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  • Name: - Roll No: MM - : Ndian Nstituteof Echnology Adras

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    This document appears to be a quiz for a Metallurgical Thermodynamics course consisting of 6 multiple choice or short answer questions covering various concepts in thermodynamics including: 1) Determining if a given infinitesimal is exact or not 2) Deriving an expression for change in volume with temperature at constant pressure given the isobaric thermal expansion coefficient varies with temperature 3) Calculating standard Gibbs energy of formation and for a reaction using standard state properties 4) Explaining conjugate state variable pairs and determining if (T/p,S) is a conjugate pair 5) Calculating adiabatic flame temperature for the combustion of methane with air 6) Explaining the Legendre transformation

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    2015-Quiz-1

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    This document appears to be a quiz for a Metallurgical Thermodynamics course consisting of 6 multiple choice or short answer questions covering various concepts in thermodynamics including: 1) Determining if a given infinitesimal is exact or not 2) Deriving an expression for change in volume with temperature at constant pressure given the isobaric thermal expansion coefficient varies with temperature 3) Calculating standard Gibbs energy of formation and for a reaction using standard state properties 4) Explaining conjugate state variable pairs and determining if (T/p,S) is a conjugate pair 5) Calculating adiabatic flame temperature for the combustion of methane with air 6) Explaining the Legendre transformation

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    © All Rights Reserved
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    13 views1 page

    Name: - Roll No: MM - : Ndian Nstituteof Echnology Adras

    Uploaded by

    Siddharth Nathan
    This document appears to be a quiz for a Metallurgical Thermodynamics course consisting of 6 multiple choice or short answer questions covering various concepts in thermodynamics including: 1) Determining if a given infinitesimal is exact or not 2) Deriving an expression for change in volume with temperature at constant pressure given the isobaric thermal expansion coefficient varies with temperature 3) Calculating standard Gibbs energy of formation and for a reaction using standard state properties 4) Explaining conjugate state variable pairs and determining if (T/p,S) is a conjugate pair 5) Calculating adiabatic flame temperature for the combustion of methane with air 6) Explaining the Legendre transformation

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    of 1

    Name:____________________________

    Roll No: MM_____________

    D E PA RT M E N T O F M E TA L L U R G I C A L & M AT E R I A L S E N G I N E E R I N G
    INDIAN INSTITUTE
    Duration: 50 min

    OF

    TECHNOLOGY MADRAS

    MM2030: Metallurgical Thermodynamics


    Quiz 1
    Date: 8-Sept-2015, Time: 8:00-8:50 am

    Marks: 25

    Answer all questions


    01.

    Determine if the following infinitesimal is exact or not.


    df := ncV dT +

    nRT
    dV
    V

    where n, cV and R are constants.


    02. Suppose the isobaric thermal expansion coefficient () of a material varies
    with temperature (T ) as a/T 2 , where a is a constant. Derive an expression for
    change in volume (V ) with temperature at constant pressure (p). It is given
    that the volume is V0 when the temperature is T0 .

    a Calculate the standard Gibbs energy of formation (f G298 ) of forsterite


    03.
    (Mg2 SiO4 ) at 298 K (1)
    b Also, calculate the standard Gibbs energy of the reaction (r G298 ) for the

    formation forsterite from periclase (MgO) and quartz (SiO2 ) at 298 K (3)

    Data (all in SI units): f H298


    (Mg2 SiO4 ) = 2173910, S298
    (Mg2 SiO4 ) = 94.11,

    S298 (O2 ) = 205.15, S298 (Si) = 18.81, S298 (Mg) = 32.67, f G298 (MgO) = 569300,
    f G298 (SiO2 ) = 856300

    a Explain with suitable examples the meaning of conjugate pairs of state


    04.
    variables (2)
    b Prove whether the pair (T /p, S) is conjugate or not? (2)

    05. Calculate the adiabatic flame temperature attained when methane, at 298 K,
    is ignited with air in the molar ratio air/methane = 9.524. Assume that carbon
    dioxide and water are the only products of combustion and air is 21 vol.%
    oxygen and 79 vol.% nitrogen at p = 1 bar.

    Data (all in SI units): f H298


    (CH4 (g)) = 78000, f H298
    (CO2 (g)) = 393500,

    f H298 (H2 O(g)) = 241800, cp (CH4 (g)) = +33.97 + 15.57 103 T , cp (CO2 (g)) =
    +44.14 + 9.04 103 T , cp (H2 O(g)) = +30 + 10.71 103 T , cp (N2 (g)) = +27.87 +
    4.27 103 T , cp (O2 (g)) = +29.96 + 4.18 103 T

    a What is meant by Legendre transformation and what is its practical use in


    06.
    the context of thermodynamics? (2)
    b Starting from the entropy fundamental equation, prove that the sate func
    tion = (U, Tp ) exists. (3)

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