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07 FinalReport PDF
07 FinalReport PDF
By Team #7:
Larae Baker
Maxine Bent
Jonathan Bush
Mike Heslinga
Adam Jones
Table of Contents
1
INTRODUCTION..................................................................................................... 4
ALKYLATION ....................................................................................................... 4
DEHYDROGENATION ............................................................................................ 6
POLYMERIZATION ................................................................................................ 7
OBJECTIVES ........................................................................................................... 8
1 Introduction
Styrene is a precursor to many polymer products such as polystyrene, acrylonitile
butadiene styrene (ABS), styrene-acrylonitrile, and various styrene-butadiene
products. These materials are used around the world in a variety of ways including
food storage, packaging, and automobile parts.1 The market for styrenics has seen
overall growth in the previous decade despite a recent down year. The market is
expected to recover and see large gains in the near future. Therefore, now is an
excellent time to join the market, particularly if current styrene production cannot
meet future demand.2
The process of producing styrene is well established. It was first produced in the
1930s by I. G. Farben in Germay and Dow Chemical in the United States. Styrene
is a clear liquid at room temperature with an aromatic odor. It is currently sold with
a minimum purity of 99.8% but is more commonly produced at 99.93%. The price
of styrene remains largely dependant on the cost of its raw materials.3
2 The Chemistry
Production of styrene requires two reactions, an alkylation and a dehydrogenation.
2.1 Alkylation
The alkylation is a basic Friedl-Crafts alkylation, where ethylene reacts with benzene
to form ethylbenzene by Reaction 1a:3
(Rxn 1a)
This reaction is exothermic and takes place in a distillation reactor system that is
partially packed with catalyst. The benzene is in vapor-liquid equilibrium and it is
alkylated as it passes through the catalyst.4 This alkylated product has a lower
boiling point than benzene and will therefore become the distillate product in the
column. The catalyst is a molecular sieve known as EBZ-500S available through
UOP, LLC. EBZ-500S minimizes the amount of byproduct, such as polyaklylated
and oligomerized products.5 The polyalkylated products that are formed come off in
the bottoms of the distillation. They are sent to a transalkylation reactor to be
converted back to ethylbenzene by Reaction 1b:
(Rxn 1b)
The catalyst in this reaction is EBZ-100, also available through UOP, LLC.
Oligomerization products are caused by the partial polymerization of ethylene.
These may either come off the top of the column or aklylate with benzene to form
byproducts that include cumene, n-propylbenzene, butylbenzenes as well as other
heavy alkybenzenes. Other byproducts come from the raw materials; for example,
toluene and C6 non-aromatics can be present in the benzene feedstock, up to
1000ppm and 2000ppm respectively. These can also be alkylated, and leave as a
bottoms product.3
2.2 Dehydrogenation
The dehydrogenation occurs in a fluidized catalyst cracking reactor, or FCC.6 An
FCC was chosen over other reactor systems because it has the advantage of
continuous catalyst regeneration. The catalyst is comprised of gallium oxide
(Ga2O3), platinum, iron oxide (Fe2O3), potassium oxide (K2O) and silica suspended
on alumina.7 It is unique in that is used to simultaneously dehydrogenate ethane and
ethylbenzene via reactions 2a and 2b:
H2
(Rxn 2a)
H2
(Rxn 2b)
These reactions are highly endothermic. The energy for the reaction is provided by
the catalyst in the regeneration reactor, where it is heated to 660C upon decoking.
The catalyst needs to be decoked continuously because two side reactions occur that
form toluene, benzene and coke, as shown in Reactions 2c and 2d:
Coke
(Rxn 2c)
Coke
(Rxn 2d)
The coke deposits on the catalyst, reducing the number of active sites, and thus
lowering the conversion of the desired reactions, 2a and 2b.8 Toluene can also lose
another carbon to become benzene. These reactions account for total of 3% loss in
conversion.3 Reactions 2a and 2b are also highly selective with 90-94% and 90-93%
selectivities respectively.9
2.3 Polymerization
Under the right conditions styrene can polymerize violently. This is an exothermic
reaction; therefore, once polymerization begins it can escalate out of control.3
Polymerization is most likely to occur in the purification and storage phases of
production. Inhibitors are necessary to prevent this. For the storage tanks 4-tert-
3 Objectives
The following objectives were satisfied in the design:
1.) To design a plant with the capacity to produce styrene monomer at a rate of 2.2
billion lbs/yr with a purity at or above the industrial standard of 99.93 wt%
2.) To analyze the design to determine whether it is economically competitive at the
average market price over the past three years
3.) To develop the design with the following design norms in mind:
a. Justice and caring Design decisions were made that consider the rights
and needs of all stakeholders, even those seemingly unaffected by the
plant. If styrene products can be made available to more people at a
lower cost, people of a wider economic range might be able to benefit
more from this product.
b. Trustworthy People living around this plant need to trust that they will
be safe, even in the case of an accident. Customers need to be able to
trust the operators of the plant to have the amount of styrene promised at
the specification needed. Customers rely on knowing that the process
will not only run continuously, but also at the required purity.
c. Stewardship Caring for the earth and all that is in it was a key motivator
in designing a chemical processing plant. Making sure that the plant is
optimized to not have more adverse affects on the environment than is
necessary and also being sure that none of our starting materials go to
waste, but are used to their fullest potential. Additionally, optimized
equipment allows the plant to operate using the less energy than nonoptimized.
4.) To simulate the design using HYSYS
5.) To choose a suitable location for the plant to be built
6.) To determine the design specifications on the following pieces of process
equipment: compressors, turbines, pumps, heat exchangers, distillation columns
and reactors.
4 Process Description
The process to synthesize styrene monomer from ethane and benzene can be
simplified to four stages: alkylation, dehydrogenation, light gas separations, and
separations of aromatic products. However, starting with different raw materials
would lead to different designs.
This reactor design has several advantages over the more industrially common
packed bed reactor:4
1.) High conversion of ethylene is controlled by having a 10:1 ratio of benzene to
ethylene and sufficiently large height of packed catalyst. This minimization of
unreacted ethylene reduces separation and recovery problems.
2.) The benzene that comes off the reactor as the distillate is recycled back to the
reactor feed. A purge is added so that very light gasses do not accumulate. Only
the benzene that has reacted leaves the distillation reactor.
3.) The continued removal of the alkylated and polyakylated products forces the
chemistry in Reaction 1a to favor the products. This also minimizes both the
polysubstitution and decomposition of the product.
4.) Because the compounds in the distillation reactor are boiling, the temperature at
which the reaction takes place is controlled by the boiling point of the mixture.
This has the further advantage that as the exothermic alkylation takes place the
reaction enthalpy increases the boil-up.
5.) The rate of reaction and distribution can be well controlled by regulating the
system pressure. Thus, upon piloting this process, the distillation reactor
efficiency can be increased significantly.
6.) Two stages are condensed into one; the first stage would consist of the reaction
of benzene and ethylene to ethylbenzene. The second would be the separation of
benzene from ethylbenzene. These two processes occur in one distillation
reactor.
The bottom products from the distillation reactor are then sent to a distillation
column, where the polyalkylated benzenes (mostly di- and tri- ethylbenzene) are
separated from ethylbenzene. This design achieves a purity of 99.78 mol%
ethylbenzene in the distillate. The bottoms product is entirely byproducts. The
polyalkylated benzenes, along with the heavier impurities, are sent to a
transalkylation reactor where reaction 1b occurs. The transalkylation unit is a
packed bed reactor. In the presence of more benzene, the formation of ethylbenzene
from the polyalkylated benzenes is favored.3 The unconverted polyalkylbenzenes
are then recycled to distillation column T-100. The 99.78 mol% pure ethylbenzene
is sent on to the dehydrogenation.
the catalyst stripper, absorbed hydrocarbons leave the catalyst particles. The catalyst
falls to the bottom of the stripping trays and is sent to regenerator R-201.16
In the regenerator the coke deposited on the catalyst is burned off via air at 560C,
producing carbon-dioxide. Hydrogen, recycled from Area-400, also enters R-201
and is combusted to produce water. By this process, the catalyst is heated to 680C
and transported back to R-200. The high temperature of the catalyst provides the
heat of reaction for Reaction 2a and 2b to occur. There are several reasons to use a
reactor-regenerator system:7
1.) The catalyst is continually regenerated. By continually removing coke the
catalyst will not degrade over time. This means the operating parameters and
catalyst performance will be constant for the lifetime of the plant.
2.) The heat for Reactions 2a and 2b are provided by the catalyst, thus super-heating
ovens are not needed.
3.) The re-mixing of the fluidized bed prevents hot spots from forming, which would
lower selectivity.
4.) The hydrogen can be recycled to R-201, where it is burned.
5.) The process can be made continuous without changing the operating parameters
of the plant over its lifetime.
6.) R-200 and R-201 are physically separate. This disallows mixing between the
hydrocarbons and any oxygen, an inherent process danger.
7.) Less inert gas needs to be used in the feeding to the reactor, thus higher
concentrations of the reactants can be used, which lead to higher reaction
selectivites.
Styrene
Ethane
250
200
g/h/kgcat
y = 498.18x-0.6678
R 2 = 0.9967
150
100
50
y = 17.28x0.5396
R 2 = 0.9996
0
0
10
Ethane/EB vol
12
The catalyst for the selective combustion of hydrogen is available through UOP and
is OC-5. It is a solid sphere with a nominal diameter of 3.8mm and a density of
750 kg/m3.17 OC-5 uses platinum as a promoter and is available at $115 per
pound.12
The column operates at vacuum conditions with a pressure of 26.7 kPa. It contains
66 stages, with the feed entering in the 50th stage. The diameter is 2.04m and its
height is 40.23m. The reflux ratio is optimized at 12:1. The distillate product is rich
in toluene (49.6 mol%) and benzene (49.1 mol%), with some n-hexane (1.2 mol%)
and the remainder ethylbenzene (0.1 mol%). These products are sent to column T301.
In T-301, a column of 23 trays, toluene is purified and leaves as the bottoms product.
It has a purity of 99.8% toluene, which is then to spot sold as high-grade toluene. T301 is a sieve-tray column with a diameter of 2.04m (6.7ft) and a height of 14.02m
(46ft). Sieve trays are used because polymerization in not a concern, and is less
expensive. The operating pressure is 26.7 kPa. The reflux ratio is optimized at 3.4:1
and the optimum feed inlet is tray ten. The distillate is mainly benzene, with some
non-aromatic impurities. It is then sent to column T-302 for further separation.
The bottoms product from column T-300 contains ethylbenzene (49.4 mol%),
styrene (50.4 mol%), the toluene (0.17 mol%) and the remainder heavy aromatic
byproducts. These are sent to column T-303, where the ethylbenzene is separated off
the top to be recycled to Area-200. Like T-300, this column uses Flexipac HC to
reduce pressure drop across the column. T-303 is 72 stages, with an optimum feed
inlet at stage 48 and optimum reflux ratio of 10:1. To further reduce operating
temperatures, and thus the possibility of polymerization, the pressure is decreased to
7.99 kPa. The diameter of T-303 is 5.33m and the height is 43.89m.
The remainder of the styrene product is then sent to T-304, where it is then purified.
Column T-304 incorporates the same packing as previously mentioned above the
feed inlet, and trays in the stages below the feed inlet. The advantage to designing a
hybrid column like this is due to some of the styrene monomer beginning to
polymerize. If any styrene polymerizes enough to form a solid within the column
then it will deposit onto the tray. Occasionally the column will need to be opened
and the trays cleaned to remove any solid polymer residue. This is easy to do with a
sieve tray and very difficult with packing. Since the highest temperatures are in the
reboiler, the polymers are most likely to form at the bottom of the column, on the
sieve trays. T-304 operates at a lower pressure (5.33 kPa) than column T-303. It has
a height of 27.4m and a diameter of 5.2m. The optimum reflux ratio is 0.75:1. The
total number of trays is 45 and the feed enters on the 24th tray. The bottoms product
is then further purified in T-305. The distillate is purified styrene and is sent to
storage or to the customer.
Column T-305 has a similar design to T-304. It is another hybrid column with
structured packing from stages one to fifteen and sieve trays from sixteen to the last
tray, thirty. It operates at 5.33 kPa, with a height of 18.3m and a diameter of 3.3m
(10.9ft). The optimum reflux ratio is 1.29:1. The bottoms product is sent to column
T-306. The distillate joins with the distillate from T-304 and goes to storage and for
sale.
The final column in Area-300 is T-306. It has the same dimensions as T-305 and
same tray design. The only difference is that it operates with a reflux ratio of 15:1.
The distillate product in columns T-304, T-305 and T-306 are mixed to produce the
final styrene product available at a purity of 99.93 wt% styrene. The bottom
products of T-306 are the heavy side-products. They are mixed with the heavy
byproducts from the alkylation and sent to be incinerated.
After removal of the 2,4-dinitrophenol, but before storage, the inhibitor 4-TBC is
mixed into the styrene product stream. It stops polymerization by interacting with
the free radicals formed in the initiation step of the polymerization mechanism. In
the storage tanks, oxygen is bubbled through the tank to activate the 4-TBC. The
styrene product is sent to customers with the 4-TBC present. Customers remove it
by adsorption when polymerization is desired.
correctly model an isoentropic expansion for this case. If throttling valves were used
a cost reduction could be seen in both the equipment savings and in the compressor
duty. Because the turbine is not 100% efficient, some of the enthalpy of expanding
the gas goes to entropy, which must be made up by the compressors. The two-phase
separators operate at a range of temperatures from -68.5C in the first stage to
-168.2C in the last stage. The temperatures after compression get as high as 42C.
Three streams leave Area-400. The first is the bottoms product of the first two phase
separator and consists of mostly styrene, ethylbenzene, and other aromatics. The
second is the distillate recovered after ten two-phase separators. At -159.4C, it is
comprised of 64.9 mol% nitrogen, 34.9% hydrogen, and the remainder ethane and
ethylene. This stream is sent to Area-200 and is burned in R-201 to provide heat for
the reaction. The third stream is the mixture of the bottoms of each two-phase
separator, and is rich in ethane and ethylene at 90.0 mol% and 9.98 mol%
respectively. This stream is fed to Area-100 and supplies the ethylene feed for
Reaction 1a. Area-400 is the most expensive area in the process.
Equation 1
where q is the total heat transferred, U the overall heat transfer coefficient, Tlm is
the log-mean temperature difference, and A is the area used for exchanger design.
The overall heat transfer coefficient is estimated from design tables provided by
Peters, Timmerhaus and West.18 Water is the coolant for streams needing to be
cooled down to 15C. It is used in the condensers in Area-300 and on exchanger E202.1. The coolant, R-22, is available to -60C and is primarily used in Area-400.19
The reboilers in Area-300 use exhaust steam available at 150 kPa and 109.95C for
heating the product streams. However, one exchanger uses saturated steam at 3550
kPa and 243.38C. Area-300 accounts for a total of sixteen exchangers. Area-400
uses thirty exchangers for interstage cooling after compression. Eleven exchangers
are used in Area-100 and ten exchangers are used in Area-200. The pressure drop
across the tube and shell side of each exchanger can be calculated. An example
calculation can be seen in Appendix E.1. The pressure drops were also increased to
account for losses due to piping and to ensure that estimates are on the conservative
side. The specifications on each exchanger can be seen in Appendix A.2. The cost
is a function of exchanger area and duty of the coolant or steam.
each compression chain was the sum of the compressor and heat exchanger costs
annualized over twenty years.
There are ten turbines in the process; all of which are used in Area-400. Each
turbine is 85% efficient and used to cool the vapor into the two phase region. The
cost on each turbine is determined from the material of construction, size and duty.
There are four pumps needed in the process. They are on the benzene feed to Area100, benzene recycle from Area-400 to Area-100, and the toluene and styrene
products from Area 300. The cost of each pump is determined from its material of
construction, capacity, duty and pressure. Calculations and specifications for each
compressor, turbine and pump can be seen in Appendices A.1, A.6 and A.3,
respectively.
again until Area-300 and cannot be used at all in Area-400. The materials of
construction greatly effect equipment cost. Therefore, whenever possible carbon
steel is used instead of stainless steel.
year.21 The designed process produces the equivalent amount of 5750 Americans in
one production year. This is a weakness of the design, and would need to be reduced
before implementation.
