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ABSTRACT
A system of partial differential equations describing miscible displacement of iluids irr porous media
is derived
Tb-e system takes into account the
influence
of gravity, the spatial distribution
of
permeability,
dijfusiorr, and jluid viscosities
and
derrsities. A numerical prccedure {or approximating
solutions to the differential systems has been tested
for a horizontal two.dimensional geometry,
In end-to-end displacements
of oil with lessviscous solvetis, the numerical salutions exhibited
fingering qualitatively similar to that observed in
Laboratory models. Small random spatial variations
irr permeability about the mean value are sufficient
to initiate fingering.
Quantitative comparisons O!
computed results with laboratory data show good
agreement,
INTRODUCTION
Miscible flooding .r>f oil by solvent is receiving
increasing
consideration
for field use, ~+ Unfortunate Iy, such floods potentially
present severe
problems in loss of recovery through the by-passing
of oil by expensive
solvent. Consequently,
their
economic evaluation requires sound techniques for
predicting
recovery.
The purposes of this work are to present a finitedifference method for calculating
the multidimensional displacement of oil by solvent and to investigate the validi~ of the method by comparing results
of calculations
with data from displacements
in
laboratory models.s The formulation of the method
COsimulate the model experiments treats a case of
limited scope in the description of solvent fIooding
in the reservoir, The model experiments were carried
out with flaids dtat were assumed to form an incompressible,
ideal, two-component systgm with constant diffusivity.
Establishing
the validity of the method even in
ita present form provides a major step toward che
goal of quantitatively
evaluating individual soIvent
flooding projects.
First, it demonstrates
the fea
.,
...
. ... .
. .
1962
... .
..._
. .
. .. .
HUMBLE OIL 4
HOUSTON, TEX.
REFININGCO.
PROBLEM
. . .. . . .. . . . --
C=:=
l-;
(4)
(vp+pgvh),
. . . .
(1)
V*: (Vp
+ pgvb)
= o
. .
(5)
. . . . . . . . . . . . .
(6)
-1
90=-
9s=-
Kvwo
Kvwa
Wou ,
4
w~u,
(2)
. . .
dwo
-V.;o=KVzWo-VeWo;=4~,
aw.
4
-V*;8=KV2W@VU#4=+;
(3)
KX
axz
KY
132W
BOUNDARY
CONDITIONS
. . . ...(7)
ay
P(Q
y)
=p(o,o)
Y d)j
-gp*
Jo
a%
= P(O,O) -gpJh(O,y)
(O,z)fk
- lJ(O,O)] , . . . (8)
and
dy2
SOCIETY
.. .
. . ... . .
. ... . . . .
P(Ltz)g(L,z)dz
(9)
328
..
Jo
m-,y)=po.,o)-g
. . ..
OF PSTROLElfht
..
.. . . .
..
ENGINEERS
. . .. . .
J~uRNhL
. . .. . . . .
Ax(fnAxgn)i,j
~ Ui+z,j,
n(gi+l,jin
n _gi.l,j,n)]/Ax2
- fi.~,jpn~gi,j,
AYVnAYgn)i,j
- gi,j, ti)
gi:j,n)
s Vi, j+~,nki,j+l,n,:
- fi,~~,n(gi,j,
n-gi,j.l,n)l/Ay2
= AJ/nAzgn)i,j
A(fnAgn)i,j
Then Eq.
equation,
5 is
+ AY(fnA.ygn)i,j.
approximated
by the
difference
Atm.
m=O
.q,n+.p
.-. . ---.-.,
On the left-hand
form
side of Eq.
ki+l,j+
Pii-l,j, n +
On the right-hand
appear.
These
Pi+l,j,
Pi,j,
n + Pi, j,n
J+l,j
Pi+l,j,
i,j
. ...
n + Fi, ),n
Pi,--l, n
= Pi,l, n
pi,N+l,n
= pi,
--------------
with hi,-~
= hi,l
--------
. . .. .. .. . ,.--.-(ll)
;-.
1962
.. .. . .. .. .. . . .........
..
. .. . . .. . . . ----
...
. . . ...
.
.-
.
i = () and i = M (by setting
~O,j, n= Pn-gP.(hf),j
-hO,O).
