23.05.2008 PREPARED BY N. MAHESWARAN.

B.Sc/PGDE/M.Phil
mikg;Gf; fl;Liu
01.
(a) gpd;tUk; %yfq;fis khj;jpuk; gad;gLj;jp fPOs;s tpdhf;fSf;F tpilfisj; jUf.
Al, Cu, Cd, Co, Ni, K, Fe, Ag, Be, Na
i. xl;rprd; (-1) xl;rpNaw;w epiyapYs;s xf;irl;L xd;wpid cUthf;Fk; %yfk;/
%yfq;fs;……………………………………………………………………………
ii. %yf mad; kpif mNkhdpahf; fiurYld; epwkw;w rpf;fy; maid cUthf;Fk; %yfk;/
%yfq;fs;…………………………………………………………………
iii. %yf mad; fiurYf;F> KI NrHj;J ed;whff;FYf;fp tbf;Fk; NghJ ntz;zpw tPo;gbT
ngwg;gLk; %yfk;/ %yfq;fs;………………………………………….
iv. %yf FNshiul;Lf;F K4[Fe(CN)6] Nru;f;Fk;NghJ Kjypy; ntz;zpwk; Njhd;wp rw;W
Neuj;jpy; ePyepwkhf khWk; %yfk;………………………………………………
v. NH4CNS cld; ePyepwj;jpidj; jUk; maidj; juf;$ba %yfk;……………….

(b) X,Y vDk; ,uz;L ,urhad %yfq;fs; gw;wpa jfty;fs; fPNo jug;gl;Ls;sd.
%yfk; X Y
mDntz; Z Z+8
X,Y ,d; rhuZj;jpzpT 60 ,Yk; FiwthFk;. mj;Jld; ,uz;bdJk; mjp caH xl;rpNaw;w
vz; + 6 MFk;.
i. Y2+ ,d; ,yj;jpud; epiyaikg;gpid 1s22s2……… tbtpy; jUf?
………………………………………………………………………………………
…..
ii. rw;W mkpyg;gLj;jg;gl;l Y ,d; xl;rpadad; fiurYf;F kpifahd rpq;Fj;J}s; NrHj;j
NghJ nrk;kQ;rs;> Cjh> ePyepwq;fs; xOq;fhf mtjhdpf;fg;gl;ld. ,e;epwq;fSf;Ff;
fhuzkhd mad;fisj; jUf.
epwk; nrk;kQ;rs; Cjh ePyk;
mad;

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 iii. Cjh epw mad;fiury; (1) NaOH (2) NaOH Kd;dpiyapy; H2O2 cld;
jhf;fkilAk; NghJ ngwg;gLk; mtjhdq;fisAk;> jhf;fq;fSf;fhd
mad;rkd;ghLfisAk; jUf.
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
……………………
(c) A,D,L,X vd;gd 2k;> 3k; MtHj;jdj;jpy; cs;s vitNaDk; ehd;F %yfq;fshFk;. XA3
NrHitapy; %yfk; X ,idr; Rw;wp ,uz;L jdpr; Nrhb ,yj;jpud;fs; fhzg;gLfpd;wd.
%yfq;fs; A,D cUthf;Fk; NrHit mad; ,ay;GilaJ. %yfq;fs; X,D cUthf;Fk; NrHit
gq;fPl;L tY ,ay;GilaJ. L,A %yfq;fs; nfhz;l NrHitnahd;W vz; KfptbtKilaJ.
i. A,D,L,X ,d; ,urhadf; FwpaPLfisj; jUf.
………………………………………………………………………………
………………………………………………………………………………
ii. Vz;Kfptbtr; NrHitapd; ,urhad #j;jpuj;jpidj; jUf.
………………………………………………………………………………
iii. ,urhadf; FwpaPLfisg; gad;gLj;jp XA3 ,d; tbtj;jpid tiue;J tbtj;jpd;
ngaiu voJf.
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
iv. D,L cUthf;Fk; NrHitapd; ,urhad #j;jpuj;jpidj; je;J mJ ePUld; milAk;
jhf;fj;jpd; ,urhad rkd;ghl;bidj; jUf.
………………………………………………………………………………
………………………………………………………………………………
(d) Jhz;lypy;yhj %yfk; T cUthf;Fk; xU xl;rp mkpyk; R jsKf;NfhztbtKilaJ.
,jw;F B kpif ePH NrHf;Fk; NghJ cUthFk; ,d;ndhU xl;rpakpyk; Z ehd;
KfptbtKilaJ.
i. R,Z ,d; ,urhad #j;jpuq;fisj; jUf.
………………………………………………………………………………