The other byproducts consist of heavy hydrocarbons. These are incinerated when
possible and treated when they cannot be incinerated. The modeling of this process,
and the reactions that govern it, is also beyond the scope of the design. Water
generated from the combustion of hydrogen in T-202 is sent for treatment as well.
The significant benefit to the process is that the dehydrogenation reactions (2a and
2b) occur simultaneously. Thus the designs for ethane to ethylene and ethylbenzene
to styrene plants are incorporated into one design. This is evidenced by the need for
two separations process, Area-300 and Area-400. A possible pollution reduction can
be accomplished by incorporating two plants into one. An in depth analysis of this
hypothesis is beyond the scope of the design.
when costing equipment. The flammability of each stream is also taken into
consideration. The only streams with oxygen present enter regenerator R-201. The
oxygen is consumed in the reaction. All other streams operate well above the upper
flammability limits. Using pressure, temperature, level, and flow controllers the
streams can be kept within the designated safety ranges.
6 Control Design
Whatever can be controlled in the process should be controlled.27 Controls are vital
to the safety of a process and are, therefore, incorporated in the design to converge
the real-world variables to the design variables. They are designed to check for
unsteady states, minimize the occurrence of unsteady states, and then correct the
problem. As such, the time lag between the occurrence of a problem and the
correction needs to be minimized. This is done by placing controls where they can
have the fastest impact.
under constant production conditions and not vary with market demand or equipment
failure. R-100 has a flow controller on the condenser, which affects the ethane going
to Area-200. Column T-100 has two level controls; one on the reboiler and
condenser each. The bottoms of T-100 are sent to R-101, but with a flow control on
the purge stream. Like the benzene inlet control on R-100, this control varies the
polyalkylated benzene feed to keep its ratio with benzene constant.
The air feed to Area-200 has a flow controller across a gate valve and then a pressure
controller on compressor K-201. This stream is heated by the product from T-201,
thus a flow controlled bypass is used to control the temperature of this stream. Its
is to set the reflux ratio, which should be converged to the designed optimum reflux
ratio. Lastly, a flow controller controls how much reflux is sent back to T-300.
Since this is the first column in the distillation chain, it may be tempting to put two
temperature controllers on the column, each one to specify the composition on either
end. However, studies have shown that this creates many problems because the two
controllers are not mutually exclusive. One controller can interfere with the other
based on how much it tries to control the exchanger duty. Using only one
temperature controller is easier and still does a good job.
Columns T-301, T-302, and T-303 are designed in a similar manner, with six
controllers per column used to control the composition, pressure and reflux ratio.
For each of these columns, the reflux ratio is greater than one, and so the gate valve
for the level control on the condenser is positioned on the product stream. When the
reflux ratio is less than one, then the level control is on the condenser coolant, as
with T-304 and T-305. The flow control is on the product stream, and another flow
control manages the reboiler steam. A level control operates a gate valve on the
bottoms product. T-306 has a reflux ratio above 1, so there is a level control on the
distillate, and flow control on the reflux. However, the bottoms are designed with
the level control on the product stream, and the flow control on the reboiler steam.
The mixed styrene product stream is then sent to storage. There is a flow control on
this final stream.
7 Economic Analysis
Capital, utility and raw material costs along with revenue from the products
determine the profitability of the design. The purchase and installation of
equipment, land and piping affect the capital cost. Of these, the largest contributor to
the capital cost is from the equipment. This is priced according the cost spreadsheets
available from Peters, Timmerhaus and West. Direct costs, indirect costs, and
working capital affect the total capital investment. A few direct costs are the
purchased equipment, delivery, installation, piping and instrumentation costs.
Indirect costs are things like construction and legal expenses, engineering and
supervision, contractor fees, and contingency costs. Working capital is the cash on
hand needed to start the plant. The total capital investment is 2,508.7 million dollars.
Raw material costs are from ethane, benzene, air, OC-5, EBZ-100, EBZ-500S, TBC,
and DNP. The annual cost of all raw materials is 731.5 million dollars. Electricity,
refrigeration, steam, water treatment, and cooling water usage determine utility costs.
The total is 197.8 million dollars per year. The revenue generated from the products
styrene and toluene is 1,976.2 million dollars per year. The selling price for styrene
is $0.99 per pound. The variable costs consist of raw material costs, utilities and
general expenses; projected at 1,084 million dollars per year. The fixed costs include
fixed charges, plant overhead and general expenses; and are 297.7 million dollars per
year.18
The price for the styrene is chosen by varying the Investors Rate of Return (IRR). If
the IRR is set to 15.0%, the price of styrene is $0.99 per pound as shown in Figure 1:
IRR Analysis - Product Price Fluctuation
35.0%
30.0%
25.0%
IRR
20.0%
15.0%
10.0%
5.0%
0.0%
$0.70
$0.80
$0.90
$1.00
$1.10
$1.20
$1.30
-5.0%
Styrene Monomer Product Price ($/lb)
15.0% IRR is a common value and a good starting point.28 The Net Present Value
for this IRR is 1.99 million dollars, which is basically zero when compared to the
high capital costs. Equation 2 can be used to solve for the IRR:
0=
i=0
CFi
(1 + IRR) i
(Equation 2)
$1.40
The return on investment (ROI) stabilizes after the sixth production year, where it is
15.4% for the lifetime of the plant.
In HYSYS, the design was simulated using the General NRTL fluid package. The
NRTL is a local-composition thermodynamic model, and therefore, analyzes the
system according to its molecular interactions.
9 Future Work
Broadening the scope of the design would lead to the possibility to do a lot of further
work. Some of the most important work could be done to minimize pollutants. The
current design produces 33,098,000 kg/hr of carbon dioxide. This amount needs to
be reduced. Public opinion of processes that produce greenhouse gases is
continually becoming more negative. In order to be good stewards, the amount of
pollutants placed in the atmosphere must be reduced. To do this analysis, a
simulation of the combustion and side reactions should be done in HYSYS. A way
to model the formation of carbon monoxide would make the simulation more
realistic. This leads to stack scrubbing costs having an impact on the economic
analysis because the costs associated with the treatment of this gas can rise quickly.
Too much carbon monoxide production (or inadequate smokestack design) would
lead to fines from the EPA.
The fluidized catalyst cracking reactor could be designed with greater detail. If a
kinetic model could be developed and then used to design the various parameters of
the reactor, then the estimates on the reactor size could be improved. This would
help in pricing the reactor system. The reactor price is currently an educated
estimate. A more accurate price would improve the economic analysis as a whole.
FCC simulation software is also available. This would help because interpolated
values in the patents do not account for catalyst degradation. In fact, the values in
the patents are for a very specific system, using a specific catalyst and reactor set-up.
Any method for further modeling the FCC system that allows these parameters to
change would only improve the simulation.
The computer simulation software, HYSYS, can simulate processes which involve
solids. However, the HYSYS software used for this design does not have this
license available. A solid modeling license would allow the catalyst regeneration
step to be simulated, thus making the simulation more realistic. Filters that remove
solid catalyst particles from the regeneration product stream could also be simulated.
A better estimate of the pressure drop across a filter could be determined. Currently,
a valve simulates the pressure drop across a filter in HYSYS.
The HYSYS simulation also has another problem: it cannot model throttling valves.
Therefore, the designed process used expanders that were 85% efficient. Since this
caused a loss of energy and increased equipment costs, the turbines are far less
favorable than throttling valves.
There are sixty-six heat exchangers used in the process. The overall heat transfer
coefficients for each exchanger could be improved. Currently, all heat transfer
values are estimated using Peters, Timmerhaus and West, which gives a range of 250
to 600 W/m2K for medium organics cooled with water, and a range of 250 to 500
W/m2K for medium organics heated with steam.18 These temperature ranges can
vary the exchanger area significantly. Because the components are generalized and
the heat transfer coefficient given a broad range of possible values, it is likely that
the estimated heat transfer coefficients used for doing heat transfer area design are
wrong. A detailed analysis of all sixty-six exchangers would be ideal.
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(20) http://www.epa.gov/oar/oaqps/greenbk/o3co.html
(21) http://pages.ca.inter.net/~jhwalsh/wfsesr.html
(22) http://msds.ehs.cornell.edu/msds/msdsdod/a98/m48796.htm#Section5
(23) http://msds.ehs.cornell.edu/msds/msdsdod/a401/m200166.htm#Section5
(24) http://msds.ehs.cornell.edu/msds/msdsdod/a49/m24066.htm#Section11
(25) http://msds.ehs.cornell.edu/msds/msdsdod/a328/m163906.htm
(26) http://msds.ehs.cornell.edu/msds/msdsdod/a194/m96822.htm
(27) VanAntwerp, Jeremy. In Class Lecture. Engr. 342. May 8, 2006.
(28) Medema, Robert. Interview. Feb. 22, 2006.
Chen, Kaidong, Alexis T. Bell, and Enrique Iglesia. "Kinetics and Mechanism of
Oxidative Dehydrogenation of Propane on Vandium, Molybdenum, and Tungsten
Oxides." J. Phys. Chem 104 (2000): 1292-99.
Chemical Industry Intelligence - Chemical Pricing Reports. www.icislor.com.
Dessau, Ralph M. Dehydrogenation and Dehydrocyclization Using a Non-Acidic NU-87
Catalyst listed in US Patent # 5,254,787.
Diephouse, Dan, Scott Dykstra, and Derek Ferwerda. Hot for Hydrogen. Grand Rapids,
MI: Calvin College, 2004.
Dreise, Manuel, Randall Elenbaas, and Eric Smith. Bond...H-Bond. Grand Rapids, MI:
Calvin College, 2004.
Egloff, Gustav. Production of Styrene listed in US Patent # 2,376,532; May 22, 1945.
Frash, M V., and R A. Santen. "Activation of Small Alkanes in Ga-Exchanged Zeolites:
A Quantum Chemical Study of Ethane Dehydrogenation." J. Phys. Chem 104
(2000): 2468-75.
Iezzi, Rodolfo; Barolini, Andrea; Buonomo, Franco. Process for Activating Catalyst
Precursors for the Dehydrogenation of C2-C5 Paraffins, and a Catalytic
Composition Activated by the Process listed in US Patent # 5,308,822; May 3,
1994.
Iezzi, Rodolfo; Sanfilippo, Domenico. Process for the Dehydrogenation of
Ethylbenzene to Styrene listed in US Patent # 6,841,712; Jan 11, 2005.
Iezzi, Rodolfo; Bartolini, Andrea; Buonomo, Franco. Process for Activating Catalyst
Percursors for the Dehydrogenation of C2-C5 Paraffins, and a Catalytic
Composition Activated by the Process listed in US Patent # 5,414,182; May 9,
1995.
Polystyrene Packaging Council Homepage. http://www.polystyrene.org/.
Ogunnaike, Babatunde A., and Harmon W. Ray. Process Dynamics, Modeling, and
Control. New York: Oxford University Press, 1994.
Seider, Warren D., J D. Seader, and Daniel R. Lewin. Product & Process Design
Principles. 2nd ed. New York City: Wiley, 2004
Stichlmair, Johann G., and James R. Fair. Distillation Principles and Practices. New
York: Wiley-VCH, 1998.
Styrene Producers Price Capacity. http://www.the-innovationgroup.com/ChemProfiles/Styrene.htm.
Wankat, Phillip C. Equilibrium Stated Separations. Upper Saddle River, NJ: Prentice
Hall, 1988.
Wood, Andrew. "Dow Joins Snamprogetti to Develope Ethane-Based Styrene Process."
Chemical Week, 20 April 2005, 17.
Wood, Andrew. "Celanese, Dow Revisit Catalytic Route from Ethane to Ethylene."
Chemical Week, 15 June 2005, 25.
Zhou, Ying; Cavis, Stephen M. Dehydrogenation Catalysts and Process for Preparing
the Catalysts listed in US Patent # 5,219,816; June 15, 1993.