. . . (12)
PM,j = - g~
+g
ki+l,j + ki,j
n+
+g
)
for~<iSM-~
fori=M,
~y2
(bi,j_hi,j+l)
Ay2
. . .. . . . . . . . . . . . . . . . . . (14)
QoM,j,n
2Yx~-~,j, n
2qM,j, n
AxAy -
each interval
has associated
with it a VX
from the new values of
fiat Eq. 10 iS equivalent rO
or a VY term, calculated
pn. We observe
xi-~,
j,n - xi+~,j,
-VY. a,j+~,n
.1
. . . . . . . . . . . . . . . . . . . . (17)
The factors of 2 arise from the reflection condition.
The total volume rate of injection of solvent at
at the input face is then
N-1
qinn ~(qo,o,n
+ qO,N,n) + E
O,j, n
j=~
~;
~.
i~M-l,
OAj
N-1
(15)
1s
<N.
n +VY. 6,j-~z ,n
...~.v.ytij+~,n+ Q%ijin-*-?o-i,j,
= !0-- .._,_(Ki)
n ---:
. .(:8)
.1
n +VY. kd-h,n
= O,.......
. .
l%us,
,Q1i,i,n = Qoi,j,n = 0
QIM,j,n
j)
~Pi,j,n-Pi,j+l,n~
~Pi,j+l, n+Pt,j, n
= 2q0,j,n
AxAy
Qoo,j,n=
o
j,n
AX2
k.C,j+l
. +ki,j
VY. .1
]+hn
2vxg, j,a
C@
Pi,/, n) (fii,j-hi+l,
(Pi+l,j,Ir
TERMS
Pi,j,n-pi+l,
Pi,j,
n = - vxM_~,j,n
Qb, j,n =
for i = &
Pi+l,j,
The alternating-direction
method used COiterate
to the solution of Eq. 10 subject to the boundary
conditions of Eqs. 11 through 13 has been given
as Eqs. B4 to B6 of the reference.lo
AND INPUT-OUTPUT
= - Vx$,j,
k)* (13)
k=O
vxi+f~,j,n =
h,j, n
xM+~,j,
j=l
VELOCITY
vx_i
9.u~n =
+(q~,(),n
+ M,/V,n)+~
9M,j,n . . (19)
j=l
cwo flow rates gin
and qOutm should be equal
wi~in the accuracy wi% which Eq. 10 is solved by
iteration.
The
OF PLTROI,EiIM
E!VCINEERS
JOURNAL
.
-.
The difference
is then
1
~
KXA:(C,
.
equation
.
h], n +
.for obtaining
Ci, f, n+ I
Ci,j, n+l )
~ a2C
~-u~-
ac
-+~9.....(21)
to
~(c~,n+l-ci,n)
. . . . . . . . . . . (22)
(c;-
$,n
I-C*1
i-~, j,n+l) xi -~,j,n
6-~,j, n
+ (C* 1
(cl+
*
+(c; j-$, n +C*i,~-~,n+l)
Vxi+$,j,n
i,j-~,n
1
i,j,n
Qi,j,n
6,/,. n+l -
n)
Ci,j,
.
+ Ci,j,n+l)
.
term
A2xci,
Xi+$,j
c;+ ~,j
AX Ay
c?,j+~ Ax !ly
.==..
1962
..-.
c*l=+(ci+l+ci)
i+~
. (20)
. .. .. . .
. . . . -. .
. . . . . . (23)
and
C!l=c
$+-L
i. .
.. . . . . . . . .
(24)
11
c=~-~erf
a
~
K vt
7r vz. ~
- . 25)
.
. .
-.
i,2
Centeredin distance
r?-
1,0
Difference Eq.
s-
Lo
M.24
0.6
Exact solution,%(25
0.8
.
,5
~
~ 0.6
:
G
0.4 VId -40 ft/day
K~ 103cm2/sec
L ..72 in,
0.4
L =72 in,
M,.L/Ax .48
vt/+L -0.50
0,2
0.2
v \ t/a
L = 0,007708
vt/6L
= 0,50
0,5
f%ctiarwl Distance,
--l%actianalDistance,-d-
--~
- --
...-
.. .....
.. . . ------ .. .. --.
-.
0.75
x/L
1.0
SW?
0,25
JO IIRN AI.
..
.
