Professional Documents
Culture Documents
1. Scope
1.1 This specification2 covers the requirements for 22
grades of titanium and titanium alloy tubing intended for
surface condensers, evaporators, and heat exchangers, as follows:
1.1.1 Grade 1Unalloyed titanium,
1.1.2 Grade 2Unalloyed titanium,
1.1.3 Grade 3Unalloyed titanium,
1.1.4 Grade 7Unalloyed titanium plus 0.12 to 0.25 %
palladium,
1.1.5 Grade 9Titanium alloy (3 % aluminum, 2.5 % vanadium),
1.1.6 Grade 11Unalloyed titanium plus 0.12 to 0.25 %
palladium,
1.1.7 Grade 12Titanium alloy (0.3 % molybdenum,
0.8 % nickel),
1.1.8 Grade 13Titanium alloy (0.5 % nickel, 0.05 % ruthenium),
1.1.9 Grade 14Titanium alloy (0.5 % nickel, 0.05 % ruthenium),
1.1.10 Grade 15Titanium alloy (0.5 % nickel, 0.05 %
ruthenium),
1.1.11 Grade 16Unalloyed titanium plus 0.04 to 0.08 %
palladium,
1.1.12 Grade 17Unalloyed titanium plus 0.04 to 0.08 %
palladium,
1.1.13 Grade 18Titanium alloy (3 % aluminum, 2.5 %
vanadium) plus 0.04 to 0.08 % palladium,
1.1.14 Grade 26Unalloyed titanium plus 0.08 to 0.14 %
ruthenium,
1.1.15 Grade 27Unalloyed titanium plus 0.08 to 0.14 %
ruthenium,
1.1.16 Grade 28Titanium alloy (3 % aluminum, 2.5 %
vanadium) plus 0.08 to 0.14 % ruthenium,
2. Referenced Documents
2.1 ASTM Standards: 3
A 370 Test Methods and Definitions for Mechanical Testing
of Steel Products
E 8 Test Methods for Tension Testing of Metallic Materials
E 29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
E 120 Test Methods for Chemical Analysis of Titanium and
Titanium Alloys
E 1409 Test Method for Determination of Oxygen in Titanium and Titanium Alloys by the Inert Gas Fusion Technique
E 1447 Test Method for Determination of Hydrogen in
Titanium and Titanium Alloys by the Inert Gas Fusion
Thermal Conductivity Method
3. Terminology
3.1 Lot Definitions:
3.1.1 castingsa lot shall consist of all castings produced
from the same pour.
1
This specification is under the jurisdiction of ASTM Committee B10 on
Reactive and Refractory Metals and Alloys and is the direct responsibility of
Subcommittee B10.01 on Titanium.
Current edition approved Nov. 1, 2003. Published November 2003. Originally
approved in 1958. Last previous edition approved in 2002 as B 338 02.
2
For ASME Boiler and Pressure Vessel Code applications, see related Specification SB-338 in Section II of that Code.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standards Document Summary page on
the ASTM website.
Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
B 338 03
3.1.2 ingotno definition required.
3.1.3 rounds, flats, tubes, and wrought powder metallurgical
products (single definition, common to nuclear and nonnuclear standards.) a lot shall consist of a material of the
same size, shape, condition, and finish produced from the same
ingot or powder blend by the same reduction schedule and the
same heat treatment parameters. Unless otherwise agreed
Grade 1
Grade 2
Grade 3
Grade 7
Grade 9
Grade 11
Grade 12
0.03
0.08
0.015
0.20
0.18
...
...
...
...
...
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
...
...
...
...
...
...
...
...
...
0.1
0.05
0.08
0.015
0.30
0.35
...
...
...
...
...
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
...
0.120.25
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.25
0.15
2.53.5
2.03.0
...
...
...
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.20
0.18
...
...
...
...
0.120.25
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
...
...
...
0.20.4
...
0.60.9
...
...
...
0.1
0.4
0.4
0.4
0.4
0.4
0.4
0.4
balance
balance
balance
balance
balance
balance
balance
Composition, %
Element
Nitrogen, max
Carbon, max
Hydrogen,B,C max
Iron, max
Oxygen, max
Aluminum
Vanadium
Tin
Ruthenium
Palladium
Cobalt
Molybdenum
Chromium
Nickel
Niobium
Zirconium
Silicon
Residuals,D,E,F max
each
Residuals,D,E,F max
total
TitaniumG
Grade 13
Grade 14
Grade 15
Grade 16
Grade 17
Grade 18
Grade 26
0.03
0.08
0.015
0.20
0.10
...