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
128680
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
25.0
59.5
101.3
135.8
Design Specifications
Centrifugal
Horizontal
Carbon Steel
141760
4000
480
75%
1624
1471
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.2100
0.7900
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
163200
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
25.0
69.2
128.8
186.8
Design Specifications
Centrifugal
Horizontal
Carbon Steel
180720
4000
480
75%
3388
3059
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9697
0.0246
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0057
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
116640
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
31.1
75.2
183.8
264.9
Design Specifications
Centrifugal
Horizontal
Carbon Steel
129160
4000
480
75%
3388
3059
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9697
0.0246
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0057
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
285600
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-28.1
124.0
173.5
Design Specifications
Centrifugal
Horizontal
Stainless Steel
315360
4000
900
75%
5050
4574
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
320300
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-68.6
-30.1
101.3
187.4
Design Specifications
Centrifugal
Horizontal
Stainless Steel
353570
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
192030
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-12.6
184.4
325.2
Design Specifications
Centrifugal
Horizontal
Stainless Steel
212010
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
109880
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-12.6
322.2
568.3
Design Specifications
Centrifugal
Horizontal
Stainless Steel
121320
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
62628
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-12.6
565.3
997.2
Design Specifications
Centrifugal
Horizontal
Stainless Steel
69151
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
35836
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-47.9
-10.6
997.2
1750.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
39564
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
21318
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-38.4
-1.6
1747.0
3003.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
23534
4000
900
75%
8730
7907
0.5804
0.0000
0.0000
0.0000
0.0000
0.0000
0.1199
0.0000
0.2367
0.0000
0.0630
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
255200
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-99.6
-52.6
101.3
229.5
Design Specifications
Centrifugal
Horizontal
Stainless Steel
281630
4000
900
75%
9509
8614
0.5550
0.0000
0.0000
0.0000
0.0000
0.0000
0.1277
0.0000
0.2520
0.0000
0.0650
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
143200
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-52.6
-8.8
229.5
443.6
Design Specifications
Centrifugal
Horizontal
Stainless Steel
158030
4000
900
75%
9509
8614
0.5550
0.0000
0.0000
0.0000
0.0000
0.0000
0.1277
0.0000
0.2520
0.0000
0.0650
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
75477
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-6.3
440.6
845.5
Design Specifications
Centrifugal
Horizontal
Stainless Steel
83311
4000
900
75%
9509
8614
0.5550
0.0000
0.0000
0.0000
0.0000
0.0000
0.1277
0.0000
0.2520
0.0000
0.0650
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
39467
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
-6.3
842.5
1617.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
43568
4000
900
75%
9509
8614
0.5550
0.0000
0.0000
0.0000
0.0000
0.0000
0.1277
0.0000
0.2520
0.0000
0.0650
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
21763
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-37.0
5.8
1617.0
3003.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
24020
4000
900
75%
9509
8614
0.5550
0.0000
0.0000
0.0000
0.0000
0.0000
0.1277
0.0000
0.2520
0.0000
0.0650
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
124400
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-116.0
-26.7
101.3
396.8
Design Specifications
Centrifugal
Horizontal
Stainless Steel
137710
4000
900
75%
8495
7671
0.0173
0.0000
0.0000
0.0000
0.0000
0.0000
0.2374
0.0000
0.4684
0.0000
0.1215
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
45424
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
34.6
393.8
1088.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
50302
4000
900
75%
8495
7671
0.0173
0.0000
0.0000
0.0000
0.0000
0.0000
0.2374
0.0000
0.4684
0.0000
0.1215
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
16480
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
34.6
1085.0
3000.0
Design Specifications
Centrifugal
Horizontal
Stainless Steel
18251
4000
900
75%
8495
7671
0.0173
0.0000
0.0000
0.0000
0.0000
0.0000
0.2374
0.0000
0.4684
0.0000
0.1215
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
108700
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-123.1
-31.8
101.3
409.6
Centrifugal
Horizontal
Stainless Steel
120400
4000
900
75%
7683
6937
0.0968
0.0000
0.0000
0.0000
0.0000
0.0000
0.2591
0.0000
0.5114
0.0000
0.1326
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
40301
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
37.1
406.6
1106.0
Centrifugal
Horizontal
Stainless Steel
44629
4000
900
75%
7683
6937
0.0968
0.0000
0.0000
0.0000
0.0000
0.0000
0.2591
0.0000
0.5114
0.0000
0.1326
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
14856
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
37.1
1103.0
3000.0
Centrifugal
Horizontal
Stainless Steel
16453
4000
900
75%
7683
6937
0.0968
0.0000
0.0000
0.0000
0.0000
0.0000
0.2591
0.0000
0.5114
0.0000
0.1326
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
95210
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-132.0
-39.8
101.3
427.2
Centrifugal
Horizontal
Stainless Steel
105410
4000
900
75%
7012
6331
0.0428
0.0000
0.0000
0.0000
0.0000
0.0000
0.2783
0.0000
0.5493
0.0000
0.1296
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
35962
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
38.5
424.2
1129.6
Centrifugal
Horizontal
Stainless Steel
39824
4000
900
75%
7012
6331
0.0428
0.0000
0.0000
0.0000
0.0000
0.0000
0.2783
0.0000
0.5493
0.0000
0.1296
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
13541
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
38.5
1127.0
3000.0
Centrifugal
Horizontal
Stainless Steel
15000
4000
900
75%
7012
6331
0.0428
0.0000
0.0000
0.0000
0.0000
0.0000
0.2783
0.0000
0.5493
0.0000
0.1296
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
86480
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-136.2
-43.0
101.3
436.2
Centrifugal
Horizontal
Stainless Steel
95756
4000
900
75%
6508
5874
0.0280
0.0000
0.0000
0.0000
0.0000
0.0000
0.2973
0.0000
0.5867
0.0000
0.0880
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
32965
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
40.1
433.2
1142.0
Centrifugal
Horizontal
Stainless Steel
36512
4000
900
75%
6508
5874
0.0280
0.0000
0.0000
0.0000
0.0000
0.0000
0.2973
0.0000
0.5867
0.0000
0.0880
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
12544
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
40.1
1139.0
3000.0
Centrifugal
Horizontal
Stainless Steel
13898
4000
900
75%
6508
5874
0.0280
0.0000
0.0000
0.0000
0.0000
0.0000
0.2973
0.0000
0.5867
0.0000
0.0880
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
78950
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-141.4
-47.9
101.3
448.1
Centrifugal
Horizontal
Stainless Steel
87432
4000
900
75%
6097
5501
0.0159
0.0000
0.0000
0.0000
0.0000
0.0000
0.3133
0.0000
0.6183
0.0000
0.0525
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
30448
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
41.0
445.1
1157.0
Centrifugal
Horizontal
Stainless Steel
33731
4000
900
75%
6097
5501
0.0159
0.0000
0.0000
0.0000
0.0000
0.0000
0.3133
0.0000
0.6183
0.0000
0.0525
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
11743
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
41.0
1154.0
3000.0
Centrifugal
Horizontal
Stainless Steel
13014
4000
900
75%
6097
5501
0.0159
0.0000
0.0000
0.0000
0.0000
0.0000
0.3133
0.0000
0.6183
0.0000
0.0525
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
72360
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-147.9
-55.9
101.3
458.4
Centrifugal
Horizontal
Stainless Steel
80145
4000
900
75%
5707
5150
0.0074
0.0000
0.0000
0.0000
0.0000
0.0000
0.3252
0.0000
0.6417
0.0000
0.0258
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
27739
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-55.9
34.3
458.4
1187.0
Centrifugal
Horizontal
Stainless Steel
30712
4000
900
75%
5707
5150
0.0074
0.0000
0.0000
0.0000
0.0000
0.0000
0.3252
0.0000
0.6417
0.0000
0.0258
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
11029
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
40.0
1184.0
3000.0
Centrifugal
Horizontal
Stainless Steel
12223
4000
900
75%
5707
5150
0.0074
0.0000
0.0000
0.0000
0.0000
0.0000
0.3252
0.0000
0.6417
0.0000
0.0258
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
66440
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-155.6
-66.6
101.3
470.8
Centrifugal
Horizontal
Stainless Steel
73585
4000
900
75%
5364
4840
0.0026
0.0000
0.0000
0.0000
0.0000
0.0000
0.3322
0.0000
0.6555
0.0000
0.0097
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
25128
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-66.6
21.0
470.8
1228.0
Centrifugal
Horizontal
Stainless Steel
27820
4000
900
75%
5364
4840
0.0026
0.0000
0.0000
0.0000
0.0000
0.0000
0.3322
0.0000
0.6555
0.0000
0.0097
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
10437
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-50.0
37.4
1225.0
3000.0
Centrifugal
Horizontal
Stainless Steel
11570
4000
900
75%
5364
4840
0.0026
0.0000
0.0000
0.0000
0.0000
0.0000
0.3322
0.0000
0.6555
0.0000
0.0097
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
ID Number:
Description:
No. Required
Date: 5/8/2006
Prepared By:
ACJ
Checked By:
MJH
61520
Ethane
n-Hexane
1 Meta 3 Ethyl Benzene
Toluene
Benzene
Ethyl Benzene
Hydrogen
Oxygen
Nitrogen
Water
Ethylene
Styrene
n-Butyl Benzene
Cumene
n-Propyl Benzene
Alpha Metal Styrene
Meta Diethyl Benzene
Carbon Dioxide
-163.4
-151.1
101.3
138.0
Centrifugal
Horizontal
Stainless Steel
68172
4000
900
75%
730
659
0.0008
0.0000
0.0000
0.0000
0.0000
0.0000
0.3350
0.0000
0.6611
0.0000
0.0031
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
366000
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
366000
0
-120
25
Temperature (C)
101
101
Pressure (kPa)
3
584
1.22
Density (kg/m )
0.0000
0.0095
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.2517
0.0000
72.03
51.96
Specific Heat (J/mol-K)
0.0000
0.0213
Thermal Conductivity - Vapor (W/m-K)
0.1840
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
270680
391
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
121640
0
0
121640
111
111
150
147
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
4697
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
124100
124100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
148
148
Temperature (C)
136
133
Pressure (kPa)
3
4.12
4.12
Density (kg/m )
0.0083
0.0083
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
178.70
178.70
Specific Heat (J/mol-K)
0.0199
0.0199
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
122700
955
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
46639
46639
0
15
111
150
147
1015.00
0.85
0.0000
0.0125
1.1360
0.0000
75.44
39.87
0.0000
0.0254
0.5953
0.0000
Heat Flux (kJ/hr-m2-K)
966
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
37920
37920
194
194
Temperature (C)
136
133
Pressure (kPa)
3
714
714
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
0.1863
0.1863
Viscosity - Liquid (cP)
322.10
322.10
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1052
0.1052
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
164800
1922
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
High Pressure Steam
93690
0
0
93690
243
243
3550
3547
14.89
804
0.0172
0.0000
0.0000
0.1099
74.72
86.22
0.0374
0.0000
0.0000
0.6242
Heat Flux (kJ/hr-m2-K)
1736
Shell Side
1
Carbon Steel
4
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
31025
31025
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
148
148
Temperature (C)
136
133
Pressure (kPa)
3
4.12
4.12
Density (kg/m )
0.0083
0.0083
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
178.70
178.70
Specific Heat (J/mol-K)
0.0199
0.0199
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
30675
239
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
46640
46640
0
15
111
150
147
1015.00
0.85
0.0000
0.0125
1.1360
0.0000
75.44
39.87
0.0000
0.0254
0.5953
0.0000
Heat Flux (kJ/hr-m2-K)
966
Shell Side
1
Carbon Steel
4
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
9480
9480
194
194
Temperature (C)
136
133
Pressure (kPa)
3
714
714
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.1863
0.1863
322.10
322.10
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1052
0.1052
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
41200
480
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
High Pressure Steam
23423
0
0
23423
243
243
3550
3547
14.89
804
0.0172
0.0000
0.0000
0.1099
74.72
86.22
0.0374
0.0000
0.0000
0.6242
Heat Flux (kJ/hr-m2-K)
1736
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
481500
612700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
131100
0
62
79
Temperature (C)
105
102
Pressure (kPa)
3
1.72
1.47
Density (kg/m )
0.0104
0.0107
Viscosity - Vapor (cP)
0.3762
0.0000
Viscosity - Liquid (cP)
75.15
73.49
Specific Heat (J/mol-K)
0.0242
0.0246
Thermal Conductivity - Vapor (W/m-K)
0.1290
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
66020
1059
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
29670
0
0
29670
111
111
150
147
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1546
Shell Side
1
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Process Streams
738600
738600
0
0
600
388
133
130
0.63
0.81
0.0281
0.0230
0.0000
0.0000
104.30
89.24
0.1025
0.0738
0.0000
0.0000
Heat Flux (kJ/hr-m2-K)
800
Shell Side
1
Stainless Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
236100
236100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
69
31
Temperature (C)
187
184
Pressure (kPa)
3
1.83
2.02
Density (kg/m )
0.0200
0.0183
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
29.54
29.34
Specific Heat (J/mol-K)
0.0287
0.0261
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
9494
176
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
64290
64290
15
50
220
217
1015
988
0.0000
0.0000
1.1360
0.5442
75.44
79.03
0.0000
0.0000
0.5953
0.6432
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
236100
232400
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
3757
75
-50
Temperature (C)
265
262
Pressure (kPa)
2.55
0.14
Density (kg/m3)
0.0202
0.0146
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
29.57
29.92
Specific Heat (J/mol-K)
0.0291
0.0203
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.4680
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
40860
310
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
148200
148200
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1609
Shell Side
1
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Used For Start Up
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Heat Flux (kJ/hr-m2-K)
0
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
738600
738600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
388
320
Temperature (C)
130
127
Pressure (kPa)
3
0.81
0.88
Density (kg/m )
0.0230
0.0221
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
89.24
83.14
Specific Heat (J/mol-K)
0.0738
0.0645
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
125500
253
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Process Streams
126500
126500
0
0
-50
846
262
259
3.95
0.79
0.0146
0.0523
0.0000
0.0000
28.74
33.09
0.0204
0.0713
0.0000
0.0000
Heat Flux (kJ/hr-m2-K)
1032
Shell Side
1
Stainless Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
21490
490800
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
240700
320
-50
Temperature (C)
126
123
Pressure (kPa)
0.87
2.58
Density (kg/m3)
0.0212
0.0088
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
1.9410
83.14
51.06
Specific Heat (J/mol-K)
0.0645
0.0221
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.1590
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
616400
2438
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
2236100
2236100
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
268300
236100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
2122
34300
186
25
Temperature (C)
130
127
Pressure (kPa)
0.23
1.66
Density (kg/m3)
0.0661
0.0180
Viscosity - Vapor (cP)
0.2882
0.8904
Viscosity - Liquid (cP)
38.64
37.82
Specific Heat (J/mol-K)
0.0918
0.0256
Thermal Conductivity - Vapor (W/m-K)
0.0382
0.6110
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
34360
676
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
84711
84711
15
111
220
217
1015
988
0.0000
0.0000
1.1360
0.5442
75.44
79.03
0.0000
0.0000
0.5953
0.6432
Heat Flux (kJ/hr-m2-K)
410
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
118700
118700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
25
550
Temperature (C)
135
133
Pressure (kPa)
3
1.05
0.38
Density (kg/m )
0.0153
0.0348
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
28.96
31.39
Specific Heat (J/mol-K)
0.0516
0.1099
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
97430
208
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Process Streams
270400
270400
0
0
580
186
132
130
0.55
0.89
0.0318
0.0223
0.0000
0.0000
32.91
31.02
0.0546
0.0355
0.0000
0.0000
Heat Flux (kJ/hr-m2-K)
1037
Shell Side
1
Stainless Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
151700
151700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
59
560
Temperature (C)
136
133
Pressure (kPa)
3
1.42
0.56
Density (kg/m )
0.0204
0.0411
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
29.36
32.29
Specific Heat (J/mol-K)
0.0284
0.0582
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
81250
283
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Process Streams
268300
270400
2122
0
713
480
134
131
0.43
0.55
0.0393
0.0318
0.1910
0.0000
34.36
32.91
0.0684
0.0546
0.0382
0.0000
Heat Flux (kJ/hr-m2-K)
1052
Shell Side
1
Stainless Steel
Description:
No. Required
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
26
3657
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
240700
237100
-50
40
Temperature (C)
101
101
Pressure (kPa)
878
73.06
Density (kg/m3)
0.0081
0.0099
Viscosity - Vapor (cP)
1.9440
0.5134
Viscosity - Liquid (cP)
149.20
176.20
Specific Heat (J/mol-K)
0.0174
0.0225
Thermal Conductivity - Vapor (W/m-K)
0.1590
0.1369
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
36680
584
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
20854
0
0
20854
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
569
Shell Side
1
Carbon Steel
Description:
No. Required
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
112200
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
112200
61
44
Temperature (C)
5
5
Pressure (kPa)
3
0.20
885
Density (kg/m )
0.0063
0.0000
Viscosity - Vapor (cP)
0.0000
0.5634
Viscosity - Liquid (cP)
137.00
184.70
Specific Heat (J/mol-K)
0.0120
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.1411
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
48142
5675
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
601200
601200
15
34
220
217
1015
1001
0.0000
0.0000
1.1360
0.7332
75.44
76.14
0.0000
0.0000
0.5953
0.6237
Heat Flux (kJ/hr-m2-K)
366
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
66800
66800
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
59
59
Temperature (C)
27
27
Pressure (kPa)
3
0.82
0.82
Density (kg/m )
0.0073
0.0073
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
105.30
105.30
Specific Heat (J/mol-K)
0.0122
0.0122
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
39440
1697
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
374100
374100
15
40
220
217
1015
996
0.0000
0.0000
1.1360
0.6514
75.44
76.15
0.0000
0.0000
0.5953
0.6315
Heat Flux (kJ/hr-m2-K)
778
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
228500
228500
96
96
Temperature (C)
27
27
Pressure (kPa)
3
818
818
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.3037
0.3037
205.00
205.00
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1253
0.1253
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
66390
3903
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
29834
0
0
29834
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1073
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
3673
3673
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
42
42
Temperature (C)
27
27
Pressure (kPa)
3
0.80
0.80
Density (kg/m )
0.0073
0.0073
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
88.81
88.81
Specific Heat (J/mol-K)
0.0109
0.0109
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
5194
370
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
82220
82220
15
30
220
217
1015
1004
0.0000
0.0000
1.1360
0.7972
75.44
76.09
0.0000
0.0000
0.5953
0.6182
Heat Flux (kJ/hr-m2-K)
780
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
4252
4252
70
70
Temperature (C)
27
27
Pressure (kPa)
3
822
822
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
0.3448
0.3448
Viscosity - Liquid (cP)
167.90
167.90
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1249
0.1249
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
3552
79
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
1596
0
0
1596
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1076
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
103
103
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
33
33
Temperature (C)
27
27
Pressure (kPa)
3
0.90
0.90
Density (kg/m )
0.0060
0.0060
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
141.80
141.80
Specific Heat (J/mol-K)
0.0130
0.0130
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
2768
453
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
52610
52610
15
28
220
217
1015
1005
0.0000
0.0000
1.1360
0.8418
75.44
76.03
0.0000
0.0000
0.5953
0.6147
Heat Flux (kJ/hr-m2-K)
612
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
3570
3570
42
42
Temperature (C)
27
27
Pressure (kPa)
3
854
854
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.4838
0.4838
131.40
131.40
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1266
0.1266