-.
if VYi,j+$
> 0 *
cz,j+~
= Ci,j
a-LJ
(i-l,j)
is a destination
point and -VXi-~,j is an output
if
either point
(i, j) or (i+l,j),
or both, is marked,
then
flow;
if VX. I
~+~,j
if VXi+~z,j >0,
C* , . = Ci,j
i+~,]
if VXi+~,j <0,
c?
Similarly,
then
if neither
1 . = Ci+l,j
t+hsJ
> 0, then
(i+l,j)
is a destination
point and VXi+~,j is an output
flow;
if. VX. I
< 0, then (i+l,j) is a source point
L+h,i
and -VXi+%,j is an input flow.
if either
point
or both, is mar~ed,
then
1.2
1,0
m--m-a
M. 12>
M=24
M. 48
0.8
=.
.2
3
~ 0.6
#
&
0.4
V/c5
.40
- K .10-3
ft/day
CONVERGENCE
cm2/sec
L =72 in.
-
0,2
t/dL
.0.007708
w/6L .0,50
0
0
-.
V \
I
I
0.75
0.25
0.5
M- - .Fractirmd_Distm@,
1,0
.. ----
is
op@site to the direction of flow. However, analysis
of the combined p~ocedure with transfer of overshoot
.,
3s9
DECEMBER,1962
.
.;
.. . ... . . ..
. . . ...
, .. . . . .. . ..
.. .
.. . . . .. .......
.. .. . . . . . .
.....
.. . . .. . .. .. . .. .. . . .,..
, -,.-.
n+k -O
+ x
qsoutmAtm
m=(j
mc F
(29)
2
9s~n Atm
m
m=()
BALANCE
n + Pa
4),(J-
bM,O)
9inn
pav
is the density at the average concentrain the rectangle,
Further, assume that this
resistance
varies linearly with time. Let Rn =
pa n(lro,o - hM, o). Then,
where
tion
1
qsoucn ~qM,O,n(cJr,O,
n + CM.O,n+l)
+~
g M, fV,n(cti,N,n + cM,N,n+l)
~~1
qM,j,n(cM,j,n
+ cM,j,n+l)
(26)
i=
The
by
sn
solvent
contained
@!.p
in the rectangle
(Ct,i,n
. . . . . . (27)
Atn
+ Ci+l,j, n
j=o
+C. t,]+l,
. n + Ci+l,j+l, n)
is given
, (28)
$***
Ipn+n
.
8@~n_ 1
n-l+
.-.11
basis
THE
EXPERIMENTAL
DATA
The
quantitative
comparison
between
data
and results
of computation was based on twodimensional experiments in which the oil recovered
was measured as a hmction of the volume of solvent
injected.
The data, repotred by Blackwell, Rayne
and Terry,5 were obtained from floods of a clear
refined oil from the pores of carefully graded Cktawa
sand packed into a Lucite channel 2ft x6ft x 3/8in.
The floods were carried out by filling the model
uniformly widt yi 1 and, with rhe 3/8-in. dimension
vertical, displacmgthe
oil at approximately constant
rate with a solvent such as hexane whose density
had been raised by the addition of carbon tetrachloride to approximate that of the oil. The displacem nts were carried out parsllel to the 6-ft
dimension -by- introducing the solvent into a header
which allows it to enter the sand along the full
2-ft width of the model. Fluid produced from the
outflow end similarly enters a header which aHows
SOCIETY
.-.
-
%+1
51~1
i=O
<1
OF PSTROI,Ell M EXCIXEEIIS
JO IIR!VAI.
~ .
observed
which
%j
distributiorl
Z=2.
at time tn,
Drwelopment
Calculations were made under conditions summarized in Appendix A, for a mobility ratio of 86,
with k.s = O.O5 and with 40 x-increments and 20
Time steps corresponding
to the
y-increments.
injection of 0.0025 pore volume were used throughout, To display the results which are qualitatively
similar to visual observations of the floods, 5 Figs.
