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NAME
HERE
ABSTRACT
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INTRODUCTION
Lorem ipsum dolor sit amet, sit
purto consulatu reformidans ea, quis
autem deserunt pri et. Ne sint magna
brute qui, laoreet salutatus cu sit. Ne
pri homero facete. In paulo affert
tempor vix. Enim intellegam sit at.
Sea ne vocent facilis reprehendunt.
Usu eu oblique efficiendi. Eu sed
pertinax sensibus suscipiantur. Tritani
eripuit intellegebat his an. Tale erat
ferri vis no, alii harum ne pro. Ut per
recusabo
constituam.
Percipit
accusamus consequat nec et, eam ei
blandit adversarium neglegentur, cu
mei ullum tamquam detracto.
2+
Fe ( SCN )(aq )
3++ SCN aq
F e(aq)
2+
FeSC N eq
3+
F eeq
SC N eq
K eq =
A=log
It
I0
A= bC
Where A
absorbance
is
the
amount
of
coefficient
b is the path length
C is the molar absorptivity
REFERENCES
[1]
Petrucci, R.H.; Herring, F.G.;
Madura, J.D.;Bissonnette, C.General
Chemistry:
Principlesand
Modern
Applications,10thed.;
Pearson
Prentice Hall: Canada, 2011
[2]
Silberberg, M. S., & Duran, R.
(2002). Chemistry:
The
molecular
nature of matter and change. New
York, N.Y: McGraw-Hill
[3]
MLA
Dean,
"Lange's handbook
(1987).
John
Aurie.
of chemistry."
[4]
Morgan, John. Using Beer's
Law To Find An Equilibrium Constant
For
Iron(III)
Thiocyanato
Ion.Bloomsberg
University
of
Pennsylvania
http://facstaff.bloomu.edu/jmorgan/Eq
uilibrium%202%20Iron
%20thiocyanate%20S09.pdf
[5]
Measuring
an
Equilibrium
Constant I: Using Color to Analyze an
Equilibrium Mixture The Chemistry
Department, University of Southern
Maine:
http://usm.maine.edu/chy/manuals/11
6/text/KeqSpec.html
[6]
Three Stooges in Chemical
Reactions Department of Chemistry,
APPENDIX
Collin
College.
http://www.collin.edu/chemistry/Hand
outs/1412/Equilibrium
%20%5BRevised2012%5D_1.pdf
Raw Data
Table 1. Absorbance and Molarity of produced
2+
Solutions
Solution
Standard 1
Standard 2
Standard
3
Standard 4
Standard 5
Molarity of
2+
Fe ( SCN ) (M)
0.00002
0.00004
0.0001
Absorbance
0.005
0.035
0.125
0.391
0.769
0.0002
0.0004
2+
Fe ( SCN )
in
Solution
Molarity
of
Absorban
2+
Fe ( SCN ) (M)
ce
Unknown 1
4
1.369383388x 10
0.234
Unknown 2
4
1.670881152x 10
0.296
Unknown 3
4
2.03073332 x 10
0.370
3+
Fe
Initial
Change
6 x 104
-(1.369383388x
4
10
Equilibrium
4.630616612
x 10
SC N
2+
Fe ( SCN )
1 x 103
-(1.369383388x
4
10
8.630616612x
4
10
1.369383388x
104
1.369383388x
4
10
Solution (M)
3+
F e initial
3+SC N
F e
Unknown 1
0.0006
Unknown 2
0.0008
Unknown 3
0.001
3+
F e eq
4.630616612
6.329118848x
7.96926668x
SC N initial
SC N eq
Table 4.
K eq
x 104
104
104
0.001
0.001
0.001
8.630616612x
8.329118848x
7.96926668x
10
10
10
K eq of Unknown Solution
Unknown 1
342.6450047
Unknown 2
316.9564685
342.6450047+ 316.9564685+319.7230532
Average K eq =
3
= 326.4415143
~ 326
Unknown 3
319.7230532
2+
Fe ( SCN )
vs Absorbance
Sample Calculations
3+
Fe /
SC N
of Standard and
M 1 V 1=M 2 V 2
M 2=Molarity of the resulting solution
Where:
M 2=
M1 V1
V2
M 2=
2+
Fe ( SCN )
at equilibrium
2+
Fe ( SCN )
y=2056.4 x0.0476
Where
y = Absorbance in equilibrium
x = Concentration of
2+
Fe ( SCN ) in equilibrium
0.234=2056.4 x0.0476
Isolating x
0.0234+0.0476
=x
2056.4
Solving for x
2+
x=1.369383388 x 104 M FeSC N
Concentration of
3+SC N
in equilibrium
F e
3+
F e eq = Concentration of
3+
F e initial
- Concentration of
SC N eq = Concentration of
SC N initial
- Concentration of
2+
FeSC N eq
Concentration of
2+
FeSC N eq
This can was derived by an ICE table in Figure 2.1
3+ eq
4
2+=4.630616612 x 10 M F e
3+1.369383388 x 104 M FeSC N eq
6 x 104 M F einitial
4. Calculating the
K eq of the reaction
3+
Molarity of SC N eq
Molarity of F e eq
2+
N eq
Molarity of FeSC
K eq =
3+
8.630616612 x 104 M SC N eq
4.630616612 x 104 M F e eq
N 2+
4
1.369383388 x 10 M FFeSC eq
K eq of Unknown 1=
K eq of Unknown 1 342
Percent Error=
Percent Error=
63.32117817
|326.4415143890|
890
x 100
x 100