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
1284
17
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
577
0
0
577
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1080
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
116100
116100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
62
62
Temperature (C)
8
8
Pressure (kPa)
3
0.30
0.30
Density (kg/m )
0.0064
0.0064
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
144.50
144.50
Specific Heat (J/mol-K)
0.0124
0.0124
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
431700
11301
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
68340
68340
15
30
220
217
1015
1004
0.0000
0.0000
1.1360
0.7972
75.44
76.09
0.0000
0.0000
0.5953
0.6182
Heat Flux (kJ/hr-m2-K)
987
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
112400
112400
70
70
Temperature (C)
8
8
Pressure (kPa)
3
861
861
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
0.4197
0.4197
Viscosity - Liquid (cP)
192.10
192.10
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1348
0.1348
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
461800
10431
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
11519
0
0
11519
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1063
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
78580
78580
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
61
61
Temperature (C)
5
5
Pressure (kPa)
3
0.20
0.20
Density (kg/m )
0.0063
0.0063
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
137.00
137.00
Specific Heat (J/mol-K)
0.0120
0.0120
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
23770
1046
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
208700
208700
15
42
220
217
1015
995
0.0000
0.0000
1.1360
0.6274
75.44
76.14
0.0000
0.0000
0.5953
0.6340
Heat Flux (kJ/hr-m2-K)
755
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
33840
33840
61
61
Temperature (C)
5
5
Pressure (kPa)
3
869
869
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.4635
0.4635
189.60
189.60
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1370
0.1370
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
53210
977
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
23911
0
0
23911
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1073
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
26940
26940
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
61
61
Temperature (C)
5
5
Pressure (kPa)
3
0.20
0.20
Density (kg/m )
0.0063
0.0063
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
137.00
137.00
Specific Heat (J/mol-K)
0.0120
0.0120
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
13900
611
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
122000
122000
15
42
220
217
1015
995
0.0000
0.0000
1.1360
0.6274
75.44
76.14
0.0000
0.0000
0.5953
0.6340
Heat Flux (kJ/hr-m2-K)
756
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
6893
6893
61
61
Temperature (C)
5
5
Pressure (kPa)
3
869
869
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
0.4641
0.4641
Viscosity - Liquid (cP)
190.20
190.20
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1369
0.1369
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
24640
453
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
11073
0
0
11073
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
1075
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
6715
6715
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
61
61
Temperature (C)
5
5
Pressure (kPa)
3
0.20
0.20
Density (kg/m )
0.0063
0.0063
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
137.00
137.00
Specific Heat (J/mol-K)
0.0120
0.0120
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
40140
1781
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Cooling Water
0
0
352400
352400
15
42
220
217
1015
995
0.0000
0.0000
1.1360
0.6274
75.44
76.14
0.0000
0.0000
0.5953
0.6340
Heat Flux (kJ/hr-m2-K)
748
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
0
0
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
178
178
73
73
Temperature (C)
5
5
Pressure (kPa)
3
838
838
Density (kg/m )
0.0000
0.0000
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.4730
0.4730
228.50
228.50
Specific Heat (J/mol-K)
0.0000
0.0000
Thermal Conductivity - Vapor (W/m-K)
0.1324
0.1324
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
42820
239
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Carbon Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
Exhaust Steam
19242
0
0
19242
111
111
220
217
0.85
52.08
0.0125
0.0000
0.0000
0.2490
39.87
75.92
0.0254
0.0000
0.0000
0.6847
Heat Flux (kJ/hr-m2-K)
4707
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
498000
498000
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-28
-47
Temperature (C)
174
171
Pressure (kPa)
3
2.22
2.41
Density (kg/m )
0.0096
0.0089
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
40.06
38.83
Specific Heat (J/mol-K)
0.0246
0.0225
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
14580
777
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
1378200
1378200
-60
-50
220
217
1465
1437
0.0000
0.0000
0.4134
0.3730
90.86
92.12
0.0000
0.0000
0.1273
0.1230
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-2
-25
Temperature (C)
3003
3000
Pressure (kPa)
3
34.71
38.00
Density (kg/m )
0.0115
0.0107
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
41.84
40.24
Specific Heat (J/mol-K)
0.0301
0.0277
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
18600
1530
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
67721
67721
-60
-50
220
217
1465
1437
0.0000
0.0000
0.4134
0.3730
90.86
92.12
0.0000
0.0000
0.1273
0.1230
Heat Flux (kJ/hr-m2-K)
311
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-30
-50
Temperature (C)
187
184
Pressure (kPa)
3
2.42
2.59
Density (kg/m )
0.0096
0.0088
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
39.93
38.67
Specific Heat (J/mol-K)
0.0244
0.0222
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
14920
429
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
559980
559980
-60
-35
220
217
1465
1394
0.0000
0.0000
0.4134
0.3231
90.86
94.28
0.0000
0.0000
0.1273
0.1163
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-13
-50
Temperature (C)
325
322
Pressure (kPa)
3
3.92
4.53
Density (kg/m )
0.0103
0.0089
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
41.09
38.67
Specific Heat (J/mol-K)
0.0264
0.0223
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
28470
447
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
106200
106200
0
-60
-18
220
217
1465
8.95
0.0000
0.0107
0.4134
0.0000
90.86
51.52
0.0000
0.0088
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-13
-50
Temperature (C)
568
565
Pressure (kPa)
3
6.85
7.95
Density (kg/m )
0.0104
0.0089
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
41.09
38.67
Specific Heat (J/mol-K)
0.0267
0.0226
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
28470
447
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
106200
106200
0
-60
-18
220
217
1465
8.95
0.0000
0.0107
0.4134
0.0000
90.86
51.52
0.0000
0.0088
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-13
-48
Temperature (C)
997
994
Pressure (kPa)
3
12.01
13.89
Density (kg/m )
0.0105
0.0092
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
41.09
38.80
Specific Heat (J/mol-K)
0.0270
0.0233
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
26740
886
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
1528700
1528700
-60
-43
220
217
1465
1418
0.0000
0.0000
0.4134
0.3497
90.86
93.02
0.0000
0.0000
0.1273
0.1201
Heat Flux (kJ/hr-m2-K)
1656
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
497900
497900
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-11
-38
Temperature (C)
1750
1747
Pressure (kPa)
3
20.92
23.36
Density (kg/m )
0.0108
0.0098
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
41.22
39.40
Specific Heat (J/mol-K)
0.0280
0.0251
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
21340
385
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
79263
79263
0
-60
-16
220
217
1465
8.89
0.0000
0.0107
0.4134
0.0000
90.86
51.73
0.0000
0.0089
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
463100
463100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
6
-14
Temperature (C)
3003
3000
Pressure (kPa)
3
33.45
36.02
Density (kg/m )
0.0119
0.0112
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
41.84
40.50
Specific Heat (J/mol-K)
0.0315
0.0293
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
14840
323
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
53835
53835
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1588
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
463100
463100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-9
-50
Temperature (C)
444
441
Pressure (kPa)
3
5.21
6.14
Density (kg/m )
0.0106
0.0090
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
40.86
38.28
Specific Heat (J/mol-K)
0.0276
0.0230
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
29230
418
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
108120
108120
0
-60
-14
220
217
1465
8.82
0.0000
0.0108
0.4134
0.0000
90.86
51.93
0.0000
0.0090
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1616
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
463100
463100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-6
-50
Temperature (C)
846
843
Pressure (kPa)
3
9.85
11.73
Density (kg/m )
0.0108
0.0092
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
41.02
38.28
Specific Heat (J/mol-K)
0.0282
0.0235
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
31010
420
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
114080
114080
0
-60
-11
220
217
1465
8.74
0.0000
0.0109
0.4134
0.0000
90.86
52.19
0.0000
0.0091
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1615
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
463100
463100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-6
-37
Temperature (C)
1617
1614
Pressure (kPa)
3
18.83
21.28
Density (kg/m )
0.0110
0.0099
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
41.02
39.07
Specific Heat (J/mol-K)
0.0289
0.0256
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
21990
359
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
80896
80896
0
-60
-11
220
217
1465
8.74
0.0000
0.0109
0.4134
0.0000
90.86
52.19
0.0000
0.0091
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1612
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
214100
214100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
35
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
26.03
35.86
Density (kg/m )
0.0149
0.0117
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
35.17
32.61
Specific Heat (J/mol-K)
0.0442
0.0311
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
27610
256
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
100160
100160
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1617
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
214100
214100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-27
-50
Temperature (C)
397
394
Pressure (kPa)
3
4.30
4.71
Density (kg/m )
0.0120
0.0110
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
33.27
32.61
Specific Heat (J/mol-K)
0.0349
0.0319
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
7408
183
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
154840
154840
-60
-32
220
217
1465
1384
0.0000
0.0000
0.4134
0.3130
90.86
94.85
0.0000
0.0000
0.1273
0.1147
Heat Flux (kJ/hr-m2-K)
1609
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
214100
214100
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
35
-50
Temperature (C)
1088
1085
Pressure (kPa)
3
9.44
12.99
Density (kg/m )
0.0146
0.0112
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
35.17
32.61
Specific Heat (J/mol-K)
0.0431
0.0324
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
27610
257
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
100160
100160
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1609
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
189700
189700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
37
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
24.98
34.70
Density (kg/m )
0.0153
0.0120
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
33.51
31.49
Specific Heat (J/mol-K)
0.0466
0.0359
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
24970
229
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
90583
90583
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
189700
189700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-32
-50
Temperature (C)
410
407
Pressure (kPa)
3
4.38
4.71
Density (kg/m )
0.0122
0.0114
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
31.88
31.49
Specific Heat (J/mol-K)
0.0363
0.0338
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
168
160
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
90583
90583
-60
-37
220
217
1465
16.18
0.0000
0.0000
0.4134
0.3282
90.86
94.02
0.0000
0.0000
0.1273
0.1171
Heat Flux (kJ/hr-m2-K)
53
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
189700
189700
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
37
-50
Temperature (C)
1106
1103
Pressure (kPa)
3
9.21
12.77
Density (kg/m )
0.0150
0.0116
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
33.51
31.49
Specific Heat (J/mol-K)
0.0456
0.0344
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
24970
229
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
90583
90583
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
171600
171600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
38
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
24.17
33.71
Density (kg/m )
0.0155
0.0123
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
32.12
30.58
Specific Heat (J/mol-K)
0.0487
0.0375
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
22790
207
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
82675
82675
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
171600
171600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-39
-50
Temperature (C)
427
424
Pressure (kPa)
3
4.60
4.77
Density (kg/m )
0.0122
0.0117
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
30.74
30.58
Specific Heat (J/mol-K)
0.0370
0.0356
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
2571
145
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
0
160040
160040
-60
-45
220
217
1465
1423
0.0000
0.0000
0.4134
0.3546
90.86
92.82
0.0000
0.0000
0.1273
0.1207
Heat Flux (kJ/hr-m2-K)
1570
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
171600
171600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
38
-50
Temperature (C)
1130
1127
Pressure (kPa)
3
9.10
12.67
Density (kg/m )
0.0153
0.0119
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
32.12
30.58
Specific Heat (J/mol-K)
0.0478
0.0361
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
22790
207
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
82675
82675
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
156600
156600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
40
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
23.44
32.86
Density (kg/m )
0.0158
0.0125
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
31.10
29.92
Specific Heat (J/mol-K)
0.0509
0.0392
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
21140
191
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
76689
76689
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1608
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
156600
156600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-43
-50
Temperature (C)
436
433
Pressure (kPa)
3
4.64
4.75
Density (kg/m )
0.0123
0.0120
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
30.00
29.92
Specific Heat (J/mol-K)
0.0383
0.0373
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
1605
145
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
76689
76689
0
-60
-48
220
217
1465
1432
0.0000
0.0000
0.4134
0.3662
90.86
92.36
0.0000
0.0000
0.1273
0.1222
Heat Flux (kJ/hr-m2-K)
1627
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
156600
156600
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
40
-50
Temperature (C)
1142
1139
Pressure (kPa)
3
8.92
12.48
Density (kg/m )
0.0155
0.0121
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
31.10
29.92
Specific Heat (J/mol-K)
0.0500
0.0378
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
21140
191
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
76689
76689
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1608
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
145400
145400
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
41
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
22.86
32.15
Density (kg/m )
0.0159
0.0126
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
30.23
29.36
Specific Heat (J/mol-K)
0.0527
0.0406
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
19800
178
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
71828
71828
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1607
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
145400
145400
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
-48
-50
Temperature (C)
448
445
Pressure (kPa)
3
4.76
4.77
Density (kg/m )
0.0123
0.0122
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
29.38
29.36
Specific Heat (J/mol-K)
0.0392
0.0389
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
448
10
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
1625
1625
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1735
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
137800
137800
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
40
-50
Temperature (C)
3000
2997
Pressure (kPa)
3
22.55
31.62
Density (kg/m )
0.0160
0.0127
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
29.57
31.62
Specific Heat (J/mol-K)
0.0538
0.0416
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
18540
167
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
67257
67257
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1608
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
145400
145400
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
41
-50
Temperature (C)
448
445
Pressure (kPa)
3
8.82
12.38
Density (kg/m )
0.0157
0.0123
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
30.23
29.36
Specific Heat (J/mol-K)
0.0518
0.0393
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
19800
178
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
71828
71828
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1607
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
137800
137800
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
34
-50
Temperature (C)
1187
1184
Pressure (kPa)
3
9.09
12.49
Density (kg/m )
0.0156
0.0124
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
29.53
28.96
Specific Heat (J/mol-K)
0.0522
0.0405
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
17340
162
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
62904
62904
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1610
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
133500
133500
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
37
-50
Temperature (C)
3000.0
2997.0
Pressure (kPa)
3
22.52
31.31
Density (kg/m )
0.0160
0.0128
Viscosity - Vapor (cP)
Viscosity - Liquid (cP)
0.0000
0.0000
29.17
28.72
Specific Heat (J/mol-K)
0.0543
0.0423
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Total Heat Transfer Area (m2)
Duty (MJ/hr)
17420
127
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
63194
63194
0
-60
-5
220.0
217.0
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
2029
Shell Side
1
Carbon Steel
1
Unit Performance & Fluid Properties
Tube Side
Inlet
Outlet
Fluid
Process Streams
133500
133500
Flow Rate - Vapor (kg/hr)
Flow Rate - Liquid (kg/hr)
0
0
21
-50
Temperature (C)
1228
1225
Pressure (kPa)
3
9.73
12.80
Density (kg/m )
0.0152
0.0125
Viscosity - Vapor (cP)
0.0000
0.0000
Viscosity - Liquid (cP)
29.09
28.72
Specific Heat (J/mol-K)
0.0512
0.0412
Thermal Conductivity - Vapor (W/m-K)
0.0000
0.0000
Thermal Conductivity - Liquid (W/m-K)
Duty (MJ/hr)
Total Heat Transfer Area (m2)
14140
143
Unit Construction
Tube Side
Number of Passes
2
Material of Construction
Stainless Steel
Date:
Prepared By:
Checked By:
5/9/2006
ACJ
MJH
Shell Side
Inlet
Outlet
R-22
0
51295
51295
0
-60
-5
220
217
1465
8.53
0.0000
0.0112
0.4134
0.0000
90.86
52.86
0.0000
0.0094
0.1273
0.0000
Heat Flux (kJ/hr-m2-K)
1612
Shell Side
1
Carbon Steel
ID Number:
Description:
No. Required
Date:
Prepared By:
Checked By:
88117
99.85% Benzene
0.1% n-Hexane
0.05% Toluene
25.0
25.0
101.3
135.8
Centrifugal
Horizontal
Cast Iron
97082
4000 (max)
300 (max)
75
1.9
2.5
5/8/2006
MJH
JRB
ID Number:
Description:
No. Required
Date:
Prepared By:
Checked By:
3570
99.85% Benzene
0.14% n-Hexane
0.01% Toluene
41.8
41.9
26.7
135.8
Centrifugal
Horizontal
Cast Iron
3946
4000 (max)
300 (max)
75
0.25
0.33
5/8/2006
MJH
JRB
ID Number:
Description:
No. Required
Date:
Prepared By:
Checked By:
4252
99.75% Toluene
0.24% Ethylbenzene
0.01% Benzene
69.5
69.6
26.7
101.3
Centrifugal
Horizontal
Cast Iron
4698
4000 (max)
300 (max)
75
0.21
0.28
5/8/2006
MJH
JRB
ID Number:
Description:
No. Required
Date:
Prepared By:
Checked By:
112240
99.93% Styrene
0.04% Cumene
0.01% Toluene
Trace Heavies
43.7
43.8
2.3
105.0
Centrifugal
Horizontal
Cast Iron
124710
4000 (max)
300 (max)
75
7.2
9.6
5/8/2006
MJH
JRB
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
ID Number:
Description:
No. Required
Liquid Effluent
2409 kgmol/hr
Vapor Feed
Vapor Effluent
8477 kgmol/hr
Liquid Effluent
1904 kgmol/hr
Date: 5/11/2006
Prepared By:
LJB
Checked By:
MJH
Outlet Flows
Nitrogen (97.0%), Water (2.5%)
Trace: Carbon Dioxide
Water (100%)
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
25.0
Temperature (C)
25.0
128.8
Pressure (kPa)
128.8
Design Data
Two Phase Separator
Vertical
6.93
1.98
Carbon Steel
21.34
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
8268 kgmol/hr
Outlet Flows
Nitrogen (99.4%)
Trace: Carbon Dioxide
Liquid Effluent
208.5 kgmol/hr
Water (100%)
Trace: Carbon Dioxide
Date: 5/11/2006
Prepared By:
LJB
Checked By:
MJH
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-50.0
Temperature (C)
-50.0
261.9
Pressure (kPa)
261.9
Design Data
Two Phase Separator
Vertical
4.27
1.22
Carbon Steel
4.99
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
19080 kgmol/hr
Liquid Effluent
0 kgmol/hr
Outlet Flows
Ethane (58.0 mol%), Nitrogen (23.7%), Hydrogen (12.0%),
Ethylene (6.3%)
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-68.6
Temperature (C)
-68.6
Pressure (kPa)
101.3
101.3
Design Data
Two Phase Separator
Vertical
9.60
2.74
Stainless Steel
56.61
Additional Equipment
N
Agitation Required?
