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Nettability Literature Survey - Part 1: Rock/Oivbrine Interactions and The Effects of Core Handling On Wettabiiity
Nettability Literature Survey - Part 1: Rock/Oivbrine Interactions and The Effects of Core Handling On Wettabiiity
Summary. Nettability is a major factor controlling the location, flow, +d .@stributiOn Of fl~d? @ a
reservoir. The wettabdity of a core will affect almost all types of core analyses, including capillary pressure,
refative permeability, waterflood behavior, electrical properties, and simulated tertiary recovery. The most
accurate resuks are obtained when natiye- or restored-state cOr~ Me ~ with native cmde Oil~d brine at
reservoir temperattrre and pressure. Such conditions provide cores that have the same wettab~ky as the
.
reservoir.
~.
The wettabih@ of, ori&lly
water-yet reservoir rock can be altered by the adsorption of polar com~ounds
and/or the deposition of organic materiaf that was originally in tie crude oil. The degree of alteration is determined by the interaction of the oil constituents, the mineral su~ace,. and tie brine chefi$~.
The PrO:~ures
for obtaining native-irate, clesned, and rsstored-state cores are diSCUSSe4ss we~ aS the eff@s Of cOnng,
preservation, and experimental conditions on nettability. Also reviewed are methods for artificially controlling
the wetmbflity during laboratory experiments.
htrodirotion
This paper is the first of a series of literature surveys
covering the effectsof nettability on core analysis. 1-3
Changes in nettability have been shown to affect capilIq pressure, relative permeability, waterflood behavior,
dispersion of tracers, simulated terdaiy recovery, imedncible water saturation (IWS), residual 01 saturation
(ROS), and electilcal properties. 4-26 For core analysis
to predict the behavior of a reservoir accurately, the nettability of a core must be the same as tbe nettability of
the undisturbed reservoir rock. A seriousproblem occurs
because many aspects of core handling can drastically affect nettability.
Water-Wet, Oil-Wet, and Neutrafly Wet. Wettabfity
is defined as the tendency of one fluid to spread on or
adhere to a solid surface in the presence of other irmniscible fluids. 7 In a rock/oif/brine system, it is a measure of the preference that tie rock has for either the oil
or water. When the rock is water-wet, there is a tendency for water to occupy the smsll pores and to contact the
majority of the rock surface. Siarly,
in an oil-wet system, the rock is preferentially in contact with the oil; the
location of the two fluids is reversed from the water-wet
case, and oil will occupy the small pores and con~ct tie
majority of the rock surface. It is importunt to note, however, that the teim wettabWy is used for the wetting
preference of the rockand does not necessarily refer to
the fluid that is in contact with tie rock at any given time.
For example, consider a clean sandstone core that is
saturated with a refined ofl. Even though the rock surface is coated with oil, the sandstone core is still preferentially water-wet. Thk wetting preference can be
coP&h!1986society.+Pe!role.mEngineers
lmral
of Petmlc.mTechnology,October19S6
Water-wet
Intermediate wet
Oil-wet
Total
. .
Contact
Angle
(degrees)
o to 75
75 to 105
105to 180
Silicate
Resewoirs
Carbonate
Reservoirs
13
2.
1:
30
A
25
Total
Reservoirs
15
3;
55
TABLE 2DiStribUtiOn
OF dARBONATE
RESERVOIR WETTABILITIES35
contact
Water-wet
Intermediate wet
oil-wet
Strongly oil-wet
Angle
(degreas)
O to 80
.80 to 100
100to 160
160 to 180
Percent of
Reservoirs
.
a
:
15
,,
placed alf of the cmde ofl from the slide. They first aged
a clean glass slide in crude mrdfound that a film, d6posited
over several days, made the slide moderately oil-wet.
They modified the experiment by immersing the slide in
water before aging it in crude. Surprisingly, the oil-wet
fti formed much more rapidly. when a NaCl solution
was used instead of water, the slide also became oil-wet,
but it was necessary to age the slide for a longer period
of time.
