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Chapter 1
INTRODUCTION
.1 HISTORY
Refrigeration is a process in which work is done to move heat from one location
to another. The work of heat transport is traditionally driven by mechanical work,
but can also be driven by heat, magnetism, electricity, laser, or other means.
Refrigeration
has
many
applications,
including,
but
not
limited
to:
rugged,
reliable,
and
quiet.
They
use
no
ozone
depleting
When a Current (I) is made to flow through the circuit, heat is evolved at the
T
T
upper junction ( 2 ) and absorbed at the lower junction ( 1 ). The Peltier
heat absorbed by the lower junction per unit time is equal to
= AB I
AB
Where
.2 APPLICATIONS
Electronic
Medical
Aerospace
Telecommunications
Commercial
Military
Submarines
.3 ADVANTAGES
Eco-friendly
Compact Size
Light Weight
Lower Price
Less Consumption of Energy
-
Two unique semi-conductors, one n-type and one p-type, are used because they
need to have different electron densities. The semi-conductors are placed
thermally in parallel to each other and electrically in series and then joined with a
thermally conducting plate on each side. When a voltage is applied to the free
ends of the two semiconductors there is a flow of DC current across the junction
of the semi-conductors causing a temperature difference. The side with the
cooling plate absorbs heat which is then moved to the other side end of the device
where the heat sink is. TECs are typically connected side by side and sandwiched
between two ceramic plates. The cooling ability of the total unit is then
proportional to the number of TECs in it.
Thermoelectric refrigeration replaces the three main working parts with: a cold
junction, a heat sink and a DC power source. The refrigerant in both liquid and
vapor form is replaced by two dissimilar conductors. The cold junction
(evaporator surface) becomes cold through absorption of energy by the electrons
as they pass from one semiconductor to another, instead energy absorption by the
refrigerant as it changes from liquid to vapor. The compressor is replaced by a DC
power source which pumps the electrons from one semiconductor to another. A
heat sink replaces the conventional condenser fins, discharging the accumulated
heat energy from the system. The difference between two refrigeration methods,
then, is that a thermoelectric cooling system refrigerates without use of
mechanical devices, except perhaps in the auxiliary sense, and without refrigerant.
Tc
(1)
(2)
K(Th - Tc)
KT
(3)
Combining Equations (1), (2), and (3) into an energy balance at the end of the
thermoelectric couple gives the following:
Qc = Qsb 0.5Qj Qcd = Tc - 0.5R KT
(4)
R + T
(5)
=
=
Qc / Qe
ITck T 0.5 I R
I R +IT
(6)
It is seen that the COP is a function of the material dimension property of
thermocouple, the temperature of the hot side and cold side Th, Tc and the current
input. There exists an optimum current for maximum COP, if Th, Tc, and
thermoelectric material are fixed.
Solving the equation /I = 0, the optimum current for the maximum (optimum)
COP can be given by
I opt
T
R
( 1+ ZTm )1
(7)
(7)
Replacing I in Equation (6) by Iopt, the optimum COP can be given by
opt
Th
)
Tc
(ThTc)( 1+ZTm +1)
Tc( 1+ZTm
(8)
Where
Tm = (Th+Tc)
(9)
Z = / kR
(10)
It is seen that the optimum COP under the optimum current is a function of Th, Tc
and the figure of merit of thermoelectric material.
density and the ratio of the heat exchanger base plate area to the
thermoelectric module area. Higher ratios of the heat exchanger base plate
area to the thermoelectric module area result in a lower thermal
resistance;
1
2) Forced air convection: 0.531-5.759mK k W
flow rate. Larger air flow rate result in a lower thermal resistance;
The data provided by Melcor shows the typical allowances of temperature
difference between the hot side and ambient, with respect to the heat exchange
mode. That is:
1) Natural convection: 20-40C;
2) Forced air convection: 10-15C
Chapter 2
COMPONENTS
i.
Rm
Km
) = 0.344
) = 0.1815 W/k
10
ii.
