LARSEN & TOUBRO LIMITED

MFY, Hazira

Project : SIDEM-MOBIN Customer : SIDEM Procedure No. : PC-SIDEM-SS PIC!"IN# - $% &e'isio( No. :% Date : )*-$+-)$$,

PROCEDURE FOR CLEANING, DESCALING (PICKLING) AND PASSIVATION OF STAINLESS STEELS

%.$ 1 ) -.is sta(dard /rocedure co'ers t.e re0uireme(ts 1or c2ea(i(3 4 desca2i(3 5Pic62i(37 a(d /assi'atio( o1 stai(2ess stee2 o1 )$$,,$$ series 1u228 a((ea2ed materia2 4 9$$ series co(tai(i(3 Cr e0ua2 to or more t.a( %:;. Pic62i(3 a(d /assi'atio( s.a22 <e do(e o( t.e area as i(dicated i( dra=i(3. I( case o1 co(12ict <et=ee( t.is /rocedure a(d sidem s/eci1icatio(, sidem s/eci1icatio( s.a22 /re'ai2. ).$ REFERENCE ).% ).) )., ,.$ Sidem s/ec $$$$H9$> ?S-M Desi3(atio( ?,>$->> Cata2o3ue o1 Sur1ace I((o'ators SCOPE

PROCEDURE ?(8 o(e o1 t.e 1o22o=i(3 met.ods s.a22 <e used 1or Pic62i(3 a(d /assi'atio(. ,.% ,.) Pic62i(3 4 Passi'atio( usi(3 c.emica2 c2ea(i(3 as recomme(ded i( ?S-M ?,>$ 4 Sidem s/ec. Pic62i(3 4 Passi'atio( usi(3 !-) Paste or S/ra8. 5Sur1ace I((o'ators ma6e7

C.2oride co(te(t o1 =ater used 1or /rocedure s.a22 <e @A ,$ //m. ,.% Pickling & P !!i" #i$n %!ing c&'(ic l! ! )'c$(('n*'* in ASTM A+,- & Si*'( !.'c
,.%.% Cl' ning Mec.a(ica228 c2ea(ed sur1ace s.a22 <e 1ree 1rom 3rease, oi2, dirt, /ai(t etc. -.is ca( <e ac.ie'ed <8 usi(3 soa/ or deter3e(ts. Or3a(ic so2'e(ts s.a22 (ot <e used. I( (o case c.2oride /roduct s.a22 <e used.

,.%.)

D'!c ling (Pickling)

Fo22o=i(3 so2utio( s.a22 <e used 1or desca2i(3.

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LARSEN & TOUBRO LIMITED

MFY, Hazira

Project : SIDEM-MOBIN Customer : SIDEM Procedure No. : PC-SIDEM-SS PIC!"IN# - $% &e'isio( No. :% Date : )*-$+-)$$,

Nitric ?cid 5HNO,7 ,:$Be :+; H8dro12uoric ?cid 5HF7 Bater Sodium F2uoride

%$$ 2itres )$ 2itres *$$ 2itres )$ !3

So2utio( tem/erature s.a22 <e )%-:$$ C. -.e so2utio( s.a22 <e a//2ied a22 o'er t.e c2ea(ed sur1ace <8 suita<2e mea(s 1or a /eriod o1 %$ mi(utes i1 t.e so2utio( is .eated u/ to :$ $ C or 1or ) .ours i1 t.e so2utio( is at room tem/erature. -.e sur1ace s.a22 <e scru<<ed i(termitte(t28 =it. stai(2ess stee2 <rus. or 1i<er <rist2e <rus. i( co(ju(ctio( =it. /ic62i(3 to 1aci2itate t.e remo'a2 o1 sca2e /artic2es a(d /roducts o1 c.emica2 reactio(. ?1ter c.emica2 desca2i(3, sur1ace must <e t.orou3.28 ri(sed to remo'e residua2 acids. -o mi(imize stai(i(3, sur1ace must (ot <e /ermitted to dr8 <et=ee( successi'e ste/s o1 acid desca2i(3 a(d ri(si(3 /rocedure. &u((i(3 =ater jet ma8 <e used to remo'e a22 traces o1 acids 1rom t.e sur1ace. -.e sur1ace s.a22 2ea'e to dr8 t.orou3.28. -.e sur1ace a1ter c2ea(i(3 a(d desca2i(3 s.a22 .a'e du22 to <ri3.t a//eara(ce. ,.%., P !!i" #i$n