...
...
0.040.06
...
...
...
...
0.40.6
...
...
...
0.1
0.03
0.08
0.015
0.30
0.15
...
...
...
0.040.06
...
...
...
...
0.40.6
...
...
...
0.1
0.05
0.08
0.015
0.30
0.25
...
...
...
0.040.06
...
...
...
...
0.40.6
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
...
0.040.08
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.20
0.18
...
...
...
...
0.040.08
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.25
0.15
2.53.5
2.03.0
...
...
0.040.08
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
0.080.14
...
...
...
...
...
...
...
...
0.1
0.4
0.4
0.4
0.4
0.4
0.4
0.4
balance
balance
balance
balance
balance
balance
balance
B 338 03
TABLE 1 Continued
Element
Nitrogen, max
Carbon, max
Hydrogen,B,C max
Iron, max or range
Oxygen, max
Aluminum
Vanadium
Tin
Ruthenium
Palladium
Cobalt
Molybdenum
Chromium
Nickel
Niobium
Zirconium
Silicon
Residuals,D,E,F max
each
Residuals,D,E,F max
total
TitaniumG
Grade 27
Grade 28
Grade 30
Grade 31
Grade 33
Grade 34
Grade 35
Grade 36
0.03
0.08
0.015
0.20
0.18
...
...
...
0.080.14
...
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.25
0.15
2.53.5
2.03.0
...
0.080.14
...
...
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
...
0.040.08
0.200.80
...
...
...
...
...
...
0.1
0.05
0.08
0.015
0.30
0.35
...
...
...
...
0.040.08
0.200.80
...
...
...
...
...
...
0.1
0.03
0.08
0.015
0.30
0.25
...
...
...
0.02-0.04
0.01-0.02
...
...
0.1-0.2
0.35-0.55
...
...
...
0.1
0.05
0.08
0.015
0.30
0.35
...
...
...
0.02-0.04
0.01-0.02
...
...
0.1-0.2
0.35-0.55
...
...
...
0.1
0.05
0.08
0.015
0.20-0.80
0.25
4.0-5.0
1.1-2.1
...
...
...
...
1.5-2.5
...
...
...
...
0.20-0.40
0.1
0.03
0.04
0.0035
0.03
0.16
...
...
...
...
...
...
...
...
...
42.047.0
...
...
0.1
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
balance
balance
balance
balance
Remainder
Remainder
Remainder
Remainder
A
Analysis shall be completed for all elements listed in this table for each grade. The analysis results for the elements not quantified in the table need not be reported
unless the concentration level is greater than 0.1 % each or 0.4 % total.
B
Lower hydrogen may be obtained by negotiation with the manufacturer.
C
Final product analysis.
D
Need not be reported.
E
A residual is an element present in a metal or an alloy in small quantities and is inherent to the manufacturing process but not added intentionally. In titanium these
elements include aluminum, vanadium, tin, chromium, molybdenum, niobium, zirconium, hafnium, bismuth, ruthenium, palladium, yttrium, copper, silicon, cobalt, tantalum,
nickel, boron, manganese, and tungsten.
F
The purchaser may, in his written purchase order, request analysis for specific residual elements not listed in this specification.
G
The percentage of titanium is determined by difference.
4. Ordering Information
Element
Aluminum
Carbon
Chromium
30Cobalt
Hydrogen
Iron
Molybdenum
Molybdenum
Nickel
Niobium
Nitrogen
Oxygen
Oxygen
Palladium
Palladium
Ruthenium
Ruthenium
Ruthenium
Silicon
Vanadium
ResidualsA (each)
Maximum or
Specified Range
2.5 to 3.5
0.10
0.1 to 0.2
0.2 to 0.8
0.015
0.80
0.2 to 0.4
1.5 to 4.5
0.3 to 0.9
>30
0.05
0.30
0.31 to 0.40
0.01 to 0.02
0.04 to 0.25
0.02 to 0.04
0.04 to 0.06
0.08 to 0.14
0.06 to 0.40
2.0 to 3.0
0.1
Permissible Variation
in Product Analysis
60.40
+0.02
60.02
60.05
+0.002
+0.15
60.03
60.20
60.05
60.50
+0.02
+0.03
60.04
60.002
60.02
60.005
60.005
60.01
60.02
60.15
+0.02
A
A residual is an element present in a metal or an alloy in small quantities
inherent to the manufacturing process but not added intentionally. In titanium these
elements include aluminum, vanadium, tin, iron, chromium, molybdenum, niobium,
zirconium, hafnium, bismuth, ruthenium, palladium, yttrium, copper, silicon, cobalt,
tantalum, nickel, boron, manganese, and tungsten.