Heat sink:
The heat sink usually made of aluminum, is in contact with the hot side of
a thermoelectric module. When the positive and negative module leads are
connected to the respective positive and negative terminals of a Direct
Current (D. C.) power source, heat will be rejected by the modules hot
side, the heat sink expedites the removal of heat. Heat sink typically is
intermediates stages in the heat removal process whereby heat flows into a
heat sink and then is transferred to an external medium. Common heat
sinks include free convection, forced convection and fluid cooled,
depending on the size of the refrigerator.
iii.
Cold slide:
The cold side also made of aluminum is in contact with the cold side of a
thermoelectric module, when the positive and negative module leads are
connected to the respective positive and negative terminals of a direct
current (D. C.) power source, heat will be absorbed by the modules cold
side. The hot side of a thermoelectric module is normally placed in contact
with the object being cold.
iv.
Power source:
Thermoelectric module is a Direct Current (D.C.) device. Specified
thermoelectric module performance is valid if a Direct Current (D. C.)
Power supply is used. Actual D. C. power supply has a rippled output. This
D. C. component is detrimental [7]. Degradation of thermoelectric module
performance due to the ripple can be approximately by [7]:
11
T Max
T Max
v.
1
N
1+
2
Thermoelectric coolers:
The thermo-electric module (40x40 mm) allows the temperature below
63C at 25 W of dissipated power and the outer temperature of 25C. It
provides the lowest temperature than alternative fans and radiators. For
normal work of this cooler it's necessary to provide 5 V and 1.5A
(maximum).The fan for this cooler require 12V and 0,1A (maximum). The
fan parameters: ball-bearing, 47,5mm, 65000 hours, 26 decibel. The whole
size of the cooler is 25x25x28,7mm.
vi.
Transformer:
Two coils are wound over a Core such that they are magnetically
coupled. The two coils are known as the primary and secondary
windings.
In a Transformer, an iron core is used. The coupling between the coils
is source of making a path for the magnetic flux to link both the coils.
A core as in fig.2 is used and the coils are wound on the limbs of the
core. Because of high permeability of iron, the flux path for the flux is
12
only in the iron and hence the flux links both windings. Hence there is
very little leakage flux. This term leakage flux denotes the part of the
flux, which does not link both the coils, i.e., when coupling is not
perfect. In the high frequency transformers, ferrite core is used. The
transformers may be step-up, step-down, frequency matching, sound
output, amplifier driver etc. The basic principles of all the transformers
are same.
vii.
13
viii.
Capacitor:
It is an electronic component whose function is to accumulate charges and
then release it.
To understand the concept of capacitance, consider a pair of metal plates
which all are placed near to each other without touching. If a battery is
connected to these plates the positive pole to one and the negative pole to the
other, electrons from the battery will be attracted from the plate connected to
the positive terminal of the battery. If the battery is then disconnected, one
plate will be left with an excess of electrons, the other with a shortage, and a
potential or voltage difference will exists between them. These plates will be
acting as capacitors. Capacitors are of two types: - (1) fixed type like
ceramic, polyester, electrolytic capacitors-these names refer to the material
they are made of aluminium foil. (2) Variable type like gang condenser in
radio or trimmer. In fixed type capacitors, it has two leads and its value is
written over its body and variable type has three leads. Unit of measurement
14
Small
unit
capacitor
are
pico-farad
denoted
by pf
Fig.2.8 capacitor
15
be 0.3-0.5 for a typical operating temperature of 5oC with ambient at 25oC. The
potential improvement in the cooling performance of a thermoelectric refrigerator
is also investigated employing a realistic model, with experimental data obtained
from this work. The results show that an increase in its COP is possible through
improvements in module contact resistances, thermal interfaces and the
effectiveness of heat exchangers.
Adeyanju et al. [10] carried out a theoretical and experimental analysis of a
thermoelectric beverage chiller. Comparison were also made between the
hermoelectric beverage chillers cooling time with cooling times obtained from
the freezer space and cold space of a household refrigerator. The result shows that
for the refrigerator freezer space, the temperature of the water decreased linearly
with increasing time and for thermoelectric beverage chiller the temperature of the
water decreased exponentially with increasing time.