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 ………………………………………………………………………………
ii. R,Z xl;rpakpyq;fspd; fl;likg;Gf;fisAk; IUPAC ngaiuAk; jUf.
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
iii. T cUthf;Fk; NtW xl;rpakpyq;fs; ,Ug;gpd; mtw;wpd; ,urhad #j;jpuq;fis jUf.
………………………………………………………………………………
………………………………………………………………………………
02.
(a) mkpy Clfj;jpy; MO42- MdJ H2O2 ,dhy; MO+ Mfj; jho;j;jg;gLfpd;wJ.
i. jho;j;jpapd; miu mad; jhf;f rkd;ghl;bidj; jUf.
………………………………………………………………………………
ii. Xl;rpNaw;wpapd; miumad; jhf;f rkd;ghl;bidj; jUf?
………………………………………………………………………………
iii. jhf;fj;jpd; mad;rkd;ghl;bidj; jUf
………………………………………………………………………………
………………………………………………………………………………
iv. 0.1mol dm-3,24cm3 mkpy MO42- mad;fSld; kl;Lkl;lhfj; jhf;fk; GupAk;
0.3moldm-3 H2O2 fiurypd; fdtsT ahJ?
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………

v. Nky; jhf;fj;jpy; ntsptUk; thAtpd; fdtstpid STP ,y; fzpf;f.

………………………………………………………………………………
………………………………………………………………………………
(b) nkd;dkpyk; HA 298 K ,y; ,jd; ePHf;fiurypd; POH=11 MFk; ,f;fiurypd;
25cm3 Kfitapy; vLf;fg;gl;L mstpapYs;s NaOH fiurYld; epakpf;fg;gl;l
NghJ mstpthrpg;G 50cm3 Mf ,Ue;jJ. ,Nj mkpyf;fiurypd; 25cm3 ,w;F>
25cm3 mNj NaOH NrHf;fg;gl;l fiury; X ,d; POH 298 K ,y; 9 Mff;
fhzg;gl;lJ.

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 i. ePHf; fiurypy; nkd;dkpyk; HA ,d; rkepiyf;F rkd;ghl;bidj; je;J>
Ka ,w;F xU Nfhitapidj; jUf?
………………………………………………………………………………
………………………………………………………………………………
ii. 298K ,y; nkd;dkpyj;jpd; Ka ahJ?
………………………………………………………………
………………
………………………………………………………………………………
iii. nkd;dkpyk; HA ,d; Muk;g nrwpT ahJ?
………………………………………………………………………………
………………………………………………………………………………
iv. fiury; X ,w;F nkhj;jf; fdtsT 100cm3 MFk; tiuAk; tbj;j ePH
NrHf;fg;gl;lJ 298 K ,y; ,f;fiurypd; PH ,id fzpf;f.
………………………………………………………………………………
………………………………………………………………………………
v. NkYs;s epakpg;gpd; NghJ Vw;gLk; PH khw;wj;jpid NrHf;fg;gl;l
fhuj;jpd; fdtstpw;F vjpuhf tiugpy; Fwpj;Jf; fhl;Lf.
PH
14

NrHf;fg;gl;l NaOH (aq)

25 50
(c) KfitapYs;s 10cm3 H2A vDk; ,U %ynkd;dkpyj;jpw;F mstpapYs;s mNj
H
nrwpTila KOH fiury; Jspfshfr; NrHf;fg;gLk; NghJ P khw;wj;jpid
fPOs;s tiugpy; Fwpj;Jf; fhl;Lf.