B 338 03
TABLE 3 Tensile Requirements
Tensile Strength, min
ksi
MPa
ksi
MPa
Elongation
in
2 in. or 50
mm,
min, %
25
40
55
40
105
70
25
50
25
40
55
40
25
105
70
40
25
70
40
55
40
55
120
60
170
275
380
275
725
483
170
345
170
275
380
275
170
725
483
275
170
483
275
380
275
380
828
410
45
65
80
65
...
...
45
...
...
...
...
65
45
...
...
65
45
...
65
80
65
80
...
95
310
450
550
450
...
...
310
...
...
...
...
450
310
...
...
450
310
...
450
550
450
550
...
655
24
20
18
20
10
15C
24
18C
24
20
18
20
24
10
15C
20
24
15
20
18
20
18
5
10
min
Grade
ksi
A
1
2A
3A
7A
9B
9A
11A
12A
13A
14A
15A
16A
17A
18B
18A
26
27
28
30
31
33
34
35
36
35
50
65
50
125
90
35
70
40
60
70
50
35
125
90
50
35
90
50
65
50
65
130
65
max
MPa
240
345
450
345
860
620
240
483
275
410
483
345
240
860
620
345
240
620
345
450
345
450
895
450
7. Product Analysis
7.1 When requested by the purchaser and stated in the
purchase order, product analysis for any elements listed in
Table 1 shall be made on the completed product.
7.1.1 Elements other than those listed in Table 1 are deemed
to be capable of occurring in the grades listed in Table 1 by, and
only by way of, unregulated or unanalyzed scrap additions to
the ingot melt. Therefore, product analysis for elements not
listed in Table 1 shall not be required unless specified and shall
be considered to be in excess of the intent of this specification.
7.2 Product analysis tolerances, listed in Table 2, do not
broaden the specified heat analysis requirements, but cover
variations between different laboratories in the measurement of
chemical content. The manufacturer shall not ship the finished
product that is outside the limits specified in Table 1 for the
applicable grade.
8. Tensile Requirements
8.1 The room temperature tensile properties of the tube in
the condition normally supplied shall conform to the requirements prescribed in Table 3. Mechanical properties for conditions other than those given in this table may be established by
agreement between the manufacturer and the purchaser. (See
Test Methods E 8.)
6. Chemical Requirements
6.1 The titanium shall conform to the chemical requirements prescribed in Table 1.
6.1.1 The elements listed in Table 1 are intentional alloy
additions or elements that are inherent to the manufacture of
titanium sponge, ingot, or mill product.
6.1.2 Elements intentionally added to the melt must be
identified, analyzed, and reported in the chemical analysis.
6.2 When agreed upon by the producer and the purchaser
and requested by the purchaser in the written purchase order,
9. Flattening Test
9.1 Tubing shall withstand, without cracking, flattening
under a load applied gradually at room temperature until the
4
B 338 03
TABLE 4 Flaring Requirements
Grade
(1)
1
2
3
7
9A
11
12
13
14
15
16
17
18A
26
27
28A
30
31
33
34
35
where:
H = the minimum flattened height, in. (mm),
t = the nominal wall thickness, in. (mm), and
D = the nominal tube diameter, in. (mm).
For Grades 1, 2, 7, 11, 13, 14, 16, 17, 26, 27, 30, and 33:
e 5 0.07 in. for all diameters
(2)
(3)
(4)
Annealed.
B 338 03
TABLE 5 Permissible Variations in Outside Dimensions Based
on Individual Measurements
Outside Diameter, in. (mm)
Under 1 (25.4), excl
1 to 112 (25.4 to 38.1), excl
112 to 2 (38.1 to 50.8), excl
2 to 212 (50.8 to 63.5), excl
212 to 312 (63.5 to 88.9), excl
Diameter
Tolerance,
in. (mm)A
60.004
60.005
60.006
60.007
60.010
(60.102)
(60.127)
(60.152)
(60.178)
(60.254)
TABLE 6 Straightness
Length, ft (m)
Permissible
VariationsB in
Wall Thickness, t, %
Over
Over
Over
Over
610
610
610
610
610
3 16
14
A
These permissible variations in outside diameter apply only to tubes as
finished at the mill before subsequent swaging, expanding, bending, polishing, or
other fabricating operations.
B
When minimum wall tubes are ordered, tolerances are all plus and shall be
double the values shown.
