Professional Documents
Culture Documents
y
L
i
n
e
s
4he fa-ora*le erfor!ance of )/136fa in ener.y reco-ery, if adoted *y industrial facilities,
would ease de!and for electricity, conco!itantly decrease the *urnin. of fossil fuels, and increase
the consu!erHs o-erall ener.y efficiency. Solar/dri-en ener.y con-ersion syste!s could also *e
de-eloed around )/136fa. In the sa!e way, this would lead to lower ollution le-els *y cur*in.
fossil fuel *urnin..
In 4a*le D, *oiler ressure, condenser ressure and ther!odyna!ic efficiency are co!ared for
)/00, )/012 and )/136fa. It can *e seen that as !olecular chain len.th increases, so does the
ther!odyna!ic efficiency.
7able ,- Crganic .an:ine Cycle Comparion $
1-
(
>#iler te(perat're 149 ?C 1 C#%/e%&er te(perat're 3" C
+@C1!40)a +C@C11!3 C@C111
b#iler pre&&'re4 kPa 3!13 190" 197!
c#%/e%&er pre&&'re4 (kPa 13!.4 4!.1 61.4
Ther(#/y%a(ic 2))icie%cy (6 09.9 06.6 01."
<#lec'lar Chai% Le%*th 31carb#% !1carb#% 11carb#%
/ D /
WORKING FLUID APPLICATIONS: SENSI6LE HEAT TRANSFER
Sensi*le heat transfer descri*es the heat e@chan.e rocess in which the heat transfer fluid does
not chan.e hase. 4yically, the heat transfer fluid is in the li=uid state for such a heat e@chan.e
rocess. Sensi*le heat transfer alications include a nu!*er of industrial and co!!ercial
alications includin. use as a secondary loo fluid for co!!ercial refri.eration alications, for
e@a!le, in suer!arkets.
In the ast, fluids such as CFC/00, CFC/002 and HCFC/030* would ha-e *een a!on. the
-arious fluorocar*on fluids used in such alications. 4he use of HFC/136fa would ro-ide a non
fla!!a*le, non corrosi-e fluid with fa-ora*le heat transfer and transort roerties +hi.h heat
e@chan.er efficiency and low u! ower re=uire!ents,.
4he ratio of heat transfer coefficient to friction factor si.nifies the heat transfer erfor!ance
efficiency +one wants to !a@i!i(e heat transfer and !ini!i(e fluid friction or u!in. ower,.
Fi.ure 3 *elow illustrates that HFC/136fa has a hi.her heat transfer coefficient to friction factor
ratio than !any other co!!ercially a-aila*le heat transfer fluids.
Pekasol is a re.istered trade!ark of roIJhlsole
Hycool is a re.istered trade!ark of #orsk Hydro
HF</7055 +2M,
Cowfrost is a re.istered trade!ark of 4he Cow Che!ical Co!any
4yfo@it +<n-iron!ental Process Syste!s Ltd,
/ 7 /
Figure 4- )erformance of Heat 7ranfer Flui>
0
0000
10000
10000
!0000
!0000
30000
30000
130 130 1!0 1!0 110 110 10 0
7emperature $
o
C(
H
e
a
t
7
r
a
n
f
e
r
C
o
e
f
f
&
9
F
r
i
c
t
i
o
n
F
a
c
t
o
r
+@C1!40)a
+@217100
+yc##l 40
Peka&#l 00
Ty)#Ait ("03!0
4!6 Pr#pyle%e ;lyc#l
(=#$)r#&t
006 Pr#pyle%e ;lyc#l
(=#$)r#&t
C@C1113
C@C111 3 +C@C1141b
NOMENCLATURE
&CGIH/&!erican Council of Go-ern!ental and
Industrial Hy.ienists
&IH&/&!erican Industrial Hy.iene &ssocation
C?4/Ceart!ent of 4ransortation
LCCP/ +Life Cycle Cli!ate Perfor!ance,,
?SH&/?ccuation Safety and Health &d!inistration
)C)&/)esource Conser-ation and )eco-ery &ct
S#&P/ Si.nificant #ew <ernati-es Pro.ra!
4SC&/4o@ic Su*stances Control &ct
:?C/:olatile ?r.anic Co!ound
'<<L/'orklace <n-iron!ental <@osure Li!it
<fficiency/ k'K4on, C?P +coefficient of erfor!ance,
<ner.y/ k' +kilowatt,
H, LH/ <nthaly, <nthaly chan.e, resecti-ely
Pressure/ kPa
)efri.eration Caacity/ k'
S/<ntroy
4, L4 /4e!erature, 4e!. chan.e, resecti-ely> GC
:olu!e/ !
2
+cu*ic !eters,
:olu!etric Flow )ate/ !
2
K!in.
/<ndnotes/
0. Honeywell Material Safety Cata Sheet, Genetron
M
136fa, Section 8, <@osure Guidelines.
1. ?utut *ased on #ational Institute of Standards and 4echnolo.y, )efro -.D.50.
2. Le!!on, <ric '., McLinden, Mark ?. and Hu*er, Marcia L., #IS4 )eference Fluid 4her!odyna!ic and
4ransort Proerties N )efro 7.5, #IS4 Std. Cata*ase, 1551
3. Carr, Mathew &., <@eri!ental and 4heoretical Study of Surface 4ension <ffects on <@tended Surface
Condensation, Catholic %ni-ersity of &!erica, Coctoral Cissertation, 'ashin.ton CC, 1551.
6. &twood, 4., Murhy, I.P, &n In-esti.ation of )efri.erants for Sin.le/Sta.e Centrifu.al 'ater Chillers,
&SH)&< 4ransactions, 0971 #o1020.
D. IPPC, Cli!ate Chan.e 1550/ 4he Scientific "asis, Inter.o-ern!ental Panel on Cli!ate Chan.e,
Ca!*rid.e %ni-ersity Press, 1550.
7. &rthur C. Little +&CL,, Glo*al Co!arati-e &nalysis of HFC and <ernati-e 4echnolo.y for
)efri.eration, &ir Conditionin., Foa!, Sol-ent, &erosol Proellant, and Fire Protection &lications,
1551.
8. Conald &. Mc Ouarrie, Statistical Mechanics, Harer and )ow, #ew $ork, 097D, . 027.
9. httFKKwww.ea..o-Ko(oneKtitleDKsnaKlistsK00cent.ht!l .
05. www.eere.ener.y..o-KderK!icrotur*inesKdfsKhau.htats.df, C?< &d-anced Microtur*ine Pro.ra!
%date, Ce**ie Hau.ht, First &4S &nnual Pro.ra! )e-iew Meetin., Cece!*er 3/D, 1555, &le@andria,
:ir.inia, .02
00. &ir Conditionin. and )efri.eration Institute, P'ater Chillin. Packa.es %sin. the :aor Co!ression
CycleQ, Standard 665/695. &rlin.ton :&. 0998.
Cisclai!er
<hou.h all state!ents and infor!ation contained herein are *elie-ed to *e accurate and relia*le, they are
resented without .uarantee or warranty of any kind, e@ressed or i!lied. Infor!ation ro-ided herein does
not relie-e the user fro! the resonsi*ility of carryin. out its own tests and e@eri!ents, and the user assu!es
all risks and lia*ility for use of the infor!ation and results o*tained. State!ents or su..estions concernin. the
use of !aterials and rocesses are !ade without reresentation or warranty that any such use is free of atent
infrin.e!ent and are not reco!!endations to infrin.e on any atents. 4he user should not assu!e that all
to@icity data and safety !easures are indicated herein or that other !easures !ay not *e re=uired.
/ 8 /