: 2015

: +

04:

:



03.5( :)

)( .
( )

2ClO(aq ) = O2 (g) + 2Cl

) (aq
- 1
0
- 2 0 0 100 1 1 1 = 4
-1-2

-4 -
25mL
100mL
50mL

- 2
25mL
300mL
50mL

- 3
25mL
100mL
50mL

-1 -
100mL
100mL
50mL

VB = 1,2L 100mL S1
T = 290 K P0 = 105 Pa P
) O2 (g

P = Pmes P0
RT
Pmes = P0 + n O 2 V Pmes
B

t
2
7
X X = 5 . 10 P
3 ) P = f(t 1

4
) 65 s) = 2.104Pa
1 dx
5 Vvol = V dt
Vvol
dP
-6 Vvol = 5 . 106 dt
t 1

7 Vvol

1 8

 ) Cl2(g T = 273 P0 = 105 Pa

Cl2(g) + 2OH(aq
1L ) = ClO(aq ) + Cl(aq ) + H2 O
1L 48 Cl2(g) 2,1mol
- 0 C1 S1

ClOS1 100mL
) (aq
1 ) ( 10 minE

02.75( :(
2
t=0
R=100 E=6V
) i(t

.1 i = A. e , A .
.2 Uc .
i
EXAO 3 t
0

I0 t=0
.1
.2 . C
.3 Ec
Ec () t=

(=

i
I0
1

)(

( e )
)t(s
0,1

02.5( :)

.
40
40.
19 18
V=8,1.10-3cm3

m=1,67.10-6g .

.1 40 .
.2 Mev .

.3 t=0s 40 40

1 +
2
2

2 8

= :

: = 1,3. 109 ans :

t1

,,:1u = 931,5Mev c 2 = 22,4 L. mol1 , = 1,02.1023

= 39,9624 u

40
18

= 39,9740 u , :

40
19

01 = 0,00054 u,

03.5(:)
-1- .
-1- 0,2 mol
-1- .
- 1
- 2 .
- 3 -1- .
- 4 . Qr x . t
- 5 xeq . K = 4:
- 6 f .
- 8 0,05mol 0,02mol
2
xeq 8,110 .mol 90%: .

- 9
:
5 - - -
- .
.
: .

C3H6O2

103 Kg.m-3

-1-

C4H10O

8,10.102 Kg.m-3

74,.0g mol -1

141,0 C

74,.0g mol

117,5 C

-1

04( :)
: :1 = 2,70.103 3
:2 = 1,26.103 3
: = 4,20.106 3 :g = 9,80 m s 2
= 0

( )4 ( )5

3 8

 - 1 :

1
1
- 1- 1
- 2- 1
1 1 , 1 , g ,
- 3- 1 = ()
. 1 1 - 2 :
f =

( = 5,2 26 .... .... )1

- 1- 2
- 2- 2
- 3- 2 = () ( )1
- 4- 2

03.75( :)
-6 - :
1 = 100
s2
2 1

1

7
- 1 2 s1
- 2
2 s1
- 3
- 4 T m a , g,
- 1 1
= 2
- 2 = 30
= = 80 :g = 9,80 m s 2

4 8


4( :)
) H2C2O4 (aq
)) (2K+(aq) + Cr2O72-(aq , 100mL
C1 = 6,0.10-2 mol/L 100mL C2 =
1,67.10-2 mol/L .
Cr3+ =20C ( )1
[Cr3+ (aq)] . t
.1
.2
.3
.4
.5
.6
.7
.8

(Cr2O72-(aq)/ Cr3+ (aq) ) , (Ox/Red)

))(CO2(aq)/H2C2O4(aq

.

t1/2
[Cr3+ (aq)]t
t = 0 s
t mol/L

C2 > C2

2,75( :(
: ,1 = 365 ,:1u = 931,5Mev c 2 = 6,02.1023

.
238
94Pu
m0
- 1- 1 ,

5 8

 - 2- 1
- 3- 1 Bq
- 4- 1
- 2 ()
A0 = 0
, N0
m0

30%

2,5( :(
-2-:
E=5v R=240 L , r K
t=0 UR
)UR(V

: -2-

1,2
t(ms
0,2 -3-
)
- 1 -2-

- 2 .UR
- 3 UR t = A + Bemt : m B A
1

- 4 m .
- 5 :
.
.
- 6 r L.
- 7 .

6 8

 3,5(:)

Sn 2CLaq

Sn

2
aq

2
0,1mol / l
Snaq Ni

2
2

Ni+2
Niaq 2CLaq aq = 10 mol / l

CLaq

2
aq

K 8,8 104 250 C

2
2
SnS Niaq
NiS Snaq

.1
.2
.3
.4
.5
.6
.7
.8

25 C
.
.


10 10m. A X
F = 96500 c = 59/mol =:
119/mol
0

3,75( :)
-4- )(
-1- )( .

- 1
- 1- 1 )(
- 2- 1 )( 2 g D sin

1
- 3- 1 VC = 2,2
- 4- 1

= VB

- 2 )(
= 0 )(
- 1- 2
- 2- 2 )(

- 3- 2 )( =

7 8

 - 4- 2 )(
- 5- 2 )( X2 = 0,60 X1 = 0,55
- 6- 2 D )( Xf = 0,57

= 10 ,hC = 0,40 , = 0,20 , D = = 0,50 , = 30

04( :)

/ ) ( /
) ( /
) (25

( /3,75
)
46

( )3 /3
4,75
60

(2 5 /
4,87
74
) 2 5

( /7,30
)
52,5

1 = 0,10 1 S2 = 0,10 1 1 2 1
2

1
2
3
4
5
6
7
8
)( 1
4
10
20
30
40
40
40
40
)( 2
40
40
40
40
30
20
10
4
4,2
4,5
4,7
4,9
5 ,1
5,4
5,8
3,8
1
2
1

2
- 1

- 2 = ( 1) 4 1 1 0,5
2

V1

] [A

- 3 [HA ] = V

] [A
][HA

- 4 a ) ( /
) ( /
- 5 43
- 6 /
1
=C

2 0,10mol
- 7 = 1,85 L V = 250

) ( /

8 8