4(a), 4(b) and 4(c) are included. These were prepared at successive
times corresponding
to the
three injected volumes of 0.1, 0.25 and 0.5, respectively, They indicate the concentration distribution
aa a map prepared using the line printer. To represent the 6-fk wdirection, 216 lines (six to the inch)
were used;
119 characters (10 to the inch) were
used to represent the 2-fr y-direction. The concentrafrom
tion distribution waa hi-linearly interpolated
the calculated
vaIues at (xf, yj) to yield a value
ccmresuonding to each character position in the
map;. &en I if I I characters was printed, depending onwhe~er the coiicentratioh was-in the intervar
100 to 95 per cent, 95 to 85 per cent, . . ., below
5 per cent. The sequence of characters chosen was
,,
,.
.. . . .. . . . . . .
RESULTS OF CALCULATIONS
t)llw. %tRER,1962
.. . .... .. . . . . .
k talc
measurements
were available
of
No individual
the permeability
variations
with position ..in the
model, i.e., the data to provide values of k;, ~
The visual observations
of the finger formation
implied a permeability distribution
that waa not
strictly uniform. This suggested that setting ki, c =
a constant might not be adequate since the Distribution might not trigger finger formation. On the
other hand, it was thought possible thai round-off
error might provide sufficient variation of velocity
wi~ y to start fingers, To test this, a calculation
with 27-bit floating-point arithmetic was made using
the procedure outlined in the previous paragraph
with M = 20, N ~ 10. No fingering developed. Thus,
it was concluded that a nonuniform permeability
- distribution would be ~equired. -Many-choices of a:
nonuniform distribution could be made which would
Yield an average permeability kav equal to that
. . . . . . . (31)
qino~o
L
Pernreabilit y Distribution
. .. ...
= kav(l + kJ$,jW
k talc =
Iv PO
.
-.
.-
. ...
...
.. .. . . ..
. ----
.. .
:J33
- -:-
-.
M, 8, B, D, X, S, E, C, comma, hyphen and blarik,
respectively.
The result is a picture similar in
appearance
to the visual iihpression
from the
displacement
experiment using dyed solvent. The
early forma tion of a number of small fingers followed
J by the subsequent
inhibition of their gr~wth is
visible from these figures.
Results of these calculations are shown quantitatively in Fig. 5 and compared there with experimental
data. In this figure the oil recovered, plott d in
pore volume of the model, is shown vs the volume
of solvent injected in the same units, Solvent
breakthrough is indicated for the experiment and
the calculations.
The data are shown as the points;
the results of calcu Iation are shown as the curve.
The breakthrough time and subsequent production
performance are considered to be within the range
o f experimental
duplicabi lity of tie datet. The
material-balance
ratio rnc was 1.0 ~ 0.6505 for
~ every time step.
Another comparison for k~ = 0.025 was run with
the 40 x 20 grid using the same values of ~i,j. The
quantitative results are substantially
identical with
those obtained for k x = 0.05. However, the breakthrough time is somewhat later, suggesting that the
effect of decreasing the permeability dispersion is to
delay
the fingering process.
This observation
suggests plotting the results in a different form.
Fig. 6 shows the penetration of the leading finger
plotted against the pore volume of solvent injected.
The two curves at the right are plots for the ~.05
I
0,6
Experimental
Calculated
Breakthrough
k~
0.025
k~
0,05
Colculoted
Observed Breokfhrouqh
o
o
0,4
0.2
0,6
1.0
Experimental
0.8
Calculated
[b} 0.25
PoreVolume +@ed
0.2
o
(c) 0.5 PoreWalvmeInloctwl
.,--4
0.1
0.2
0.3
0,4
0.s
JO IIR!Vri L
,..
k~,i -0,
-
k~,j - k~,i ,
. . , ..(32)
> kav
-
Mobility Ratio = 5
o/ Permeabitiiy
Dis tribrition
-,
Enperimenta I Dato
Mob, Ratio
S4:1
5:1
93,1
A5,1
D 93:1
110
AA
Cnlcula!ed
with lsI k.distn.
Mobility R.tI.
5:1
0,8 -
(al
First k.distribution,
A=
0
0,6
0,4
m 5:1
:/
\
-F
~Colculated
with 1s? k.dism,
Mob. RQI$O = 86:1
Observed
Breekthcc.u~
(S4.9334
0.2
aicu!q~ed-~r~k~~~ough
2nd k-distn,
1s!
k-d, atn.
(86: IJ
,~
o
0.2
0.4
0.6
Poye Volimss
FIG. 7--
0.8
$olvent
1.0
Iniected
1.2
-
1.4
(b)
---
. .-
.... .. .... .. . . . ..