October 1986
1129
,113,114
Clementz %120,121 eximined adsorption under mhydroua conditions of the heafl endsthe nonvolndle, highmolecuiar-weight fraction-of
cmde oil, which are
primarily asphal~nes snd resins. He found that rhe compounds adsorbed rapidly onto montmorillonhe, forming
a stable clay/organic compound and chsnging the nettability from water-wet to oil-wet. Clementz also looked
at adsorption under anhydrous coiiditions of the heavy
ends onto Berwcorca that contain significant amounts of
kaolinite. The adsorption of tie heavy ends made the core
neutrally wet as determined by an imblbhion test. The adsorption also,reduced the expansion of swelling clays, clay
surface area, cation exchange capacity, and water sensitivity. The materials that adsorbed onto both the montmorillonite and kaolinite were difficult to remove,
although most of them could be exmacted with a chloroformlacetone mixture.
Clementzused dry cores and clays. As discussed C&
er, the presence of a water fdm will gen@ly reduce the
adsorption of wettabfity-altering materials, typically by
a factor of two to four, although in some cases, it will
completely inhibk adsorption. >@ Collins and Melmse70
measured the adsorption onto kaolinite of asphaltenes dksolved in tolucne. The dry clay adsorbed a maximum of
about 30 mg asphaltene/g clay. The addkion of 6.6%
water t? the clay reduced the adsorption to 13 mg/g. In
addition to reducing the adsorption, the water l@ may
alter the d:tied mechanism of asphaltene adsor@on because the asphaltenes and water will coadaorb. 7 For example, in contrast to his work with anhydrous cores,
ClemenE found that the adsorption of asphaltene onto
Berea cores in the presence of water dld not reduce the
water sensitivity of the kaoliidte. lW
Non-Water-Wet Mineral.% When all of the surface contaminants are carefully removed, most minerals, including quartz, carbonates, and sulfates, are wrongly
water-wet. go,1o7,lx From flotation studies, however, a
few minerals have been found that are naturally but weakly
water-wet or even oil-wet. These minerals include sulfnr; graphite, talc, coal, snd msny sulfides. Pyrophyllhe
and other talc-like silicates (sificates with a sheet-liie
also neutrally wet to Oil&rncture) are ~obably
~et, 30,107,134-12~ese finer~~ ~ ~OW~ tO be SO~ewhat hydrophobic
because air can be used to float them
on water ir3froth flotation, implying a large waterlairhnineral contact angle. Because they are non-water-wet with
air, it is probable that they are also oil-wet.
On the bsais of core-cleaning attempts in a limited number of reservoirs, it appears that cores containing conl are
sometimes na.tur@ly neutrally wet because they can be
cleaned only to a neutfsll wet condition rsther than a
~Uon lY wa~r.wet one. 1za,129 Cuiec96 and Cuicc et
al. 138 cleaned unpreserved cores with different solvents
and then measured wettabdity. In four cases where cores
contained large ixnounts of unexmactable organic carbon,
they were able to clean the cores only ti neutmf nettability. Wendel et al. 12s cleaned core from the Hutton reserv6ii contaminated with an invefi-oil-emulsion drilling
mud. Core from most zones in thk reservoir could be
cleaned to a water-wet state. However, in one zone that
contained si=tilcant amounts of coal, the core was neutrally wet after cleaning. About 50% of the rock surface
in tie neutrally wet zone was covered by a thin layer of
organic matter less than 300 ~ [30 mn] thick. ThIS fayer
1131
Journalof PetroleumTechnology,October1986
--
1132
~onmt,
Newcombe
et d. 136 stated
,.
cores, 160-68 which are prepared by compressing teflon
powder and sintering it at elevated temperatures to
produce a consolidated core. Mungan 167 completely
describes the process. Lefebvr.e du Prey lm has 81s0us<d
Sinter.Sd5tifle88 8tee] and altina
cores.