N
Vapor Feed
Vapor Effluent
17920 kgmol/hr
Outlet Flows
Ethane (55.5 mol%), Nitrogen (25.2%), Hydrogen (12.8%),
Ethylene (6.5%)
Liquid Effluent
1161 kgmol/hr
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-115.3
Temperature (C)
-115.3
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
8.00
2.29
Stainless Steel
32.95
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
9642 kgmol/hr
Liquid Effluent
8281 kgmol/hr
Outlet Flows
Ethane (17.3 mol%), Nitrogen (46.8%), Hydrogen (23.7%),
Ethylene 12.2%)
Ethane (100%)
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-116.0
Temperature (C)
-116.0
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
9.60
2.74
Stainless Steel
56.61
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
8831 kgmol/hr
Liquid Effluent
810.2 kgmol/hr
Outlet Flows
Nitrogen (51.1%), Hydrogen (25.9%), Ethylene (13.3%)
Ethane (9.7 mol%)
Ethane (100%)
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-123.1
Temperature (C)
-123.1
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
5.87
1.68
Stainless Steel
13.01
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
8222kgmol/hr
Liquid Effluent
609 kgmol/hr
Outlet Flows
Nitrogen (54.9%), Hydrogen (27.8%), Ethylene (13.0%)
Ethane (4.3%)
Ethane (82.6%), Ethylene (17.4%)
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-132.0
Temperature (C)
-132.0
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
5.30
1.52
Stainless Steel
9.62
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
7697 kgmol/hr
Liquid Effluent
524.9 kgmol/hr
Outlet Flows
Nitrogen (58.7%), Hydrogen (29.7%), Ethylene (8.8%)
Ethane (2.8%)
Ethylene (74.0%), Ethane (26.0%),
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-136.2
Temperature (C)
-136.2
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
5.33
1.52
Stainless Steel
9.67
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
7304 kgmol/hr
Liquid Effluent
393.3 kgmol/hr
Outlet Flows
Nitrogen (61.8%), Hydrogen (31.3%), Ethylene (5.3%)
Ethane (1.6%)
Ethylene (74.7%), Ethane (25.3%),
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-141.4
Temperature (C)
-141.4
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
4.80
1.37
Stainless Steel
7.08
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
7038 kgmol/hr
Liquid Effluent
393.3 kgmol/hr
Outlet Flows
Nitrogen (64.2%), Hydrogen (32.5%), Ethylene (2.6%)
Trace: Ethane
Ethylene (75.8%), Ethane (24.2%),
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-147.9
Temperature (C)
-147.9
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
4.80
1.37
Stainless Steel
7.08
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
6890 kgmol/hr
Liquid Effluent
148.7 kgmol/hr
Outlet Flows
Nitrogen (65.6%), Hydrogen (33.2%)
Trace: Ethylene, Ethane
Ethylene (77.2%), Ethane (22.8%),
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-155.6
Temperature (C)
-155.6
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
4.80
1.37
Stainless Steel
7.08
Additional Equipment
Agitation Required?
N
N
Vapor Feed
Vapor Effluent
6832 kgmol/hr
Liquid Effluent
58.1 kgmol/hr
Date: 5/11/2006
Prepared By:
LJB
Checked By:
MJH
Outlet Flows
Nitrogen (66.1%), Hydrogen (33.5%)
Trace: Ethylene, Ethane
Ethylene (78.6%), Ethane (21.4%),
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Height (m)
Diameter (m)
Material of Construction
Volume (m3)
Heat Exchange Required?
Exit
-163.4
Temperature (C)
-163.4
101.3
Pressure (kPa)
101.3
Design Data
Two Phase Separator
Vertical
4.27
1.22
Stainless Steel
4.99
Additional Equipment
Agitation Required?
N
N
M-400
1st Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
497960
58.04% Ethane
23.67% Nitrogen
11.99% Hydrogen
6.30% Ethylene
Trace Amounts Heavies
-47.5
-68.63
173.5
101.3
Centrifugal
Horizontal
Stainless Steel
549770
85
4739
M-401
2nd Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
497920
58.04% Ethane
23.67% Nitrogen
11.99% Hydrogen
6.30% Ethylene
Trace Amounts Heavies
-25.4
-115.3
3000.0
101.3
Centrifugal
Horizontal
Stainless Steel
549740
85
25280
M-402
3rd Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
463070
55.50% Ethane
25.20% Nitrogen
12.77% Hydrogen
6.54% Ethylene
-15.7
-100.3
3000.0
101.3
Centrifugal
Horizontal
Stainless Steel
511190
85
24900
M-403
4th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
214070
17.27% Ethane
56.84% Nitrogen
23.74% Hydrogen
12.15% Ethylene
-50.0
-123.1
3000
101.3
Centrifugal
Horizontal
Stainless Steel
237330
85
10820
M-404
5th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
189700
9.68% Ethane
51.14% Nitrogen
25.91% Hydrogen
13.26% Ethylene
-50.0
-132.0
3000
101.3
Centrifugal
Horizontal
Stainless Steel
210370
85
9811
M-405
6th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
171600
4.28% Ethane
54.93% Nitrogen
27.83% Hydrogen
12.96% Ethylene
-50.0
-136.2
3000
101.3
Centrifugal
Horizontal
Stainless Steel
190400
85
8963
M-406
7th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
156600
2.80% Ethane
58.67% Nitrogen
29.73% Hydrogen
8.80% Ethylene
-50.0
-141.4
3000
101.3
Centrifugal
Horizontal
Stainless Steel
173860
85
8209
M-407
8th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
145370
1.59% Ethane
61.83% Nitrogen
31.33% Hydrogen
5.25% Ethylene
-50.0
-147.9
3000
101.3
Centrifugal
Horizontal
Stainless Steel
161500
85
7634
M-408
9th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
137780
0.74% Ethane
64.17% Nitrogen
32.52% Hydrogen
2.58% Ethylene
-50.0
-155.6
3000
101.3
Centrifugal
Horizontal
Stainless Steel
153180
85
7276
M-409
10th Turbine
1
Date: 5/8/2006
Prepared By:
MJH
Checked By:
LJB
Fluid Properties
133540
0.26% Ethane
65.55% Nitrogen
33.22% Hydrogen
0.97% Ethylene
-50.0
-163.4
3000
101.3
Centrifugal
Horizontal
Stainless Steel
148560
85
7136
Operating Conditions
Feed
Distillate
236400
7924
0
1
0.0000
0.0000
0.0005
0.0002
0.0223
0.0202
0.4808
0.0000
0.0000
0.0000
0.0000
0.0000
0.4754
0.0000
0.0002
0.0000
0.0002
0.0001
0.0000
0.0000
0.0000
0.0000
0.0128
0.0000
0.4947
0.4913
0.0012
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
59.08
40
26.66
26.66
Design Specifications
66
Flood Vapor Velocity (ft/s)
24
Design Vapor Vel. (ft/s)
50
12
Height of Packing (m)
3.3
0.95
Tower Construction
Carbon Steel
Flexipac HC
2.12
40.23
95.54
26.66
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Bottoms
228500
0
0.0000
0.0000
0.0000
0.0002
0.0020
0.0000
0.5014
0.0000
0.0000
0.0000
0.0000
0.0000
0.4958
0.0000
0.0003
0.0000
0.0003
0.0001
0.0000
0.0000
95.54
26.66
3.878
3.856
11.58
Operating Conditions
Feed
Distillate
7924
3673
1
1
0.0000
0.0000
0.0128
0.0000
0.4947
0.4913
0.0012
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0254
0.0000
0.0001
0.9745
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
59.08
41.54
26.66
26.66
Design Specifications
Flood Vapor Velocity (ft/s)
23
24
Design Vapor Vel. (ft/s)
10
3.41
1.15
0.85
Tower Construction
Carbon Steel
Sieve Tray
0.80
14.02
69.54
26.66
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Bottoms
4252
0
0.0000
0.0000
0.0000
0.0000
0.9975
0.0001
0.0024
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
69.54
26.66
13.033
13.033
Operating Conditions
Distillate
Feed
228500
116100
0
1
0.0000
0.0000
0.0000
0.0002
0.0020
0.0000
0.5014
0.0000
0.0000
0.0000
0.0000
0.0000
0.4958
0.0000
0.0003
0.0000
0.0003
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0041
0.0000
0.9957
0.0000
0.0000
0.0000
0.0000
0.0000
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
95.54
61.68
26.66
8.00
Design Specifications
72
Flood Vapor Velocity (ft/s)
Design Vapor Vel. (ft/s)
24
48
Height of Packing (m)
10
3.6
0.95
Tower Construction
Carbon Steel
Flexipac HC
5.63
43.89
69.77
8.00
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Bottoms
112400
0
0.0000
0.0000
0.0000
0.0005
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.9982
0.0000
0.0005
0.0000
0.0005
0.0002
0.0000
0.0000
69.77
8.00
21.85
21.84
12.19
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Operating Conditions
Distillate
Feed
112400
78580
0
1
0.0000
0.0000
0.0000
0.0005
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.9982
0.0000
0.0005
0.0000
0.0005
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.9994
0.0000
0.0003
0.0000
0.0000
0.0000
0.0000
0.0000
69.77
60.6
8.00
5.33
Design Specifications
Flood Vapor Velocity (ft/s)
45
24
Design Vapor Vel. (ft/s)
24
0.76
Height of Packing (m)
2.25
0.95
Tower Construction
Carbon Steel
Flexipac HC
5.61
27.43
60.65
5.33
Bottoms
33840
0
0.0000
0.0000
0.0000
0.0013
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9954
0.0000
0.0010
0.0000
0.0016
0.0007
0.0000
0.0000
60.65
5.33
22.575
22.573
19.51
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Operating Conditions
Feed
Distillate
33840
26940
0
1
0.0000
0.0000
0.0000
0.0013
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9954
0.0000
0.0010
0.0000
0.0016
0.0007
0.0000
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9994
0.0000
0.0005
0.0000
0.0000
0.0000
0.0000
0.0000
60.65
60.61
5.33
5.33
Design Specifications
30
Flood Vapor Velocity (ft/s)
Design Vapor Vel. (ft/s)
24
16
1.29
Height of Packing (m)
1.5
0.95
Tower Construction
Carbon Steel
Flexipac HC
3.59
18.29
60.82
5.33
Bottoms
6893
0
0.0000
0.0000
0.0000
0.0058
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9798
0.0000
0.0028
0.0000
0.0078
0.0037
0.0000
0.0000
60.82
5.33
18.93
18.93
19.51
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Operating Conditions
Feed
Distillate
6893
6715
0
1
0.0000
0.0000
0.0000
0.0058
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9798
0.0000
0.0028
0.0000
0.0078
0.0037
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9994
0.0000
0.0006
0.0000
0.0000
0.0000
0.0000
0.0000
60.82
60.6
5.33
5.33
Design Specifications
Flood Vapor Velocity (ft/s)
30
24
Design Vapor Vel. (ft/s)
16
15
Height of Packing (m)
1.5
0.95
Tower Construction
Carbon Steel
Flexipac HC
3.64
18.29
73.30
5.33
Bottoms
178
0
0.0000
0.0000
0.0000
0.2572
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.1312
0.0004
0.1000
0.0000
0.3480
0.1632
0.0000
0.0000
73.3
5.33
4.614
4.571
17.07
Operating Conditions
Feed
Distillate
3673
366.2
1
1
0.0000
0.0000
0.0254
0.0000
0.0001
0.9745
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.2480
0.0000
0.0000
0.7520
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
41.51
38.27
26.66
26.66
Design Specifications
40
Flood Vapor Velocity (ft/s)
Design Vapor Vel. (ft/s)
24
28
15
2
0.85
Tower Construction
Carbon Steel
Sieve Tray
0.34
24.38
41.82
26.66
Date: 5/11/2006
Prepared By:
MSB
Checked By:
ACJ
Bottoms
3307
0
0.0000
0.0000
0.0014
0.0000
0.0001
0.9985
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
41.82
26.66
3.449
7.976
Date:
5/11/2006
Prepared By: MSB
Checked By: ACJ
Ethylbenzene Recovery
1
Feed 1
111800
0
Feed 2
50190
0.0459
Distillate
124100
1
Bottoms
37920
0
0.0000
0.0000
0.0000
0.0005
0.0000
0.0000
0.8299
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0094
0.0011
0.0000
0.0000
0.1591
0.0000
0.0000
0.0000
0.0000
0.0004
0.0000
0.0002
0.0000
0.7444
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0207
0.0000
0.0000
0.0000
0.2343
0.0000
0.0000
0.0000
0.0000
0.0001
0.0004
0.0001
0.0000
0.9982
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0009
0.0000
0.0000
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0660
0.0000
0.0000
0.0000
0.9340
0.0000
0.0000
152.50
135.9
155.6
135.8
147.5
135.8
193.9
135.8
49
24
12
3
4.9
0.85
4.793
4.793
Temperature (C)
Pressure (kPa)
Design Specifications
Number of Trays
Tray Spacing (in.)
Feed Tray
Reflux Ratio
Pressure Drop (kPa)
Tray Efficiency
Tower Construction
Material of Construction
Tray Type
Tower Diameter (m)
Tower Height (m)
Design Temperature (C)
Design Pressure (kPa)
Carbon Steel
Sieve Tray
3.55
29.87
69.54
26.66
Vapor Feed
Vapor Effluent
R-10
Catalyst Regenerator
4
Date:
Prepared By:
Checked By:
5/8/2006
MJH
11408 kgmol/hr
10380 kgmol/hr
Outlet Flows
Nitrogen (79.2 mol%), Water (20.4%)
Trace: Carbon Dioxide
Operating Conditions
Inlet
Temperature (C)
Pressure (kPa)
Type
Position
Material of Construction
Volume (m3)
Tube Diameter (m)
Tube Length (m)
Heat Exchange Required?
Exit
554.7
Temperature (C)
134.3
Pressure (kPa)
Design Data
Regenerator
Vertical
Stainless Steel
220.4
1.4
14.2
Additional Equipment
Agitation Required?
N
712.6
134.3
Vapor Feed
Vapor Effluent
R-200
Alkylation Reactor
4
Date:
Prepared By:
Checked By:
31144 kgmol/hr
11060 kgmol/hr
Outlet Flows
Ethane (99.99 mol%)
Trace: n-Hexane, Nitrogen, Ethylene
5/8/2006
MJH
Liquid Effluent
1008 kgmol/hr
Liquid Feed
R-201
Transalkylator
4
441 kgmol/hr
Date:
Prepared By:
Checked By:
5/8/2006
MJH
Outlet Flows
Diethylbenzene (23.4 mol%), n-Butylbenzene (2.1%)
Liquid Effluent
441 kgmol/hr
Ethylbenzene (74.4%)
Trace: Cumene, Toluene, Polyalkylates
Operating Conditions
Inlet
Exit
121.4
Temperature (C)
Temperature (C)
155.6
Pressure (kPa)
135.8
Pressure (kPa)
135.8
Design Data
Type
Packed Bed
Position
Vertical
Material of Construction
Stainless Steel
Volume (m3)
17
Void Volume (m3)
0.75
Packed Volume (m3)
0.25
Tube Diameter (m)
1.1
Tube Length (m)
19.1
Additional Equipment
Heat Exchange Required?