?22 acid c2ea(ed a(d /ic62ed or <ri3.t28 /o2is.ed Cmac.i(ed sur1ace s.a22 <e /assi'ated usi(3 o(e o1 t.e so2utio(s recomme(ded i( -a<2e ?).% o1 ?S-M ?,>$. ? t8/ica2 com/ositio( to <e used is as 1o22o=s. Nitric ?cid 5HNO,7 ,:$Be Bater )+$ 2itres D+$ 2itres

-.e so2utio( s.a22 <e a//2ied a22 o'er t.e c2ea(ed sur1ace <8 suita<2e mea(s 1or a /eriod o1 %+ mi(utes i1 t.e so2utio( is .eated to +$O or 1or ) .ours i1 t.e so2utio( is at room tem/erature. -.e sur1ace s.a22 <e c2ea(ed usi(3 =ater. ?1ter c2ea(i(3 sur1ace s.a22 <e 1ree 1rom traces o1 acids, t.is ma8 <e e(sured <8 c.ec6i(3 =it. 2itmus. PH 'a2ue o1 e112ue(t. -.e PH 'a2ue s.a22 <e same as t.e PH o1 t.e i(comi(3 =ater. ,.) Pickling & P !!i" #i$n %!ing k/0 S$l%#i$n ,.).% Cl' ning -.e sur1ace s.a22 <e 1ree 1rom 3rease, oi2, dirt, /ai(t, rust, sca2es, /artic2es o1 iro( a(d ot.er meta2s, =e2di(3 12uE etc. -.is ca( <e ac.ie'ed <8 usi(3 SI-+: 5Soa6 c2ea(er F /o=der +$3mC"it.7 ,.).) Pickling ,.).).% -.e stee2 tem/ at t.e time o1 a//2icatio( o1 !) /aste or s/ra8 s.a22 <e )$ to 9$ de3 C.

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LARSEN & TOUBRO LIMITED

MFY, Hazira

Project : SIDEM-MOBIN Customer : SIDEM Procedure No. : PC-SIDEM-SS PIC!"IN# - $% &e'isio( No. :% Date : )*-$+-)$$,

,.).).) !-) /aste s.a22 <e used 1or c2ea(i(3 o(28 =e2d seams re0uired to c2ea(. !-) /aste s.a22 <e a//2ied o( t.e =e2d seams 4 surrou(di(3 area 5H?G7 =it. a <rus.. ,.).)., !-) s/ra8 s.a22 <e used 1or c2ea(i(3 2ar3e 1a<ricated e0ui/me(t. !-) s/ra8 s.a22 <e s/ra8ed o( to t.e SS sur1ace =it. a /ressurized /2astic s/ra8 <ott2e or s/ra8 /um/. ,.).).9 ?1ter s/ra8i(3 !-) /aste or !-) s/ra8 2ea'e it 1or ,$-:$ mi(utes. Be2d 4 H?G s.a22 <e 'i3orous28 <rus.ed =it. a stai(2ess stee2 <rus.. ,.).).+ -.e( =as. t.e sur1ace t.orou3.28 =it. =ater. -.is ma8 <e accom/2is.ed =it. a .i3.-/ressure =ater jet s8stem. ,.).).: "ea'e t.e sur1ace to 3et dried com/2ete28. ,.)., P !!i" #i$n ,.).,.% -.e stee2 tem/ at t.e time o1 a//2icatio( o1 !-) /assi'atio( s.a22 <e )$ to 9$ de3 C. ,.).,.) NeEt a//28 !-) /assi'atio( so2utio( a(d 2ea'e it 1or )$-,$ mi(utes. ,.).,., &i(se t.e sur1ace t.orou3.28 =it. =ater. 5O(28 /ota<2e =ater s.a22 <e used7 9.$ INSPECTION 9.% 9.) 9., 9.9 I(s/ectio( s.a22 <e carried out at 2east ) da8s a1ter t.e /assi'atio( treatme(t ?22 /assi'ated sur1aces s.a22 .a'e a =.ite meta2 as/ect. -o /er1orm t.e i(s/ectio( a /o=er1u2 2i3.ti(3 s.a22 <e i(sta22ed 5%$$$ 2E is recomme(ded7 -i(ted or dou<t1u2 areas s.a22 <e c.ec6ed =it. FerroE82 test. I( additio( to dou<t1u2 areas, %; at 2east o1 treated sur1ace s.a22 <e ra(dom28 c.ec6ed =it. t.e HFerroE82 -estI.