~,
Teflon is preferred for two reaaons: it is chemically inert
and has a low surface energy. 16g Most minerals found
in reservoir rock have ahigh sutface energy, soabn08t
all liquid8 will spread,,op and wet them against $r. The
w&abiMy of such high-energy solids must bec$mtroUed
with either adsorbed fti
on the solid 8urface or 8urfactants in the fluids. Both of these inethod8 raise the problem of changes in the wettab~ty during the experiment
as a result of adsorptionldesorption phenomena. On the
other hand, the surface energy of teflOn iS low enouti.
that a wide range of contact angles can be obtained with
various combinations of pure fluids that do not contain
surfactants. The u8e of pwe flbids with teflon also avoids
difflcukies with contact-angle hysteresis associated with
adsorption/desorption equilibrium and the problems associated with contact angle and IFT aging phenomena.
Thisis dlscus8ed in more detail in Ref. 1. fiany experiments in tetlon cores use air or Nz anfl various fluida to
va~ the contact angle. Contact angles from Oto 1080 [0
to 1.9 rad] can be obtained by the proper ChOiCeof liqui~gas pati8. 161For ~x~ple, an air/water/teflOn sYstern hasa contact angle through the water of 108 [1.9
rad]. Lefebvre du Prey 160 used mixtures of water,
glycerol, glycol, and alcohols to represent the water pbaae
and mixtures of pure hydrowbons for the oil phaae. Contact angles through the oil phase of from O to 168 [Oto.
2.9 rad] were reported for hk teflm, steel, and alumina
cores.
wet
1133
Native.State Core
Coring. In a nativi-stite (fresh) core, every precaution
is taken to minimtie changes from the undkturbed reservoir nettability condhion, starting when the core ig frost
flushed by the dr~g mud. In pyticukw, a mid with s~factants or a pH that differs greatly from the reservoir
fluids must be avoided. Ofl-based-emulsion muds ?nd
other muds containing surfactaits, caustics, mud thinners,
organic coriosion, in&itors,
and lign@fonates must be
avoided. 175,177Note that, @hIle they probably exist, no
commercially available oil-based muds have been m rted
P
thatcan preserve the reservoir nettability. 175>17178
The different coring fluids for obtaining native-stati
cye have been recomriended. (1) synthetic formation
brine, (2).unoxidized lease crude oil, or (3) a water-breed
mud with a miniznuin of addhives. Bobek et al. 175recommend coring with brine and noadditives. If ,.hk is not
possible, a water-based mud containing only bentonite,
cnrboxymeibyl cellulose, rock salt,, and barite should be
used. This is recommended b~ause they found that this
would not alter the wembfiity of strongly water-wet cores.
Note, however, that the carboxymethyl celkdose,may ~ter
the wettabfit of oil-wet cores, rendering them more
water-wet, 152.~75 Bbrlich and Wygsl 179 recommend a
synthetic formation brine coritaining CaC12 powder for
fluid loss control and no o~er additives. Mungait 180recotiends coriug with lease crude oil. Note f.hatthere are
tio possible problems with the use of crude oil: (1) it
is flammable, and (2) surfactams can be formed by oxidation. of the cmde, which could alter tie wettabili@. ,103
rhfortummly, very MtIe work has been published about
the effects of individual drilling mud components cmwettabiihy, particularly for oif-wet cores. Burkhardt .r al. 176
exaniined the effects of mud filtrate flushing on restored,stitecores snd found no significant effects. Unfortunately, the cores were in contact with the crude oil for only
12 to 16.hours, so it is doubtfol that the wettabtity was
restored before testing.
Bobek ei al. 175 tested several dit%r<nt drillkm mud
componerits used in water-baaemuds on both wat~r-wet
and oil-wet pings The drilling mud :omp6nen@ to be tested were dksolved in or leachdwith distied water then
the resulting solntion was filtcreii. Concentrations of the
compamds were chosen to duplicate those encountered
in the field: Water-wet limestone and s~dstone plugs were
saturated .wltb the test solution and wetibflity alteration
monitored by the irgblbkion method., As,dkcussed earlier,.theyfonnd flat rock salt, carboxymethyl celhdose,.
bentonite, and bake had ho effect on tie wetmbfli~ Of
these initially water-wet plugs. Starch, lime, tetmsoditirn
phosphate, and calcium lignosujfomte altered the wettabtity of the sandstone and/or limestone plugs.