..
.. .
,.
. . . .
-.
_,
. .
..-
._,
..
9,
Raimondi,
P,, Gardner, G, H. F. and Petrick,
C, B,:
a Effect
of Pore St~cture
and Molecular
Diffw ion
hkdia,
APPENDIX
lb)
CONSTANTS
Valuee of the constants
used in computing
model performance are shown in Table A-1.
and three-dimensional
geometry are not included
in the present formulation, although these should
be tractable by extension of the method.
Comparison with data of the results of calculations
made to simulate horizontal two-dimensional
dissimilarities.
striking
placerrE nts
demonstrated
Viscous fingers were calculated to form spontaneously in the presence of small, random variations
of permeability with position. Although early finger
development
was more complex than could be
practically
computed with a uniform grid, the rate
of propagation of the fingers was in close agreement with rhat observed in experiments.
Furthermore, comparison of the calculated
and experimentally observed dependence of oil recovery on
the quantity of solvent injected showed agreement
within
the reproducibility
of the experimental
results,
FUNCTIONAL
the
DATA
as the following
function
c
,
c +41-C)
x .
REFERENCES
1. ~~MI~cibI@Drive
Groeneveld,
FL:
tlThe
pembha
Miscible Displacement pilot and
Analysis of Its Performance, Trsrns,, AIhlE( 1960)
TABLE
Length
=72
Width
Thickness
F 24 in,
= 3/8
Flow Rate
.-.
Porosity ----Permeability
(avg.)
.. . .
... . . . .... . . .. . .. .
. .
. ., ..
... ....
In.
=
=
60.96 cm
0.953 cm
16.72 cc/rein
---
=- ---= 187.5x
= 190 darcies
10+
sq cm
= l@
sq cm/sOe
= 4 X l~s sq cm/sec
SO CIRIY
= 182.E8 cm
in,
=40 ft/D
-=0,34---
----
KX
KY
33s
. .. . . . . - . . .. .. .
.
A-l
. . . .
OF
ii
,,,
/,;.
. ..
-.
.-
..-
. -------
Es(;
INKx Rs
JO IrRS,tl.
. .
. .
.TABLE
A-2
Calculation
1
Mobility Ratio
Vlscoslty
86
of oil
(pDise)
Experlmsntol
86
86
86
No.
0,35
O*35
0.35
0.35
0.019
0.00408
0.00406
0.00408
0.00408
0.0037
o.d4
0,44
0.44
0,71
Emplricol Vls.
C05 ity Constant,
0,44
a
1r.t
1St
k- f3istributkm
0.05
ks
far
Po~P~ =76
.polp~ = 5,1
VI Scoslt
y of
SOlvOnt(peis*)
Data
Solvent-Oil Poirs
Accelerate
Fingers?
1St
0,025
2nd
0.05
0,05
No
No
Yes
Yes
0.0025
0.0025
0.0025
0.0025
0,52
0,43
1St
0,0s
Yes
Pe:t:;l.ep
\lm.
s?.,
0.005
(;:;
J*)
(~:9J
1.27
,,
,Eq,
Al with a=O.71
the
0
0.2
0.4
0,6
0.8
1..0
Concentration af Salvsmt, C
f,j
= ~Lj(M+l)+l
The coefficients
The ite~tion
sUMMARY OF CALCULATIONS
The calculations
are summarized
in TabIe A-2.
APPENDIX B
SOLUHON OF EQ. 20 BY ITERATION
Eq. 20 is of the generic
form
()
2q5
ai,jci-l,j,
n+l -i-b.
At
Ci,jci+l,j,
n+l
bi c..Z,I,
,
n+l+ i,jct,j-l,
n+l
where
is the iteration
number, Ci$)n+l
iterate
+ i,~ci,~i-l,
n+-l + ~i,j = 0
where
.(_,__)
_ ___
is the M
parameter,
used.
The
2+
i,l = ai,jci-l,j,n
+ ~
,...-,___ ,___
+ ci,jei+l,j,
fNXkMlfER,
19(5LI
- bt 9j ct,j,n,.
.- .
.
n + i,jci,j-l,
with
--. ....
f chosen
iterations
at
sufficed.
IFS.
General]y
three
to
five
***
3s9