0.601 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 100% 0.574 Answer: 0.574 Score: 1/1 Correct Answer