N
Agitation Required?
N
114/
202
113/
324
Byproducts
To Separations
110
105/
452
119
E-100
118
106
116
12
112
49
T-100
R-100
111
R-101
109
Benzene
From Separations
117
104/
327
115
102
101
100
Benzene Feed
P-100
103
213/
455
216
217
E-207
208
209
E-208
Air Feed
K-201
230
215
218
210
R-200
214
E-206
R201
207
219
212
E-201
206
E-203
231
K-200
211
236/
401
K-200
Light Gas
To L.G.Separations
PFD pg. 6
205
232
233
V-202
234
E-204
E-205
E-200
235/
301
PFD pg. 6
Products
To Separations
204
K-202
Ethylbenzene
From Separations
203/
316
114/
202
K-202
V-200
225
223
221
V-201
Water treatment
222
220
E-202
200
Ethane Feed
226
201
224
227
Purge
inerts
inerts
311
Incinerated
T-302
Steam
308
Light Gases
Vented
327
312
Benzene
To Alkylation
inerts
306
P-302
T-301
Steam
310
309
307
Toluene For
Sale
P-301
Products
From Dehydrogenation
235/
301
303
304
305
T-300
Steam
E-300
inerts
Products
From L.G. Separations
453/
302
313
203/
316
314
Ethylbenzene
To Dehydrogenation
K-303
T-303
Steam
315
Styrene Finish
To Separations pg. 2
inerts
329
317
325
328
E-301
E-302
inerts
P-303
Styrene
to Customer
and Storage
P-1017
FC
319
inerts
321
Styrene Finish
From Separations pg. 1
315
T-304
P-1018
Steam
T-305
318
P-1019
Steam
320
T-306
Steam
322
Byproducts
From Alkylation
113/
324
323
Heavy Byproducts
To Treatment
Light Gas
From Dehydrogenation
236/
401
402
K-400
403
404
V-400
405
M-400
E-400
406
K-401
407
408
V-401
409
M-401
E-401
411
K-402
PFD pg. 6
412
413
PFD pg. 6
410
415
416
K-403
417
418
V-403
420
M-403
E-403
421
K-404
PFD pg. 6
422
423
K-406
432
433
V-406
435
M-406
E-406
436
K-407
437
438
V-407
M-407
E-407
447
448
V-409
M-409
440
441
442
450
V-405
443
V-408
M-408
E-408
PFD pg. 6
439
451
K-410
PFD pg. 6
428
M-405
429
K-408
PFD pg. 6
E-409
427
E-405
PFD pg. 6
434
446
426
K-405
424
PFD pg. 6
K-409
425
PFD pg. 6
431
445
V-404
414
M-404
E-404
419
430
V-402
M-402
E-402
454
444
213/
455
E-410
456
To Treatment
449
105/
452
453/
302
Products
To Separations
L.G. Separations
K-403
205.
1
205
K-200.1
205.
2
K-200.2
205.
3
K-200.3
206
K-403.1
E-200.1
221.
1
K-202.1
221.
2
E-202.1
221.
3
K-202.2
222
415.
3
K-403.2
415.
4
E-403.2
416
K-403.3
K-404.1
420.
2
E-404.1
420.
3
K-404.2
420.
4
E-404.2
421
K-404.3
L.G. Separations
K-405
405.
1
K-401.1
405.
2
E-401.1
405.
5
K-401.3
405.
3
K-401.2
405.
6
E-401.3
405.
4
E-401.2
405.
7
K-401.4
425.
1
425
K-405.1
405.
8
405.
10
E-401.5
K-401.5
425.
2
E-405.1
425.
3
K-405.2
425.
4
E-405.2
426
K-405.3
L.G. Separations
K-406
E-401.4
430.
1
430
405.
9
406
K-406.1
430.
2
E-406.1
430.
3
K-406.2
430.
4
E-406.2
431
K-406.3
K-401.6
L.G. Separations
K-407
L.G. Separations
K-402
435.
1
435
409.
1
409
E-403.1
420.
1
420
E-202.2
L.G. Separations
K-401
405
415.
2
L.G. Separations
K-404
Dehydrogenation
K-202
221
415.
1
415
K-402.1
409.
2
E-402.1
409.
5
K-402.3
409.
3
K-402.2
409.
6
E-402.3
409.
4
435.
2
E-407.1
435.
3
K-407.2
435.
4
E-407.2
436
K-407.3
E-402.2
409.
7
K-402.4
K-407.1
409.
8
L.G. Separations
K-408
E-402.4
440.
1
440
K-408.1
440.
2
E-408.1
440.
3
K-408.2
440.
4
E-408.2
441
E-408.3
411
402.5
L.G. Separations
K-409
445.
1
445
K-409.1
445.
2
E-250
445.
3
E-251
445.
4
E-248
446
E-252
114/
202
113/
324
Byproducts
To Separations
110
LC
V-93
105/
452
119
E-100
118
106
116
12
112
FC
49
T-100
R-100
111
R-101
LC
109
Benzene
From Separations
117
104/
327
115
FC
102
101
103
100
Benzene Feed
P-100
FC
213/
455
FC
TC
TC
PC
216
217
E-207
208
209
E-208
Air Feed
K-201
230
215
218
210
R-200
214
TC
E-206
R201
207
FC
219
212
E-201
E-203
TC
206
231
K-200
211
236/
401
K-200
TC
P&ID pg. 6
Light Gas
To L.G.Separations
TC
E-204
205
232
233
234
E-205
E-200
TC
226
235/
301
P&ID pg. 6
Products
To Separations
204
K-202
Ethylbenzene
From Separations
203/
316
FC
221
K-202
Water treatment
E-202
Ethylbenzene and Ethane
From Alkylation
114/
202
225
223
222
220
TC
FC
200
201
224
Ethane Feed
227
Purge
inerts
LC
PC
inerts
311
Incinerated
FC
T-302
TC
FC
Steam
308
LC
LC
PC
Light Gases
Vented
327
312
inerts
Benzene
To Alkylation
FC
306
P-302
T-301
TC
FC
Steam
LC
LC
310
PC
309
307
Toluene For
Sale
FC
FC
Products
From Dehydrogenation
235/
301
303
304
305
P-301
T-300
TC
FC
E-300
Steam
inerts
Products
From L.G. Separations
453/
302
LC
LC
313
PC
203/
316
314
Ethylbenzene
To Dehydrogenation
FC
K-303
T-303
TC
FC
Steam
LC
315
Styrene Finish
To Separations pg. 2
inerts
FC
329
317
325
326
328
E-301
E-101
E-181
inerts
LC
FC
PC
319
inerts
321
Styrene Finish
From Separations pg. 1
315
T-304
TC
LC
FC
PC
Steam
LC
FC
T-305
318
LC
TC
FC
PC
Steam
FC
LC
T-306
320
TC
FC
Steam
LC
322
Byproducts
From Alkylation
113/
324
323
Heavy Byproducts
To Treatment
Light Gas
From Dehydrogenation
236/
401
402
K-400
403
404
405
M-400
E-400
406
K-401
407
408
411
K-402
P&ID pg. 6
V-400
409
M-401
E-401
V-401
412
413
M-402
E-402
V-402
P&ID pg. 6
410
415
416
K-403
417
418
420
M-403
E-403
421
K-404
P&ID pg. 6
422
423
431
K-406
432
433
E-406
435
436
K-407
437
438
P&ID pg. 6
447
E-409
448
E-407
K-408
V-407
451
K-410
V-409
441
442
443
M-408
E-408
P&ID pg. 6
V-408
439
450
M-409
V-405
429
440
M-407
P&ID pg. 6
V-406
446
K-409
428
M-405
P&ID pg. 6
V-404
434
445
427
E-405
424
M-406
P&ID pg. 6
426
K-405
419
430
425
M-404
E-404
P&ID pg. 6
V-403
414
454
444
213/
455
E-410
456
To Treatment
449
105/
452
453/
302
Products
To Separations
L.G. Separations
K-403
205.
1
205
K-200.1
205.
2
K-200.2
205.
3
K-200.3
206
415
K-403.1
E-200.1
415.
2
E-403.1
415.
3
K-403.2
415.
4
E-403.2
416
PC
K-403.3
FC
TC
L.G. Separations
K-404
Dehydrogenation
K-202
221.
1
221
K-202.1
221.
2
E-202.1
221.
3
K-202.2
222
K-404.1
L.G. Separations
K-401
K-401.1
405.
2
E-401.1
405.
5
K-401.3
405.
3
K-401.2
405.
6
E-401.3
405.
4
E-401.2
405.
7
K-401.4
425.
1
425
K-405.1
405.
8
420.
3
K-404.2
420.
4
E-404.2
421
K-404.3
405.
10
E-401.5
K-401.5
425.
2
E-405.1
425.
3
K-405.2
425.
4
E-405.2
426
K-405.3
L.G. Separations
K-406
E-401.4
430.
1
430
405.
9
406
K-406.1
430.
2
E-406.1
430.
3
K-406.2
430.
4
E-406.2
431
K-406.3
K-401.6
L.G. Separations
K-407
L.G. Separations
K-402
435.
1
435
409.
1
409
420.
2
E-404.1
L.G. Separations
K-405
405.
1
405
420.
1
420
E-202.2
K-402.1
409.
2
E-402.1
409.
5
K-402.3
409.
3
K-402.2
409.
6
E-402.3
409.
4
435.
2
E-407.1
435.
3
K-407.2
435.
4
E-407.2
436
K-407.3
E-402.2
409.
7
K-402.4
K-407.1
409.
8
L.G. Separations
K-408
E-402.4
440.
1
440
K-408.1
440.
2
E-408.1
440.
3
K-408.2
440.
4
E-408.2
441
E-408.3
411
402.5
L.G. Separations
K-409
445.
1
445
K-409.1
445.
2
E-250
445.
3
E-251
445.
4
E-248
446
E-252
3.80m.
3.80m.
Dehydro
Dehydrogenation
Dehydrogenation
3.59m.
T-303
T-305
2.12m.
T-300
0.80m.
T-301
3.80m.
3.80m.
Dehydrogenation
Dehydrogenation
0.34m.
3.64m.
T-306
5.61m.
T30
2
T-304
V-407
V-408
1.90m.
1.90m.
1.90m.
1.90m.
Alkylator
Alkylator
Alkylator
Alkylator
V-409
V-400
V-406
V-404
V-405
3.55m.
V-401
Alkylation Tower
V-403
V-402
AREA 400
LIGHT GASES SEPARATION
FRONT
Trans
Akylator
Trans
Akylator
Trans
Akylator
Trans
Akylator
1.10m.
1.10m.
1.10m.
1.10m.
10.00m.
10.00m.
10.00m.
T-300
Dehydro
Tr
a
n
s
Al
k
yl
at
or
T
3
0
2Alkyl
ator
Tr
Tr
a
a
n
n
s
s
Al Alkylation
Al
k Tower k
yl
yl
T-304
at
at
or
or
Alkyl
ator
Alkyl
ator
Tr
a
n
s
Al
k
yl
at
or
10.00m.
Dehydro
Alkyl
ator
V-400
V-401
V-402
V40
6
10.00m.
T-306
T
3
0
1
Appendix C: Separations
R := 1.314 lbmol K
atm
lb
MWv := 85.187
L := 4791
lbmol
lbmol
v := 5.1336 10
lb
Wl := L MWl
Wv := V MWv
Wl
= 28.833
Wl v
Flv :=
Wv l
Flv = 0.914
0.5
l := 51.077
T := 368.69 K
lb
MWl := 105.15
V := 205.1
hr
ft
Wv
lbmol
lbmol
hr
lb
ft
v := 7.3254 10
:= 21.913
dyne
cm
NumberOfTrays := 66
cP
Csb := 10
Csb = 0.121
20
0.2
K := Csb
K = 0.123
v = 0.051
l = 51.077
l v
uflood := K
0.5
uflood = 3.878
fraction := 0.75
uop := ( fraction ) uflood
uop = 2.909
Finding the Diameter using equation 12-14 Wankat
:= 0.95
Dia :=
( 4 V MWv)
fraction
uflood
3600
Dia = 6.6
ft
Diameter := Dia
30.48
100
Diameter = 2.012
0.5
R := 1.314 lbmol K
atm
lb
MWv := 85.187
L := 4791
lbmol
lbmol
v := 5.1336 10
hr
lb
Wl := L MWl
Wv := V MWv
Wv
= 28.833
Flv :=
Wl v
Wv
l
Flv = 0.914
0.5
l := 51.077
T := 363.45 K
lb
MWl := 105.15
V := 205.1
ft
Wl
lbmol
lbmol
hr
lb
ft
v := 7.3254 10
:= 21.913
dyne
cm
NumberOfTrays := 66
cP
Csb := 10
Csb = 0.121
20
0.2
K := Csb
K = 0.123
v = 0.051
l = 51.077
l v
0.5
uflood := K
uflood = 3.878
fraction := 0.75
uop := ( fraction ) uflood
uop = 2.909
Finding the Diameter using equation 12-14 Wankat
:= 0.95
Dia :=
( 4 V MWv)
)
v fraction uflood 3600
Dia = 6.6
ft
Diameter := Dia
30.48
100
Diameter = 2.012
0.5
R := 1.314 lbmol K
atm
lb
MWv := 85.187
L := 4791
lbmol
lbmol
v := 5.1336 10
lb
Wl := L MWl
Wv := V MWv
Wl
= 28.833
Wl v
Flv :=
Wv l
Flv = 0.914
0.5
l := 51.077
T := 332.23 K
lb
MWl := 105.15
V := 205.1
hr
ft
Wv
lbmol
lbmol
hr
lb
ft
v := 7.3254 10
:= 21.913
dyne
cm
NumberOfTrays := 66
cP
Csb := 10
Csb = 0.121
20
0.2
K := Csb
K = 0.123
v = 0.051
l = 51.077
l v
0.5
uflood := K
uflood = 3.878
fraction := 0.75
uop := ( fraction ) uflood
uop = 2.909
Finding the Diameter using equation 12-14 Wankat
:= 0.95
Dia :=
( 4 V MWv)
fraction
uflood
3600
Dia = 6.6
ft
Diameter := Dia
30.48
100
Diameter = 2.012
0.5
Toluene/EB Column
T-302
n-Hexane/Benzene Split
Pressure
0.2666
1.0133
0.2631
deg Celsius
59.08
90.3
95.54
81.64
24
66
1584
39.37
40.23
Pressure
0.267
1.013
0.263
deg Celsius
38.27
41.51
41.82
40.53
24
40
960
39.37
24.38
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
bar
bar/atm
atm
K
332.23
363.45
368.69
354.79
in.
in.
in./m
m
132 ft
Column Diameter
Top
2.12 m
6.96 ft
Based on Previous Models the Diameter of the
Total Column will be assumed to not change drastically
because changes in temperature are minimal
Diameter of Packing
1.31 m
4.29 ft
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
Column Diameter
Top
bar
bar/atm
atm
K
311.42
314.66
314.97
313.68
in.
in.
in./m
m
0.34 m
80.00 ft
1.10 ft
Benzene/Toluene Column
T-303
EB/Styrene Column
Pressure
0.2666
1.0133
0.2631
deg Celsius
41.51
58.17
69.54
56.41
24
23
552
39.37
14.02
Pressure
0.080
1.013
0.079
deg Celsius
61.68
62.42
69.77
64.62
24
72
1728
39.37
43.89
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
Column Diameter
Top
bar
bar/atm
atm
K
314.66
331.32
342.69
329.56
in.