Drilhg components that, did not.affect the water-wet
plugs were tested on oil-wet sandstone plugs. The dry,
initially water-wet plugs were made oil-wet before testing by saturation with Elk Basin crude and aging for one
day. Notethit becanse of the short duration of the aging,
the wettabiity may not have been in equilibri~. The aged
cores were flushed witi a drilling mud component fkraW,
then the wettabfity was measured. by the imbibition
method. .Sa.kdid not affect the wettabfity, whfle carboxymethyl cellulose made. the plugs more water-wet
(bariti was not tested). Bobck et al. found that the PH
,.
1134
residue from the crude will be deposited on &e rock surface if the core is allowed to dry out. To prevent wetEbility alteration, Bobek et al. 175 recommended two
sltemitive packaging procedure: that are now gene@y
used for native-state cores. The fwst ia to wrap the cores
at the weUii@in polyethylene or polyvinylidene film and
then in aluminum foil. The wrapped cores we then sealed
with a thick layer of paraffin or a special plastic sealer
designed to exclnde oxygen aid prevent evaporation. The
second, preferred method is to immerse the cores at tip
wellsite in deoxygenated formation or synthetic brine in
a glass-lined steel or plastic tube, which is then seafid
to prevent leakage and the entrance of oxygen. ImbibG
tion wettabihw tests showed that the nettability of core
packaged by either of these WO methods was unchanged
from the wettabfily mesaimed at the wellsite. Instid of
deoxygenated brine, Mungari180 recommended tit the
cores be cut and stored in degassed l&ae crude oil. Morgan and Gordan 183and McGhee et al. 62 recommended
that the cores be stored in their wetting fluid, either forntstion brine or crude oil. Thewettabiky would be,determined by an imblbhion test at the wellsite. Finally, not?
that cores taken in a robber sleeve, fiberglass, or PVC
Journalof Petroleum Tedmo108y, Octpber 1986
iescriplion
Native state
Exposed to air at
70 to 100nF for 1 day
Exposed to air at
75F for 60 days
Exposed to air at
225F for 7 days
Itiszero
Average
Oisplacementby-oi Ratio
0,97
0,00
0.63
0.00
0.42
0.00
0.18
0.00
Average .
Dlsplacementby-Water Ratio
forneuqally
mdofl-wetcO~~s
aod
In obtaining a cleaned core, an attempt is made to remove all of the fluids and adsorbed material, leaving a
clean rock surface. Gant aid Anderson 129 discuss the
meibcdsused,tu clean core. One common method is reflux
extraction (l)ean-Stark or Soxhfet) with a solvent such as
toluene, sometimes followed by extraction with cfdoroform or methanol. Alternatively, a flow-through system
where the solvents are injected under pressure is sometimes used. 57,&,65lf the cleaning procedure is successful, the core is left strongly water-wet. Cuiec$5 mid
others 57,1w discussed the chemicalreactions involved in
the cleanin process.
Cui&ca,& compared me efficiency of different solvents
in flow-through core cleaning. Initially water-wet outcrop
sandstone and limestone cores were saturated with different cntdes (sometimes the cores also contained brine), then
aged. The aged cores ivere ncyrmfly neutr~- to oil-wet,
as determined. by the Amott wettabflity test. The cores
were then cletied with dlffererit solvents, and the Amott
test was used to determine cleauing efficiency. Cuiec
found that he could clean both sandstone and liiestone
cores by flowing the f?ll@ig seven solvents through the
core: pdarte, hexane, heptane, cyclobexane, beuzene,
pyridine, and ethanol. Chloroform, tohtene, and methanol
used singly were not very effective. Cuiec also looked
at several dtiercnt acidic and basic solvents used individually and found that the acidic solvents tended to be more
effective in cleaning sandstone, whiie the basic solvents
were better in cleaning Iimcstone. This difference was attributed to the acidic nature of the sandstone surface and
the basic mture of the limestone surface. For examplei
because sandstone (silica) has a weakly acidic surface,
it tends to adsorb bases from tie crude oif. When a
stronger acid flows through the sys@m, it will gradually
react with and strip off the adsorbed bases, Ieaviug a clean
silica surface.