Lertsatitthanakorn et al. [11] evaluated the cooling performance and thermal
comfort of a thermoelectric ceiling cooling panel (TE-CCP) system composed of
36 TEM. The cold side of the TEM was fixed to an aluminum ceiling panel to
cool a test chamber of 4.5 m3 volume, while a copper heat exchanger with
circulating cooling water at the hot side of the TE modules was used for heat
release. Thermal acceptability assessment was performed to find out whether the
indoor environment met the ASHRAE Standard-55s 80% acceptability criteria.
The standard was met with the TE-CCP system operating at 1 A of current flow
with a corresponding cooling capacity of 201.6 W, which gives the COP of 0.82
with an average indoor temperature of 27oC and 0.8 m/s indoor air velocity.
Chapter 3
PROJECT
16
In order to visualize the energy flow in the entire system, a thermal circuit is
constructed, which is schematically shown in Figure 2. Rc and Rh and are the
overall thermal resistances for the internal heat sink and external heat sink,
respectively. The components of the air cooler are an internal heat sink, a
thermoelectric module, and an external heat sink as shown in Figure 2 is the
amount of heat transported at the internal heat sink, which is actually the design
requirement (33 Watts).
17
Fig.3.4 Common heat exchanger designs: (a) natural air convection, (b) forced
air convection.
.2 GEOMETRY
Two main geometries were considered for the device the first was a rectangle. The
advantage of rectangle is its simplicity to build and insulate. A door can easily be
attached to one of the sides. Finally any insulation, thermoelectric modules or heat
sinks are easily fastened to the sides. The second choice for cooler geometry was a
cylinder. The advantage found with this shape is that it has the largest volume to
surface area ratio of the two designs considered. This is a good property when the
objective is to minimize heat loss. But considering the simplicity to build and
insulate rectangle box is considered.
The geometry of the project is given below:
Outer dimension = 30 cm 27 cm 38 cm
Internal dimension = 28.5 cm 25.5 cm36.5 cm
18
.3 MATERIAL
We explored three different materials for the construction of the cooling box and
frame of the device. These were aluminum, wood and thermacol. High impact
polystyrene is desirable as it has a low thermal conductivity. Building the device
out of would make it very light, portable while maintaining rigidity is readily
available and reasonably priced, is easy to cut and drill. The outer casing and
container would be made by first making a positive mold and applying a cloth
coated with resin.
Chapter 4
ANALYSIS
.1 EXPERIMENTAL SETUP
The experimental setup of the given project is shown below. It is a protype of
thermoelectric refrigeration system.
19
20
21
.2 EXPERIMENTAL ANALYSIS
Experimental analysis was done in three stages. This helps to know about the
detailed information about the instruments, working procedure and operating
parameters of the thermoelectric cooling system. They are as follows:
1) COP :
It is seen that the COP is a function of the material dimension property of
thermocouple, the temperature of the hot side and cold side Th, Tc and the
current input. There exists an optimum current for maximum COP, if Th, Tc,
and thermoelectric material are fixed.
So analysis of COP is done by varying the various parameters such as input
current, voltage and temperature difference and their effect on COP is study
for fix geometric parameters.
22
COP vs I
1.5
1
0.5
0
0
10
12
-0.5
-1
2) Time vs temperature :
The experimental result (Fig.4.) shows that at input electrical current condition
0.5Imaxi and at forced air convection condition the temperature reduction at
cold side of module with respect to ambient at 30oC was maximum.
With these optimized operating condition (I=0.5Imaxi and at forced air
convection) experiments were conducted for performance evaluation of
23
time vs temp.
30
25
20
15
10
5
0
0
10
20
30
40
50
60
70
80
24
time vs temp.
30
25
20
15
10
5
0
0
10
20
30
40
50
60
70
80
.3 COST ANALYSIS
The cost analysis of the project is given below:
S. No.
1
2
3
4
5
6
7
8
9
Items
Thermoelectric module
Wood
Aluminium foil
Thermocol
Transformer
Capacitor
Switch
Digital Temp. Control
Device
Extra
25
Chapter 5
RESULT
26
27
28
Fig.5.1. Readings
TEC Retention:
The retention time is calculated as per test procedure. As the current carrying
capacity of Peltier cell is high as 9 Amp the battery to be used will be 12 V.