46.00 ft
in.
in./m
m
0.80 m
0.00 ft
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
bar
bar/atm
atm
K
334.83
335.57
342.92
337.77
in.
in.
in./m
m
144 ft
Column Diameter
Top
5.63 m
18.47 ft
Diameter of Packing
6.38 m
20.94 ft
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
T-306
0.053
1.013
0.053
deg Celsius
60.6
60.61
60.65
60.62
24
45
1080
39.37
27.43
bar
bar/atm
atm
K
333.75
333.76
333.8
333.77
in.
in.
in./m
m
Pressure
90.00 ft
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
0.053
1.013
0.053
deg Celsius
60.6
60.69
73.3
64.86
24
30
720
39.37
18.29
bar
bar/atm
atm
K
333.75
333.84
346.45
338.01
in.
in.
in./m
m
60.00 ft
Column Diameter
Top
5.61 m
18.41 ft
Column Diameter
Top
3.64 m
11.96 ft
Diameter of Packing
5.88 m
19.27 ft
Diameter of Packing
1.72 m
5.63 ft
T-305
Pressure
Top
Middle
Bottom
Average
Tray Spacing
Number of Trays
Column Height
0.053
1.013
0.053
deg Celsius
60.61
60.63
60.82
60.69
24
30
720
39.37
18.29
bar
bar/atm
atm
K
333.76
333.78
333.97
333.84
in.
in.
in./m
m
60.00 ft
Column Diameter
Top
3.59 m
11.77 ft
Diameter of Packing
3.44 m
11.29 ft
1.358
1.013
1.340
deg Celsius
Top
147.5
Middle
193.8
Bottom
193.9
Average Temp
178.4
Tray Spacing
24
Number of Trays
49
Column Height
1176
39.37
29.87
Column Diameter
Top
bar
bar/atm
atm
K
420.65
466.95
467.05
451.55
in.
in.
in./m
m
3.55 m
98.00 ft
11.65 ft
Bp
-252.6
-195.8
-103.75
-88.6
68.73
80.09
110.65
136.2
145.16
152.41
159.24
161.33
165.5
181.14
183.3
K
8.72E+03
4.31E+03
3.11E+02
2.46E+02
1.18E+00
7.85E-01
2.70E-01
1.01E-01
6.86E-02
4.39E-02
8.49E-03
3.52E-02
2.70E-02
1.30E-02
9.95E-03
alpha
2.02
13.84
1.27
207.78
1.51
2.91
2.67
1.47
1.56
5.17
0.24
1.31
2.07
1.31
Mol fraction
0.0000
0.0000
0.0000
0.0000
0.0005
0.0200
0.0223
0.4821
0.4744
0.0002
0.0000
0.0002
0.0002
0.0001
0.0000
Bp
-252.6
-195.8
-103.75
-88.6
68.73
80.09
110.65
136.2
145.16
152.41
159.24
161.33
165.5
181.14
183.3
K
8.72E+03
4.31E+03
3.11E+02
2.46E+02
1.18E+00
7.85E-01
2.70E-01
1.01E-01
6.86E-02
4.39E-02
8.49E-03
3.52E-02
2.70E-02
1.30E-02
9.95E-03
alpha
2.02
13.84
1.27
207.78
1.51
2.91
2.67
1.47
1.56
5.17
0.24
1.31
2.07
1.31
Vent Gas
Distillate
Distillate
T-300
Bottoms
Bottoms
T-303
BEB
7.79
TS
3.93
BT
2.91
TEB
2.67
TT
1.00
EBEB
1.00
EBT
0.37
SEB
0.68
zB
0.0200
zT
2.11E-03
zEB
0.4821
zS
0.49
zT
0.0223
zEB
0.50
FRA,dist
0.9999
FRA,dist
0.98
FRB,dist
0.9999
FRB,dist
0.98
Nmin
FRC,dist
19
0.9999
Nmin
FRC,dist
20
1.00
Mol fraction
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0021
0.5025
0.4945
0.0002
0.0000
0.0002
0.0002
0.0001
0.0000
T-304
Bp
-252.6
-195.8
-103.75
-88.6
68.73
80.09
110.65
136.2
145.16
152.41
159.24
161.33
165.5
181.14
183.3
K
alpha
Mol fraction
8.72E+03
0.0000
4.31E+03
2.02
0.0000
3.11E+02
13.84
0.0000
2.46E+02
1.27
0.0000
1.18E+00
207.78
0.0000
7.85E-01
1.51
0.0000
2.70E-01
2.91
0.0000
1.01E-01
2.67
0.0001
6.86E-02
1.47
0.9982
4.39E-02
1.56
0.0005
8.49E-03
5.17
0.0000
3.52E-02
0.24
0.0005
2.70E-02
1.31
0.0005
1.30E-02
2.07
0.0002
9.95E-03 1.309709
0.0000
Styrene/Cumene Split
By Products
MW
Hydrogen
2.02
Nitrogen
28.01
Ethylene
28.05
Ethane
30.07
n-Hexane
86.18
Benzene
78.11
Toluene
92.14
Ethylbenzene
106.17
Styrene
104.15
cumene
120.19
n-p-benzene
120.19
1M3-EBenzene
120.19
-methylstyrene
118.18
m-DiEBenzene
134.22
n-Butyl-Benzene
134.22
Distillate
T-305
Bottoms
EBC
2.30
EBS
1.47
1.00
2.30
SS
EBS
1.47
CS
0.64
SS
1.00
zEB
0.000
CS
0.64
zC
0.001
zEB
0.000
zS
zC
0.001
FRA,dist
0.9993
1.00
FRB,dist
0.9993
FRA,dist
0.9993
Nmin
FRB,dist
0.9993
FRC,dist
Nmin
FRC,dist
32
1.00
K
alpha
8.72E+03
4.31E+03
2.02
3.11E+02
13.84
2.46E+02
1.27
1.18E+00
207.78
7.85E-01
1.51
2.70E-01
2.91
1.01E-01
2.67
6.86E-02
1.47
4.39E-02
1.56
8.49E-03
5.17
3.52E-02
0.24
2.70E-02
1.31
1.30E-02
2.07
9.95E-03 1.309709
Distillate
EBC
zS
Bp
-252.6
-195.8
-103.75
-88.6
68.73
80.09
110.65
136.2
145.16
152.41
159.24
161.33
165.5
181.14
183.3
1.00
32
1.00
Bottoms
Mol fraction
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9955
0.0010
0.0000
0.0013
0.0016
0.0007
0.0000
Bp
-252.6
-195.8
-103.75
-88.6
68.73
80.09
110.65
136.2
145.16
152.41
159.24
161.33
165.5
181.14
183.3
K
alpha
Mol fraction
8.72E+03
0.0000
4.31E+03
2.02
0.0000
3.11E+02
13.84
0.0000
2.46E+02
1.27
0.0000
1.18E+00
207.78
0.0000
7.85E-01
1.51
0.0000
2.70E-01
2.91
0.0000
1.01E-01
2.67
0.0000
6.86E-02
1.47
0.9800
4.39E-02
1.56
0.0028
8.49E-03
5.17
0.0005
3.52E-02
0.24
0.0057
2.70E-02
1.31
0.0078
1.30E-02
2.07
0.0000
0.0099538 1.309709
0.0037
T-306
EBC
2.30
Distillate
EBS
1.47
Bottoms
SS
1.00
CS
0.64
zEB
0.000
zC
0.003
zS
0.98
FRA,dist
0.9983
FRB,dist
0.9983
Nmin
FRC,dist
28
1.00
T-303
Molar Mass:
Liquid
Molar Mass (kg/kgmole)
Surface tension
dyne/cm
kg/s2
21.913
0.021913
Surface tension
dyne/cm
kg/s2
25.695
0.025695
0.30367 0.007325
3.04E-04 7.33E-06
Viscosity
cP
kg/m*s
0.41967 0.0063562
4.20E-04 6.3562E-06
Viscosity
cP
kg/m*s
Flows
kmol/h
kmol/s
104.18
Vapor
106.11
Flows
kmol/h
kmol/s
1199
0.3331
1222
0.3394
T-304
Molar Mass:
Liquid
Vapor
Molar Mass (kg/kgmole)
104.23
104.16
T-305
Molar Mass:
Liquid
Molar Mass (kg/kgmole)
104.51
Vapor
104.16
Surface tension
dyne/cm
kg/s2
Surface tension
dyne/cm
kg/s2
26.619
0.026619
0.46407
4.64E-04
0.0062951
6.30E-06
73.27
0.02035
287.4
0.07983
2421
0.6725
102.8
0.0286
26.67
0.02667
Viscosity
cP
kg/m*s
0.46345 0.006295
4.63E-04 6.30E-06
Viscosity
cP
kg/m*s
Flows
kmol/h
kmol/s
360.7
0.100194
Flows
kmol/h
kmol/s
838.3
0.23286
T-306
Molar Mass:
Molar Mass (kg/kgmole)
Liquid
Vapor
119.68
104.16
Surface tension
dyne/cm
kg/s2
23.651
0.023651
Viscosity
cP
kg/m*s
0.47297 0.006295
4.73E-04 6.30E-06
Flows
kmol/h
kmol/s
1.634
0.000454
71.64
0.0199
Gas Phase
Molar Mass
kg
Ml := 105.15 kmol
Density
l := 818.17
kg
Mg := 85.19 kmol
kg
Surface Tension
:= 0.021913
kg
g := 0.82233
kg
2
kg
6 kg
g := 7.33 10
m s
m s
Liqflow := 0.6725 kmol
s
4
l := 3.04 10
Viscosity
kmol
s
Gasflow := 0.0286
Flow := 2.0 Pa
ug :=
Flow
(g0.5)
ug = 2.205
m
s
Vg := Gasflow
Mg
g
3
Vg = 2.963
m
s
Cross section Ac
Ac :=
Vg
ug
Ac = 1.343
0.5
Ac
Dc := 4
Dc = 1.308
HETP assumed as 2 ft
Column 100
Column 100
Column 100
Pressure(kPa)
26.66
Condenser Temp (deg C)
86.23
Reboiler Temp (deg C)
97.09
Comp Recovery of Toluene
0.9999
Reflux Ratio
3
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.0698
0.0000
n-Hexane
0.0022
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.1129
0.0000
Benzene
0.1118
0.0000
Ethyl Benzene
0.5757
0.3287
Hydrogen
0.0001
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0023
0.0000
Water
0.0000
0.0000
Ethylene
0.0046
0.0000
Styrene
0.1207
0.6640
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0023
n-P-Benzene
0.0000
0.0026
AMS
0.0000
0.0023
Pressure(kPa)
26.66
Condenser Temp (deg C)
82.23
Reboiler Temp (deg C)
96.95
Comp Recovery of Toluene
0.9999
Reflux Ratio
5
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.0931
0.0000
n-Hexane
0.0030
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.1508
0.0000
Benzene
0.1492
0.0000
Ethyl Benzene
0.5909
0.3447
Hydrogen
0.0001
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0030
0.0000
Water
0.0000
0.0000
Ethylene
0.0061
0.0000
Styrene
0.0037
0.6486
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0021
n-P-Benzene
0.0000
0.0024
AMS
0.0000
0.0021
Pressure(kPa)
Condenser Temp (deg C)
Reboiler Temp (deg C)
Comp Recovery of Toluene
Reflux Ratio
Total Trays w/o C & R
Tray Position
26.66
73.20
96.48
0.9999
10
67
50
Composition of Exiting streams
Chemicals
Overhead exiting
Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.1510
0.0000
n-Hexane
0.0049
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.2444
0.0000
Benzene
0.2419
0.0000
Ethyl Benzene
0.3429
0.3985
Hydrogen
0.0001
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0049
0.0000
Water
0.0000
0.0000
Ethylene
0.0099
0.0000
Styrene
0.0000
0.5954
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0019
n-P-Benzene
0.0000
0.0022
AMS
0.0000
0.0019
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Vessel Parameters
Vessel
Diameter (m)
Height(m)
3
Volume(m )
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
6.36911E+07
1.04578E+08
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
1.500
0.550
0.972
0.088
0.00
26.66
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
7.93204E+07
1.14809E+08
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
1.500
0.550
0.972
0.088
0.00
26.66
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
9.88086E+07
1.28452E+08
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
1.500
0.550
0.972
0.088
1.2E+08
1.0E+08
8.0E+07
6.0E+07
4.0E+07
2.0E+07
0.0E+00
3
10
0.1400
0.1200
0.1000
0.0800
0.0600
0.0400
0.0200
0.0000
15
Reflux Ratio
10
12
14
16
1.6E+08
1.4E+08
Reboiler Duty (kJ/h)
8
Reflux Ratio
1.2E+08
1.0E+08
8.0E+07
6.0E+07
4.0E+07
2.0E+07
0.0E+00
3
10
Reflux Ratio
15
0.6600
0.6500
0.6400
0.6300
0.6200
0.6100
0.6000
0.5900
0.5800
0.5700
0
8
Reflux Ratio
10
12
14
16
Column 100
Column 100
Column 100
Pressure(kPa)
26.66
Condenser Temp (deg C)
43.59
Reboiler Temp (deg C)
95.48
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
3
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2965
0.0000
n-Hexane
0.0095
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.1890
0.0186
Benzene
0.4750
0.0000
Ethyl Benzene
0.0007
0.4169
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0096
0.0000
Water
0.0000
0.0000
Ethylene
0.0195
0.0000
Styrene
0.0000
0.5587
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0018
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0018
Pressure(kPa)
26.66
Condenser Temp (deg C)
49.96
Reboiler Temp (deg C)
96.02
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
5
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting
Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2472
0.0000
n-Hexane
0.0080
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.3238
0.0059
Benzene
0.3960
0.0000
Ethyl Benzene
0.0005
0.4223
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0080
0.0000
Water
0.0000
0.0000
Ethylene
0.0163
0.0000
Styrene
0.0000
0.5659
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0018
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0018
Pressure(kPa)
26.66
Condenser Temp (deg C)
51.86
Reboiler Temp (deg C)
96.26
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
10
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting
Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2299
0.0000
n-Hexane
0.0074
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.3709
0.0001
Benzene
0.3684
0.0000
Ethyl Benzene
0.0005
0.4248
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0075
0.0000
Water
0.0000
0.0000
Ethylene
0.0151
0.0000
Styrene
0.0000
0.5692
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0019
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0019
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Vessel Parameters
Vessel
Diameter (m)
Height(m)
3
Volume(m )
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
1.39669E+07
3.87203E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
1.500
0.550
0.972
0.088
0.00
26.66
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
2.79917E+07
5.37519E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
1.500
0.550
0.972
0.088
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
6.01163E+07
8.63321E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
1.500
0.550
0.972
0.088
Column 100
Optimal Reflux
4.00E+07
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
Use levels and nozzles
0.00
26.66
0.00
26.66
2.50E+08
2.00E+08
1.50E+08
1.00E+08
5.00E+07
0.00E+00
0.00E+00
3
10
15
10
12
Reflux Ratio
15
20
30
40
50
Reflux Ratio
50
40
30
20
10
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3
1.500
0.550
0.972
0.088
6.00E+07
2.00E+07
7.21977E+07
9.84124E+07
Reboiler
1.193
1.789
2.000
50.000
8.00E+07
Vessel Parameters
Vessel
Diameter (m)
Height(m)
3
Volume(m )
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
3.00E+08
1.00E+08
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
3.50E+08
1.20E+08
Pressure(kPa)
26.66
Condenser Temp (deg C)
51.90
Reboiler Temp (deg C)
96.27
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
12
Total Trays w/o C & R
67
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting
Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2298
0.0000
n-Hexane
0.0074
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.3715
0.0000
Benzene
0.3681
0.0000
Ethyl Benzene