G@ and Anderson 129 surveyed most of the corecleouing experiments in the literature. They found that
the best choice of solvents depends heavily on the cmde
~d the mineral surfaces becavse they help determine the
amount and @pe of nettability-altering compounds adsorbed. Solvents that give good results with some cores
and cmdes often faif in other cases. For example, Grist
et al. 1s4 and Holbrook and Beruard45 both found that
they could clean core to a strongly water-wet state using
a cliloroformfmerhanol mixture, while Jennings5s repOrted. fiat thk was unsuccessful. For cleaning for routine
core analysis, API 1s5 reports that cbfom form is excellent for many midcontinent .ctudes,wh~e toluene is us6ful for asphaltic cntd:s..
hi many cases, it appears that any single solvencis relatively ineffective in core cleaning and that much better
results can be obtained wiih a mixtttfe or series of
solvents. 129 The followhg solvents have, been rCpOfied for specflc binbinations of crude and core to give
pcor resufts when used alone: chloroform, ,65 benzene, 5S,1M,120~=bon di~~fide, lU,120 ~~mol, @ ~d
toluene.5@.@.65
.1~.120,1T.l~,1s6
Many of the researchers cited above have found that
toluene used alone is one of the least effective solvents.
However, when combined with other solvents, such as
methanol (CHs OH) 184 or ethanol (CH3 CH zOH), 61
toluene is often ve~ effective. The toluene is effective
in removing the hydrocarbons, including asphal1136
tenes 130JW
and some of the weakly polar compcmmi.s,lW
wbiletbe more,spongly polar methanol (ethanol) qcmoves
the strongly adsorbed polar compounds that are often
responsible for altering wettabilky. In addition to
toluenelmethanol and tolueneletbonol, successful cleaning has ako been reported with cbforoforndacetone 1wZ120.
1= and cfdorofordmetfranol, 1s4 as well as
a number of different series of solvents. ,65
CuieCand his coworkers made the most extensive study
of core cleaning for nettability restoration. In a recent
paper, Cuiec et az. 130statkd that their core cleaning always begins with a toluene flush to remove hydrocarbons
and asphaltenes. A number of solvents are then.tested to
determine the most effective, including (1) a series of nonpolar solvents, e.g., cyclohexane or heptane; (2) acidic
solvents, e.g., cblorofonn, ethanol, or metbanoh (3) basic solventi, e.g., dioxane or pyridine; ond (4) mixtures
of solvents, e.g., methanollacetoneltoluene. When none
of these procedures are effective, other tests are performed
by combining the above procedural, using otler solvents,
ad incremfig the Circdatiog time.
Tohtene is generally not a very effective solvent, but
it canalter the nettability of some core. Jennings 186
cleaned sever,d cores by toluene extraction and found that
the wettabilities and relative penn.eabilities were not
changed. He stoted that this indicated that tolueneextmcted core retoined the reservoir wettabi!ity and coufd
be used for relative p+mneabtity rneosurements, However,
this generally is not the case. Aftbough it is less et%cient
than other solvents, we have found that toluene extraction can alter the wettabili@ and relative penneabtitics
of native-state core. fn some cases, neutmlly wet or tidly
oil-wet mtive-state core becomes strongly water-wet titer extraction witi toluene. The relative permeability
cume~ ~~o ~E,fi. AMOU177 ako found that toluene extraction can clean some cores, while it had Wt3e effect
for other ones, such as the strongly oil-wet Bradford cores.
Therefore, because tolueneextraction will alter the wettabilky and relative permeability of many. native-state
cores, m%uremcnts shouId be tie on mtive-state cores
before toluene extinction.