SEt
P 5 R 2 0.4t
o
Maximum Curvature
Depth of Arc
(5)
where:
P = minimum hydrostatic test pressure, psi (or MPa),
S = allowable fiber stress of one half the minimum yield
strength, psi (or MPa),
t
= wall thickness, in. (or mm),
Ro = outside tube radius, in. (or mm),
E = 0.85 welded tube, and
E = 1.0 seamless and welded/cold worked tube.
11.3.2 The maximum hydrostatic test pressure shall not
exceed 2500 psi (17.2 MPa) for sizes 3 in. (76 mm) and under,
or 2800 psi (19.3 MPa) for sizes over 3 in. Hydrostatic pressure
shall be maintained for not less than 5 s. When requested by the
purchaser and so stated in the order, tube in sizes 14 in. (356
mm) in diameter and smaller shall be tested to one and one half
times the specified working pressure, provided the fiber stress
corresponding to those test pressures does not exceed one half
the minimum specified yield strength of the material as
determined by the equation given in 11.3. When one and one
half times the working pressure exceeds 2800 psi (19.3 MPa),
the hydrostatic test pressure shall be a matter of agreement
between the manufacturer and purchaser.
11.4 Pneumatic Test Each tube so tested shall withstand
an internal air pressure of 100 psi (0.69 MPa), minimum, for 5
s, minimum, without showing evidence of leakage. The test
method used shall permit easy detection of any leakage by
using the pressure differential method or by placing the tube
under water. Any evidence of leakage shall be cause for
rejection of that tube.
13. Finish
13.1 The finished tube shall be clean and free of foreign
material, shall have smooth ends free of burrs, and shall be free
of injurious external and internal imperfections. Minor defects
may be removed, provided the dimensional tolerances of
Section 12 are not exceeded.
14. Number of Tests
14.1 One sample shall be selected from lots of 5000 ft (1600
m) or less. For lots greater than 5000 ft (1600 m), one sample
shall be selected from the first 5000 ft (1600 m), and one
additional sample shall be selected from each additional 5000
ft (1600 m) or less in the lot. Samples are to be selected at
random, and in no case shall more than one sample be taken
from a single tube length. The size of the lot may be either the
manufactured lot or the purchased lot at the manufacturers
option.
14.1.1 Chemical composition of the lot shall be the ingot
manufacturers analysis, except for hydrogen, which shall be
determined on each sample from the lot.
14.1.2 One tension test shall be made on each sample.
14.1.3 One flattening test in accordance with 9.1 shall be
made on each sample.
B 338 03
for acceptance of the material. Otherwise, the manufacturer
shall report to the purchaser or his representative the results of
the chemical analyses and mechanical tests made in accordance
with this specification.
15. Retests
15.1 If the results of any chemical or mechanical property
test lot are not in conformance with the requirements of this
specification, the lot may be retested at the option of the
manufacturer. The frequency of the retest will double the initial
number of tests. If the results of the retest conform to the
specification, the retest values will become the test values for
certification. Only original conforming test results or the
conforming retest results shall be reported to the purchaser. If
the results for the retest fail to conform to the specification, the
material will be rejected in accordance with Section 20.
20. Rejection
20.1 Material not conforming to this specification or to
authorized modifications shall be subject to rejection. Unless
otherwise specified, rejected material may be returned to the
manufacturer at the manufacturers expense, unless the purchaser receives within 3 weeks of notice of rejection other
instructions for disposition.
21. Certification
21.1 If so requested by the purchaser, the manufacturer shall
supply at least one copy of his report certifying that the
material supplied has been inspected and tested in accordance
with the requirements of this specification and that the results
of chemical analysis and mechanical tests meet the requirements of this specification for the appropriate grade.
22. Product Marking
22.1 Each length of tube 12 in. (13 mm) in outside diameter
and larger, manufactured in accordance with this specification,
shall be legibly marked, either by stenciling, stamping, or
rolling, with the manufacturers private identifying mark, the
ASTM designation, the tube class, the grade, and heat number.
On smaller than 12 in. outside diameter tubing that is bundled,
the same information may be legibly stamped on a metal tag
securely attached to each bundle.
17. Inspection
17.1 All tests and inspection required by this specification
shall be made at the place of manufacture prior to shipment and
at the manufacturers expense unless otherwise specified, and
shall be so conducted as not to interfere unnecessarily with the
operation of the works. When specified in the order, the
manufacturer shall notify the purchaser in time so that the
purchaser may have his inspector present to witness any part of
the tests that may be desired.
17.2 When agreed upon in writing between the manufacturer and the purchaser, a certification that the material conforms to the requirements of this specification shall be the basis
B 338 03
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