0.0005
0.4248
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0075
0.0000
Water
0.0000
0.0000
Ethylene
0.0151
0.0000
Styrene
0.0000
0.5693
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0019
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0019
10
12
15
Reflux Ratio
20
30
40
50
10
20
30
Reflux Ratio
40
50
60
Column 100
Column 100
Pressure(kPa)
Condenser Temp (deg C)
Reboiler Temp (deg C)
Comp Recovery of Ethylbenzene
Reflux Ratio
Total Trays w/o C & R
Tray Position
26.66
51.88
96.27
0.9999
12
67
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Vessel Parameters
Vessel
Diameter (m)
Height(m)
3
Volume(m )
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
Pressure(kPa)
Condenser Temp (deg C)
Reboiler Temp (deg C)
Comp Recovery of Ethylbenzene
Reflux Ratio
Total Trays w/o C & R
50
Tray Position
Bottoms Exiting
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4248
0.0000
0.0000
0.0000
0.0000
0.0000
0.5693
0.0000
0.0019
0.0021
0.0019
7.21977E+07
9.84124E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
1.500
0.550
0.972
0.088
Column 100
26.66
51.88
96.27
0.9999
12
66
Pressure(kPa)
Condenser Temp (deg C)
Reboiler Temp (deg C)
Comp Recovery of Ethylbenzene
Reflux Ratio
Total Trays w/o C & R
50
Tray Position
26.66
51.88
96.26
0.9999
12
65
50
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
7.21863E+07
9.84041E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
1.500
0.550
0.972
0.088
0.00
26.66
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
7.21704E+07
9.83869E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
1.500
0.550
0.972
0.088
Column 100
Column 100
Column 100
Pressure(kPa)
26.66
Condenser Temp (deg C)
51.88
Reboiler Temp (deg C)
96.27
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
12
Total Trays w/o C & R
66
Tray Position
50
Composition of Exiting streams
Chemicals
Overhead exiting
Methane
0.0000
Ethane
0.2298
n-Hexane
0.0074
Ethyl Toluene(1M3-Ebenzene)
0.0000
Toluene
0.3714
Benzene
0.3682
Ethyl Benzene
0.0005
Hydrogen
0.0002
Oxygen
0.0000
Nitrogen
0.0075
Water
0.0000
Ethylene
0.0151
Styrene
0.0000
n-B-Benzene
0.0000
Cumene
0.0000
n-P-Benzene
0.0000
AMS
0.0000
Pressure(kPa)
26.66
Condenser Temp (deg C)
51.90
Reboiler Temp (deg C)
96.27
Comp Recovery of Ethylbenzene 0.9999
Reflux Ratio
12
Total Trays w/o C & R
66
Tray Position
10
Composition of Exiting streams
Chemicals
Overhead exiting Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2297
0.0000
n-Hexane
0.0074
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.3717
0.0000
Benzene
0.3679
0.0000
Ethyl Benzene
0.0005
0.4249
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0075
0.0000
Water
0.0000
0.0000
Ethylene
0.0151
0.0000
Styrene
0.0000
0.5693
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0019
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0019
Pressure(kPa)
26.66
Condenser Temp (deg C)
51.90
Reboiler Temp (deg C)
96.27
Comp Recovery of Ethylbenzene
0.9999
Reflux Ratio
12
Total Trays w/o C & R
66
Tray Position
20
Composition of Exiting streams
Chemicals
Overhead exiting Bottoms Exiting
Methane
0.0000
0.0000
Ethane
0.2297
0.0000
n-Hexane
0.0074
0.0000
Ethyl Toluene(1M3-Ebenzene)
0.0000
0.0000
Toluene
0.3717
0.0000
Benzene
0.3680
0.0000
Ethyl Benzene
0.0005
0.4249
Hydrogen
0.0002
0.0000
Oxygen
0.0000
0.0000
Nitrogen
0.0075
0.0000
Water
0.0000
0.0000
Ethylene
0.0151
0.0000
Styrene
0.0000
0.5693
n-B-Benzene
0.0000
0.0000
Cumene
0.0000
0.0019
n-P-Benzene
0.0000
0.0021
AMS
0.0000
0.0019
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Heating Duties
Condenser (kJ/h)
Reboiler (kJ/h)
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
7.21863E+07
9.84041E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
0.00
26.66
Tray Section
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
Bottoms Exiting
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4248
0.0000
0.0000
0.0000
0.0000
0.0000
0.5693
0.0000
0.0019
0.0021
0.0019
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
7.22308E+07
9.84525E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
Tray Section
1.500
0.550
0.972
0.088
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
0.00
26.66
Vessel Parameters
Vessel
Diameter (m)
Height(m)
Volume(m3)
Liq Vol. (%)
Level Calculator
Fraction Calculator
Vessel Delta P (kPa)
Fixed Vessel P Spec. (kPa)
7.22285E+07
9.84495E+07
Reboiler
1.193
1.789
2.000
50.000
Condenser
1.193
1.789
2.000
50.000
Horizontal cylinder
Horizontal cylinder
0.00
26.66
Tray Section
1.500
0.550
0.972
0.088
Diameter (m)
Tray/Packed Space (m)
Tray/Packed Vol.(m3)
Hold up (m3)
1.500
0.550
0.972
0.088
0.00
26.66
K-401
Total Cost/Year
$ 135,211,913.38
$ 46,301,845.84
$ 36,120,548.92
$ 34,700,489.93
$ 34,117,414.99
$ 34,019,360.00
$ 34,056,600.61
K-402
Compressors Total Cost/Year
1
$ 83,109,284.25
2
$ 36,885,784.77
3
$ 31,026,285.60
4
$ 30,567,660.67
5
$ 30,323,544.51
6
$ 30,344,373.78
7
$ 30,474,470.36
Compressors
1
2
3
4
5
6
7
K-403
Total Cost/Year
$ 16,723,672.81
$ 13,259,425.74
$ 12,954,054.50
$ 12,974,991.53
$ 13,112,584.04
$ 13,270,201.88
$ 13,343,714.61
Compressors
1
2
3
4
5
6
7
K-404
Total Cost/Year
$ 14,393,491.14
$ 11,988,687.07
$ 11,738,395.62
$ 11,816,536.09
$ 11,976,656.42
$ 12,141,798.15
$ 12,181,480.61
K-405
Compressors Total Cost/Year
1
$ 11,799,344.63
2
$ 10,330,926.05
3
$ 10,156,880.73
4
$ 10,263,640.47
5
$ 10,423,114.77
6
$ 10,534,134.01
7
$ 10,598,345.00
Compressors
1
2
3
4
5
6
7
K-406
Total Cost/Year
$ 11,552,286.13
$ 10,271,294.13
$ 10,070,266.22
$ 10,211,462.87
$ 10,394,355.66
$ 10,482,010.82
$ 10,562,234.00
Compressors
1
2
3
4
5
6
7
K-407
Total Cost/Year
$ 9,993,175.16
$ 9,272,843.40
$ 9,079,644.47
$ 9,266,368.96
$ 9,465,635.45
$ 9,515,501.58
$ 9,613,541.49
K-408
Compressors Total Cost/Year
1
$ 9,442,799.04
2
$ 9,054,784.68
3
$ 8,820,671.40
4
$ 9,072,796.99
5
$ 9,210,912.53
6
$ 9,321,584.03
7
$ 9,418,821.32
Compressors
1
2
3
4
5
6
7
K-409
Total Cost/Year
$ 8,645,010.91
$ 8,584,023.83
$ 8,343,378.82
$ 8,654,569.23
$ 8,748,205.56
$ 8,897,823.72
$ 8,968,179.58
Compressors
1
2
3
4
K-410
Total Cost/Year
$
442,471.46
$
453,857.44
$
454,264.96
$
471,742.91
K-400
Compressors Total Cost/Year
1
$ 3,085,513.74
2
$ 3,284,760.49
3
$ 3,424,930.82
4
$ 3,742,178.44
Compressors
1
2
3
4
5
K-200
Total Cost/Year
$ 11,254,434.85
$ 10,294,761.84
$ 10,194,445.14
$ 10,546,200.01
$ 10,949,864.13
K-201
Compressors Total Cost/Year
1
$
928,140.44
2
$
960,210.75
3
$
968,565.58
K-202
Compressors Total Cost/Year
1
$ 4,124,658.09
2
$ 4,081,197.03
3
$ 4,144,069.67
4
$ 4,328,521.09
5
$ 4,486,006.45
K-300
Compressors Total Cost/Year
1
$ 1,749,431.52
2
$ 3,673,363.34
$14,500,000.00
Cost Annually
$14,000,000.00
$13,500,000.00
$13,000,000.00
$12,500,000.00
$12,000,000.00
$11,500,000.00
1
4
# Compressors
p
T2 = T1 2
p1
( k 1) / k
(10-67)
3 mol
M := 13841 10
hr
T2 := ( 273.15 + 122.03)K
3
p 2 := 263.38 10 Pa
G := 5.8282 10
5 kg
hr
T1 := ( 273.15 + 86.93)K
3
p 1 := 135.78 10 Pa
M W :=
G
M
R c := 8.314
k := 1.1204
( k 1)
k
k R c T1 p 2
Had :=
1
k1
p 1
(10-64a)
Had = 4.882 10 Sv
(10-65a)
Pad := G Had
6
Pad = 7.904 10 W
J 1
mol K M W
w := .01241 poise
NP := 200
Temp. In and Out:
Cp at Bulk Temp.:
C p := 1.542 1000
kg C
Totherin := ( 60 + 273.15) K
Length:
Constants:
Length := 6 m
Density:
:= 2.224
n p := 2
kg
Kc := 0.3
S := 0.5
kg m
kconstant := 0.000163
4
s A
m
Equations:
Ac := Di
G :=
k := ( 1 S) + Kc +
Taverage :=
0.5 n p 1
np
Tin + Tout
2
T1 := Totherin Taverage
0.14
Mt
Ac NP
Di G
Re :=
Pr :=
Di
P = 80.234 Pa
kconstant
.2
f := 0.046 Re
0.28
0.51 k n p T1
B := 1 +
2
:= 1.02
2 B f G2 Length n
p
P :=
Cp
(Tout Tin) Pr
Known:
M t := 1435000
:= 1465
kg
:= .41330 poise
hr
kg
w := .4251 poise
Ds := 2.5 m
Pd := 0.1 m
Lb := 3 m
Ls := 6 m
Pt := 0.2 m
f := 0.025
t b := 0.1 m
Do := 0.1 m
Equations:
Sm :=
De :=
Re :=
Ds Pd Lb
Mt
Gs :=
Sm
Pt
4 0.86 Pt 0.25 Do
Do
De Gs
4 f G 2 D ( 1 + N )
s s
b
P :=
0.14
2 De
w
P = 5.542 Pa
Ls
Nb :=
1
Lb + t b
Two := 293.15K
h air := 20
h s := 1000
m K
ksteel := 45
m K
W m
2
m K
xsteel := 0.075m
Air and Styrene
1
Utank :=
1
h air
xsteel
ksteel
h := 36m
D := 20m
A := D h +
kg
Utank = 18.987
3
s K
1
hs
3 2
A = 2.576 10 m
T := Tair Tsin
T = 13.889 K
q := Utank A T
q = 6.794 10 W
( Tso Twin)
Uhe := 425
Tlm = 5.832 K
W
2
m K
A :=
q
Uhe Tlm
A = 274.11 m
Time := 8000 hr
Molar_Flow := 19158000
mole
hr
Vol_Flow :=
Molar_Flow
48.281
mole
3
m
Vol :=
Vol_Flow
GHSV
3
Vol = 1.764 10 m
Numreactors := 4
Vol reactor :=
Vol
Numreactors
3
Vol_Flow = 110.223
m
s
TOTAL
Direct Costs
Purchased Equipment Costs:
Delivery Costs:
Installation Costs:
Instrumentation & Controls:
Piping:
Electrical Systems:
Buildings:
Yard Improvements:
Service Facilities:
Total Direct Costs:
$384.6
$38.5
$198.8
$152.3
$287.7
$46.5
$76.2
$42.3
$296.1
$1,523.0
Total Direct Costs:
$1,523.0
$609.2
Indirect Costs
Engineering and Supervision:
Construction Expenses:
Legal Expenses:
Contractor's Fee:
Contingency:
Total Indirect Costs:
$139.6
$173.5
$16.9
$93.1
$186.1
$609.2
$2,132.2
Working Capital
Working Capital:
Total Working Capital:
TOTAL CAPITAL INVESTMENT
$376.5
$376.5
$2,508.7
Product
Styrene
Toluene
Total
Utility
Electricity
Refrigeration (to -50C)
Steam, Saturated
3550 kPa (243.38C)
150 kPa (109.95C)
Water Treatment
Cooling Water (15C)
Total
Price
($/kg)
0.34
0.83
0.45
115.00
105.00
40.00
63.80
260.00
Annual Amount
(million kg/yr)
317.07
704.93
9.43
0.24
0.02
0.01
0.02
0.02
Price
($/kg)
2.17
0.76
Annual Amount
(million kg/yr)
898.11
34.01
Price
Annual Amount
7.54 /kWh
14 $/GJ
1.16E+09
5.68E+06
8 $/1000kg
2 $/1000kg
36 $/1000kg
8 /m3
1.51E+06
3.88E+05
3.05E+05
8.51E+07
12.1
0.8
11.0
6.8
197.8
Equipment Type
REACTOR VESSELS
DISTILLATION VESSELS
TRAY COSTS
HEAT EXCHANGERS
COMPRESSORS
PUMPS
TURBINES
STORAGE TANKS
TOTAL
Equipment Cost
(2007 MM$)
6.447
14.690
2.411
94.289
189.822
0.115
69.590
9.644
387.008
TOTAL
Raw Materials
Benzene
Ethane
Air
Dehydogenation Catalyst
Alkylation Catalyst
Transalkyation Catalyst
TBC (Inhibitor)
DNP (Inhibitor)
Total Raw Materials:
$581.8
$108.1
$4.2
$27.8
$1.7
$0.3
$1.4
$6.2
$731.5
$731.5
$12.1
$0.8
$6.8
$79.5
$87.7
$11.0
$197.8
$197.8
$2.7
$0.4
$131.4
$19.7
$0.4
$154.6
$154.6
$1,084.0
$1,084.0
Utilties
High Pressure Steam
Low Pressure Steam
Cooling Water
Refrigeration
Electricity
Waste Treatment
Total Utilities:
General Expenses
Operating Labor
Operating Supervision
Maintainance/Repairs
Operating Supplies
Laboratory Charges
Total Byproducts:
TOTAL
Fixed Charges
Property Taxes
Insurance
Total Fixed Charges:
$43.8
$21.9
$65.7
$65.7
$80.7
$80.7
$80.7
$26.9
$69.1
$55.3
Total General Expense: $151.3
$151.3
Plant Overhead
General Plant Overhead
General Expense
Administration
Distribution/Selling
Research & Development
TOTAL
$297.7
Percentage
of Design
Capacity
Sales
Capital Costs
0.0%
Construction
-$319.8
0.0%
Construction
-$746.3
0.0%
Construction
-$1,066.1
45.0%
$988.1
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
90.0%
$1,976.2
**All numbers are in millions of dollars
Fixed Costs
Depreciation
Allowance
(MACRES)
Taxable Income
Income Tax
Costs
Net Earnings
-$376.5
$376.5
-$542.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$1,084.0
-$148.8
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-$297.7
-426.4
-682.3
-409.4
-245.2
-245.2
-123.7
$0.0
$0.0
$185.2
$349.3
$349.3
$470.9
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$594.6
$0.0
$0.0
-$64.8
-$122.3
-$122.3
-$164.8
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
-$208.1
$297.3
$594.6
$529.7
$472.3
$472.3
$429.7
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
Cumulative Net
Annual Cash
Present Value at
Flow
15.0%
-$319.8
-$746.3
-$1,442.6
$297.3
$594.6
$529.7
$472.3
$472.3
$429.7
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$386.5
$763.0
-$319.8
-$968.8
-$2,059.6
-$1,864.1
-$1,524.2
-$1,260.8
-$1,056.6
-$879.1
-$738.6
-$628.7
-$533.2
-$450.2
-$377.9
-$315.1
-$260.5
-$213.0
-$171.7
-$135.8
-$104.6
-$77.4
-$53.8
-$33.3
$2.0
15.0%
The Net Present Value (NPV) at 15% for this Project is:
$1.99
$1,976.2
-$1,381.7
$0.0
-$208.1
$386.5
$2,508.7
15.40%
Product Prices
Product Prices ($/lb)
$0.75
$0.80
$0.85
$0.90
$0.95
$0.99
$1.05
$1.10
$1.15
$1.20
$1.25
$1.30
$1.35
$1.65
$1.76
$1.87
$1.98
$2.09
$2.17
$2.31
$2.43
$2.54
$2.65
$2.76
$2.87
$2.98
IRR
-0.8%
3.6%
7.2%
10.4%
13.2%
15.0%
18.2%
20.4%
22.4%
24.2%
26.1%
27.8%
29.5%
20.0%
15.0%
10.0%
5.0%
0.0%
$0.70
-5.0%
$0.80
$0.90
$1.00
$1.10
$1.20
$1.30
$1.40