One problem with a cleaned core is that it is sometimes
difficult, if not impossible, to remove all of the adsorbed
material. If this occurs, the wetta.bfity of tie cleaned core
wifl be left in some indefinite staie, causing variations in
core analyses. Grist et al. lW cleaned cores by three curently used methods and then examined how ROS and endpoint effective permeabilities vtied after a waterflood.
ROS was very similar for W methods. However, the endpoint effectiye water permeability varied by more than
a factor of three betwtin different cleaning methods. Their
explanation for this behavior was that some methods were
able to extract more of the adsorbd. components, leaving.the rock more water-wet. In the more water-wet cores,
the rwidti oil had a greater tendency to form trapped
droplets, blocking pore throats and lowering water permeabtity. The least effective of the three cleaniug me~ods
was overnight reflux extinction with toluene. More effective was reflux extraction with toluene followed by 2
days of extraction with a mixture of cbloroforin oud
methanol. Finally, tie most efficient method was reflux
extraction with tcduene followed by 3 weeks of extraction with chloroform and methanol. In the last stage of
cleaning, methanol was used alone.
Journalof PetroleumTechnology,October1986
Another draivback of cleaned cores is that it is occassionafly possible for cIeaning to change an originally
water-wet rock to an ofi-wet one. The extraction process
may quickfy boil off the connate water, allowing the remaining oif to contact the rock surface and form oil-wet
deposits that are afmost impossible to remove. 187
The cleaning experiments discussed examine the best
methods to remove. cmde oil constituents from the pore
walk. In many cases, core is also contaminated with drilling mud surfactits, which mustalso be removed before
the wettabifity of acore can be restored. 12ar129The best
choice of solvents depends on the crude, the mineraf s~rfaces, and the drilfiig mud surfactsnts. Gant and
Anderson 129cleaned Berea sandstone and Guelph (Baker) dolomite plugs contaminated with an invert-oilemufsion rfrifling mud. filtrate. The best solvent fOr bOfh
rock types was a 50/50 mixture of toluene/methanol, oi
the equivalent, containing 1% ammonium hydroxide. A
three-step method (three successive Dean-Stark
extractions-toluene, foffowed by glacial acetic acid, followed by ethanol) was the second best choice for Berea,
while 2-methoxyetiyl ether was the second best choice
for dolomite, demonstrating that the choice of solvents
can depend O? the mineral surfaces in the core.
Restored-State Core
,
If one conld be positivethat the original reservoir wettabilhy hadizotbeen inadvertently modified, a native-state
core would give resnks closest to those of the reservoir.
However, riative-st@ecores present scveraf problems. The
necessary procedures to preserve the wettabtiq are
troublesome and time-consuming. Even when sll of the
precautions iwe tsken, there is still a possibility that the
nettability has been chtiged through oxidation or through
deposition as tie temperature and pressure dropped when
the core was brought to the surface. In addition, tic question arisesabout tie procedure to follow to obtah the most
reliable information from cores in which the nettability
WaS aftered
When onfy core with alt&ed wei@bfity is available,
the best possible mukiphase measurements ore obtained
by resto& the resefioir wettabfi~ with a three-step
~roces~. 47,F0,64,65.,96,115,128,130,1S0,18SThe f~st ste~ is to
~leaa the core to rernoVeall compounds from th~ rock
surface. After the core is cleaned, the second step is to
flow reservoir fluids into the core sequentially. F~y,
the core is aged at the reservoir temperamre for a suKLcient dine b establish adsorption equilibrium. Seversl experimenters have compared measurements made on core
in the native, cleaned, and rsatored states. In each experiment, measurements in the restored state were slmost
identical to the,previous mtive-sta.te ones,demons@atin
that this procedure will restore nettability. 50,115Js0;18~
~,, The first and most @fficult step in nettability restoration is to clean the contaminated core by use of the
methods described to remove all compounds adsorbed on
the surfaces and to make the core as water-wet as possible. All compounds must be removed from the core because we have no knowledge of which compounds were
adsorbed on the undisturbed reservoir rock and which
were deposited afterward. The USBM or Amott nettability measurements are used to verify that the core is
strongly water-wet., Unforttzmtely, detemining which solvent wiII successfoffy clean the core is still a trial-andIourmt of Petroleum Technology, October 1986
<
make it necesssry
to saturate
Journal
of PetroleumTechnology,October1986
1. The nettability of a rsaeryoir ample affects ita capillmy pressure, relative pe,rmwbtity, waterflood behavior,
dispersion, mid electrical properties. fn addhion, simulated teftiary recovery can be 51ter,cd.The tcfi,~ recove~ PrOcesses affected by we~biE~ include hot-water,
surfactant, miscible, aid caustm floodlng.