PH

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 (d) ntg;gNkw;wtjd; %yk; iejurd; thAtpidg; ngw;W> ,yl;rpa thA khwpyp R
,id Ma;T $lj;jpy; Jzptjw;fhd cgfuz mikg;gpid tiue;J ngaupLf.
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………
03.
(a) xU Nrjdr; NrHit A MdJ C, H, O vd;gtw;iwf; nfhz;Ls;sJ
,r;NrHitapy;; C jpzpTg;gb 81.35% k; H , 5.10%k; fhzg;gLfpd;wJ (C =12, H
=1, O =16)
i. A ,d; mDgtr; #j;jpuk; ahJ?
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
ii. A ,d; njhlHG %yf;$w;Wj; jpzpT 236 Mapd; A ,d; %yf;$w;W
#j;jpuk; ahJ?
………………………………………………………………………………
………………………………………………………………………………
iii. A xU gpujpaPl;L mNuhkw;wpf; NrHitahf ,Ug;gJld; Cis, trans rk
gFjpa tbtq;fspy; fhzg;gLfpd;wJ. A ,d; Cis- trans tbtq;fis
tiuf.
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
iv. A njhydpd; Nrhjidg; nghUSld; gupfupj;j tpisT mkpyg;gLj;jpa
NghJ C4H3O mDgtr; #j;jpuKila> Cis trans rkgFjpaKila NrHit
D ,idj; je;jJ D,d; %yf;$w;W #j;jpuk; ahJ?

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 ………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
v. D d; trans rk gFjpaj;jpd; fl;likg;gpid tiuf.
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
1 2 4
(b) H – C ≡ C – CH – CH – CH – //C – O CH2 – CH3
3CHO NH2 OH O

vDk; NrHit X ,d; IUPAC ngaH ahJ?

………………………………………………………………………………………………
………………………………………………………………………………………………
i. NrHit X y;
(1) – CHO (2) – CH - (3) H−C≡C vDk; $l;lq;fs;
,Ug;gij
OH vLj;Jf;fhl;l
,urhad
Nrhjidfs; jUf?

………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
……………………
ii. 1,2,3,4 ,yf;fq;fs; ,lg;gl;l fhgd; mZf;fspd; fyg;ghf;f tiffisj;
jUf.
………………………………………………………………………………………
…..
………………………………………………………………………………………
…..

(c) Fwpj;j xU Nrhjidia nra;tjd; %yk; gpd;tUtdtw;iw vq;fdk;

NtWgLj;jpawpayhk;.

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 OH
ii.
NH2

NH2
i. CONH2 NO2 OH

CH2 CH3
iii. H- C ≡ C- CH3

(d) CH3COCl ,w;Fk; CH3CH2NH2 ,w;FkpilNaahd jhf;fk; nghwpKiwapidj;

jUf.

jhf;fp Nrhjidg;nghUs; tpisT/ tpisTfs;

i……………………………………………………………………………………nghwpKiwtif

CH2CH3………
Fe/Br2
………………………………………………………………………………………
i.
……
ii……………………………………………………………………………………
CH3 – CH -CH
……...
3

Cl2 rk%y;
………………………………………………………………………………………
ii.
……
hv
iii……………………………………………………………………………………
CH2CH2Br
……
mw;fNfhy;
iii. ………………………………………………………………………………………
……KCN
………………………………………………………………………………………………
C- CH3
NH3
………………………………………………………………………………………………
iv.
O
………………………………………………………………………………………………
<jH
………………………………………………………………………………………………
C ≡ C- H
v …………………… Br2/CCl4

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 f)Muk;g Nru;it> Nrhjidg; nghUl;fs; vd;gtw;wpid fPNoAs;s gl;baypy; ,Ue;J

CH3 CH3
khj;jpuk; njupT nra;J CH CH – CH - - C = CH – CH3 vDk;
3 2
NrHitapid vq;fdk; njhFf;fyhk;. jhf;fq;fs; xt;nthU gb khw;wq;fshFk;.

CH3CH2CH2CH2 Br , CH3CH2CH2Br, BrCH2CH2CH2Br, mw;fNfhy;> ngd;rPd;>

<jH> ePH> nrwp HCl , nrwp H2SO4, Al2O3, KOH, nrwp HNO3, Fe, Na, Mg, Zn,
HgSO4, AlCl3, HBr, Br2, CCl4

2
b f

3 7

g
c

4 8
h
d

5 9

6
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