Therefore different method has to be employed to achieve the desired temperature.
All this method was mentioned above.
.2 CONCLUSION
The research effort made by different researchers for design and development of
novel thermoelectric refrigeration and space conditioning systems has been
thoroughly reviewed in this paper. Also the advantages and cost-effectiveness
offered by thermoelectric cooling system over conventional cooling system have
been explained. A temperature reduction of 11C without any heat load at 30C
ambient temperature in first 20 minutes has been experimentally found at
optimized operating conditions. The calculated COP of developed experimental
thermoelectric refrigeration cabinet was 0.1. The available literature shows that
thermoelectric cooling systems are generally only around 515% as efficient
compared to 4060% achieved by conventional compression cooling system. This
is basically limited by figure of merit of thermoelectric material and efficiency of
heat exchange system. Continuous efforts are given by researchers for
development of higher figure of merit thermoelectric materials may provide a
potential commercial use of thermoelectric refrigeration and space conditioning
system. Also compatibility of thermoelectric cooling systems with solar energy
made them more useful and appropriate for environment protection.
29
.3 FUTURE SCOPE
With recent development taking place in field of thermoelectric and nano science
different thermoelectric material with figure of merit ZT more than 1 with high
temperature difference to be explored this will further help to reduce the
temperature, current below and can also perform better at higher ambient
conditions. To improve the power retention in this thermoelectric cooler sandwich
heater needs to be explored with quick switching mechanism from thermoelectric
cell off state of heater to on state, so that temperature drop in thermoelectric cell
can be reduced.
.4 REFERENCES
1. Rowe D. M., 1995, CRC handbook of Thermoelectrics
2. Huang B.J., Chin C.J. & Duang C.L., 2000, A design method of
thermoelectric cooler, International Journal of Refrigeration, 23: 208-218.
3. Rowe D. M., 2006, Thermoelectrics handbook: Macro to Nano, CRC,
Taylor & Francis
4. Xi Hongxia, Luo Lingai and Fraisse Gilles, 2007, Development and
applications of solar-based thermoelectric technologies, Renewable and
Sustainable Energy Reviews, 11(5): 923-936.
5. Dai Y. J., Wang R. Z. and L. Ni, 2003, Experimental investigation and
analysis on a thermoelectric refrigerator driven by solar cells, Solar
energy material and solar cells 77:377-391.
6. Gao Min and Rowe D.M., 2006, Experimental evaluation of prototype
thermoelectric domestic-refrigerators, Applied Energy, 83 (2): 133-152.
7. Sabah A. Abdul-Wahab, Ali Elkamel, Ali M. Al-Damkhi, Is'haq A. AlHabsi, Hilal S. Al-Rubai'ey', Abdulaziz K. Al-Battashi, Ali R. Al-Tamimi,
Khamis H. Al-Mamari and Muhammad U. Chutani, 2009, Design and
experimental investigation of portable solar thermoelectric refrigerator,
Renewable Energy, 34 (1): 30-34.
8. Abdullah M. O., J. L. Ngui, K. Abd. Hamid, S. L. Leo, and S. H. Tie,
2009, Cooling Performance of a Combined Solar ThermoelectricAdsorption Cooling System: An Experimental Study, Energy Fuels, 23:
56775683.
9. Putra N., 2009, Design, manufacturing and testing of a portable vaccine
carrier box employing thermoelectric module and heat pipe, Journal of
Medical Engineering & Technology, 33 (3): 232-237.
30
.5 INDEX
The tables for different data are given below:
1. COP vs. Current (I) at 20C temperature difference.
S. No.
I (in Ampere)
C.O.P
-0.6743
1.3336
1.3135
1.1153
0.9250
0.7651
0.6337
0.5252
0.4348
10
10
0.3585
11
11
0.2934
31
Temperature in C
28
25
10
22
20
19
25
17
30
15
35
13
40
11
45
10
10
50
11
55
12
60
13
65
14
70
15
75
16
80
Temperature in C
28
27
10
26
15
25
20
24
32
25
23
30
22
35
22
40
22
10
45
21
11
50
21
12
55
21
13
60
21
14
65
20
15
70
20
16
75
20