2. Cleaned, strongly water-wet cores should be used
onfy in such c6re analyses as porosity. and air permeability, where the wettabilky is unhpportmrt. h addition, they
may be used in other tests when the reservoir is known
to be strongly water-wet.
3. The nettability of originally water-wet mineral sgrfaces can be altered by the adsorption of pokw compounds
aui/or the deposition of orgariic rnattertlmtwas origiMUY in the crude oil. Fmrfactants in the crude oil are
generally believed to ,be polar compounds that contain
oxygen, nitrogen, ,mdlor sulfur. These compounds ~
most prevalent in the heavier fractions of crude oil, such
as the resins and asphaltenes.
4. Nettability alteration is determined by the interaction of the oil constituents, the mineral surface, and the
brine chemistfy, including ionic composition and pH. In
siIicafoiVbrine systems, trace amounts of mukivalent meM. cations can alter *e nettability. The catiom can reduce
the solubti~ of crude oil surfactants and/or activate the
adsorption of aniotiic surfactants onto the silks. Mfdtivalent ions :$tathave altered tie wettabfity of sihcafoil/brine
systems tnclude Ca2, .Mg2, Cu2, Ni2, and Fe3.
5. Work on mineral flotation indicatca that coal,
Acknowledgments
graphite, sulfur, talc, the talc-liie silicates, and many sultidca are probably naturally,neutrally wet to oil-wet. Most
I w grateful to Jeff Meyers for hk many helpful suggesother minerals-includhg
quartz, carbonates, and
tions and comments. I also thank the management of
sulfatesare strongly water-wet in their natural s@.te.
Conoco h.c. for permission to publish this paper,
6. Contact-angle measurements suggest ti.at most carbonate reservoirs range frpm neutralIy to oil-wet as a re- References
sult of the adsorption of surfactimts from the crude oil.
1. Andemm, W, G.: <Weuabitily LiteratureSurvey-Parr 2 Wet7. Very little work has been reported about the changes
Iabitim Measurenimt,, to be published in JPT (Nov. 19S6).
in wetibility caused by drioiig mud addhives. Three
2. Anderson, W.G.: .Wetmbili~ Literature SUrvey-PaX % The Efdifferent Cciring.flrtidshave been recommended to obtain
fects of Watabtity on,the E2ectrkaJProperties of Porous Media,>,
to be published in JPT (Dec. 1986),
native-state core: (1) synthetic formation brine, (2) un-PemmalmmmunlcatimwilhD,J.Wend.at,PetroleumTestingS6wkeS,Santa
Fe SP,ingS,GA,N.. 19S0,
,,----
,...% . . . .. . . . . ..-. -, . . . .
23. Pra{s, M.: 7l?zermalRecoveV, Monograph Series, SPE, Richardson, TX (1982) ?T,55-57.
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1140
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.
,.
1144
X 1.745329
(F32)/l.8
E.O2
= rad
= .0c
m
Ori@.d !m..mdpt
(SPE1 3932) recai.ed in the Sociely of Pelrolwn
Enginem
Dec. %,19%.
PW.raCCePted
f.r P"bU.atlon J"ly23,'19ffi.
Rmn&mm"9CtiPt
ceived Feb.3, 1986.
Jomtiof
Pewoleum Te&olo~,
oMce
Te-
October 1986