1 )ning2 D$ n$# c$n*%c# 3'))$45l #'!# $n *i!#ill #' !i*' $3 '" .$) #$)6

+.$

MET7OD FOR FERRO89L TEST +.% Pre/are a test so2utio( <8 miEi(3 1o22o=i(3 i(3redie(ts. - Disti22ed Bater : *9; 5%$$$CM,7
Page 9 of 5

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LARSEN & TOUBRO LIMITED

MFY, Hazira

Project : SIDEM-MOBIN Customer : SIDEM Procedure No. : PC-SIDEM-SS PIC!"IN# - $% &e'isio( No. :% Date : )*-$+-)$$,

+.) +., +.9 +.+ +.: +.D

- Nitric acid :$-:D; : ,; 5)$CM,7 - Potassium Ferric8a(ide : ,; 5,$37 C2ea( t.e sur1ace =it. a c2ea( c2ot. 4 demi(era2ized =ater. ?//28 t.e so2utio( usi(3 a /2astic s/ra8 a//2icator. Co(tami(atio( is i(dicated <8 a//eara(ce o1 a 3ree(is. <2ue co2our a1ter % mi(ute. Ye22o= co2our i(dicates a (o( co(tami(ated /assi'ated area. -.e so2utio( s.a22 <e remo'ed immediate28 a1ter i(s/ecti(3 =it. demi(era2ized =ater s/ra8 a(d a dam/ c2ot.. ?22 traces o1 t.e testi(3 /roduct s.a22 <e remo'ed. Pre/are 1res. miEture e'er8 time.

?(8 co(tami(ated sur1ace s.a22 <e /assi'ated a3ai( :.$ PROTECTION BEFORE AND AFTER PASSIVATION ?222 /ic22i(3 a(d /assi'atio( acti'ities s.a22 <e carried out i( t.e area so as to a'oid sett2i(3 o1 car<o( stee2 /artic2es o( stai(2ess stee2 sur1ace. -o a'oid a(8 co(tami(atio( o1 /assi'ated areas, t.e 'esse2 s.a22 immediate28 <e c2osed a1ter c2ea(i(3 is com/2eted. ?22 o/e(i(3 s.a22 <e c2osed =it. suita<2e co'er to a'oid e(tr8 o1 a(8 car<o( stee2 /artic2es i( /assi'ated 'esse2.
For a(8 (ecessar8 =or6 i(side t.e 'esse2, /erso(a2 s.a22 use c2ea( /rotecti'e c2ot.es o( s.oes.

D.$

SAFET9 ?22 t.ese /roducts <ei(3 acid a(d da(3erousJ t.e o/erator s.a22 /rotect t.emse2'es =it. mas6, 3o332es, ru<<er 32o'es, a/ro( a(d <oots. -.e su/er'isor a(d i(s/ector 3oi(3 i(side s.a22 a2so use suita<2e /erso(a2 /rotecti'e e0ui/me(t. I( c2osed area a suita<2e air su//28 a(d 'e(ti(3 s.a22 <e mai(tai(ed. In n5 c !', !%..li') in!#)%c#i$n! !& ll :' c )'3%ll5 3$ll$;'*6

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